• Journal of the Korean Chemical Society
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• v.18 no.4
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• pp.297-303
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• 1974

An investigation has been performed to find an effective separation method of steriols and tocopherols from the deodorized condensates of vegetable oils. Simple heating of the starting mixture isolated the oil layer from water, and the former was collected. It was then methyl esterified followed by a distillation for the removal of fatty acid. The ensuing step was to saponify the residue. The unsaponifiable matter was extracted by both methanol and concentrated. The sterol was crystallized by cooling such concentrated solution. To obtain tocopherol, the mother liquor was first dissolved in methanol. Cooling this solution to $-20^{\circ}C$ trapped fatty acid which was filtered out. The filtrate was then treated with ion exchange resin.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.566-567
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• 2006

The characteristics of residual stresses occurring in PM steel based nickel (FLN2-4405) was investigated. The measurements of residual stresses were carried out by electrochemical layer removal technique. The values and distributions of residual stresses occurring in PM steel processed under various densities and heat treatment conditions were determined. In most of the experiments, tensile residual stresses were recorded in surface of samples. The residual stress distribution on the surface of the PM steels is affected by the heat treatment conditions and density. Maximum values of residual stresses on the surface were observed sinter hardened condition and $7.4\;g/cm^3$ density. Minimum level of recorded tensile residual stresses are150 MPa and its maximum level is 370 MPa.

• Laser Solutions
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• v.6 no.3
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• pp.37-45
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• 2003

Pulsed laser ablation is important in a variety of engineering applications involving precise removal of materials in laser micromachining and laser treatment of bio-materials. Particularly, detailed numerical simulation of complex laser ablation phenomena in air, taking the interaction between ablation plume and air into account, is required for many practical applications. In this paper, high-power pulsed laser ablation under atmospheric pressure is studied with emphasis on the vaporization model, especially recondensation ratio over the Knudsen layer. Furthermore, parametric studies are carried out to analyze the effect of laser fluence and background pressure on surface ablation and the dynamics of ablation plume. In the numerical calculation, the temperature, pressure, density, and vaporization flux on a solid substrate are obtained by a heat-transfer computation code based on the enthalpy method. The plume dynamics is calculated considering the effect of mass diffusion into the ambient air and plasma shielding. To verify the computation results, experiments for measuring the propagation of a laser induced shock wave are conducted as well.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.165-165
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• 2013

Nickel oxide was deposited on mesoporous silica by atomic layer deposition (ALD) consisting of sequential exposures to Ni(cp)2 and $H_2O$. NiO/silica samples were characterized by inductively coupled plasma-mass spectroscopy (ICP-MS), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), etc. The flow-type reactor was used to measure activity of NiO/silica catalyst for catalytic combustion of toluene. The activity of NiO/silica catalyst was evaluated in terms of toluene removal efficiency and selectivity to $CO_2$ and compared with those of bare nickel oxide nanoparticles. In order to investigate influence of reaction temperature on combustion aspect, the catalytic combustion experiments were carried out at various temperatures. We show that both bare and supported NiO can be efficient catalysts for total oxidation of toluene at a temperature as low as $250^{\circ}C$.

• Proceedings of the SAREK Conference
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• 2009.06a
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• pp.751-756
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• 2009

In the perspective of saving energy in buildings, the high performance of insulation and air tightness for improving the heating and the cooling efficiency, has brought economically positive effects. However, these building energy saving technologies cause the lack of ventilation, which is the direct cause of increasing the indoor contaminants, and is also very harmful to the residents, because they spend over 90% of their time indoors. Therefore, the ventilation is important to keep the indoor environment clean and it can also save the energy consumption. In this study, a HEPA type nano ceramic filter is designed as a passive ventilation system to collect airborne particles and to supply fresh outdoor air. The double layer filter, which has $30{\mu}m$ in diameter at the conditions of 10wt% of concentration and 3kV/cm of the electric intensity, is produced by electrospinning. The filtration coating technology is confirmed in the solution with $SiO_2$ nano particles using polymer nano fibers. Also double layer filters are coated with $SiO_2$ nano particles and finally the porous construction materials are made by sintering in the electric furnace at $200{\sim}1400^{\circ}C$. The efficiency is measured 96.67% at the particle size of $0.31{\mu}m$, which is slightly lower than HEPA filter. However the efficiency is turned out to be sufficient.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.9 no.1
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• pp.89-99
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• 2006

