• 한국자기학회지
• /
• 제19권5호
• /
• pp.171-175
• /
• 2009

Ir(001) 표면 위에 얹혀진 철 단층의 자성을 제일원리 전자구조 계산방법을 이용하여 이론적으로 탐구하였다. 비교를 위하여 Fe와 Ir이 규칙적으로 반반 섞인 위층에 대하여도 계산하였다. 모두 Fe로 이루어진 단층의 경우 철원자의 자기모멘트는 2.95 보어마그네톤으로 비교적 큰 값을 가졌으며, Fe와 Ir이 반반 섞인 위층에서 Fe의 자기모멘트는 2.83 보어마그네톤이었다. 이러한 자성과 전자구조의 자세한 면은 계산된 상태밀도와 스핀밀도를 통하여 논의한다. 각 위층 원자의 평형위치를 구하기 위해 총에너지와 원자힘 계산을 하였다. 그 결과 Fe 위층에서의 Fe 원자위치가 Fe와 Ir이 반반 섞인 위층의 Fe 위치보다 Ir 기판에 다소 가까웠다.

• 한국자기학회지
• /
• 제7권6호
• /
• pp.308-313
• /
• 1997

조성과 강자성 상하지층이 CoFe-Ag 나노입상 합금박막의 거대자기저항과 포화자기장에 미치는 효과에 대하여 연구하였다. 3000 .angs. 두께의 ( $Co_{92}$Fe$_{8}$)$_{31}$Ag$_{69}$ 합금박막에서 최대 자기저항 25.7%를 얻었고, 그 때 포화자장은 2.1 kOe 이었다. 100 .angs. 두께의 박막은 자기저항비가 1.2%이고 포화자장은 5.2 kOe 이었다. 200 .angs. 두께의 합금 박막에 100 .angs. Fe를 상하지층으로 증착하였을 때 자기저항은 9.5 %dptj 11 %로 증가하였고 포화자기장은 2.8 kOe에서 1.8 kOe로 개선되었다. 300 .angs. 이하의 합금박막에 강자성 상하지층의 피복은 교환결합에 의하여 합금박막의 포화자기장을 감소시키는 효과가 있었다. 강자성 상하지층에 의한 자기저항의 증가는 표면에서의 전도전자의 스핀 전도산란의 감소와 계면저항에 의한 전류새흐름의 감소로 기인되는 것으로 보인다. 자기저항의 증가 효과는 합금박막의 두께가 약 300 .angs. 이하에서 나타났다. 교환결합 강자성체인 NiFe 그리고 Fe 중에서 Fe가 교환결합에 의한 포화자기장 감소에 좀더 효과적이었다.

• 공업화학
• /
• 제10권8호
• /
• pp.1109-1113
• /
• 1999

함침법에 의하여 제조된 $Pt/MoO_3$와 $Pt/MoO_3/SiO_2$ 및 $Pt^{\circ}$와 $MoO_3$를 기계적으로 혼합한 촉매를 사용한 $50^{\circ}C$ 등온 환원 실험에서 소성 온도가 증가할수록, $H_2$ spillover에 의하여 Pt로부터 $MoO_3$로 이동하여 저장되는 $H_2$가 증가하는 것을 측정하였다. 연속적으로 실행한 CO chemisorption에 의하여 $H_2$ spillover에 참가하는 $H_2$에 노출된 Pt 표면적이 감소하는 것을 알 수 있었다. 또한, TEM 결과로부터 $400^{\circ}C$에서 소성 후 Pt결정 표면에 $MoO_x$ overlayer가 형성되는 것을 관찰하였다. 그러므로, 표면 형상 변화에 따른 Pt과 $MoO_3$간의 활성접촉점 증가가 $H_2$ spillover에 의한 $MoO_3$로의 $H_2$ 이동을 증가시키는 원인 중의 하나인 것으로 판명된다.

• E2M - 전기 전자와 첨단 소재
• /
• 제11권10호
• /
• pp.72-77
• /
• 1998

The effects of Al micro-bumps on the magnetic properties of CoCr(Pt)Ta/Cr films deposited on glass substrates were investigated. The coercivity increased and the coercivity squareness decreased by incorporating Cr/Al underlayers. The cause of the coercivity increase is attributed to the reduction of Co(0002) texture, the increase of magnetic isolation of CoCr(Pt)/Ta grains, and the refinement of CoCr(Pt)/Ta grains deposited on Cr/Al underlayers. The effects of an Al overlayer on the magnetic properties of CoCr(Pt)Ta/Cr films were also studied. The decrease of coercivity squareness is ascribed to the magnetic isolation of CoCr(Pt)Ta grains.

