• 제목/요약/키워드: Oxygen enrichment

검색결과 118건 처리시간 0.027초

소연평도 함티타늄 자철광상의 암석지구화학적 연구 (Petrochemistry of the Soyeonpyeong titaniferous iron ore deposits, South Korea)

  • 김규한;이정은
    • 자원환경지질
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    • 제27권4호
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    • pp.345-361
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    • 1994
  • Lens shaped titanomagnetite ore bodies in the Soyeonpyeong iron mine are embedded in amphibolites, which were intruded into Precambrian metasediments such as garnet-mica schist, marble, mica schist, and quartz schist. Mineral chemistry, K-Ar dating and hydrogen and oxygen stable isotopic analysis for the amphibolites and titanomagnetite ores were conducted to interpret petrogenesis of amphibolite and ore genesis of titanomagnetite iron ore deposits. Amphibolites of igneous origin have unusually high content of $TiO_2$, ranging from 0.94 to 6.39 wt.% with an average value of 4.05 wt.%. REE patterns of the different lithology of the amphibolite show the similar trend with an enrichment of LREE. Amphiboles of amphibolites are consist mainly of calcic amphiboles such as ferro-hornblende, tschermakite, ferroan pargasite, and ferroan pargasitic hornblende. K-Ar ages of hornblende from amphibolite and gneissic amphibolite were determined as $440.04{\pm}6.39Ma$ and $351.03{\pm}5.21Ma$, respectively. This indicates two metamorphic events of Paleozoic age in the Korean peninsula which are correlated with Altin orogeny in China. The titanomagnetite mineralization seems to have occurred before Cambrian age based on occurrence of orebodies and ages of host amphibolites. The Soyeonpyeong iron ores are composed mainly of titanomagnetite, ilmenite, and secondary minerals such as ilmenite and hercynite exsolved in titanomagnetite. The temperature and the oxygen fugacity estimated by the titanomagnetite-ilmenite geothermometer are $500{\sim}600^{\circ}C$ (ave. $550^{\circ}C$) and about $2{\pm}10^{-23}bar$, respectively. Hornblendes from ores and amphibolites which responsible for magnetite ore mineralization, have a relatively homogeneous isotopic composition ranging from +0.8 to +3.9 ‰ in ${\delta}^{18}O$ and from -87.8 to -113.3 ‰ in ${\delta}D$. The calculated oxygen and hydrogen isotopic compositions of the fluids which were in equilibrium with hornblende at $550^{\circ}C$, range from 2.8 to 5.9‰ in ${\delta}^{18}O_{H2O}$ and from -60.41 to -81.31 ‰ in ${\delta}D_{H2O}$. The ${\delta}^{18}O_{H2O}$ value of magnetite ore fluids are in between +6.4 to + 7.9 ‰. All of these values fall in the range of primary magmatic water. A slight oxygen shift means that $^{18}O$-depleted meteoric water be acted with basic fluids during immiscible processes between silicate and titaniferous oxide melt. Mineral chemistry, isotopic compositions, and occurences of amphibolites and orebodies, suggest that the titanomagnetite melt be separated immisciblely from the titaniferous basic magma.

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Study of Euglenophytes Bloom and it's Impact on Fish Growth in Bangladesh

  • Rahman, M.M.;Jewel, M.A.S.;Khan, S.;Haque, M.M.
    • ALGAE
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    • 제22권3호
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    • pp.185-192
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    • 2007
  • A study was carried out in nine fertilized fish ponds under three treatments (T-I, T-II and T-III) at Bangladesh Agricultural University, Mymensingh to see the bloom of euglenophytes with the intention of observing its impact on the growth of fish in culture condition. Some water quality parameters viz., temperature, dissolved oxygen, pH, PO4-P and NO3-N concentration and some biological parameters viz., phytoplankton population and growth of fish were monitored at fixed intervals. Euglenophytes showed a heavy bloom in late August in the ponds of T-II. The bloom was occurred by the genera, Euglena, Phacus and Trachelomonas of which Euglena was the most dominant genus. In relation of water quality parameters with euglenophytes bloom, it was hypothesized that euglenophytes prefers higher temperature and acidic environment with higher nutrient concentrations. Acidic environment and nutrient enrichment enhanced the bloom of euglenophytes which hampered the growth of other beneficial algal groups (chlorophytes and bacillariophytes) and fish. Due to heavy bloom, the fishes breathed with difficulty at the surface. The fishes in the heavy bloom ponds presented the weight values were lower than verified for those in the ponds where the bloom did not occur. Total production (calculated) of fish in different treatments ranged from 1355.89 to1760.63 kg ha–1 with significantly (p < 0.05) lowest in the ponds of T-II.

