• Title/Summary/Keyword: P-V diagram

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Study on Gaseous Nitrocarburizing Treatment (가스침질탄화법(浸窒炭化法)에 관한 연구(硏究))

  • Lee, S.Y.;Bell, T.
    • Journal of the Korean Society for Heat Treatment
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    • v.1 no.1
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    • pp.8-12
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    • 1988
  • This study has been carried out to evaluate gaseous nitrocarburizing treatment undertaken for pure iron at $570^{\circ}C$ in an atmosphere containing 50% endothermic gas, generated from natural gas, and 50% ammonia. The results obtained from the experiment are as follows ; 1) The microstructure of gaseous nitrocarburized pure iron consists of the compound layer on the surface and the diffusion zone beneath it. The compound layer progresses uniformly into ferrite with a thickness of $20{\mu}$ obtained after treating for 3 hours. 2) Chemical analysis has shown that the compound layer has a C/N ratio of 0.19 and that the average combined interstitial content of the compound layer is about 30 atomic percent, which is close to the lower limit of the ${\varepsilon}$-carbonitride phase field in Fe-C-N phase diagram. 3) X-ray diffraction analysis has revealed that the compound layer consists mainly of the c.p.h. phase, ${\varepsilon}-Fe_3$(C.N) and a small amount of $Fe_4N$ and traces of ferrite are also present in the compound layer. 4) The microhardness of the compound layer is about 600 V.H.N and shows a relatively sharp fall-off at the compound layer/diffusion zome interface. 5) The average actual degree of ammonia dissociation is calculated to be 27% for a gaseous nitrocarburizing treatment carried out at $570^{\circ}C$.

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Gas Pulsation Analysis in a T-Shaped Suction Passage of a CO2 Twin Rotary Compressor (CO2 트윈 로타리 압축기의 흡입관로에서의 가스맥동 해석)

  • Kim, Woo-Young;Ahn, Jong-Min;Kim, Hyun-Jin;Cho, Sung-Oug
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.8
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    • pp.549-555
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    • 2011
  • For a $CO_2$ one-stage twin rotary compressor, a T-shaped suction port was used to effectively supply the suction gas stream into two individual suction chambers of the twin cylinders. Suction gas pulsations were observed in the pressure sensor signals and these were simulated by using the acoustic modeling of Helmholz resonators in parallel. The module of acoustic modeling was combined to a computer simulation program for the compressor performance. Validation of the simulation program has been carried out for a bench model compressor in a compressor calorimeter. Cooling capacity and the compressor input power were reasonably well compared between the simulation and the calorimeter test. Particularly, good agreement on P-V diagram between the simulation and the test was obtained.

TiO2 Nano-doping Effect on Flux Pinning and Critical Current Density in an MgB2 Superconductor

  • Kang, J.H.;Park, J.S.;Lee, Y.P.;Prokhorov, V.G.
    • Journal of Magnetics
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    • v.16 no.1
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    • pp.15-18
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    • 2011
  • We have studied the $TiO_2$ doping effects on the flux pinning behavior of an $MgB_2$ superconductor synthesized by the in-situ solid-state reaction. From the field-cooled and zero-field-cooled temperature dependences of magnetization, the reversible-irreversible transition of $TiO_2$-doped $MgB_2$ was determined in the H-T diagram (the temperature dependence of upper critical magnetic field and irreversibility line). For comparison, the similar measurements are also obtained from SiC-doped $MgB_2$. The critical current density was estimated from the width of hysteresis loops in the framework of Bean's model at different temperatures. The obtained results manifest that nano-scale $TiO_2$ inclusions served as effective pinning centers and lead to the enhanced upper critical field and critical current density. It was concluded that the grain boundary pinning mechanism was realized in a $TiO_2$-doped $MgB_2$ superconductor.

A Study on the Additives of mixed Gas charged in Thermostatic Bulb for Expansion Valve (팽창밸브 개폐용 감온통 혼합가스의 첨가제 연구)

  • Kim, Si-Young;Ju, Chang-Sik;Koo, Su-Jin
    • Journal of Power System Engineering
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    • v.18 no.6
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    • pp.126-132
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    • 2014
  • The P-T characteristics of mixed refrigerant in thermostatic expansion valve sensing bulb were studied using R-134a and R-410A refrigerant. The characteristics of mixed refrigerant were investigated according to pressure variation and the variation of composition ratio of R-134A and R-410A in the temperature range of $-15^{\circ}C{\sim}15^{\circ}C$. The Thermodynamic characteristic values of the mixed refrigerants were identified using the characteristic value analysis program of mixed refrigerant(Refrop v9.0, NIST). The P-T characteristics in the case of the mixing ratio of 90:10 for R-410A and R-134A were the same result as R-22. And the physical properties showed similar results with R-22. The Maximum operating pressure(MOP) of mixed refrigerant showed a tendency to decrease with decreasing the mixing ratio of additive gases($N_2$ or He) gases. The characteristics in the case of the mixing ratio of 80:1 for mixed refrigerant and additive gases were the similar result as Reference refrigerant.(R-22 MOP, Sporlan company) In addition $N_2$ and He, both showed the same results. It was able to confirm that a MOP on the thermostatic expansion valve sensing bulb can be maintained by adjusting the mixing ratio of mixed refrigerant gases and additive gases.

