• Title/Summary/Keyword: PA-12

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Preparation of EPDM/Polyamide12 Elastomers through Electron Beam Irradiation (전자선 조사를 통한 EPDM/Polyamide12 탄성체의 제조에 관한 연구)

  • Jung, Hyo Shin;Park, Jung Il;Kang, Phil-Hyun;Choi, Myung Chan;Chang, Young-Wook;Hong, Sung Chul
    • Polymer(Korea)
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    • v.37 no.5
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    • pp.571-578
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    • 2013
  • Polyamide12 (PA12) is blended with ethylene propylene diene rubber (EPDM) at various compositions in the presence of maleated EPDM (mEPDM) to afford blend materials having the characteristics of thermoplastic elastomer (TPE). The EPDM/PA12 melt-blends are further irradiated with electron-beam (e-beam) at 0~100 kGy dosage, yielding selective crosslinking between EPDM chains while retaining melt-processibility originated from PA12 phase. mEPDM acts as a compatibilizer and affords additional improvements in mechanical properties of the EPDM/PA12 blend. With 25 kGy of e-beam irradiation and mEPDM, the EPDM/PA12 blends successfully exhibit TPE behaviors with reasonable elastomeric and mechanical properties.

Characterization of Poly(ether-block-amide)s Prepared from Oligomeric Polyamide 12 via Dispersion Polymerization (분산중합에 의한 폴리아미드 12 올리고머의 제조와 그를 이용한 Poly(ether-block-amide)의 특성)

  • Kim, Doo-Hyeon;Lee, Ji-Hun;Kim, Hyung-Joong
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.513-518
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    • 2012
  • Polyamide 12 (PA12) oligomers (oPA1) were prepared by dispersion polymerization of ${\omega}$-amino carboxylic acid and dibasic acid in a dispersion medium, thermally stable hydrocarbon liquid paraffin, YK-D130 (a step polymerization). The molecular weight and various properties of other oligomeric PAs (oPA2) obtained by bulk polymerization without the medium were compared with those of oPA1s. The oPA1s showed lighter white color and narrower molecular weight distribution than oPA2s at the same molecular weight. Moreover elastomeric poly(ether-block-amide) (PEBA)s were synthesized with oPA1 and oPA2 as hard segments and poly(tetramethylene glycol) (PTMG) as a soft segment. The molecular weight distribution, and mechanical property of the PEBA originated from the both oligomeric PAs were characterized.

Evaluation of Rhizobacterial Isolates for Their Antagonistic Effects against Various Phytopathogenic Fungi (식물 근권에서 분리한 미생물의 식물병원성 진균에 대한 길항효과 검정)

  • Kim, Yun Seok;Kim, Sang woo;Lamsal, Kabir;Lee, Youn Su
    • The Korean Journal of Mycology
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    • v.44 no.1
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    • pp.36-47
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    • 2016
  • This study was conducted to evaluate five different strains of rhizobacterial isolates viz. PA1, PA2, PA4, PA5 and PA12 for biological control against Colletotrichum acutatum, C. coccodes, C. gloeosporioides, C. dematium, Botrytis cinerea, Rhizoctonia solani, Sclerotinia minor and Fusarium sp. In vitro inhibition assay was performed on three different growth mediums, potato dextrose agar (PDA), tryptic soy agar (TSA), and PDA-TSA (1:1 v/v) for the selection of potential antagonistic isolates. According to the result, isolate PA2 showed the highest inhibitory effect with 65.5% against C. coccodes on PDA and with 96.5% against S. minor on TSA. However, the same isolate showed the highest inhibition with 58.5% against C. acutatum on PDA-TSA. In addition, an in vivo experiment was performed to evaluate these bacterial isolates for biological control against fungal pathogens. Plants treated with bacteria were analyzed with phytopathogens and plants inoculated with phytopathogens were treated with isolates to determine the biological control effect against fungi. According to the result, all five isolates tested showed inhibitory effects against phytopathogens at various levels. Mode of action of these rhizobacterial isolates was evaluated with siderophore production, protease assay, chitinase assay and phosphate solubilizing assay. Bacterial isolates were identified by 16S rDNA sequencing, which showed that isolates PA1 and PA2 belong to Bacillus subtilis, whereas, PA4, PA5, and PA12 were identified as Bacilus altitudinis, Paenibacillus polymyxa and Bacillus amyloliquefaciens, respectively. Results of the current study suggest that rhizobacterial isolates can be used for the plant growth promoting rhizobacteria (PGPR) effect as well as for biological control of various phytopathogens.

