• Title/Summary/Keyword: Overall Equilibrium

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Solvent Extraction of Cu(II) by 2,4-Heptadione in Chloroform (2, 4-Heptadione에 의한 Cu(II)의 용매추출특성)

  • Shin, Jeong-Ho;Jeong, Kap-Seop;Lee, Sang-Hoon;Park, Sang-Wook;Park, Dae-Weon
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.672-682
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    • 1993
  • 2, 4-Heptadione(abbreviated to 24HTD) was synthesized from methylpropyl ketone and ethyl acetate with sodium amide, and the equilibrium and the kinetic characteristics of copper extraction by 24HTD-chloroform were investigated. Equilibrium constants such as the dissociation constant and the distribution coefficient of 24HTD and the stability constant of the 24HTD-Cu chelate were evaluated from the spectrophotometry, and the overall equilibrium constant of the extraction was also determined. The extracted species of the 24HTD-Cu chelate was found to be $CuR_2$ and the initial rate of the extraction of coupper by 24HTD in chloroform was expressed by $R_0=k[\bar{HR}]([Cu^{2+}]/[H^+])^{0.5}$.

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An Empirical Study on Mutual Influence between Economic Index and Distribution Industry in Korean (한국 유통산업이 한국 경제에 미치는 상호영향력에 관한 실증적 연구)

  • YIM, Byung-Jin
    • The Journal of Industrial Distribution & Business
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    • v.10 no.9
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    • pp.53-60
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    • 2019
  • Purpose - The objective of this paper is to discover if there exists a relationship between the economic index and distribution industry index in Korean. Because of the distribution industry boom in the recent years, a lot of interest in the relationship between the economic index and distribution industry index in Korean and the economy has been generated. This article examine on the mutual influence between economic index and distribution industry index in Korean. Research design, data, and methodology - For this purpose, we use the vector-auto regression model, impulse response function and variance decomposition of the economic index and distribution industry index, Granger causality test using weekly data on the economic index and distribution industry price index in korea. The sample period is covering from January 2, 2010 to August 31, 2019. The VAR model can also be linked to cointegration analysis. Cointegration Analysis makes possible to find a mechanism causing x and y to move around a long-run equilibrium (Engle and Granger, 1987). This equilibrium means that external shocks may separate the series temporarily at any particular time, but there will be an overall tendency towards some type of long-run equilibrium. If variables are found to have this tendency they are said to be cointegrated and a long-run relationship between these series is established. These econometric tools have been applied widely into economics and business areas to analyze intertemporal linkages between different time series. Results - This research showed following main results. First, from the basic statistic analysis of the economic index and distribution industry index in Korean, the economic index and the distribution industry index in korea have unit roots. Second, there is at least one cointegration between the economic index and distribution industry index in Korean. Finally, the correlation between of the economic index and the distribution industry index in korea is (+) 0.528876. Conclusions - We find that the distribution industry price index Granger cause the economic index in korea. As a consequence, the distribution industry index affect the economic index in Korean. The distribution industry index to the economic index is stronger than that from the economic index to the distribution industry index.

Impact Assessments of High Oil Prices on the Agro-Food System and the Role of Bioenergy Crops

  • Lee, Duu-Hwa;Lin, Hsin-Chun;Chang, Ching-Cheng;Hsu, Shih-Hsun;Chen, Chi-Chun;Sun, Jenny Chin-Hwa
    • Environmental and Resource Economics Review
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    • v.16 no.3
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    • pp.653-682
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    • 2007
  • In this study, multi-sectoral partial equilibrium and computable general equilibrium models of Taiwan are used to investigate the direct and indirect effects of energy price increases on overall economies and agro-food sector in Taiwan. The results suggest that agricultural prices, production cost would increase between 0.27% to 1.88%, and a reduction in GDP around 0.39% to 0.54 %. The negative impact on livestock sector is slightly higher than that on the crop sector. Negative impacts are also observed in the employment and wages. The rising oil price has the potential to discourage production of energy-intensive activity because of the possibility of substitution and adaptations. The growth rate of real GDP will shrink by 0.64% to 1.06% and CPI will increase by 1.17% to 1,95%. Both the agriculture and non-agricultural sector also respond by raising output prices by 0.80% to 1.33%. The rising international oil price has urged the government to take policy actions like using alternative fuels such as biodiesel, bioethanol, and adopting measures to cut down on energy consumptions mainly in transportation sectors in response to public concern over economic shocks.