• Journal of Korean Vacuum Science & Technology
• /
• 제3권2호
• /
• pp.139-144
• /
• 1999

Hydrogen concentration depth profiles in homoepitaxial Si(001) films grown from hyper-thermal Si beams generated by ultrahigh vacuum (UHV) ion-beam sputtering have been measured by nuclear reaction analyses as a function of film growth temperature and deposition rate. Bulk H concentrations CH in the crystalline Si layers were found tio be below detection limits, 1${\times}$1019cm-3, with no indication of significant H surface segregation at the crystalline/amorphous interface region. This is quite different than the case for growth by molecular-beam epitaxy (MBE) where strong surface segregation was observed for similar deposition conditions with average CH values of 1${\times}$1020cm-3 in the amorphous overlayer. The markedly decreased H concentrations in the present experiments are due primarily to hydrogen desorption by incident hyperthermal Si atoms. Reduced H surface coverages during growth combined with collisionally-induced filling of interisland trenches and enhanced interlayer mass transport provide an increase in critical epitaxial thicknesses by up to an order of magnitude over previous MBE results.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2011년도 제40회 동계학술대회 초록집
• /
• pp.61-61
• /
• 2011

Using ab initio calculations, we study the MgO(001) and Fe/MgO(001) surface phases and the effects of interface structure on the Fe/MgO magnetic anisotropy. The surface phase diagrams of MgO(001) and Fe/MgO(001) show that the most stable surface structures are either defect-free surface or the surfaces with oxygen vacancies in c($2{\times}1$) periodicity for the systems. By the formations of the oxygen vacancy rows on MgO(001) surface, the in-plane magnetic anisotropy energy of Fe overlayer is reduced while the perpendicular magnetic anisotropy energy is increased from 0.1 to 0.5 meV per Fe atom.

• Journal of Magnetics
• /
• 제1권1호
• /
• pp.9-13
• /
• 1996

The effects of surface relaxation on surface and interface magnetism in Fe/Cr (001) are investigated using the highly precise all-electron total-energy full-potential linearized augmented plane wave method. The Fe-Cr interlayer spacing is deter-mined by total-energy calculation and it is found to be relaxed downward by 18%. For the relaxed system, the magnetic moment of surface Fe is highly suppressed to be $1.72\mu_B$compared to the unrelaxed case ($2.39\mu_B$). This reduction of magnetic moment is considered as a result of the enhanced hybridization between Fe-d and Cr-d states, which can be seen from the calculated density of states. This work suggests the importance of effect of relaxation to the surface and interface magnetism in Fe/Cr system.

• Journal of Welding and Joining
• /
• 제18권6호
• /
• pp.68-73
• /
• 2000

In case of overalyered wrapping roll, beadmark shape appear at wrapping roll surface due to irregular wear between weld bead. Irregular wear of this is caused by difference of hardness between weld bead. This study aims at investigating which matrix is good for removing of beadmark at wrapping roll surface. So, we make specimen with martensitic matrix and austenitic matrix. The overlayered alloys were deposited 4 times on a SS41 steel plate using self-shielding flux cored arc welding method. Difference of hardness between weld bead of specimen with matrix of martensite was higher than specimen with matrix of austenite both as-welded and after heat treatment. Therefore, austenitic matrix is between than martensitic matrix for removing of beadmark of wrapping roll surface.

• Journal of Magnetics
• /
• 제4권4호
• /
• pp.107-110
• /
• 1999

In order to investigate the magnetism of Ru submonolayer on Pb(001), we have performed first-principles calculations for half-layer of Ru on Pd(001) using the full-potential linearzed augmented plane wave (FLAPW) method. We have found that the magnetic moment of Ru for 0.5 layer is 2.21 B. It is found that substrate Pd layers are polarized by the 0.5 Ru overlayer to have significant magnetic moments. Our results are compared with those obtained by the anomalous Hall effect. The calculated electronic structures, i,e., the spin densities and density of states are presented and discussed in relation with magnetic properties.

• Bulletin of the Korean Chemical Society
• /
• 제20권7호
• /
• pp.786-790
• /
• 1999

Relatively inert surface of microcrystalline MgO was modified into chemically active one by carrying out controlled hydration followed by dehydration at elevated temperature under dynamic vacuum. Even though the treatment by the first cycle of hydration-dehydration did not alter the porosity of MgO, it largely enhanced surface reactivity of the MgO toward adsorbed water, turning its outer layer into brucite upon rehydration. Treatment by the second cycle of hydration-dehydration generated micropores, and slit-shaped mesopores, raising the porosity of the MgO. The overlayer of Fe2O3 of the core/shell type composite magnesium oxide enhanced this surface modification, turning its surface into more porous and more active one than that of uncoated MgO, after the treatment by the hydration-dehydration.