• Title/Summary/Keyword: P(VDF)

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Fabrication of Triboelectric Nanogenerator based on a Composite of P(VDF-TrFE)/Graphene Flower (P(VDF-TrFE)/그래핀플라워 복합소재 기반 마찰전기 나노발전기 제작)

  • Muhammad Saqib;Woo Young Kim
    • Journal of the Korean Applied Science and Technology
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    • v.40 no.4
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    • pp.913-923
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    • 2023
  • In this study, a triboelectric nanogenerator was fabricated using the composite of teflon-based polymer and graphene flower, which are stable in air and have relatively high electronegativity. The composite was used to fabricate an electronegative layer of a nanogenerator using a spin-coating method. For the electropositive layer, a zinc oxide film was prepared using a sol-gel method. The fabricated triboelectric nanogenerator produced a maximum power of about 44 ㎼. In conclusion, since all the active layers of the triboelectric nanogenerator was made by the solution process, it is scalable to a large area.

The Efficiency Characteristics of the Ferroelectric Polymer Added Organic Solar-cells (강유전 고분자를 첨가한 유기태양전지의 효율 특성)

  • Park, Ja young;Jung, Chi Sup
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.9
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    • pp.589-594
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    • 2016
  • P3HT:PCBM bulk heterojunction solar cells added with ferroelectric polymer were fabricated and characterized. By incorporating P3HT:PCBM solar cell with P(VDF-TrFE) ferroelectric additive, the power conversion efficiency was increased up to nearly 50%. Photoacoustic analysis on this phenomena was carried out for the first time. Through this study, we find that the ferroelectricity of the polymer additive plays the key role in the enhancement of the power conversion efficiency of the organic solar cell by suppressing the non-radiative recombination of charge transfer exciton more effectively.

Synthesis of Poly(vinylidene fluoride-co-hexafluoropropylene) (비닐리덴 플루오라이드와 헥사플루오르프로필렌 공중합체의 합성)

  • Lee, Sang Goo;Ha, Jong-Wook;Park, In Jun;Lee, Soo-Bok;Lee, Jong Dae
    • Polymer(Korea)
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    • v.37 no.1
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    • pp.74-79
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    • 2013
  • Polyvinylidene fluoride (PVDF) and its copolymer with hexafluoropropylene (HFP) were successfully prepared from free radical solution polymerizations using diisopropyl peroxidicarbonate (DIPPDC) in the presence of 1,1,2-trichlorotrifluoroethane (R-113). The reactivity ratios of VDF and HFP were estimated as$r_{VDF}=2.06{\pm}0.03$ and $r_{HFP}{\approx}0$. This result indicates that HFP cannot undergo self propagation. The weight-average molecular weight and molecular weight distribution of copolymers were found to decrease with increasing HFP content. The melting temperature of copolymers linearly decreased with the increase of HFP content because of the introduction of HFP. Moreover, no melting peak was observed for the copolymers with high HFP content. The glass transition temperature of copolymers gradually increased with the increase of HFP content due to the restricted flexibility of the polymer chains.

The Relaxation of Nonlinear Optical Properties in a Poled Polymer (극화된 고분자에서 비선형 광학특성의 완화)

  • Jung, Chi-Sup
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.6
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    • pp.491-496
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    • 2010
  • The relaxation behavior of aligned electric dipoles in a mixed polymer of P2ANS with P(VDF-TrFE) is studied with optical second harmonic generation (SHG). In this work, a macroscopic noncentrosymmetry of the spin coated film was achieved by an electrical poling. The relaxation of induced polar order of nonlinear optic(NLO) chromophores after poling leads to an insufficient long-term stability of NLO properties. In this work, we develop a new technique to suppress such kind of dipole relaxation in a poled polymer. We found that the poled dipoles in a NLO polymer were effectively immobilized by the internal electric field created by a thermally annealed ferroelectric polymer. The long-term stability in a mixed system of NLO polymer/ferroelectric polymer was successively accomplished by a series of thermal treatments applied to the mixed polymer system at a temperature of $140^{\circ}C$ for at least 1hour after poling.

Characteristics of a $PbTiO_{3}$ Transmitting/P(VDF-TrFE) Receiving Ultrasonic Transducer in VHF Band

  • Ha Kang-Lyeol;Kim Moo-Joon;Kim Jung-Ho;Kim Jung-Soon
    • Proceedings of the Acoustical Society of Korea Conference
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    • spring
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    • pp.311-314
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    • 2004
  • A new type of high frequency wideband ultrasonic transducer with a separation between a transmitter and a receiver was proposed and its characteristics were simulated using the PSpice model. The piezoelectric ceramic $PbTiO_{3}$ as a transmitter and the piezoelectric copolymer P(VDF-TrFE) as a receiver were used for high sensitivity and wide bandwidth, respectively. The characteristics of a center frequency approximately 40MHz focusing transducer fabricated in this study showed very wide bandwidth which could give an axial spatial resolution better than 30um in the B-mode image for biological tissues.

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Fabrication and Characteristics of Pyroelectric IR Sensor Using $1.6{\mu}m$ P(VDF/TrFE) thin film

  • Kwon, Sung-Yeol
    • Journal of Sensor Science and Technology
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    • v.10 no.2
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    • pp.86-90
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    • 2001
  • A pyroelectric senior using P(VDF/TrFE) film for sensing materials has been fabricated and evaluated with other commercial pyroelectric sensors that use ceramic materials for sensing. The device was mounted in a TO-5 housing to detect infrared light of $5.5{\sim}14\;{\mu}m$ wavelength. The NEP (noise equivalent power) and specific detectivity $D^*$ of the device were $2.13{\times}10^{-8}\;W$ and $9.37{\times}10^6\;cm/w$ respectively under emission energy of $13\;{\mu}W/cm^2$ respectively. These result shows a better characteristics than other commercial pyroelectric sensors NEP $8.08{\times}10^{-7}\;W$ and $D^*$ $2.47{\times}10^5\;cm/w$.

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