• Title/Summary/Keyword: Oxygen permeability

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Helium/Oxygen Atmospheric Pressure Plasma Treatment on Poly(ethylene terephthalate) and Poly(trimethylene terephthalate) Knitted Fabrics: Comparison of Low-stress Mechanical/Surface Chemical Properties

  • Hwang Yoon Joong;McCord Marian G.;Kang Bok Choon
    • Fibers and Polymers
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    • v.6 no.2
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    • pp.113-120
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    • 2005
  • Helium-oxygen plasma treatments were conducted to modify poly(trimethylene terephthalate) (PIT) and poly(ethylene terephthalate) (PET) warp knitted fabrics under atmospheric pressure. Lubricant and contamination removals by plasma etching effect were examined by weight loss $(\%)$ measurements and scanning electron microscopy (SEM) analysis. Surface oxidation by plasma treatments was revealed by x-ray photoelectron spectroscopy (XPS) analyses, resulting in formation of hydrophilic groups and moisture regain $(\%)$ enhancement. Low-stress mechanical properties (evaluated by Kawabata evaluation system) and bulk properties (air permeability and bust strength) were enhanced by plasma treatment. Increasing interfiber and interyarn frictions might play important roles in enhancing surface property changes by plasma etching effect, and then changing low-stress mechanical properties and bulk properties for both fabrics.

Mitochondrial DNA Mutation and Oxidative Stress

  • Kim, Tae-Ho;Kim, Hans-H.;Joo, Hyun
    • Interdisciplinary Bio Central
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    • v.3 no.4
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    • pp.16.1-16.8
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    • 2011
  • Defects in mitochondrial DNA (mtDNA) cause many human diseases and are critical factors that contribute to aging. The mechanisms of maternally-inherited mtDNA mutations are well studied. However, the role of acquired mutations during the aging process is still poorly understood. The most plausible mechanism is that increased reactive oxygen species (ROS) may affect the opening of mitochondrial voltage dependent anion channel (VDAC) and thus results in damage to mtDNA. This review focuses on recent trends in mtDNA research and the mutations that appear to be associated with increased ROS.

Effect of $MoO_3$ addition on the permeability of Mn-Zn ferrites ($MoO_3$ 첨가가 Mn-Zn Ferrites의 투자율에 미치는 영향)

  • 장정수;한영호;신명승
    • Journal of the Korean Magnetics Society
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    • v.11 no.1
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    • pp.26-31
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    • 2001
  • The effect of MoO$_3$ addition on the permeability of Mn-Zn ferrites was studied. 600 ppm, 800 ppm and 1,000 ppm of MoO$_3$ were added to the main composition after calcination. Ferrite cores were sintered at 135$0^{\circ}C$ for 3hrs, followed by cooling according to the equilibrium oxygen concentration. The initial permeability was about 8,000 with heating rate 5$^{\circ}C$/min for 3hrs without MoO$_3$ addition. When 600 ppm and 800 ppm of MoO$_3$ were added, the initial permeabilities, 13,200 and 13,550 were obtained, respectively. However, the sample with 1,000 ppm MoO$_3$ showed lower permeabilities because of abnormal grain growth. At the heating rate 1$0^{\circ}C$/min, the ferrite cores with 1,000 ppm MoO$_3$ demonstrated the highest initial permeability greater than 15,000, without exaggerated grain growth.

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Thermal Property, Morphology, Optical Transparency, and Gas Permeability of PVA/SPT Nanocomposite Films and Equi-biaxial Stretching Films (폴리(비닐 알코올)/사포나이트 나노 복합체 필름 및 연신된 필름의 열적 성질, 모폴로지, 광학 투명성, 및 기체 투과성)

  • Ham, Miran;Kim, Jeong-Cheol;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.37 no.5
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    • pp.579-586
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    • 2013
  • Poly(vinyl alcohol)(PVA) nanocomposite films containing various saponite (SPT) clay contents were synthesized using a solution intercalation method. The thermal property, morphology, optical transparency, and gas permeability of the PVA nanocomposite films with various SPT contents in the range of 0 to 10 wt% were examined. PVA nanocomposite film containing 5 wt% SPT showed excellent thermal and gas barrier property. The hybrid films containing 5 wt% SPT were equibiaxially stretched with stretching ratios ranging from 150 to 250%. The clay dispersion, optical transparency, and gas permeability were also examined as a function of equibiaxial stretching ratio. The PVA nanocomposite films with various equibiaxial stretching ratios showed excellent optical transparency and barrier to oxygen permeability.