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Structural assessment of the tetramerization domain and DNA-binding domain of CP2c

  • Jo, Ku-Sung;Ryu, Ki-Sung;Yu, Hee-Wan;Lee, Seu-Na;Kim, Ji-Hun;Kim, Eun-Hee;Wang, Chae-Yeon;Kim, Chan-Gil;Kim, Chul Geun;Won, Hyung-Sik
    • Journal of the Korean Magnetic Resonance Society
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    • v.22 no.4
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    • pp.119-124
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    • 2018
  • Although the transcription factor CP2c has been recently validated as a promising target for development of novel anticancer therapy, its structure has not been solved yet. In the present study, the purified recombinant protein corresponding to the tetramerization domain of CP2c appeared to be well folded, whereas the Elf-1 domain showed a largely unfolded conformation. Particularly, the Elf-1 domain, which contains the putative DNA-binding region, showed a conformational equilibrium between relatively less-ordered and well-ordered conformers. Interestingly, addition of zinc shifted the equilibrium to the relatively more structured conformer, whereas zinc binding decreased the overall stability of the protein, leading to a promoted precipitation. Likewise, a dodecapeptide that has been suggested to bind to the Elf-1 domain also appeared to shift the conformational equilibrium and to destabilize the protein. These results constitute the first structural characterization of the CP2c domains and newly suggest that zinc ion might be involved in the conformational regulation of the protein.

An Efficient Game Theory-Based Power Control Algorithm for D2D Communication in 5G Networks

  • Saif, Abdu;Noordin, Kamarul Ariffin bin;Dimyati, Kaharudin;Shah, Nor Shahida Mohd;Al-Gumaei, Yousef Ali;Abdullah, Qazwan;Alezabi, Kamal Ali
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.15 no.7
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    • pp.2631-2649
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    • 2021
  • Device-to-Device (D2D) communication is one of the enabling technologies for 5G networks that support proximity-based service (ProSe) for wireless network communications. This paper proposes a power control algorithm based on the Nash equilibrium and game theory to eliminate the interference between the cellular user device and D2D links. This leadsto reliable connectivity with minimal power consumption in wireless communication. The power control in D2D is modeled as a non-cooperative game. Each device is allowed to independently select and transmit its power to maximize (or minimize) user utility. The aim is to guide user devices to converge with the Nash equilibrium by establishing connectivity with network resources. The proposed algorithm with pricing factors is used for power consumption and reduces overall interference of D2Ds communication. The proposed algorithm is evaluated in terms of the energy efficiency of the average power consumption, the number of D2D communication, and the number of iterations. Besides, the algorithm has a relatively fast convergence with the Nash Equilibrium rate. It guarantees that the user devices can achieve their required Quality of Service (QoS) by adjusting the residual cost coefficient and residual energy factor. Simulation results show that the power control shows a significant reduction in power consumption that has been achieved by approximately 20% compared with algorithms in [11].

Horizontal 2-D Finite Element Model for Analysis of Mixing Transport of Heat Pollutant (열오염 혼합 거동 해석을 위한 수평 2차원 유한요소모형)

  • Seo, Il Won;Choi, Hwang Jeong;Song, Chang Geun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.6B
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    • pp.507-514
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    • 2011
  • A numerical model has been developed by employing a finite element method to simulate the depth-averaged 2-D dispersion of the heat pollutant, which is an important pollutant material in natural streams. Among the finite element methods, the Streamline Upwind/Petrov Galerkin (SUPG) method was applied. Also both linear and quadratic elements can be applied so that irregular river boundaries can be easily represented. To show the movement of heat pollutants, the reaction term describing heat transfer was represented as an equation in which sink/source term is proportional to the difference between the equilibrium temperature and water surface temperature. The equation was expressed so that the water surface temperature changes according to the temperature transfer coefficient and the equilibrium temperature. For the calibration of the model developed, analytic and numerical results from a case of rectangular channel with full width continuous injection have been compared in a steady state. The comparisons showed that the numerical results were in good agreement with analytical solutions. The application site was selected from the downstream of Paldang dam to Jamsil submerged weir, and overall length of this site is about 22.5 km. The change of water temperature caused by the discharge from the Guri sewage treatment plant has been simulated, and results were similar to the observed data. Overall it is concluded that the developed model can represent the water temperature changes due to heat transport accurately. But the verification using observed data will further enhance the validity of the model.