Study on Impact Properties of Polyamide 12 depending on Temperature by Selective Laser Sintering Process (선택적 레이저 소결 공정 적용 폴리아미드 12의 온도별 충격 특성에 관한 연구)

  • Kim, Moosun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.10
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    • pp.136-142
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    • 2018
  • Additive manufacturing process technology, known as the 3D printing process, is expanding its utilization from simple model realization to commercialized part production based on continuous material development. Recently, research and development have been actively carried out to fabricate lightweight and high-strength parts using polymers, such as polyamide (polyamide), which is a high-strength engineering plastic material. In this study, the Izod impact characteristics were analyzed for polyamide 12 (PA12) materials. For the specimen production, selective laser sintering process technology, which has excellent mechanical properties of finished products, was applied. In addition, PA12 and glass bead reinforced PA12 materials were produced. The specimens were classified according to the production direction on the production platform, and each specimen was subjected to an Izod test at test temperatures of $-25^{\circ}C$, $25^{\circ}C$, and $60^{\circ}C$. As a result, the impact strength of PA12 and glass bead-reinforced PA12 of vertical direction specimens were 48.8% and 16.3% lower than those of the parallel specimens at a $25^{\circ}C$ test temperature and the impact strength of parallel specimens was improved by 46.5% and 20.4% at a test temperature of $60^{\circ}C$ compared to that at $-25^{\circ}C$.

Relationship between Plasminogen Activity and Plasminogen Inhibitor during the Culture of Porcine Oviduct Epithelial Cells

  • Ahn, Shin-Hye;Cheong, Hee-Tae;Yang, Boo-Keun;Kim, Dae-Young;Park, Choon-Keun
    • Reproductive and Developmental Biology
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    • v.33 no.4
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    • pp.203-209
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    • 2009
  • The present study was performed to identify changes of plasminogen activator (PA) and plasminogen activator inhibitor (PAI) in porcine oviduct epithelial cells (POECs) during the estrous cycle. POECs obtained from ovary in pre-ovulatory (Pre-Ov), early to mid-luteal stage (Early-mid L) and post-ovulatory stage (Post-Ov). For the examine of PA activity, $1{\times}10^5$ fresh cells of POECs were cultured in DMEM/Ham F-12 containing 10% FBS and 0.2% amphotericin under humidified atmosphere of 5% $CO_2$ in air and $38^{\circ}C$. The urokinase-type PA (uPA) was observed at 7 days of POECs culture. PA activity was measured with culture prolonged of 0, 3, 6, 12 and 24 h after culture of 7 days. The PA activity were high significantly (p<0.05) at 12 h of culture, but PA activity were decreased with culture periods increased. The PA activity in POECs of Post-Ov stage were higher significantly (p<0.05) than that of Early-mid L and Pre-Ov stage. When PAI-1 and PAI-2 were added during the POECs culture, the PA were observed significant low activity (p<0.05). The PA activity and protein expression were decreased by PA inhibitor. This results suggest that PAI-1 and PAI-2 have a suppressive action on change of PA activity during the estrous cycle of pigs. Specifically, this study using PA inhibitor was effect the PA activity and PAI expression in oviduct epithelial cells in pigs.

