• Title/Summary/Keyword: P-base

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Degradation analysis of AlGaAs/GaAs HBTs and improvement of reliability by using InGaP ledge emitter (AlGaAs/GaAs HBT의 열화분석과 InGaP ledge 에미터에 의한 신뢰도 개선)

  • 최번재;김득영;송정근
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.7
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    • pp.88-93
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    • 1998
  • For the self-aligned AlGaAs/GaAs HBTs, the surface states at the interface between the extrinsic base surface and the passivation nitride is a major cause of degradation of dc characteristics. In this paper the degradation mechanisms of self-aligned AlGaAs/GaAs HBT were analyzed, and GaAs HBTs, which employed an InGaP ledge emitter structure formed by the nonself-aligned process to cover the surface of the extrinsic base and reduce the surface states, produced high reliability. Accoridng to the acceleration lifetime test, the nonself-aligned InGaP/GaAs HBTs produced very reliable dc characteristics comparing with the self-aligned AlGaAs/GaAs HBTs. The activation energy was 1.97eV and MTTF $4.8{\times}10^{8}$ hrs at $140^{\circ}C$ which satisfied the MIL standard.

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Synthesis, Spectral Characterization, Electron Microscopic Study and Influence on the Thermal Stability of Phosphorus-containing Dendrimer with a 4,4'-Sulphonyldiphenol at the Core

  • Dadapeer, Echchukattula;Rasheed, Syed;Raju, Chamarthi Naga
    • Bulletin of the Korean Chemical Society
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    • v.32 no.2
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    • pp.498-502
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    • 2011
  • The divergent synthesis of novel phosphorus-containing dendrimer with 4,4'-sulphonyldiphenol at the core has been accomplished involving simple condensation reactions using $P(O)Cl_3$, $P(S)Cl_3$, 3-amino-phenol, 3-hydroxy-benzaldehyde, and 2-butyn 1, 4-diol. The final compound was a Schiff's base macromolecule possessing 4 imine bonds, 8 acetylenic bonds and 8 OH groups at the periphery. The structures of intermediate compounds were confirmed by IR, NMR ($^1H$, $^{13}C$ and $^{31}P$), LC-Mass and C, H, N analysis. The structure of the final dendrimer (5) was confirmed by IR, NMR ($^1H$, $^{13}C$ and $^{31}P$), MALDI-TOF-MS, and C, H, N analysis. The surface morphological characteristics of the final dendrimer were understood by Scanning Electronic Microscopic study (SEM). The thermal stability of the final dendrimer was studied by TGA/DTA analysis.

Field-domain dynamics and current self-oscillations in negative-effective-mass terahertz oscillators

  • Cao, J.C.;Qi, M.
    • Journal of the Korean Vacuum Society
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    • v.12 no.S1
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    • pp.36-39
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    • 2003
  • Field-domain dynamics and current self-oscillations are theoretically studied in quantum-well (QW) negative-effective-mass (NEM) $p^{+}pp^{+}$ diodes when the electric field is applied along the direction of the well. The origin of current self-oscillations is the formation and traveling of electric-field domains in the p-base. We have accurately considered the scattering contributions from carrier-impurity, carrier-acoustic phonon, and carrier-optic phonon. It's indicated that, both the applied bias and the doping concentration largely influence the current patterns and self-oscillating frequencies, which lie in the THz range for the NEM $p^{+}pp^{+}$ diode with a submicrometer p-base. The complicated field-domain dynamics is presented with the applied bias as the controlling parameter.

Partially Folded States of Mutant Ubiquitin in Mild Denaturing Conditions

  • Park, Soon-Ho
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1567-1572
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    • 2009
  • Conformational change of ubiquitin variant with valine to alanine mutation at sequence position 26 was studied by varying solvent pH. Fluorescence emission spectra indicated that this variant ubiquitin has some residual structures in acidic and basic solution as compared to denaturant-induced unfolded state. Far-UV circular dichroic spectra indicated that the base-denatured state had more secondary structure than the acid-denatured state. Near-UV circular dichroic spectra indicated that the aromatic side-chains were in the relatively more rigid environment in the base-denatured state than those in the acid-denatured state. Although it appears that the more tertiary structure present in the base-denatured state, refolding reactions measured by stopped-flow fluorescence device suggest that both the acid- and base-denatured states occur before the major folding transition state. The acid- and base-denatured states are considered to reflect the early event of protein folding process.