SPECTROSCOPY OF BRIGHT EXTRAGALACTIC PLANETARY NEBULAE

  • Richer, Michael G.
    • 천문학회지
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    • 제40권4호
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    • pp.183-186
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    • 2007
  • The spectroscopic properties of bright extragalactic planetary nebulae are reviewed, considering primarily their chemical abundances and their internal kinematics. Low-resolution spectroscopy is used to investigate how the precursor stars of bright planetary nebulae modify their original composition through nucleosynthesis and dredge up. At present, the evidence indicates that oxygen and neon abundances usually remain unchanged, helium abundances are typically enhanced by less than 50%, while nitrogen enhancements span a very wide range. Interpreting these changes in terms of the masses of their progenitor stars implies that the progenitor stars typically have masses or order $1.5M_{\bigodot}$ or less, though no models satisfactorily explain the nitrogen enrichment. High-resolution spectroscopy is used to study the internal kinematics of bright planetary nebulae in Local Group galaxies. At first sight, the expansion velocities are remarkably uniform, with a typical expansion velocity of 18 km/s and a range of 8-28 km/s, independent of the progenitor stellar population. Upon closer examination, bright planetary nebulae in the bulge of M31 expand slightly faster than their counterparts in M31's disk, a result that may extend generally to the planetary nebulae arising from old and young stellar populations. There are no very strong correlations between expansion velocity and global nebular properties, except that there are no large expansion velocities at the highest $H{\beta}$ luminosities (i.e., the youngest objects never expand rapidly). These results independently suggest that bright planetary nebulae arise from a similar mass range in all galaxies. Nonetheless, there are good reasons to believe that bright planetary nebulae do not arise from identical progenitor stars in all galaxies.

NOx 저감을 위한 하이브리드 연료희박 재연소 연구 (Experimental Investigation of NOX Reduction using a Hybrid Fuel Lean Reburning System)

  • 김학영;백승욱;황창환
    • 대한기계학회논문집B
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    • 제34권3호
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    • pp.283-290
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    • 2010
  • 이 연구의 목적은 NOx 저감을 위한 연료희박 재연소 기법과 산화제 다단 연소 기법의 혼합 기법의 실험적 연구를 목표로 한다. 실험용 연소로에서 재연소 연료 분율, 재연소 노즐 직경, 산소부하도 및 재연소 연료 분사 위치등을 고려한 실험을 수행 하였다. 또한, 산화제 다단 연소를 통하여 생성된 유동장이 NOx 저감에 미치는 영향을 연료희박 기법의 NOx 저감율과 비교하는 실험을 수행하였다. 실험을 통하여 연료희박 재연소와 산화제다단연소 기법의 혼합 기법이 NOx 저감에 미치는 긍정적인 효과를 관찰 하였다.

