• 제목/요약/키워드: PAH formation

검색결과 54건 처리시간 0.031초

Exploit the Unexploited : the Potential of the PAH 3.3mm emission feature as a star formation rate proxy and beyond

  • Kim, Ji-Hoon;Im, Myung-Shim;Lee, Hyung-Mok;Lee, Myung-Gyoon;AMUSES team, AMUSES team
    • 천문학회보
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    • 제35권2호
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    • pp.40.2-40.2
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    • 2010
  • Polycyclic aromatic hydrocarbon (PAH) features have emerged as one of the most important infrared (IR) features since these PAH features dominate mid-IR spectra of galaxies and are ubiquitous within galactic and extragalactic objects. These PAH features have the potentials to become reliable star formation rate (SFR) proxies and diagnostics of physical conditions of interstellar medium, such as ionization states of dust grains and grain sizes. While constructing an unbiased library of 44 sample galaxies selected from 5MUSES sample, AKARI mJY Unbiased Survey of Extragalactic Sources in 5MUSES (AMUSES) intends to measure and to calibrate the PAH 3.3 mm emission feature which has not been studied extensively due to its weak strength and dearth of capable instruments. Out of 20 target galaxies, we detected the 3.3mm feature from eight galaxies and measured their line strengths, line widths and line ratios with other PAH emission features. Sample galaxies whose spectral energy distributions (SEDs) are classified as starburst-type have clearly stronger 3.3mm emission features than ones with AGN-type SEDs. We also found that there is a correlation between the PAH 3.3mm luminosity and total IR luminosity within our sample galaxies, albeit a large scatter. We further discuss implications of our results.

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THE 3.3 ㎛ PAH FEATURE AS A SFR INDICATOR: PROBING THE INTERPLAY BETWEEN SF AND AGN ACTIVITIES

  • Kim, Ji Hoon;Im, M.;Kim, D.;Woo, J.H.;Park, D.;Imanishi, M.;AMUSES Team, AMUSES Team;LQSONG Team, LQSONG Team
    • 천문학논총
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    • 제27권4호
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    • pp.281-284
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    • 2012
  • We utilize AKARI's slitless spectroscopic capability to detect the $3.3{\mu}m$ polycyclic aromatic hydrocarbons (PAHs) emission and measure star formation (SF) activity for various AKARI programs. First, we obtain $2{\sim}5{\mu}m$ spectra of 20 flux-limited galaxies with mixed SED classes in order to calibrate the $3.3{\mu}m$ PAH luminosity ($L_{PAH3.3}$) as a star formation rate (SFR) indicator. We find that $L_{PAH3.3}$ correlates with $L_{IR}$ as well as with the $6.2{\mu}m$ PAH luminosity ($L_{PAH6.2}$). The correlations does not depend on SED classes. We find that ULIRGs deviate from the correlation between PAH luminosities and $L_{IR}$, while they do not for the correlation between PAH luminosities. We suggest possible effects to cause this deviation. On the other hand, how AGN activity is linked to SB activity is one of the most intriguing questions. While it is suggested that AGN luminosity of quasars correlates with starburst (SB) luminosity, it is still unclear how AGN activity is connected to SF activity based on host galaxy properties. We are measuring SFRs for the LQSONG sample consisting of reverberation mapped AGNs and PG-QSOs. This is an extension of the ASCSG program by which we investigated the connection between SB and AGN activities for Seyferts type 1s at z ~ 0.36. While we found no strong correlation between $L_{PAH3.3}$ and AGN luminosity for these Seyferts 1s, $L_{PAH3.3}$ measured from the central part of galaxies correlates with AGN luminosity, implying that SB and AGN activities are directly connected in the nuclear region.

Probing the Starburst-AGN Connection in Type I AGN based on the 3.3 micron PAH lines

  • 우종학;김지훈
    • 천문학회보
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    • 제36권2호
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    • pp.74.1-74.1
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    • 2011
  • To probe the connection between starburst and AGN activity, we investigate the relation between the 3.3 micron~PAH emission and AGN properties based on the new AKARI observations and the data collected from the literature. Using a sample of low-z Type I AGN, we measure the global 3.3 micron PAH luminosity from the AKARI slit-less spectroscopy. The 3.3 ${\backslash}$micron~PAH emissions are detected for 7 out of 26 target galaxies, but we find no strong correlation between the 3.3 ${\backslash}$micron~PAH emission and AGN luminosity, suggesting that global star formation may not be tightlyrelated with AGN activity. In contrast the to global star formation, the nuclear 3.3 micron~PAH emission luminosity, which are measured from ground-based long slit spectroscopy with a narrow slit, correlates with AGN luminosity. These results imply that starburst and AGN activity are directly connected at the nuclear region.