The Crystal and Molecular Structure of Chloramphenicol Base

  • Shin, Whan-Chul;Pyo, Myung_Ho
    • Bulletin of the Korean Chemical Society
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    • v.5 no.4
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    • pp.158-162
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    • 1984
  • The crystal structure of chloramphenicol base, $C_9H_{l2}N_2O_4$, the deacylated base of antibiotic chloramphenicol, has been determined by X-ray diffraction techniques using diffractometer data obtained by the ${\omega}-2{\theta}$ scan technique with CuK${\alpha}$ radiation from a crystal with space group symmetry $P2_12_12_1$ and unit cell parameters a = 22.322(6), b = 7.535(6), c = 5.781(5) ${\AA}$. The structure was solved by direct methods and refined by full-matrix least-squares to a final R = 0.051 for the 573 observed reflections. The overall conformation of the base is quite different from those of the chloramphenicol congeners which are similar despite the presence of many rotatable single bonds. The propane chain in the base is bent with respect to the phenyl ring, while it is extended in the chloramphenicol congeners. There is no intramolecular hydrogen bond between the hydroxyl groups of the propanediol moiety. All of the molecules in the crystal lattice are connected by a three-dimensional hydrogen bonding network.

Microsatellite-based Genetic Diversity and Evolutionary Relationships of Six Dog Breeds

  • Ye, J.-H.;Ren, D.-R.;Xie, A.-F.;Wu, X.-P.;Xu, L.;Fu, P.-F.;Zhao, H.-A.;Yang, Qianyong
    • Asian-Australasian Journal of Animal Sciences
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    • v.22 no.8
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    • pp.1102-1106
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    • 2009
  • The Tibetan Mastiff is one of the most archaic, ferocious and the largest dogs in the world. The Kunming dog is the chief working-dog breed in China. In this study, ten microsatellite loci were used to assess the genetic diversity and evolutionary relationships in six dog breeds, including Tibetan Mastiff, Kunming dog, Belgian Malinois, Labrador Retriever, English Springer Spaniel, and German Shepherd. The highest genetic diversity was exhibited by the Tibetan Mastiff, indicating useful protection and little inbreeding in the modern Tibetan Mastiff. Higher genetic diversity was observed in European breeds, supporting the hypotheses that breeders outcross their pure breed dogs occasionally to avoid deleterious effects in Europe. Evolutionary relationships showed that English Springer Spaniel and Labrador Retriever were clustered together, then with the Tibetan Mastiff, consistent with previous cluster results. German Shepherd and Kunming dog were grouped together, coinciding with the breeding history of Kunming dog. It is the first time that Tibetan Mastiff and Kunming dog have been analyzed with microsatellites.

The Effect of the Base of Support on Anticipatory Postural Adjustment and Postural Stability

  • Nam, Hye-Sun;Kim, Joong-Hwi;Lim, Yoo-Jung
    • The Journal of Korean Physical Therapy
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    • v.29 no.3
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    • pp.135-141
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    • 2017
  • Purpose: This study was to identify the anticipatory postural adjustment (APA) mechanism which is represented by the onset time of trunk muscles and the displacement of the center of pressure (COP) according to the different base of support (BOS) during upper extremity movement. Methods: Thirty healthy subjects (14 males, 16 females) participated in this study. The movement was performed for 10 trials during each of various BOS (shoulder - width double leg stance, narrow base double leg stance, tandem stance, non-dominant single leg stance) at the 1.2 Hz frequency. Electromyography was used to measure muscle onset time and biorescue was used to measure characteristics of the displacement of COP. Surface bipolar electrodes were applied over the right deltoid anterior, right latissimus dorsi, both rectus abdominis, both internal oblique and both erector spinae. The data were analyzed by repeated one-way ANOVA and Duncan's post hoc test. Results: The study has revealed following. There were significant differences with muscle onset time in each BOS (p<0.01). There were significant differences in characteristics of the COP in each BOS (p<0.01). Conclusion: The study found that the more narrowed the basis requires the more rapid anticipatory postural control in contralateral postural muscle when the upper extremity movement is performed.

