• Journal of the Korean institute of surface engineering
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• v.21 no.2
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• pp.53-67
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• 1988

The high temperature corrosion of Fe-C alloys were studied at I atm SO gas in the temperature range 500~80$0^{\circ}C$ by means of a thermogravimetric analysis. The Na2SO4 induced high tempwrature corrosion rate was also measured at atm O2 gas under above the temperature renge. The reaction products were identified with the aid of X-ray diffraction technique, and micostruction of the alloy/scale interface was observed with a optical microscope and SEM. The experimental results were disussed by the themodeynamic calcutions. Under above the experimental condition. the reaction rates decrbon with increasing carbon content. The transfer of Fe ion was limited by a residue of carbon precipitated at alloy scale interface due to the oxidation of Fe-C alloys at alloy surface. The effect of cold working on reaction rate was different between the Fe containing low carbon and Fe-C Alloy containing carbon above 0,73 wt%. In a cold worked iron containing low carbon content, the crystallization of metal surface leads to the poor adherence between the alloy and the cavity formed between the alloy and scale. The outward diffusion of ion through the scale is estimated to be hindered by the cavity formed between the scale, consequently decreasing reaction rate. In the case Fe-C containing carbon above 0.73 Wt% alloy, the reaction rate was little affected by cold working, because the effect of content on reaction rats is greater than the effect of cold working.

• Carbon letters
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• v.7 no.1
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• pp.1-8
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• 2006

The activated carbon "C" was obtained by carbonization followed by activation with steam at 40% of burn-off. Oxidized carbons C-N, C-P and C-H were obtained by oxidizing the activated carbon C with concentrated nitric acid, ammonium peroxysulfate and hydrogen peroxide, respectively. The textural properties of the carbons were determined from nitrogen adsorption at 77 K. The acidic surface functional groups were determined by pH titration, base neutralization capacity and electrophoretic mobility measurements. The cation exchange capacities of un-oxidized and oxidized carbons were determined by the removal of Cu(II) and Ni(II) from their aqueous solutions. The surface area and the total pore volume decreased but the pore radius increased by the treatment of activated carbon with oxidizing agents. These changes were more pronounced in case of oxidation with $HNO_3$. The surface pH of un-oxidized carbon was basic whereas those of the oxidized derivative were acidic. The removal of Cu(II) and Ni(II) was pH dependent and the maximum removal of the both ions was obtained at pH of 5-6. Cu(II) was more adsorbed, a phenomenon which was ascribed to its particular electronic configuration.

• Particle and aerosol research
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• v.9 no.1
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• pp.7-21
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• 2013

Twelve-hour size-resolved atmospheric aerosols were measured to determine size distributions of water-soluble organic carbon(WSOC) during daytime and nighttime, and to investigate sources and formation pathways of WSOC in individual particle size classes. Mass, WSOC, ${NO_3}^-$, $K^+$, and $Cl^-$ at day and night showed mostly bimodal size distributions, peaking at the size range of $0.32-0.55{\mu}m$(condensation mode) and $3.1-6.2{\mu}m$(coarse mode), respectively, with a predominant condensation mode and a minor coarse mode. While ${NH_4}^+$ and ${SO_4}^{2-}$ showed unimodal size distributions which peaked between 0.32 and $0.55{\mu}m$. WSOC was enriched into nuclei mode particles(< $0.1{\mu}m$) based on the WSOC-to-mass and WSOC-to-water soluble species ratios. The sources and formation mechanisms of WSOC were inferred in reference to the size distribution characteristics of inorganic species(${SO_4}^{2-}$, ${NO_3}^-$, $K^+$, $Ca^{2+}$, $Na^+$, and $Cl^-$) and carbon monoxide. Nuclei mode WSOC was likely associated with primary combustion sources during daytime and nighttime. Among significant sources contributing to the condensation mode WSOC were homogeneous gas-phase oxidation of VOCs, primary combustion emissions, and fresh(or slightly aged) biomass burning aerosols. The droplet mode WSOC could be attributed to aqueous oxidation of VOCs in clouds, cloud-processed biomass burning aerosols, and small contributions from primary combustion sources. From the correlations between WSOC and soil-related particles, and between WSOC and sea-salt particles, it is suggested that the coarse mode WSOC during daytime is likely to condense on the soil-related particles($K^+$ and $Ca^{2+}$), while the WSOC in the coarse fraction during nighttime is likely associated with the sea-salt particles($Na^+$).

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.8 no.3
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• pp.317-326
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• 2003

In order to improve our knowledge of the characteristics of organic compounds in coastal waters, water samples were collected from the Incheon coastal region, the Hyungsan River in Youngil Bay and the Busan coastal region. Also, mooring was carried out near the Kanghwa Island and Seo Island. In this study, the relationship between the total organic carbon (TOC) and salinity, chemical oxygen demand (COD) and salinity were evaluated and determined. Riverine end-member of TOC into the Korean coastal area and its COD estimated from these relationships were 5.32 mg C/l and 8.87 mg O$_2$/l, respectively. The oxidation efficiency of COD to TOC estimated using the high-temperature catalytic oxidation method was about 47％. The linear relationship between TOC and COD was derived as COD (mg O$_2$/l)=0.61${\times}$TOC (mg C/l) -0.03, (R$^2$=0.66). Therefore, it is possible to estimate total organic carbon using this equation from previously reported chemical oxygen demand.