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층류 비예혼합 C2H4 제트 화염장에서의 PAH 생성특성 해석 (Numerical Study of PAH Formation Characteristics in Laminar Non-Premixed C2H4 Jet Flames)

  • 김태훈;김용모
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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    • pp.133-134
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    • 2014
  • The full transport equation approach for laminar non-premixed flame with detailed chemistry, soot and radiation has an advantage in accuracy and describing for emission pathway, but this approach requires the excessive computational cost especially for a higher-order hydrocarbon fuel flames. On the other hand, the standard flamelet model has an efficiency and accuracy for non-premixed flame, though this model is not suitable for simulating slow processor like soot and radiation in laminar non-premixed flame situation. To overcome this limitation, modified transient flamelet model is developed which coupled with two-equation soot model involved in soot formation and evolution mechanism such as nucleation, surface growth, oxidation and agglomeration.

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Apelin-APJ Signaling: a Potential Therapeutic Target for Pulmonary Arterial Hypertension

  • Kim, Jongmin
    • Molecules and Cells
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    • 제37권3호
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    • pp.196-201
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    • 2014
  • Pulmonary arterial hypertension (PAH) is a progressive disease characterized by the vascular remodeling of the pulmonary arterioles, including formation of plexiform and concentric lesions comprised of proliferative vascular cells. Clinically, PAH leads to increased pulmonary arterial pressure and subsequent right ventricular failure. Existing therapies have improved the outcome but mortality still remains exceedingly high. There is emerging evidence that the seven-transmembrane G-protein coupled receptor APJ and its cognate endogenous ligand apelin are important in the maintenance of pulmonary vascular homeostasis through the targeting of critical mediators, such as Kr$\ddot{u}$ppel-like factor 2 (KLF2), endothelial nitric oxide synthase (eNOS), and microRNAs (miRNAs). Disruption of this pathway plays a major part in the pathogenesis of PAH. Given its role in the maintenance of pulmonary vascular homeostasis, the apelin-APJ pathway is a potential target for PAH therapy. This review highlights the current state in the understanding of the apelin-APJ axis related to PAH and discusses the therapeutic potential of this signaling pathway as a novel paradigm of PAH therapy.

Introduction to AMUSES : AKARI survey with a window of opportunity

  • 김지훈;임명신;이형목;이명균
    • 천문학회보
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    • 제35권1호
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    • pp.76.1-76.1
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    • 2010
  • With advancement of infrared space telescopes during the past decade, infrared wavelength regime has been a focal point to study various properties of galaxies, such as stellar mass, dust contents and dust-hidden star formation with respect to evolution of galaxies. Polycyclic Aromatic Hydrocarbons (PAHs) have emerged as one of the most important features since these features dominate mid-infrared spectra of galaxies. These PAH features provide a great handle to calibrate star formation rates and diagnose ionized states of grains. However, PAH $3.3{\mu}m$ feature has not been studied as much as other PAH features since it is weaker than others and resides outside of Spitzer's capability. Still its calibration and characterization are important since it will be the only PAH feature accessible by JWST for high-z galaxies. AKARI mJy Unbiased Survey of Extragalactic Sources in 5MUSES (AMUSES) intends to take advantage of AKARI's capability of spectroscopy on 2 to 5 ${\mu}m$ to provide an unbiased library of 44 sample galaxies selected from a parent sample of 5MUSES, one of Spitzer legacy projects. For these 3.3mm flux limited sample galaxies whose redshifts range between 0 < z <1, AMUSES will calibrate PAH $3.3{\mu}m$ as a SFR while measuring ratios between PAH features and investigating Bra's potential as a SFR indicator. We present preliminary results of AMUSES.

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Assessing the Formation of Polycyclic Aromatic Hydrocarbons in Grilled Beef Steak and Beef Patty with Different Charcoals by the Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) Method with Gas Chromatography-Mass Spectrometry