확률분포를 이용한 남한강 보 건설 전·후 수질변화 분석 (Analysis of Water-Quality Constituents Variations before and after Weir Construction in South Han River using Probability Distribution)

  • 김경섭
    • 한국물환경학회지
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    • 제35권1호
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    • pp.55-63
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    • 2019
  • The Four Major Rivers Restoration Project started in 2009 and completed in early 2013 is a large-scale inter-ministry SOC project investing ₩22.2 $10^{12}$ and one of the Project's objectives was to enhance the water-quality grade through recovering the river eco-system and environment. The average concentration and probability distribution of water-quality constituents at given and selected sampling sites are very significant elements for analyzing and controlling the water-quality of rivers or reservoirs effectively. Average concentration can be estimated by point estimator, distribution function of water-quality constituents or Bootstrap method, in which the distribution function estimated with more data in case of insufficient dataset, is applied. Ipo and Gangcheon water-quality monitoring stations in South Han River were selected to compare and analyze the variation of concentration before and after Ipo and Gangcheon Weirs construction, using the whole 4-year's data, from 2005 to 2008 and from 2014 to 2017. Water-quality constituents such as BOD and COD relating to oxygen demanding wastes and TP and Chlorophyll-a relating to the process of nutrient enrichment called eutrophication were also selected. The guidelines for water-quality control and management after weir construction including evaluation of water-quality constituents' variations can be presented by this paper.

남해 연안 피조개 (Scapharca broughtonii) 양식장의 환경특성 (The effect of geochemical characteristics and environmental factors on the growth of cultured Arkshell Scapharca broughtonii at several shellfish-farming bays on the South coast of Korea)

  • 최윤석;정춘구
    • 한국패류학회지
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    • 제32권3호
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    • pp.149-155
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    • 2016
  • 피조개 양식장의 해수 수온, 염분, pH, DO, 영양염, COD의 조사결과 해역별 편차가 적게 나타났다. 그리고 엽록소 a 농도는 7-8월에 부영양화 기준인 $7{\mu}g/L$ 보다 높게 나타났지만 8월 이후 부영양화 기준보다 낮은 농도를 보였다. 따라서 피조개 양식장에서 서식환경에 의한 생존율의 급감은 여름철 고수온, 낮은 용존산소량과 먹이원인 클로로필의 감소로 인하여 발생되는 것으로 사료된다. 퇴적물의 강열감량 (IL) 과 산휘발성화합물 (AVS) 및 함수율 (WC) 은 유사한 양상을 보이며 큰 차이가 나타나지 않았으며 화학적산소요구량 (COD) 은 거제만의 조사 정점에서 월별 변화가 심하게 나타났다. 퇴적물의 평균입도 (Mz) 는 8.07-8.33 범위를 보였고 분급도는 1.66-2.13 범위로 피조개 양식에 적합한 지역으로 나타났다. 퇴적물의 C/N 비는 양식장에서 5-10 사이의 값을 나타내어 해양기원의 유기물에 의한 것으로 추정되며, C/S 비는 지역에서 2.8 이상으로 유기물이 분해되기 전에 유기물의 급속한 퇴적이 이루어졌을 환경으로 조사 되었다. 중금속에 대한 농집지수 (Igeo) 의 결과는 연구지역이 Igeo class가 0에서 4 사이로 분포되어 있어 오염되지 않았거나 약간오염된 수준으로 (practically unpolluted / moderately polluted) 나타났다.

바이오매스(우드펠릿) 혼소율 및 입자크기에 따른 연소 특성에 관한 연구 (Experimental Investigation into the Combustion Characteristics on the Co-firing of Biomass with Coal as a Function of Particle Size and Blending Ratio)

  • 락와더르지;김상인;임호;이병화;김승모;전충환
    • 대한기계학회논문집B
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    • 제40권1호
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    • pp.31-37
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    • 2016
  • 최근 바이오매스와 석탄의 혼소 기술이 화력 발전의 주요한 연소 기술 중 하나로 떠오르고 있다. 그러나 혼소는 실제 발전용 보일러 적용시 많은 검증들을 필요로 한다. 본 연구에서는 바이오매스 혼소시 연소 특성을 알아보기 위해 열중량 분석기(Thermogravimetric analyzer, TGA)와 하향분류층 반응기(Drop tube furnace, DTF)를 사용하였으며, TGA의 TG/DTG 분석을 통한 반응성과 DTF를 이용한 UBC를 측정하여 연소 특성을 분석하였다. 특히 석탄과 바이오매스 혼소율(Biomass blending ratio) 및 바이오매스 입자 크기 변화에 따른 특성을 분석하였다. 그 결과, 바이오매스의 혼소율이 증가함에 따라 산소 부족으로 인한 반응 특성이 나타났으며, 이는 바이오매스가 가진 초기의 빠른 연소 특성 때문이다. 또한, 본 연구 결과를 통해 바이오매스의 최적 혼소 조건(UBC 발생량 기준)은 5%로 나타났으며, 산소 부화 조건은 바이오매스 혼소시 발생하는 산소 부족 현상을 저감시켜 미연분 상승을 완화시켜줄 수 있다.

