• 제목/요약/키워드: Oxidation/reduction potential(ORP)

검색결과 93건 처리시간 0.027초

PAC-A/O 공정을 이용한 안료폐수의 질소 제거 특성 (Nitrogen removal characteristics of pigment wastewater using PAC-A/O process)

  • 정종식
    • 상하수도학회지
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    • 제32권1호
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    • pp.19-25
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    • 2018
  • The objectives of this study were to evaluate the removal characteristics of total nitrogen, the influence factor of denitrification and the optimum operating condition in the pigment wastewater treatment using PAC-A/O process. The operating conditions of PAC-A/O process were mean BOD volumetric loading $0.86kgBOD/m^3/day$, mean F/M ratio 0.072~0.13 kgBOD/kgMLVSS/day and mean C/N ratio 3.47, respectively. The conditions of anoxic process in the field plant test were mean pH 8.3~8.7 and mean temperature $34.1{\sim}44.0^{\circ}C$. The ORP bending point knee was eventually appeared in the ORP -107 mV and $NO_3{^-}-N$ removal efficiency was increased according to the ORP decrease. In the ORP -107 mV below condition, the removal efficiency of T-N and $NO_3{^-}-N$ was 92.3~95.0% and 98.5~99.7%. Denitrification rate was calculated to be 1.581~1.791 mg $NO_3{^-}-N/gMLSS/hr$. The experimental results showed that the ORP control in the PAC-A/O process could be an effective method for treatment of pigment wastewater.

퍼지 시스템을 이용한 비선형 질소제거 SBR 공정의 모델링 (Modeling of Nonlinear SBR Process for Nitrogen Removal Using Fuzzy Systems)

  • 김동원;박장현;이호식;박영환;박귀태
    • 한국지능시스템학회논문지
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    • 제14권2호
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    • pp.190-194
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    • 2004
  • 본 논문에서는 비선형 생화학적인 공정의 모델링을 위해 퍼지시스템이 응용된 것을 보인다. SBR 반응조에서 질소제거를 위한 수처리 공정이 제시되었으며, 이 공정의 ORP값을 모델링하고 동정하기 위해 서로 다른 후반부 다항식을 가진 퍼지시스템이 소개되었다. 퍼지모델링 결과를 비교하고 분석하며 또한 제안된 방법에 의해 비선형 공정이 합리적이고 효율적으로 모델링 될 수 있음을 본 논문에서 보인다.

침출액을 이용한 지렁이 퇴비화지표 설정에 관한 연구 (A study on Establishment of Vermicomposting Index Using Leakage Water)

  • 이창호;김종오;최석순
    • 유기물자원화
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    • 제15권1호
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    • pp.178-184
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    • 2007
  • 분변토 처리의 기계화 및 자동화 공정 개발을 위하여, 본 연구에서는 슬러지 침출액을 이용한 지렁이 퇴비화 지표에 대하여 고찰하였다. 이 연구에서는 회분식 및 연속식 실험을 위하여 현장 하수 슬러지가 사용되었다. 슬러지 처리방버버에 따른, 발생되는 침출수의 이화학적 특성 변화는 거의 유사함을 나타내었다. 그러나, 산화환원전위, pH, 전기전도도, $NH_3-N$ 항목에서는 퇴비화 전후, 분명한 차이를 보였다. 또한, 지렁이 퇴비화 지표 설정에 가장 적합한 변수들은 ORP과EC임을 알 수 있었다. 이러한 연구 결과들은 실제적으로 분변토 처리가 이루어지는 지렁이 퇴비하 기술로 사용될 수 있을 것이다.

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효모를 사용한 친환경 인디고 염색: 알칼리수용액 종류에 따른 환원력 (Eco-friendly Indigo Dyeing using Baker's Yeast: Reducing Power according to Alkaline Solution Type)

  • 손경희;신윤숙
    • 한국염색가공학회지
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    • 제31권4호
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    • pp.249-257
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    • 2019
  • Baker's yeast(Saccharomyces cerevisiae) was used as a biocatalyst for eco-friendly indigo dyeing and the reducing power of yeast according to the alkaline solution type was compared. NaOH solution, lye, and buffer solution were used as alkaline solutions. The reducing power(K/S value, oxidation/reduction potential(ORP), pH) was monitored according to the elapsed time including the initiation of reduction, peak reduction, and the end of reduction. In all alkaline solutions, it was confirmed that yeast can be used reducing agent in indigo reduction dyeing. The pH stability and reducing power of buffer solution was better than that of NaOH alone. Although, pH and ORP stability of the reduction bath in lye were better than that of buffer solution, K/S value in buffer solution was higher compared to lye. The reducing power was different depending on the starting pH of the dye bath, and it was better when starting at pH 10.70 than at pH 11.30. Fastnesses to washing, rubbing, and light were relatively good with above rating 4. There was no significant difference in colorfastness depending on the type of alkaline solutions.