Calcitonin Transport through Skin Using Iontophoresis

  • Kim, Kyung-Min;Oh, Seaung-Youl
    • Journal of Pharmaceutical Investigation
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    • v.41 no.1
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    • pp.9-17
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    • 2011
  • The objective of this work is to study transdermal delivery of calcitonin using iontophoresis and to evaluate various factors which affect the transdermal transport. We have studied the effect of polarity, current density, drug concentration, penetration enhancers (isopropyl myristate [IPM] and ethanol) and laser treatment on transdermal flux and the results were compared. We also investigated the iontophoretic flux from microemulsions containing calcitonin together with oleic acid (OA) or IPM. In vitro flux study was performed at $33^{\circ}C$, using side-by-side diffusion cell and full thickness hairless mouse skin. Anodal delivery at pH 3.0 was much larger than cathodal and passive delivery, due to the positive charge of calcitonin. Cumulative amount delivered (CUM) by cathodal or passive delivery was close to zero for 10 hours. The pretreatment of skin by neat IPM markedly increased the CUM anodically. CUM increased as the current density, drug concentration or the duration of IPM treatment increased. Microemulsion containing IPM or oleic acid was prepared and the phase diagram was constructed. CUM also increased when IPM was incorporated into a microemulsion. OA microemulsion showed similar enhancing effect to IPM microemulsion. The delivery of calcitonin from 70% (v/v) ethanol aqueous solution showed a large increase in flux. Laser treatment of skin before flux experiment exhibited about 2 fold increase in total calcitonin amount transported for 12 hours, when compared to that delivered by IPM microemulsion. Based on these results, we have evaluated the possibility of delivering enough amount of calcitonin to reach the therapeutic level. The data suggest that it is highly possible to deliver clinically effective amount of calcitonin using iontophoresis patch with small area (<10 $cm^2$).

Petrology of Puu Oo lavas from the Big Island, Hawaii (하와이, 빅 아일랜드의 푸우오오 용암에 대한 암석학적 연구)

  • Kwon, Suk-Bom;Jang, Yun-Deuk;Park, Byeong-Jun;Kim, Yeong-Kyoo;Kim, Jung-Jin
    • The Journal of the Petrological Society of Korea
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    • v.16 no.4
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    • pp.217-232
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    • 2007
  • The Puu Oo eruption in Hawaii since 1983 is one of the largest eruptions on Hawaii's volcanic history with prominent compositional variation ($5.6{\sim}10.1wt.%$ in MgO content). Although intense researches of Hawaiian eruption have been conducted for recent years, there is no up-to-date study on Puu Oo lavas that is erupting hot lavas today. in oder to obtain basic information on the geological characteristics of the eruption including any noticeable change in its petrological trend and magma dynamics, we applied several geological approaches such as field survey, systematic sampling, petrography, mineralogy, and geochemistry. Clinopyroxene and Plagioclase phenocrysts are rarely observed on the thin section, however Olivine crysts are much more obvious in the study area. It indicates that Puu Oo is early stage of magma differentiation. Variation diagram of whole rock composition shows that the elements such as $TiO_2,\;Al_2O_3,\;SiO_2$ and $Na_2O$ decrease with increasing MgO. In the trace element Sr, Y Zr and V versus $K_2O$, P18, P19 samples are plotted in primitive area. Variations of the Ni contents during $2003{\sim}2006$ may suggest a sudden change in magma composition probably caused by new magma injection.

Analysis of Inverter Circuit with External Electrode Fluorescent Lamps for LCD Backlight (LCD 백라이트용 외부전극 형광램프의 인버터 회로 해석)

  • Jeong, Jong-Mun;Shin, Myeong-Ju;Lee, Mi-Ran;Kim, Ga-Eul;Kim, Jung-Hyun;Kim, Sang-Jin;Lee, Min-Kyu;Kang, Mi-Jo;Shin, Sang-Cho;Ahn, Sang-Hyun;Gill, Do-Hyun;Yoo, Dong-Gun;Koo, Je-Huan
    • Journal of the Korean Vacuum Society
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    • v.15 no.6
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    • pp.587-593
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    • 2006
  • The circuit of the EEFL system and the inverter has been analyzed into the resistance RL, the capacitance C of the EEFL-backlight system, and the inductance of transformer in the inverter. The lamp resistance and capacitance are deter-mined from the phase difference is between the lamp current and voltage and from the Q-V diagram, respectively. The single Lamp of EEFL for 32' LCD-BLU has the resistance of $66\;k\Omega$ and the capacitance of 21.61 pF. The resistance, which is connected by parallel in the 20-EEFLS BLU, is $3.3\;k\Omega$ and the capacitance is 402.1 pF. The matching frequency in the operation of lamp system is noted as $\omega_M=1/\sqrt{L_2C(1-k^2)}$, where $L_2$ is the inductance of secondary coil and k is the coupling coefficient between primary and secondary coil. The lamp current and voltage has maximum value at the matching frequency in the LCD BLU system. The results of analytic solutions are in good agreement with the experimental results.

