• 한국세라믹학회지
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• 제45권2호
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• pp.90-93
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• 2008

The oxygen gas behavior in PDP (plasma Display Panel) glass melts doped with sulfate ($SO_4^{-2}$) or blast furnace slag (BFS, $S^{2-}$) or both by means of yttria-stabilized zirconia (YSZ) electrodes was observed after the first fining. The temperature dependence of oxygen equilibrium pressure ($P_{O2}$) in each melt showed typical behavior, namely $P_{O2}$ decreased as temperature decreased. This suggests that an oxidation of $S^{4+}$ to $S^{6+}$ took place. However, the $P_{O2}$-value at constant temperature increased in the following order: BFS$P_{O2}$ of the melt doped with sulfate+BFS was much lower than that of the melt with only sulfate, although only 10% of sulfur was added by the BFS. This behavior can be explained by the redox reaction between sulfide ions in the BFS and dissolved oxygen ions in the melt during the first fining.

• 한국세라믹학회지
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• 제44권8호
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• pp.419-423
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• 2007

The behavior of oxygen gas participating in fining was observed in CRT (Cathode Ray Tube) glass melts doped with $Sb_2O_5\;or\;CeO_2$ by means of a yttria-stabilized zirconia (YSZ) electrode. The temperature dependence of the oxygen equilibrium pressure ($P_{o2}$) or the activity in both melts showed typical behavior corresponding to a theoretical redox reaction. In other words, the $P_{o2}$ value of melts with $CeO_2$ was lower than that of melts with $Sb_2O_5$ above $1250^{\circ}C$. The result implies that $Sb_2O_5$, is more efficient as a fining agent compared to $CeO_2$. On the other hand, melts from a batch containing $Sb_2O_5\;and\;KNO_3$ showed much higher $P_{o2}$ values compared to melts without $KNO_3$ above $1350^{\circ}C$. It is suggested that the addition of $KNO_3$ to CRT glass batch contributes partly to the first fining of the melts.

• The Korean Journal of Ceramics
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• 제4권2호
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• pp.68-71
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• 1998

The effect of Mn and Nb additions on the electrical properties of BaTiO$_3$ has been studied by means of equilibrium electrical conductivity as a function of temperature, oxygen partial pressure(Po$_2$) and composition. If the manganese ion is added to the normal Ti site, i.e. BaTi$_{1-x}Mn_xO_{\delta-6}$, the equilibrium conductivity shows strong evidence of acceptor-doped behavior. The conductivity minimum, corresponding to the transition from oxygen excess, p-type behavior to oxygen deficient, n-type behavior with decreasing Po$_2$, is displaced to lower Po$_2$ and is broadened and flattened. The partial replacement of Mn ion with Nb decreases the acceptor-doped effect and the total replacement exhibits a typical donor-doped behavior. It was confirmed that unlike undoped or other acceptor-doped behavior. It was confirmed that unlike undoped or other acceptor-doped samples, for the p-type region, the electrical conductivity follows the 1/6th power dependence of oxygen partial pressure.

• 한국표면공학회지
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• 제29권5호
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• pp.593-598
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• 1996

Previously, in trying to prepare perovskite type oxide powders by microwave heating, we found out a non-equilibrium argon plasma is generated around the powders and discharge continues stable at atmospheric pressure. In this study, we tried the plasma decomposition of heat-stable higher organic compound such as palmitic acid which is the principal constituent of the fimger fats. It was proved that suitable amount of coexistence of oxygen radicals into the argon flow accelerates the decomposition of palmitic acid. The argon-oxygen mixed gas plasma was able to perform a complete elimination of higher organic compound.

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2004년도 학술논문집
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• pp.105-114
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• 2004

This study investigated the thermal behavior of the nuclear graphite waste generated from the decommissioning of the Korean nuclear research reactor, The first part study investigated the decomposition rate of the nuclear graphite waste up to $1000^{\circ}C$ under various oxygen partial pressures using a thermo-gravimetric analyzer (TGA). Tested graphite waste sample not easily destroyed in the oxygen-deficient condition. However, the gas-solid oxidation reaction was found to be very effective in the presence of oxygen. No significant amount of the product of incomplete combustion was formed even in the limited oxygen concentration of 4% $O_2$. The influence of temperature and oxygen partial pressure was evaluated by the theoretical model analysis of the thermo-gravimetric data. The activation energy and the reaction order of graphite oxidation were evaluated as 128 kJ/mole and 1.1, respectively. The second part of this study investigated the behavior of radioactive elements under graphite oxidation atmosphere using thermodynamic equilibrium model. $^{22}Na$, $^{134}Cs$ and $^{137}Cs$ were found be the semi-volatile elements. Since volatile uranium species can be formulated at high temperatures above $1050^{\circ}C$, the temperature of incinerator furnace should be minimized. Other corrosion/activation products, fission products and uranium were found to be the non-volatile species.