The growth and biomass of reeds(Phragmites australis) growing in a subsurface treatment wetland system were investigated from April 2003 to October 2003. Nitrogen(N) and phosphorous(P) concentrations in above-ground(AG) and below-ground(BG) tissues of reeds were examined and the removal rate of N and P by reeds were analyzed. The system, 29 m in length, 9 m in width and 0.65 m in depth, was constructed in June 2001 on a floodplain in the down reach of the Kwangju Stream in Korea in order to purify polluted water of the stream. A bottom layer of 45 cm in depth was filled with crushed granites(15~30 mm in diameter) and a middle layer of 10 cm in depth was filled with pea pebbles(10 mm in diameter). An upper layer of 5 cm contained course sand. Reeds were transplanted on the surface of the system, which were dug out of natural wetlands, and their shoots were trimmed 40 cm in height. The height and density of the shoots averaged 237.7 cm and 244.0 shoot/$m^2$, respectively, when the reeds grew fully. The maximum biomass of AG and BG tissues were 1,964 and 1,577 g/$m^2$, respectively, and the AG : BG ratio of biomass was 1.26. Mean AG and BG dry weights were recorded as 1,355 and 748 g/$m^2$, respectively. The AG and BG tissue concentrations of N averaged 12.37 and 10.01 mg/g, respectively, and those of P 2.37 and 2.03 mg/g, respectively. Inflow to the system averaged 40 $m^3$/day. The concentrations of total nitrogen(T-N) in influent and effluent were 8.4 mg/L and 3.2 mg/L, respectively, and those of total phosphorous(T-P) were 0.73 and 0.38 mg/L, respectively. The total removal of T-N and T-P by the system during the investigation period averaged 140.2 and 9.7 g/$m^2$, respectively, and the total uptake of N and P by the reeds were calculated as 24.39 and 4.73 g/$m^2$, respectively. Average removals of about 17% of N and about 49% of P by reeds were recorded. The N and P concentrations in AG tissues were significantly different among the three zones of the system:near to inflow(St1), in the middle of system(St2), and near to outflow(St3). The N and P concentrations in BG tissues were also significantly different among St1, St2 and St3. N and P concentrations in AG and BG tissues of reeds growing in St1 were higher than those in St2 and St3. The height and density of shoots of reeds in St1 were larger than those in St2 and St3. Significant amounts of N and P in the influent were taken up by reeds in St1.

• Journal of Conservation Science
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• v.31 no.4
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• pp.499-506
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• 2015

The artifacts of Admiral Yi Sun-sin (Treasure No.326) consist of six items with two long swords, a jade decoration, a belt and two peach-shaped cups. In commemoration of the opening of Chungmugong Yi sun-sin Memorial Museum (April 28, 2011), there were conservation treatments for those artifacts at the beginning of 2011. At that time, from the result of non-destructive surface analysis on pigments in blood-colored grooves of the two long swords, it was presumed to be synthetic resin paints. This study shows the accurate identification on pigments which was presumed as synthetic resin paints and its removal. To identify pigments in blood-colored grooves, the optical microscope, scanning electron microscope, Micro-XRF, XRD and FT-IR were used for the analysis. The results turned out that the thickness of $10{\sim}90{\mu}m$ in a single layer was measured. And major components containing Pb and Cr and lead chromium molybdenum oxide were identified and to identify components of adhesives from the analysis by FT-IR, it turned out to be alkyd resin, which can be presumed that they were recently colored with synthetic paints. The synthetic paints easily react with most of the organic solvents. And it is so easy to handle without the effect on metal that it was removed with acetone. While removing synthetic paints, all of paints on it were collected for identifying whether there is traditional pigment but nothing was identified.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.1
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• pp.76-83
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• 2013

Polymer electrolyte membrane fuel cells (PEMFCs) are regarded as a promising alternative to replace the existing automotive power sources. To get high performance and long-term durability for PEMFC systems, novel water management is essential. To this end, a comprehensive understanding of dynamics of the liquid water droplets within an operating PEMFC plays an important role. In this work, direct visualization of dynamic behaviors of the water droplet in the ex situ unit flow channel of a PEMFC including gas diffusion layer (GDL) is carried out as one of the fundamental studies for novel water management. Water droplet dynamics such as the movement and growth of liquid water droplets are mainly presented. Effects of GDL characteristics and inlet air flow rate on the water droplet transport and its removal from the flow channel are also discussed. The data obtained in this study can contribute to build up the fundamental operating strategy including balanced water removal capacity for automotive PEMFC systems.