Mathematical Simulation for the Prediction of the Shelf Life of Tofu Packaged in a Polyethylene Container (폴리에틸렌 필름으로 포장된 두부의 보관수명 예측을 위한 수치모사)

  • Kim, Jai Neung;Rim, Byung-O;Shon, Tae-Won;Chung, Gui-Yung
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.889-893
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    • 1998
  • In this research, mathematical models for predicting the shelf life of packaged tofu in a polyethylene container were developed. Transfer of oxygen in air through the package and then diffusion of oxygen into the filled water and the tofu with the simultaneous oxygen consumption by micoorganisms were studied. The results of simulation showed that the increase of microorganisms in the filled water was more than that in tofu. As a result, it turns out that the shelf life of packaged tofu was not determined by the number of microorganisms in the tofu, but by that in the filled water. Additionally, the effects of physical properties of packaging material and packaged materials, such as the oxygen permeability of packaging material, oxygen diffusion coefficient and the initial oxygen concentration in filled water, and the depth of the filled water, on the shelf life of packaged tofu, were observed.

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Nitrogen-Oxygen Separation Characteristics by Polyimide Membrane System for Controlled Atmosphere Storage (CA저장을 위한 폴리이미드 막 시스템의 질소-산소 분리특성)

  • 이호원;현명택;고정삼
    • Food Science and Preservation
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    • v.5 no.3
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    • pp.239-246
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    • 1998
  • Polyimide membrane system was designed for manufacturing nitrogen-enriched gas, and basic technical data was suggested for appling this system to controlled atmosphere storage. The permeability characteristics of pure oxygen and nitrogen could be explained by dual-mode sorption model. There was substantial decrease in the permeation rates of oxygen, which is the more permeable gas, through the polyimide membrane due to the presence of nitrogen in comparison with pure oxygen. However, the permeation rates of nitrogen was increased by the presence of oxygen. The ideal separation factor was in the range of 5 to 6 in the range of temperature and pressure difference studied, and the separation factor of air was lower than the ideal separation factor. The increase of ideal separation factor with increasing temperature is due to the fact that the activation energy for oxygen is larger than that for nitrogen. Nitrogen concentration decreased rapidly with increasing product recovery, and it was found that this is a major operating factor to obtain nitrogen concentration required for controlled atmosphere storage. A relation equation, by which nitrogen concentration in storehouse can be predicted, was suggested under the establishment of a hypothetical model for controlled atmosphere storage process using polyimide membrane system.

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Comparison of Physical Properties of Domestic Contact Lenses -Focusing on oxygen transmissibility- (국내 생산 콘택트렌즈의 물리적 특성 비교 -산소전달률을 중심으로-)

  • Kim, Ki-Sung
    • Journal of the Korea Convergence Society
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    • v.9 no.1
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    • pp.393-403
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    • 2018
  • Although the use of silicone hydrogel contact lenses which are known to have high oxygen transmissibility is increasing, they are being sold without any product labeling of physical properties such as water content and oxygen transmissibility. To analyze the physical properties such as the water content and oxygen transmissibility of approved silicone hydrogel contact lenses, this study collected and analyzed the approval information published on the KFDA website. Of 68 cases of domestic silicone hydrogel contact lenses analyzed in this study, 61 cases (89.7%) did not meet the international standard for oxygen permeability. This is because lenses that are not different from hydrogel contact lenses were submitted for approval as silicone hydrogel contact lenses because there is no domestic standard for silicone hydrogel contact lenses. In future, besides the information published on the website, analysis of the physical properties of a wide variety of actual silicone hydrogel contact lenses on the market is required.

