• Title/Summary/Keyword: Out-diffusion

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An Equilibrium Diffusion Model of Demand and Supply of New Product and Empirical Analysis (신기술 제품의 확산에 관한 수요$\cdot$공급의 균형확산모형과 실증분석)

  • Ha, Tae-Jeong
    • Journal of Technology Innovation
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    • v.13 no.1
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    • pp.113-139
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    • 2005
  • The purpose of this study is to analyse the diffusion process of personal computer (PC) in Korea during the 1990's. To achieve the goal, five research steps have been done such as the literature survey of diffusion theory, set-up of theoretic equilibrium model of supply and demand, derivation of an equilibrium path using Hamiltonian, and empirical analysis. The empirical analysis has been performed based on that equilibrium path. The results can be summarized as follows : First, technological attribute of diffusing product influences the diffusion speed of Product. It has been proven that the size of the network has a significant effect on the diffusion of PC in empirical study Second, supply factors have an important role in the diffusion process. According to the empirical analysis, decreasing cost of production as a result of technological advance promotes the speed of diffusion. This point seems to be manifest theoretically, but existing empirical models have not included supply factors explicitly, Third, it has been found out that expectation of decreasing cost would influence the speed of diffusion negatively as expected ex ante. Theoretically this result is supported by arbitrage condition of purchasing timing.

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Water Diffusion and Resaturation in Unsaturated Compacted Bentonite (불포화 압축 벤토나이트에서의 수확산 및 재포화)

  • 고은옥;이재완;조원진;현재혁;전관식
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1998.11a
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    • pp.216-220
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    • 1998
  • Experimental studies were carried out to investigate water diffusion in unsaturated compacted bentonite for a landfill of hazardous wastes. Water content distributions were measured and water diffusion coefficients were determined when the dry densities of compacted bentonite were in the range of 1.4 - 1.8 g/㎤. Resaturation times were also calculated to analyze the ability of the compacted bentonite to retard water movement. The results obtained were as follows: Diffusion model described properly the water migration in unsaturated compacted bentonite. Water diffusion coefficients ranged from 4.30$\times$10$^{-6}$ $\textrm{cm}^2$/sec to 1.93$\times$10$^{-6}$ $\textrm{cm}^2$/sec, and decreased with increasing the dry density. The dry density of compacted bentonite was found to be an important factor to control the resaturation time by water. This study suggests that the domestic compacted bentonite should be a good barrier material against water movement in a landfill of hazardous wastes.

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Fabrication and Interface Properties of TiNi/6061Al Composite (TiNi 형상기억합금을 이용한 복합재료의 제조 및 계면 특성)

  • Kim, Sun-Guk;Lee, Jun-Hui
    • Korean Journal of Materials Research
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    • v.9 no.4
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    • pp.419-427
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    • 1999
  • TiNi shape memory alloy was shape memory heat-treated and investigated its mechanical properties with the variation of prestrain. Also 6061 Al matrix composites with TiNi shape memory alloy fiber as reinforcement have been fabricated by Permanent Mold Casting to investigate the microstructures and interface properties. Yield stress of TiNi wire was the most high in the case of before heat-treatment and then decreased as increasing heat-treatment time. In each heat-treatment condition, the yield stress of TiNi wire was not changed with increasing the amount of prestrain. The interface bonding of TiNi/6061Al composite was fine. There was a 2$\mu\textrm{m}$ thickness of diffusion reaction layer at the interface. We could find out that this diffusion reaction layer was made by the mutual diffusion. The diffusion rate from Al base to TiNi wire was faster than that of reverse diffusion and the amount of the diffusion was also a little more than that of reverse.

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The Effects of Solvents in Reservior Solution on Protein Crystallization Using Vapor Diffusion method (증기확산법에 의한 단백질 결정화에 미치는 Reservicr 용액의 영향)

  • 이정희;정용제
    • Korean Journal of Crystallography
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    • v.5 no.1
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    • pp.33-38
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    • 1994
  • 'Heterogeneous' vapor diffusion experiments were carried out using hen egg white Iysozyme and equine serum albumin as model proteins: droplets were equilibrated against reservoir solutiorls containing an alternative precipitant which is different from results showed that the use of polyethylene glycol as an alternative precipitant instead of NaCl or ammonium sulfate reduces equilibration rate between droplet and reservoir solution. By using the heterogeneous vapor diffusion techniqlue it is possible to control the equilibration rate by adjusting the relative amounts of ionic salts and nonionic yecipitants in reservoir solutions.

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The Penetration and Diffusivity of Chloride ion into Concrete using Blended Cement (혼합계시멘트를 사용한 콘크리트의 염화물이온 침투 및 확산특성)

  • Yang, Seung-Kyu;Kim, Dong-Seuk;Um, Tai-Sun;Lee, Jong-Ryul
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.489-492
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    • 2006
  • A chloride is an important deteriorating factor which governs the durability of the reinforced-concrete structures under marine environments. Also, the main penetration mechanism of chloride ion into concrete is a diffusion phenomenon and numerous methods have been proposed to determine the diffusion coefficient of chloride ion quickly. In this study, electrically accelerated experiments were carried out in order to evaluate diffusion coefficient of the chloride ion into concrete. The methods were diffusion cell test method in which the voltage of 15V(DC) was applied. The type of cement is blended cement in which the admixtures of blast-furnace slag and fly ash were used. In conclusion, the diffusion coefficient of chloride ion is much affected according to mineral admixtures and the diffusion coefficient of ternary blended cement showed very low values. it is presumably said that this result is due to highly densified pore structures by the aid of slag substitution and pozzolanic activity of fly ash.