• 한국지구과학회지
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• 제34권1호
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• pp.28-40
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• 2013

한반도에서 산출되는 초염기성 맨틀포획암의 지화학적 특징과 평형 온도와 압력 조건을 계산하고, 산소동위원소비를 분석하였다. 연구 결과 (1) 한반도 맨틀포획암은 전형적인 초염기성 포획암(MgO: 49.12-50.95 wt.%, Mg값: 90.1-92.2)으로 구성되어 있다. (2) 한반도 맨틀포획암의 평형온도는 $854-1016^{\circ}C$이고, 압력은 4.6-24.4 kbar로 얻어졌다. (3) 맨틀포획암을 구성하는 감람석의 산소동위원소비(${\delta}^{18}O_{ol}$)는 5.06-5.51‰의 균질한 값으로 N-MORB와 상부 맨틀 감람석의 값(${\delta}^{18}O$: $5.2{\pm}0.2$‰)과 유사하다. 그러나 백두산과 제주도의 맨틀포획암을 구성하는 감람석의 산소동위원비는 각각 5.07-5.51‰과 5.07-5.45‰로 상대적으로 넓은 범위의 ${\delta}^{18}O$ 값을 갖고 있다. 이 결과를 바탕으로, 이 연구에서는 백두산 맨틀포획암의 높은 ${\delta}^{18}O$가 맨틀포획암 물질에 재순환된 퇴적물원 EM2 물질의 혼입 때문일 수 있다는 가능성을 제안하였다.

• 한국추진공학회지
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• 제2권3호
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• pp.90-98
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• 1998

본 연구에서 개발한 고압증발 모델을 이용하여 고압 연소장에서의 액체연료추진제의 증발 과정을 수치적으로 해석하였다. 고압상태에서 액적의 증발 특성에 중요한 영향을 미치는 실제 기체의 거동, 온도 및 압력에 따른 가변물성치의 영향, 주위기체의 용해현상을 고려하였고 일반적인 상평형 관계식을 이용하였다. 실험치와 비교하여 고압증발모델의 예측능력을 체계적으로 검증하였고 로켓엔진의 고온 고압 연소실조건에서 LOX 액적의 증발 특성을 상세하게 논의하였다.

• 한국수소및신에너지학회논문집
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• 제23권2호
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• pp.173-182
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• 2012

Effects of temperature, pressure, and gas residence time on methane combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using methane and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction condition and very low NO emission at oxidation condition. Moreover OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration. However, $CO_2$ selectivity increased as pressure increased and fuel conversion increased as gas residence time increased.

• 대한기계학회논문집B
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• 제27권4호
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• pp.440-446
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• 2003

Steady-state structure and acoustic pressure responses of GH$_2$-LOx diffusion flames in stagnation-point flow configuration have been studied numerically with a detailed chemistry to investigate the acoustic instabilities. The Rayleigh criterion is adopted to judge the instability of the GH$_2$-LOx flames from amplification and attenuation responses at various acoustic pressure oscillation conditions for near-equilibrium to near-extinction regimes. Steady state flame structure showed that the chain branching zone is embedded in surrounding two recombination zones. The acoustic responses of GH$_2$-LOx flame showed that the responses in near-extinction regime always have amplification effect regardless of realistic acoustic frequency. That is, GH$_2$-LOx flame near-extinction is much sensitive to pressure perturbation because of the strong effect of a finite-chemistry.

• 한국세라믹학회지
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• 제37권3호
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• pp.271-279
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• 2000

5 m/o Yb-doped SrCeO3 proton conductor was prepared by a solid state reaction method and its total electriccal conductivity measured as a function of both oxygen partial pressure and water vapor partial pressure in the temperature range of 500~100$0^{\circ}C$. From the total conductivity have been deconvoluted the partial conductivities of oxide ions, protons, and holes, respectively, on the basis of the defect model proposed. The equilibrium constant of hydrogen-dissolution reaction, proton concentration, and mobilities of oxygen vacancies and protons have subsequently been evaluated. It is verified that SrCe1-xYbxO3 is a mixed conductor of holes, protons and oxide ions and the proton conduction prevails as temperature decreases and water vapor pressure increases. The heat of water dissolution takes a representative value of $\Delta$HoH=-(140$\pm$20) kJ/mol-H2O, but tends to be less negative with increasing temperature. Migration enthalpies of proton and oxygen vacancy are extracted as 0.83$\pm$0.10 eV and 0.81$\pm$0.01 eV, respectively.