Analysis of Performance Characteristics by Inner Flow Path of Side Channel Type Ring Blower (사이드 채널형 링블로워의 임펠러 내부 유로에 따른 성능변화 분석)

  • Lee, Kyoung-Yong;Choi, Young-Seok;Jeong, Kyung-Ho;Park, Woon-Jean
    • The KSFM Journal of Fluid Machinery
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    • v.15 no.4
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    • pp.67-71
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    • 2012
  • This study analyzed performance changes by an inner flow path of impeller groove for side channel type ring blower using CFD. Two models have the same side channel and clearance while one has an inner flow path and the other doesn't. To analyze the performance change of a ring blower, overall performance and local flow field were analyzed. For the overall performance, pressure increase and impeller torque were checked under the design flow condition. Under the design flow condition, pressure increase was greater for the model with the inner flow path. The model with the inner flow path showed improved efficiency because the area subject to torque decreased due to the creation of inner flow path. To analyze local flow field, a section was created from the representative location of each impeller groove toward the direction of radius. Inner channel pressure distribution depending on the rotation direction shows that the model with the inner flow path has pressure equilibrium of working fluid through the inner flow path. Velocity distribution of inside impeller groove shows that flow field was coupled and appeared to form an inner wall where the flow field was stabilized.

Determination of hey Fuel Ratio According to Fuel Composition (IV) - Overall Estimation of Methods- (연료 조성에 따른 공연비 산정 (IV) - 공연비 계산방식의 평가-)

  • Park Chanjun;Ohm Inyong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.10
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    • pp.1155-1162
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    • 2004
  • This paper is the forth paper of several companion papers which compare the method of Air-Fuel ratio determination. In the previous work, various AFR calculations were performed for various fuels and the results were compared with each other. The comparison, however, were limited to numerical value and estimation of each equation or method was insufficient. In this paper, the overall estimation of the methods was attempted. Also, the method of trouble shooting of instrumentation was presented. Through the estimation of methods, it is concluded that the Eltinge method contains inherently the most perfect thermal dissociation model as far as the exhaust composition is concerned; therefore, this might be regarded as the most general equation of AFR determination among the existing ones. The others might be considered as approximate form. In addition, the mal-distribution factor in Eltinge method is qualitatively equivalent to thermal dissociation chemical equilibrium constant K. Lastly, it is illustrated that all instrumentation error, including the sampling line leakage, can be easily detected through the analyzing the exhaust component on the Eltinge chart.

A Study on the Curing Bladder Shaping of Tire by Finite Element Method Using Contact Element (접촉요소를 이용한 유한요소법에 의한 타이어 가류브레더 팽창거동에 관한 연구)

  • Kim, Hang-Woo;Hwang, Gab-Woon;Cho, Kyu-Zong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.3
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    • pp.378-384
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    • 1997
  • In curing process of tire, contact and slip occurs between green tire and curing bladder. The curing process is a critical step in the manufacture of tires. In this investigation, curing bladder shaping is examined using a finite element method. Specifically, a finite element model between the inner part of green tire and the outer part of curing bladder is generated using contact element and curing bladder is generated using incompressible element. Numerical analysis are performed on two different bladder types, different overall outer diameters of curing bladder and different heights of curing bladder. Numerical results show that contact pressure is increased by using toroidal type of curing bladder, increasing overall diameter and increasing height of curing bladder. To obtain natural equilibrium carcass line, there is a requirement in increasing contact pressure of the section between side and bead.

A study on the Average Factor of Safety in Slope Stability Being Applied to Wedge theory (Wedge 이론을 적용한 사면안정해석의 평균 안전율에 관한 연구)

  • 김경진
    • Journal of the Korean Professional Engineers Association
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    • v.19 no.1
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    • pp.3-11
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    • 1986
  • The analysis of Geotechnical stability problems by the limit equilibrium method involve assuming the shape of the failure and then investigating many surfaces of the shape to identify the one on which failure seems most likely to occur. These arbitrary assumptions most frequently concern to the locations or directions of side force on slice and the overall factor of safety is considered identical to the local factor of safety. In this paper, let the factor of safety of a slope at wedge block stage differently, when an upper part of the potential sliding mass has a simple active stress field and the lower part of the passive stress field and overall factor of safety is obtained by the average of local factor and computer program based on the modified wedge Method is proposed for this thesis. The new algorithm based on tile modified new method is made for estimating the safety factor of Earth Dam. Compared with conventional method for many cases tile average values of the factor of safety determined by the modified new method are very nearly the same. For all of the cases studied the difference was found 0.03. Finally this new method is thought to be very useful in slope stability analysis.

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