• Korean Journal of Environmental Agriculture
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• v.22 no.4
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• pp.278-283
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• 2003

This study was carried out to examine the nitrogen removal rate of a subsurface-flow treatment wetland system which was constructed on floodplain of the Kwangju River from May to June 2001. Its dimensions were 29m in length, 9m in width and 0.65m in depth. A bottom layer of 45cm in depth was filled with crushed granite with about $15{\sim}30\;mm$ in diameter and a middle layer of 10cm in depth had pea pebbles with about 10 mm in diameter. An upper layer of 5 cm in depth contained course sand. Reeds (Phragmites australis) were transplanted on the surface of the system. They were dug out of natural wetlands and stems were cut at about 40 cm height from their bottom ends. Water of the Kwangju River flowed into it via a pipe by gravity flow and its effluent was funneled back into the river. The height of reed stems was 44.2 cm in July 2001 and 75.3cm in September 2001. The number of stems was increased from $80\;stems/m^2$ in July 2001 to $136\;stems/m^2$ in September 2001. Volume and water quality of inflow and outflow were analyzed from July 2001 through December 2001. Inflow and outflow averaged 40.0 and $39.2\;m^3/day$, respectively. Hydraulic detention time was about 1.5 days. Average nitrogen uptake by reeds was $69.31\;N\;mg/m^2/day$. Removal rate of $NO_3-N$, $NH_3-N$, T-N averaged 195.58, 53.65, and $628.44\;mg/m^2/day$, respectively. Changes of $NO_3-N$ and $NH_3-N$ abatement rates were closely related to those of wetland temperatures. The lower removal rate of nitrogen species compared with that of subsurface-flow wetlands operating in North America could be attributed to the initial stage of the system and inclusion of two cold months into the six-month monitoring period. Increase of standing density of reeds within a few years will develop both root zones suitable for the nitrification of ammonia and surface layer substrates beneficial to the denitrification of nitrates into nitrogen gases, which may lead to increment in the nitrogen retention rate.

• Journal of Conservation Science
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• v.32 no.3
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• pp.377-384
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• 2016

There are physical and chemical method for removement of a lacquered layer existing on the surface when gilding an iron Buddha, these caused environmental pollution by surface degradation and is very noxious for conservation scientist's health. Thus, on this study, we conducted a lacquered layer removement experiments using Nd:YAG Laser which is contactless and eco-friendly. Specimens were made by polishing $5{\times}5$ size of iron(99.9%) specimens surfaces evenly and by differing of number of coating of unrefined lacquer, so there were thickness differences of $10{\mu}m$, $20{\mu}m$, and $30{\mu}m$. The laser machine used in this study was Nd:YAG Laser, and we used two wavelength modes; 1064 nm(160~180 mJ) for infrared light region and 532 nm(50~350 mJ) for ultraviolet light region. The experiment done by investigating the transition of specimens' surfaces with laser wavelength, energy, and numbers of investigation. The remain amount of lacquered layer surfaces before/after laser irradiation was investigated by stereoscopic microscope, observation by SEM, Non-contact Surface Roughness Measurement Device, and FT-IR etc. As a result of each analysis, we could verify the thickness of $10{\mu}m$, $20{\mu}m$ of lacquered layer removed without surface degradation when using 1064 nm wavelength with $1.0J/cm^2$ density. We could find out that Nd:YAG Laser is effective for removing remained lacquered layers when gilding an iron Buddha. In the future, when not only the metal has made various studies also wood lacquered furniture or the like, it seems to be utilized to remove the lacquer without surface damage.