식품 폐기물을 이용한 친환경 생촉매의 발굴과 인디고 환원에 응용 (Utilization of Food Waste Extract as an Eco-friendly Biocatalyst for Indigo Reduction)

  • 손경희;류동일;신윤숙
    • 한국염색가공학회지
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    • 제32권4호
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    • pp.193-198
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    • 2020
  • In this study, the validity of extracts from food waste as biocatalyst for indigo reduction was examined. Dried food wastes such as apple peel and corn waste were water-extracted and freeze-dried. The reducing power of extracts for indigo was evaluated by the oxidation-reduction potential(ORP) measurement of reduction bath and color strength(K/S value) of the fabrics dyed in the indigo reduction bath. Total sugar contents of the apple peel and corn waste extracts were 60.56% and 62.36%, respectively. Antioxidant activity was 64.78% for the extract of apple peel and 7.96% for the extract of corn waste. Indigo reduction took place quickly with both extracts, and maximum color strength was obtained up to 15.91 and 12.11 within 1-3 days, respectively. The oxidation-reduction potential of reduction bath was stabilized in the range of -500 ~ -620 mV according to the kinds of food waste and the extract concentration. At higher concentration of the extracts, reduction power was maintained for longer time and stronger color strength was obtained. Compared to sodium dithionite, the reducing power of the studied extracts was lower, but the reduction stability was superior to it. The studied extracts were effective biocatalyst as biodegradable and safe alternatives to sodium dithionite for indigo reduction.

연속회분식 반응기(Sequencing Batch Reactor)를 이용한 분뇨중 유기물과 질소 및 인의 동시제거 (Removal of Simultaneously Biological Organic, Nitrogen, and Phosphorus Removal in Sequencing Batch Reactors using Night-soil)

  • 한기백;박동근
    • 한국환경과학회지
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    • 제6권6호
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    • pp.697-709
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    • 1997
  • Sequencing Batch Reactor(SBR) experiments for organics and nutrients removal have been conducted to find an optimum anaerobic/anoxic/aerobic cycling time and evaluate the applicability of oxidation-reduction potential(ORP) as a process control parameter. In this study, a 61 bench-scale plant was used and fed with night-soil wastewater in K city which contained TCODcr : 10, 680 mg/l, TBm : 6, 893 mg/l, $NH_4^+-N$ : 1, 609 mg/l, $PO_4^{3-}-P$ : 602 mg/l on average. The cycling time In SBRs was adjusted at 12 hours and 24 hours, and then certainly included anaerobic, aerobic and inoxic conditions. Also, for each cycling time, we performed 3 series of experiment simultaneously which was set up 10 days, 20 days and 30 days as SRT From the experimental results, the optimum cycling time for biological nutrient removal with nlght-soil wastewater was respctively 3hrs, 5hrs, 3hrs(anaerobic-aerobic-anoxic), Nitrogen removal efficiency was 77.9%, 77.9%, 81.7% for each SRT, respectively. When external carbon source was fed in the anoxic phase, ORP-bending point indicating nitrate break point appeared clearly and nitrogen removal efficiency increased as 96.5%, 97.1%, 98.9%. Phosphate removal efficiency was 59.8%, 64.571, 68.6% for each SRT. Also, we finded the applicability of ORP as a process control parameter in SBRs.

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해조소금의 성분 특성에 관한 연구 (Characteristics of Seaweed Salts Prepared with Various Seaweeds)