시화방조제의 건설은 저서동물군집의 시${\cdot}$공간 분포에 어떠한 영향을 미쳤는가? (How are the Spatio-Temporal Distribution Patterns of Benthic Macrofaunal Communities Affected by the Construction of Shihwa Dike in the West Coast of Korea?)

  • 홍재상;정래홍;서인수;윤건탁;최병미;유재원
    • 한국수산과학회지
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    • 제30권5호
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    • pp.882-895
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    • 1997
  • 본 연구는 시화방조제 건설로 인하여 외해수와의 순환이 차단된 후 유기물오염과 담수화가 진행된 시화호 내에서 방조제 완공 전과 후의 저서동물 군집을 비교함으로써 시화호 내에서 저서동물군집이 어떤 천이과정을 거쳤는지, 그리고 군집의 천이를 일으킨 주된 요인은 무었인지, 또한 방조제 건설 전의 시화지구 해역 저서동물 군집과 건설 후 방조제 외곽해역의 저서동물 군집을 비교함으로써 방조제 건설이 주변 해역에 미친 영향을 파악하는데 그 목적이 있다. 방조제 완공 후 시화호 내에서의 저서동물 군집의 천이는 두 방향으로 진행되었다. 첫번째는 유기물 유입의 증가에 따른 저층수의 무산소 및 빈산소 환경의 형성으로 인해 저서동물이 완전히 사라진 중오염역 (Grossly Polluted Zone)의 출현이다. 두번째는 저서동물 군집이 계속 유지되고 있는 방조제 근처의 낮은 수심에서의 기회종으로 구성된 오염역 (Polluted Zone)으로의 저서동물 군집의 천이이다. 이런 군집의 천이는 방조제의 배수갑문을 통한 빈번한 해수 유입으로 인하여 저층수의 염분도와 용존산소량의 변화에 크게 영향을 받는 것으로 나타났다. 또한 시화방조제 건설은 주변 외곽지역의 저서동물 군집에도 영향을 미쳐 건설 전보다 후에 평균 출현종수는 2.6배, 밀도는 7배나 증가하는 전형적인 부영양화의 특징적 현상을 보임으로서 방조제 외곽해역의 저서동물 군집 또한 불안정한 상태로 변하고 있음을 알 수 있다.

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저층수 용존산소가 당동만 저서다모류군집 구조의 시간적 변동에 미친 영향 (The Influence of the Dissolved Oxygen of Bottom Water on the Temporal Variation of the Benthic Polychaetous Community Structure in Dangdong Bay)