The Characteristics of Shallow Groundwater in Petroleum Contaminated Site and the Assessment of Efficiency of Biopile by Off-gas Analysis (유류오염지역의 지하수 수질특성과 토양가스 분석을 통한 바이오파일의 효율평가)

  • Cho, Chang-Hwan;Sung, Ki-June
    • Journal of Soil and Groundwater Environment
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    • v.18 no.2
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    • pp.36-44
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    • 2013
  • The objectives of this study were to identify the characteristics of shallow groundwater from the oil-contaminated site for a long period and to evaluate the applicability of biopile technology to treat the soil excavated from it. The eight monitoring wells were installed in the contaminated site and pH, Electrical Conductivity (EC), Dissolved Oxygen (DO), Oxidation Reduction Potential (ORP), Temperature and the concentrations of major ions and pollutants were measured. The VOCs in soil gas were monitored during biopile operation and TPH concentration was analyzed at the termination of the experiment. The pH was 6.62 considered subacid and EC was 886.19 ${\mu}S/cm$. DO was measured to be 2.06 mg/L showing the similar characteristic of deep groundwater. ORP was 119.02 mV indicating oxidation state. The temperature of groundwater was measured to be $16.97^{\circ}C$. The piper diagram showed that groundwater was classified as Ca-$HCO_3$ type considered deep groundwater. The ground water concentration for TPH, Benzene, Toluene, Xylene of the first round was slightly higher than that of the second round. The concentration of carbon dioxide of soil gas was increased to 1.3% and the concentration of VOCs was completely eliminated after the 40 days. The TPH concentration showed 98% remediation efficiency after the 90 days biopile operation.

Analysis of genetic characteristics and development of substrate for cultivation in brown strains of Flammulina velutipes (갈색팽이버섯의 유전적 특성검정 및 배지재료 개발)

  • Choi, Jae-Sun;Noh, Jae-Goan;Jang, Who-Bong;Choi, Seong-Yeol;Min, Kyoung-Beom;Kong, Won-Sik
    • Journal of Mushroom
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    • v.5 no.1
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    • pp.13-20
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    • 2007
  • Analysis of genetic characteristics of Flammulina velutipes showed that strains have a range of 85% in genetic distribution diagram. According to this result, we divided these strains into five groups. In experiment of determinating the optimum media and condition in cultivating F. velutipes, we found the optimum temperature and pH range for hypha growth were $25^{\circ}C$ and 6.0 to 7.0, respectively. in addition, the best media for growth of that in plate was MCM (Mushroom Complete Media) which have a growth length from 68 to 83 mm. In vivo test, we observed that fast growth and good density of hyphae in mixture media of douglas fir sawdust, cotton seed meal and beet pulp (6:2:2 V/V). Also when we cultivated F. velutipes in this media, we harvested high yield of fruiting body.

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Geochemical Characteristics and Nitrates Contamination of Shallow Groundwater in the Ogcheon Area (옥천지역 천부지하수의 지구화학적 특성 및 질산염 오염 특성)

  • Lee, In-Gyeong;Choi, Sang-Hoon
    • Economic and Environmental Geology
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    • v.43 no.1
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    • pp.43-52
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    • 2010
  • The geochemical and nitrogen isotopic analyses for shallow groundwater of Ogcheon area were carried out to characterize the geochemical characteristics of the groundwater and to identify the source of nitrate. Groundwater shows a neutral pH to weakly alkalic condition with pH values ranging from 6.9 to 8.4. The average of EC, Eh and DO is $344.2\;{\mu}s/cm$, 195 mV, 4 mg/L, respectively. According to piper diagram, chemical composition of groundwater is dominantly characterized by Ca-$HCO_3$ type. On the other hand, groundwater type in the study area include Ca-Cl+$NO_3$ type that were highly influenced by agricultural activities. $NO_3$-N concentration of the collected samples(n=45) range from 12.4 to 34.2 mg/l. These data show that the $NO_3$-N concentration exceeds Korea Drinking Water Standard (10 mg/l). The $\delta^{15}N-NO_3$ values range from $2.7^{\circ}/_{\circ\circ}$ to $18.8^{\circ}/_{\circ\circ}$. The enrichments of heavy isotope in the groundwater indicate that major origin of nitrate pollution were associated with animal and human waste. Also the denitrification may have partly contributed as one of the sources of nitrogen.