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Modeling of sulfate ionic diffusion in porous cement based composites: effect of capillary size change

  • Gospodinov, Peter N.
    • Computers and Concrete
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    • v.4 no.2
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    • pp.157-166
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    • 2007
  • The paper considers a theoretical model to study sulfate ion diffusion in saturated porous media - cement based mineral composites, accounting for simultaneous effects, such as filling micro-capillaries (pores) with ions and chemical products and liquid push out of them. Pore volume change and its effect on the distribution of ion concentration within the specimen are investigated. Relations for the distribution of the capillary relative radius and volume within the composite under consideration are found. The numerical algorithm used is further completed to consider capillary size change and the effects accompanying sulfate ion diffusion. Ion distribution within the cross section and volume of specimens fabricated from mineral composites is numerically studied, accounting for the change of material capillary size and volume. Characteristic cases of 2D and 3D diffusion are analyzed. The results found can be used to both assess the sulfate corrosion in saturated systems and predict changes occurring in the pore structure of the composite as a result of sulfate ion diffusion.

Diffusion Coefficient of Iron in ZnSe Polycrystals from Metal Phase for mid-IR Gain Medium Application

  • Jeong, Junwoo;Myoung, NoSoung
    • Applied Science and Convergence Technology
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    • v.23 no.6
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    • pp.371-375
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    • 2014
  • Diffusion coefficient of Fe in polycrystalline host ZnSe as a mid-IR gain medium has been measured in the annealing temperature ranges of 850 to $950^{\circ}C$. The synthesis of the samples was carried out in quartz ampoule in which the Fe thin film deposited by physical vapor evaporation method on the ZnSe. One can realize that the diffusion coefficient strongly depends on the surface active surfactants through the cleaning process and the substrate temperature during the thin film deposition leading to $2.04{\times}10^{-9}cm^2/s$ for $Fe^{2+}:ZnSe$. The Annealing temperature dependence of the Fe ions diffusion in ZnSe was used to evaluate the activation energy, $E_a$=1.39 eV for diffusion and the pre-exponential factor $D_0$ of $13.5cm^2/s$.

A Study on Adoption/Diffusion Models for New Product (신제품 수용$\cdot$확산모형에 관한 연구)

  • 김용준;박영근
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.10 no.16
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    • pp.149-158
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    • 1987
  • The Adoption/Diffusion of Innovations(New Product), a topic of study and research that has frown rapidly in the past few decades, deals with how a new product is adopted in a society. It is of high importance to marketing organizations because New Products must be brought out continuously in order to service. The purpose of this paper is to examine the Adoption/Diffusion Models for New product which will help to analyze the Adoption/Diffusion process of Adopters. There are a number of models that, with varying degrees of success, have been used to predict market acceptance of new product. In this paper, following types of new product Adoption/Diffusion Models was suggested. (1) Adoption Models : The Alternative Models of Adoption. The Rogers Model of the Innovation Decision Process. (2) Diffusion Models : First Purchase Models(Basic Models, Extension of the Basic Models), Repeat Purchase Models

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Diffusion Controlled Alkylation of Aromatic Compounds in Cation-Exchanged ZSM-5 Zeolites

  • Chon, Hak-Ze;Lee, Kyung-Yul;Park, Dong-Ho;Ahn, Byoung-Joon
    • Bulletin of the Korean Chemical Society
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    • v.12 no.6
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    • pp.625-628
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    • 1991
  • Using uniform flat plate-like samples of ZSM-5 zeolites, diffusion coefficients were measured volumetrically for the diffusion of xylene, ethyltoluene and diethylbenzene by direct measurement of sorption rate. Toluene disproportionation over H(100)-, K(72)-and Cs(82)-ZSM-5 at 773 K and toluene methylation, toluene ethylation and ethylbenzene ethylation over Cs(75)-ZSM-5 at 623 K were carried out. The selective formation of para xylene during the toluene disproportionation, presumably due to the increased tortuosity over Cs-ZSM-5, could be explained by smaller diffusion coefficient in Cs-ZSM-5 than in K-and H-ZSM-5. The para selectivity increased in the order; toluene methylation < toluene ethylation < ethylbenzene ethylation. As the chain length of the alkyl substituent in dialkylbenzenes is increased, the para selectivity of the products was improved. It may be attributed to the differences in the ratios of diffusion coefficient of para products to that of ortho ones. Diffusion coefficient of m-xylene was about 1 order of magnitude smaller than that of o-xylene.

The Factors Affecting Breadth and Depth of Diffusion for Knowledge Management Systems (지식관리시스템의 수직적 확산과 수평적 확산에 관한 실증적 연구)

  • Suh, Chang-Kyo;Seol, Jin-Young
    • Knowledge Management Research
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    • v.9 no.3
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    • pp.77-105
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    • 2008
  • This study primarily aims at identifying what factors significantly affect the diffusion of knowledge management systems(KMS) and finding out how these identified factors can be effectively managed, especially for Korean companies. The research model is derived based on previous researches on innovation diffusion, information systems implementation, and KMS. The model is used to examine the role of determinants in influencing the extent to which KMS is diffused within organizations. Independent variables of this research are composed of technical characteristics, organizational characteristics and environmental characteristics. 'Breadth of diffusion' and 'depth of diffusion' concept are used to measure the extent of KMS diffusion which is the dependent variable of this model. The 101 companies of total 1,000 samples responded to the survey. To analyze tile results of this empirical study, we performed the multiple regression analysis. As a result, it was shown that the relative advantage, complexity, information system maturity, size, top management support, champion, competitive pressure have influences on both the breadth and the depth diffusions. On the other hand, the organizational culture, valuation and compensation, and uncertainty of environmental factors were not verified to be significant. This empirical study will provide Korean companies with insights into effective ways to diffuse the KMS and succeed in business competition.

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