  • 양진경;신현출
    • Ocean and Polar Research
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    • 제42권3호
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    • pp.233-247
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    • 2020
  • This study was carried out at 5 sites 11 times over two years to identify the variation of benthic environments and benthic polychaetous community and analyze the benthic healthiness in Dangdong Bay, a small semi-enclosed inner bay of Jinhae Bay. The temperature of bottom water showed the typical temporal fluctuation of a temperate zone and was in the range of 5.94 ~ 23.94℃. The salinity did not change significantly during the study period and was in the range of 32.93 ~ 35.72 psu. The concentration of dissolved oxygen of bottom water fluctuated a great deal and was in the range of 0.31 ~ 10.20 mg/L. The lowest DO value was recorded in July 2015, as 0.31±0.04 mg/L corresponding to the hypoxic water mass. The hypoxic water mass was formed continuously at some sites also in July and August 2016. The mean grain size was in the range of 7.57 ~ 9.81Ø and the average was 8.89±0.20Ø. The surface sediments were mainly composed of fine sediment (mud) above 85%. The mean of TOC was 3.09±0.22% and LOI was 13.30±0.47%, showing very high levels in Korean coastal waters. The concentration of AVS was in the range of 0.33 ~ 1.28 mgS/g-dry. The high values of organic contents and AVS indicated that there had been the serious organic enrichment in Dangdong Bay. The number of species and the density of the benthic polychaetous community in Dangdong Bay were in the range of 2 ~ 38 species and 2 ~ 2,185 ind./㎡ during the study period. The number of species and density were highly sustained in winter and spring, and then decreased gradually with the formation of a hypoxic water mass in summer, and the lowest number of species and density were recorded in autumn. In September and November 2015, the dead zone expanded to almost the whole study area. Dominant polychaetous species were Capitella capitata, Lumbrineris longifolia, Paraprionospio patiens and Sigambra tentaculata, each known as opportunistic species and potential organic pollutant indicator species. In particular, Paraprionospio patiens showed a very high population density of 2,019 ind./㎡ in December 2016. Polychaetous communities at each sampling time were classified into 4 temporal groups according to dominant species in each period by cluster analysis and nMDS. 'Period Group AI' was formed in winter and spring of 2015, dominated by Capitella capitata, 'Period AII' in summer dominated by Lumbrineris longifolia, 'Period B' in autumn with no fauna in the dead zone, and particularly 'Period C' in winter of 2016 dominated by Paraprionospio patiens. As a result of analysis of benthic healthiness, the study area was estimated to be in a Fair~Very Poor condition by AMBI and in a Poor~Very Poor condition by BPI during the study period. Both AMBI and BPI showed that the study area was in a Very Poor condition in September and November 2015, and when the dead zone occurred. In Dongdong Bay, the fact that the formation of a hypoxic water mass occurred in summer and a dead zone in autumn were confirmed. In addition, the dominance of opportunistic and organic pollutant indicator species was also observed clearly. The benthic healthiness indexes such as AMBI and BPI showed that organic enrichment was serious in Dangdong Bay.

안정만 패류양식해역의 표층퇴적물의 지화학적특성과 중금속 함량 (Physiochemical Characteristics and Heavy Metal in the Surface Sediments of Marine Shellfish Farming Waters in Anjung Bay, Korea)

  • 정우건;조상만;이상준
    • 한국패류학회지
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    • 제30권4호
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    • pp.421-428
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    • 2014
  • 굴양식이 성행하는 안정만 해역은 인근 연안에 LNG비축기지, 조선소 등의 공단이 가동되고 있어 일부 양식장은 품종을 전환하고 있다. 이 연구는 안정만 해역의 연안생태계에 영향을 미치는 저질환경 특성을 조사하기 위하여 2009년부터 2010년까지 2회에 걸쳐 20개 정점의 표층퇴적물을 채집, 분석하였다. 안정만 해역의 표층퇴적물의 IL은 6.41-11.68% (평균 $9.52{\pm}1.28%$)의 범위였고, COD는 17.99-43.84 mg/g (평균 $27.53{\pm}6.39mg/g$), 그리고 AVS는 0.05-0.61 mg/g (평균 $0.17{\pm}0.14mg/g$)의 범위였다. 유기물함량은 저질의 수분함량과 밀접한 상관관계가 있었고, 이는 양식품종의 분포 패턴과도 관계가 있어 흰멍게로 양식품종이 변화된 북부해역의 COD가 비교적 높게 나타났다. 일부 조사정점을 제외하고 대부분의 중금속함량은 NOAA의 ERL 기준치 이하였고, 중금속 부화지수는 0.96-1.12의 범위로 중금속 오염에서는 비교적 청정한 것으로 판단되지만, 증가하는 선박 통행량을 고려할 때, 지속적인 저질환경 모니터링이 요구된다.