Syntheses and Properties of Polydentate Schiff Base and Their Cu(Ⅱ) Complexes (여러자리 시프 염기 리간드와 구리(Ⅱ) 착물의 합성과 성질)

  • Kim, Seon Deok;Sin, Yun Yeol;Jang, Gi Ho
    • Journal of the Korean Chemical Society
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    • v.38 no.4
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    • pp.319-327
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    • 1994
  • The novel Schiff base hexadentate ligand, bis-(salicylaldehyde)-triethylentetramine (BSTT) and heptadentate ligand, bis-(salicylaldehyde)-tetraethylenpentamine(BSTP) were synthesized by the reaction of salicylaldehydes with triethylenetetramine and tetraethylenepentamine, having four and five nitrogen atoms, respectively. These liquid Schiff base ligands were become in form of the pale-yellow crystals in the specific pH 4.0 by adding acetic acid concentrated hydrochloric acid. The Cu(Ⅱ) complexes of the Schiff bases were synthesized by reaction of the Schiff base with Cu(Ⅱ) ion and their possible structures were proposed by several analytical data, and physical and chemical properties.

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Optimization of Base Plates and Contact Switches in Trunk Latches (트렁크 래치의 베이스 플레이트와 접촉스위치의 최적화)

  • Kim, Kyungnam;Noh, Yoojeong;Kim, Donghoon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.3
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    • pp.97-104
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    • 2014
  • Automobile trunk latches enable trunks to be opened and closed by a latch mechanism, which can be selectively positioned between a locked condition and an open condition. To maintain structural and electronic performance of the trunk latch, the latch needs to endure impact load that occurs in its open and close motion, and a dynamic mechanism needs to be electronically controled by a contact switch connected with a small DC motor. A base plate, which is the most important component relating to the structural safety, commonly uses a high stiffness material SAPH440-P with high manufacturing cost. In this paper, through structural analysis and optimization, production cost is significantly reduced by replacing SAPH440-P used in some region of the base plate with engineering plastic PBT GF 20%. The optimized contact switch reduces difference between distributed pressures of its two legs, which leads to improve the electronic performance of the trunk latch.

Effect of Litter on the Soil Condition(II) Varieties of Soil Fertility due to the Decomposition of Litters on the Soil. (토양조건에 미치는 낙엽의 영향(제2보) 낙엽부패에 의한 토양성분 변화)

  • 차종환
    • Journal of Plant Biology
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    • v.12 no.1
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    • pp.15-21
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    • 1969
  • In this experiment, the litters of each five species of neadle-leaf trees and broad-leaf trees were laid on each pot soils, which had same soil conditions, is the green house and the sil fertility of each pots were determined after four years. Chemical properties among each pot soils under litters of needle-laef trees showed remarkable different values in the pH, base exchange capacity, total exchangeable base, base saturation, organic matter, available phosphorus, exchangeable potassium and calcium, and that of broad-leaf trees showed respectively significant difference. The content of chemical components, such as total exchangeable base, organic matter, total nitrogen, available phosphorus and exchanbeable potassium, between pot soils under litters of the needle-leaf trees and the broad-leaf trees were significant at the 0.01 and 0.05 levels of the statistical probability. The fertility of soil under the influence of decayed fallen leaves is the highest value in the posts of broad-leaves and next to the pots of needle-leaves and the control pots the lowest. The pH value of the soil with various kinds of fallen leaves showed little difference among themselves, but it especially approached in the broad leaves plots gradually to neutral and hte non-treated plot showed acidity. Lespedeza bicolar and Castanea crenata are supposed to contribute to the fertility of soil. Pinus rigida showed excellent exchanged properties of soi. The leaves of Robinia pseudoacacia and Pinus koraiensis did not contribute much to the promotion of fertility of soil.

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