Implementation of Public Address System Using Anchor Technology

  • Seungwon Lee;Soonchul Kwon;Seunghyun Lee
    • International journal of advanced smart convergence
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    • v.12 no.3
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    • pp.1-12
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    • 2023
  • A public address (PA) system installed in a building is a system that delivers alerts, announcements, instructions, etc. in an emergency or disaster situation. As for the products used in PA systems, with the development of information and communication technology, PA products with various functions have been introduced to the market. PA systems recently launched in the market may be connected through a single network to enable efficient management and operation, or use voice recognition technology to deliver quick information in case of an emergency. In addition, a system capable of locating a user inside a building using a location-based service and guiding or responding to a safe area in the event of an emergency is being launched on the market. However, the new PA systems currently on the market add some functions to the existing PA system configuration to make system operation more convenient, but they do not change the complex PA system configuration to reduce facility costs, maintenance, and management costs. In this paper, we propose a novel PA system configuration for buildings using audio networks and control hierarchy over peer-to-peer (Anchor) technology based on audio over IP (AoIP), which simplifies the complex PA system configuration and enables convenient operation and management. As a result of the study, through the emergency signal processing algorithm, fire broadcasting was made possible according to the detection of the existence of a fire signal in the Anchor system. In addition, the control device of the PA system was replaced with software to reduce the equipment installation cost, and the PA system configuration was simplified. In the future, it is expected that the PA system using Anchor technology will become the standard for PA facilities.

Correlation between Positive·Negative Affect and Quality of Life in different Sasang Constitutions (사상체질별 긍정적, 부정적 성격특성과 삶의 질의 연관성 연구)

  • Kim, Ho-Seok;Kim, Sang-Hyuk;Lee, Si-Woo;Back, Young-Hwa;Yoo, Jong-Hyang
    • Journal of Sasang Constitutional Medicine
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    • v.26 no.1
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    • pp.75-81
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    • 2014
  • Objectives The purpose of this study was to examine the effects of positive and negative emotion on the quality of life(QoL) in each Sasang contitution, using Positive Affect and Negative Affect Schedule(PANAS) and Short Form-12 Health Survey Questionnaire(SF-12) questionnaire. Methods A total of 1,123 participants completed the Korean version of the PANAS and SF-12 questionnaire. The participants were classified into one Sasang constitution by QSCC II. The effects of emotion on the QoL were compared between the each Sasang contitution using analysis of variance(ANOVA). Results We found significant differences between constitutions in Positive Affect(PA), PA-Joy, PA-Interest and PA-Activation of PANAS. And we found significant differences between constitutions in Mental Component Summary(MCS) of SF-12. Negative correlation of less -0.4 was shown in Negative Affect(NA), NA-Afraid, NA-Upset of PANAS and MCS of SF-12. Conclusions The Soyangin has significantly higher score than Soeumin in PA, PA-Joy, PA-Interest and PA-Activation of PANAS as previous studies. This study also shows the correlation between negative emotion and decline in the quality of mental status.

A Study on the Compatibility of Polycarbonate/Polyamide 6 Blends (Polycarbonate/Polyamide 6 블랜드의 상용성에 관한 연구)

  • Park, Tae-Wook;Lee, Chi-Giu;Haw, Jung-Rim
    • Applied Chemistry for Engineering
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    • v.4 no.3
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    • pp.601-615
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    • 1993
  • A series of polycarbonate(PC)/polyamide 6(PA6) blends were prepared by three different blending methods to investigate their compatibility. From the DSC results, all of these blends have two Tg's in their own Tg regions, and there was no significant depression of the melting point and the crystallization temperature of PA6. With respect to the microstructure of the blends by SEM, the phase separation occurred at very low blend compositions, PC/PA6=95/5 and 5/95, already. In addition, a method is proposed to determine the Flory-Huggins polymer-polymer interaction parameter(${\chi}_{12}$) in polymer blend systems by using the experimentally determined Tg's. The values of ${\chi}_{12}$ obtained were 0.0381, 0.0411, 0.0418, for solution casting, solution precipitation, and extrusion blending methods, respectively. These values were higher than the critical value of ${\chi}_{12}$,($({\chi}_{12})_c$, 0.0271). Therefore it was concluded that the PC/PA6 blend system have little compatibility.

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A Study in the PA12 Tube Spring-back (PA120 튜브의 스프링 백에 관한 연구)

  • 김대식;문찬용;김상우;최형태;정영득;김영수
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.825-828
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    • 1997
  • The market share of plastic fuel tube in automobile part is now growing rapidly. Especially fuel tube makers have had their efforts to develop tube module not only with dimensional accuracy, spring back and cost competitiveness. In this study, we used steam bending process for heat relaxation on PA12 plastic fuel tube's 128 types experimental bending conditions. we present the results of this process system in term of dimensional accuracy, and spring back.

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