Electrospun Magnetic Nanofiber as Multifunctional Flexible EMI-Shielding Layer and its Optimization on the Effectiveness

  • Yu, Jiwoo;Nam, Dae-Hyun;Lee, Young-Joo;Joo, Young-Chang
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.2
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    • pp.57-63
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    • 2016
  • We developed a flexible and micro-thick electromagnetic interference (EMI) shielding nanofabric layer that also functions as a water resisting and heat sinking material. Electrospinning followed by a simple heat treatment process was carried on to produce the EMI-shielding Ni/C hybrid nanofibers. The ambient oxygen partial pressure ($pO_2$ = 0.1, 0.7, 1.3 Torr) applied during the heat treatment was varied in order to optimize the effectiveness of EMI-shielding by modifying the size and crystallinity of the magnetic Ni nanoparticles distributed throughout the C nanofibers. Permittivity and permeability of the nanofibers under the electromagnetic (EM) wave frequency range of 300 MHz~1 GHz were measured, which implied the EMI-shielding effectiveness (SE) optimization at $pO_2$ = 0.7 Torr during the heat treatment. The materials' heat diffusivity for both in-plane direction and vertical direction was measured to confirm the anisotropic thermal diffusivity that can effectively deliver and sink the local heat produced during device operations. Also, the nanofibers were aged at room temperature in oxygen ambient for water resisting function.

Effect of Residual Impurity on Magnetic Properties of the Permalloy Soft Magnet by Powder Injection Molding (분말사출성형으로 제조된 퍼말로이 연자성체에서 잔류 불순물이 자기특성에 미치는 영향)

  • 정원용;최준환;정우상
    • Journal of the Korean Magnetics Society
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    • v.10 no.6
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    • pp.291-296
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    • 2000
  • The manufacturing method of permalloy soft magnet with the Ni contents of 46.6 and 47.2 wt% was investigated by powder injection molding technology. The magnetic properties of permalloy were greatly affected on the residual carbon and oxygen content of the sintered magnet. Solvent extraction and thermal debinding process to minimize the residual carbon content in sintered magnet were developed by controlling the debinding atmosphere. The residual carbon content depends on the debinding condition of the binder system for powder injection molding and the residual oxygen content on the sintering atmosphere. The sintered magnet produced by powder injection molding process had a 50 ppm. residual carbon, 150 ppm. residual oxygen. The coercivity and maximum relative permeability of permalloy soft magnet were 0.46 Oe and 14,600 respectively.

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Model development to design modified atmosphere packaging of Mandarin oranges

  • Kim, Jong-Kyoung;Lee, Sang-Duk;Ha, Young-Sun;Lee, Jun-Ho
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.10a
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    • pp.192.1-192
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    • 2003
  • The aim of this study was to develop a model that could be used in the design of modified atmosphere packaging (MAP) for Mandarin oranges. Respiratory data at 5, 10, 20$^{\circ}C$ for mandarin oranges were gathered and altered for create useful respiration model. The maximum rate of oxygen uptake increased with increasing temperature. The packaging materials were conventional low density polyethylene and polypropylene with anti-fog, and anti-fungi treatments, and thickness was 30 $\mu\textrm{m}$ and 50 $\mu\textrm{m}$. Permeability tests were performed to find their oxygen, carbon dioxide, water vapor transmission rate as increases in temperature. Test results were then converted to logarithm format for MAP modeling. Optimum gas composition in the package system for fruits were set according to literature and upper or lower limits of oxygen and dioxide established. To predict gas composition at certain storage time, weight of fruits, film thickness, film type, and other variables, respiration rate was studied at various storage conditions. The validity of the model was tested experimentally by observing actual atmospheric changes inside packages. It is concluded that the strategy developed is of use in designing dynamic gas exchange MAP systems, and also has potential uses in similar agricultural products.

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