  • 김동한;임종환;이상복
    • 한국식품과학회지
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    • 제35권1호
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    • pp.62-66
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    • 2003
  • 해조류와 소금물을 이용하여 해조소금을 제조하고 이화학적 특성과 무기성분을 비교하였다. 해조소금 제조에 사용한 해조류의 회분함량은 미역이 22.78%로 많았고 김이 9.81%로 적었으나 무기성분으로 미역은 Na함량이 많은 반면 다시마와 톳은 K와 Ca가 많았다. 건조만 한 소금을 회화시켜 물불용해성분을 제거하면 소금의 순도가 증가하여 색이 밝아졌으며 pH와 ORP가 저하하였고, K와 Ca함량은 증가하나 Mg가 감소하였다. 해조소금의 수율은 미역소금에서 높았고 ORP는 다시마와 톳소금에서 낮았으며, K와 Ca함량은 미역소금에 비하여 다시마와 톳소금이 현저히 많았다. 해조소금 제조시 소금물의 농도가 증가하면 소금의 수율과 순도는 증가하나 pH는 저하하였고, ORP와 Ca, Mg함량이 증가하였다. 해조소금을 SEM에 의해 표면관찰 한 바 소금의 외형이 작고 특징적인 결정구조를 보였다.

소규모 현장 오수처리시설의 유지관리를 위한 Monitoring System 개발 (Development of the Monitoring System for maintaining On-site Wastewater Treatment Plants)

  • 조영현;권순국
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 2001년도 학술발표회 발표논문집
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    • pp.417-420
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    • 2001
  • The monitoring system for maintaining on-site wastewater treatment plants(Biofilter) was developed. Proposed system applied PLC(Programmable Logic Controller) technique. In process of development, the research against the monitoring parameters which will be able to represent condition and operation of the plants was accomplished. These parameters are ORP(Oxidation-Reduction Potential), Water Level, Pump and Power on/off. Also, to measure, collect, transfer and display these parameters, DMU(Data Measurement Unit), MCU(Main Controller Unit) and Display Board were produced.

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폐광산주변 토양의 환경영향해석을 위한 수학적 접근 (Mathematical Approach for Environmental Impact Analysis of Soils from Abandoned Mines)

  • 김광태;강미아
    • 지질공학
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    • 제18권3호
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    • pp.297-302
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    • 2008
  • 폐광산 인근의 토양과 광미에서 발생하는 오염원은 중금속과 강산성의 배수가 주요한 원인물질이다. 이러한 오염원들은 인근의 토양까지 오염이 확산되어 결국 사람에게 건강상 유해성을 나타낸다. 본 연구에서는 중금속 오염이 심각한 폐광산을 대상으로 이들의 관리를 최적화하기 위해 요구되는 중금속 오염수준예측을 위한 수학적 접근방법을 시도하였다. 이를 위해 폐광산으로부터의 거리와, pH 및 산화환원전위(ORP)의 경시변화를 조사하여 이들의 상관성을 방정식으로 도출하였다. 대상으로 한 폐광산에 따라 다소의 차이는 보였으나, 60일간의 실험기간동안 변화되는 pH와 ORP는 초기의 pH와 ORP를 기준으로 할 때, 변화율이 $0.95{\sim}1.03$의 범위로 나타났다. 이것은 초기의 pH와 ORP를 기초로 폐광산 인근의 토양에서 발생하는 중금속류의 용출정도를 예측하여 환경영향평가를 실시할 수 있음을 시사하며, 이러한 접근방법은 다른 폐광산에도 적용할 수 있으므로 제거 또는 제어 대상인 중금속류의 관리에 유용하게 사용될 것으로 기대한다.

Evaluation of Electrolyzed Oxidizing Water as a Control Agent of Cucumber Powdery Mildew

  • Lee, Yong-Hwan;Cha, Kwang-Hong;Ko, Sook-Ju;Park, In-Jin;Park, Boung-In;Seong, Ki-Young
    • The Plant Pathology Journal
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    • 제16권4호
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    • pp.206-210
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    • 2000
  • The effect of the electrolyzed oxidizing water on Sphaerotheca fuliginea was investigated with germination and sporulation of the fungal conidia. The sporulation was inhibited by the electrolyzed oxidizing water of pH 2.5, 3.5, and 4.5, but was not inhibited by the distilled water adjusted pH with 1N-HCL solution. However, the electrolyzed oxidizing water did not affect conidial germination. The oxidation-reduction potential at pH 2.5 and pH 3.5 of electrolyzed oxidizing water were 1130 mV and 1060 mV, respectively, but those of distilled water adjusted with HCL solution were 550 mV and 490 mV, respectively. When the electrolyzed oxidizing water of ORP over 1100 mV was sprayed on cucumplanting, the disease severities of powdery mildew were about 8.5% and 19.2%, respectively. Disease severity of a standard control (triflumizole 30% WP, $500\textrm{mg}\textrm{/L}$) was about 3.0%, while that of plants without electrolyzed oxidizing water was to 45.8%.

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