• Korean Chemical Engineering Research
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• v.62 no.1
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• pp.13-18
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• 2024

To develop flexible electrode materials for wearable devices, we investigated the electrochemical characteristics of carbon fibers tow according to pretreatment. And an electrochemical non-enzymatic sensor was fabricated using glucose as a target. The carbon fibers tow was pretreated through desizing and activation processes, and activation was performed in two ways: chemical oxidation and electrochemical oxidation. Surface morphology of carbon fibers tow samples was observed by SEM and their electrochemical characteristics and sensing performance were investigated by cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. Carbon fibers tow samples showed improved electrochemical properties such as reduced R_et, ΔE_p, and increased I_p through pretreatment. And similar electrochemical properties were obtained with both activation methods. We selected electrochemically activated carbon fibers tow as the final electrode material for application of electrochemical sensor. The non-enzymatic glucose sensor based on this electrode has an enhanced sensitivity of 0.744 A/mM (in a linear range of 0.09899~3.75423 mM) and 0.330 mA/mM (3.75423~50 mM), respectively. Through this study, the possibility of using carbon fibers tow was confirmed as an electrode material. It is expected to be used as basic research for development of high-performance flexible electrode materials.

• Journal of the Korean Ceramic Society
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• v.13 no.1
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• pp.11-19
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• 1976

This study was focused on the improvement of production techniques of small crucibles in relation with the appropriate selection of raw materials, various batch compositions and physical and chemical characteristics of the crucibles. Various tests gave the optimum batch composition for the carbon bond graphite cructble as follows: Pyontaek graphite flake (refractory aggregate) : 40Part Silicon carbide: 15Part Tar pitch (binder) : 11Part Inorganic additives (to improve the oxidation resistance) : 15 Part Cryolite : 3 Part Ferro manganese : 2 Part Ferrosilicon : 25 Part Crucibles pressed with 400kg/$\textrm{cm}^2$ at 12$0^{\circ}C$. and fired in reducing atmosphere at 120$0^{\circ}C$ brought the most favorable results as follows: Bulk density : 2.31 Apparent density : 2.58 Porosity : 15.2% Oxidation loss at 1, 50$0^{\circ}C$. for 3 hrs : below 3.77% Water absorption : 6.01% Compressive strength : 438kg/$\textrm{cm}^2$ Tensile strength : 256kg/$\textrm{cm}^2$.

• Journal of Korean Society of Water and Wastewater
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• v.14 no.1
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• pp.99-107
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• 2000

In this article, the removal of surfactant by ozone and BAC was studied. Batch and pilot tests were carried out for these studies. In batch tests, efficiency of ozone oxidation process was evaluated for LAS(Linear Alkylbenzen Sulfonate) and SLS(Sodium Lauryl Sulfate) removal. Under oxidant conditions, the removal of LAS was more effective than that of SLS. The removal of surfactant was more enhanced with increasing pH in oxidant systems. Pilot tests are carried out with BAC single process and ozone oxidation/BAC combined process. The removal of LAS was more effective in ozone oxidation/BAC combined process than BAC single process about 10-20%. In the case of SLS, the efficiency of BAC single process was similar to that of ozone oxidation BAC combined process. According to temperature, the removal efficiency of SLS changed from 70% to 95% and initial concentration of surfactant had no effects on removal efficiency of SLC under applied temperature above $15^{\circ}C$.

• Journal of Environmental Health Sciences
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• v.31 no.5 s.86
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• pp.404-410
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• 2005

The pH efforts on the removal of 1,4-dioxane and the biodegradobility enhancement of dioxane contaminated water were investigated using $O_3/H_2O_2$ baled advanced oxidation process. Experiments were conducted using a bubble column reactor under different initial pH. The $O_3/H_2O_2$ process effectively converted 1,4-dioxane to more biodegradable intermediates which had a maximum $BOD_5$ enhancement at pH 11 within the experimental range, precisely, when the initial pH increased, $BOD_5$ enhanced. However, in case of removal efficiencies of 1,4-dioxane during $O_3/H_2O_2$ oxidation the optimum condition was shown at pH 9 compared with pH 6 and 11. TOC and COD values were not largely changed for all reaction time. From the results of 1,4-dioxane removal efficiency, TOC, COD, and $BOD_5$ enhancement with reaction time, it was surely observed that 1,4-dioxane was just converted to biodegradable materials, not completely oxidized to carbon dioxide.

• Journal of the Korean Chemical Society
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• v.28 no.2
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• pp.102-108
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• 1984

The catalytic oxidation of CO has been investigated on $ZnCe_{1+y}O_2$ at temperatures from 300 to $500^{\circ}C$ under various P_{CO} and PO_2 conditions. The oxidation rates have been correlated with 1.5-order kinetics: first order with respect to CO and 0.5 order with respect to O2. CO appears to be absorbed essentially on the O lattice of $ZnCe_{1+y}O_2$ as a molecular species, while $O_2$ adsorbs on an O vacancy as an ionic species. The conductivity data show that CO adsorption contributes electron to the conduction band and the adsorption process of $O_2$ withdraws it from an O vacancy. The oxidation mechanism and the defect model of $ZnCe_{1+y}O_2$ are inferred at given temperature and $PO_2'$s from the agreement between the conductivities and kinetic data. It is suggested that CO absorption is the rate-controlling.

• Proceedings of the Materials Research Society of Korea Conference
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• 2005.05a
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• pp.89-89
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• 2005