  • Ali Samet Babaoglu
    • 한국축산식품학회지
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    • 제43권5호
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    • pp.826-839
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    • 2023
  • This study investigated the effects of different charcoals on the occurrence of 16 polycyclic aromatic hydrocarbons (PAHs) in grilled beef steaks and beef patties. Seven different charcoals were used as follows: from oak wood (C1), from orange wood (C2), from Valonia oak wood (C3), from Marabu wood (C4), extruded charcoal from beech wood (C5), from coconut shells (C6), and from hazelnut shells (C7). The grilling times for each charcoal type were 6 min for the beef patties and 7 min for the beef steaks, until the internal temperature reached at least 74℃. The total concentration of 16 PAHs (PAH16) in beef steaks grilled with C1 (35.75 ㎍/kg) and C7 (36.39 ㎍/kg) was higher than that of C3 (23.80 ㎍/kg) and C6 (24.48 ㎍/kg; p<0.05). The highest amounts of PAH16 (216.40 ㎍/kg) were determined in the beef patty samples grilled using C5 (p<0.05). The summation of benzo[a]anthracene, chrysene, benzo[b]fluoranthene and benzo[a]pyrene, referred to as PAH4, was not detected in any of the beef steaks, whereas it was determined in the beef patties grilled with C2 (7.72 ㎍/kg) and C5 (22.95 ㎍/kg; p<0.05). The PAH16 concentrations of the beef patty samples in each charcoal group were significantly higher compared to the beef steaks (p<0.05). To avoid the formation of high PAH levels, the use of extruded charcoal and hazelnut shell charcoal should therefore be avoided when charcoal grilling beef steaks and beef patties, and low-fat meat products should be preferred.

대향류 확산 화염에서 에틸렌-프로판 혼합 연료의 매연 생성 상승 효과 (Synergistic Effect of Ethylene-Propane Mixture on Soot Formation in Counterflow Diffusion Flame)

  • 황준영;정석호
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1997년도 제15회 KOSCO SYMPOSIUM 논문집
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    • pp.89-102
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    • 1997
  • 대향류 확산 화염의 매연 생성 특성에 대한 실험적 연구가 수행되었으며, 그 결과 에틸렌 ($C_2H_4$)-프로판($C_3H_8$) 혼합 연료의 경우 매연 생성 상승 효과 (synergistic effect)가 관측되었다. 프로판과 에틸렌의 PAH 생성 양상이 상이하게 나타났으며, 소량의 프로판을 에틸렌 확산 화염에 첨가할 경우 순수 연료에 비하여 매연 및 PAH (다중 고리 방향족 탄화수소; polycyclic aromatic hydrocarbon) 생성이 증대되었다. 단조적으로 변화하는 아세틸렌($C_2H_2$) 농도와 단열 화염 온도를 고려할 때, 이러한 결과는 HACA (H-abstraction-$C_2H_2$-addition) 반응만으로는 확산 화염에서의 매연 발생 및 성장을 설명할 수 없음을 의미한다. 수치해석과 실험 결과의 비교로부터 초기 PAH의 생성 과정을 규명하였으며 이 과정에서 C3 화학종의 재결합 반웅이 매우 중요함을 확인할 수 있었다. 또한, 이러한 C3 화학종과 C2 화학종의 상호 보완적인 역할에 의하여 에틸렌-프로판 혼합 연료에서 매연 생성이 증대됨을 밝혔다.

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압력조건에서 공기로 희석된 프로판 확산화염의 매연 생성과 산화 특성 (Soot Formation and Oxidation in Air-Diluted Propane Diffusion Flames under Elevated Pressures)

  • 배승만;남연우;이원남
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2012년도 제44회 KOSCO SYMPOSIUM 초록집
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    • pp.267-268
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    • 2012
  • Soot formation and oxidation characteristics of air-diluted propane diffusion flames have been experimentally investigated under the elevated pressure conditions. PAH concentrations showed more pressure sensitive behavior comparing to soot volume fractions. The flame/soot temperatures in soot oxidation region were obtained using the MOLLIP technique. Under the complete soot oxidation environment, the flame/soot temperature is increased with pressure. The increased temperature could accelerate the soot oxidation process and then exothermic oxidation reaction, in turn, could further raise the flame/soot temperature, which would result in the enhancement of soot oxidation process.

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THE 3.3 MICRON PAH EMISSION OF THE MID-INFRARED EXCESS GALAXIES DISCOVERED BY THE AKARI MID-INFRARED ALL-SKY SURVEY

  • Yamada, R.;Oyabu, S.;Kaneda, H.;Yamagishi, M.;Ishihara, D.;Kim, J.H.;Im, M.;Toba, Y.;Matsuhara, H.
    • 천문학논총
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    • 제27권4호
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    • pp.299-300
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    • 2012
  • We investigate the relation between star formation activity and PAH $3.3{\mu}m$ emission. Our targets are mid-infrared-excess galaxies selected from the AKARI all-sky survey point source catalog. We performed AKARI near-infrared spectroscopy for them. As a result, we obtained $2.5-5{\mu}m$spectra of 79 galaxies, and selected 35 star-forming galaxies out of them. Comparing the PAH $3.3{\mu}m$ luminosities with the infrared luminosities, we find a linear correlation between them. However, by adding the results from literatures for luminous infrared galaxies and ultra-luminous infrared galaxies that are more luminous than our sample, the ratio of the PAH to the infrared luminosity is found to decrease towards the luminous end.