• Polymer(Korea)
• /
• v.37 no.5
• /
• pp.587-591
• /
• 2013

Poly(3,4-ethylenedioxythiophene) (PEDOT) has good properties such as high conductivity, optical transmittance, and chemical stability, while offering relatively weak physicochemical properties. The main purpose of this paper is the improvement of physicochemical properties such as solvent resistance and pencil hardness of PEDOT. Carboxyl groups in the anionic type waterborne polyurethane (WPU) chains can effectively crosslink each other in the presence of aziridine, resulting in physicochemically robust PEDOT/WPU organic-organic hybrid conductive thin films. The electrical conductivity, optical properties, and physicochemical properties of the hybrid conductive film were compared by varying the solid content and WPU portion in the coating precursor solution. From the results, the transparency and surface resistance of the hybrid film show a decreasing tendency with increasing solid content in the coating precursor. Moreover, solvent resistance and hardness were dramatically enhanced by hybridization of PEDOT and crosslinked WPU due to curing reactions between carboxyl groups.

• Journal of Korean Society on Water Environment
• /
• v.29 no.6
• /
• pp.762-776
• /
• 2013

Load duration curve was applied to determine important water quality parameter control term for improvement of Paldang lake water quality. Load duration curve was analyzed with long term data from 1985 to 2012 including water quality, flow rate and climate state of Paldang water environment. From the result of flow rate patterns of paldang lake, differences between high and low flow rate of each year showed tendency of increase because rainfall characteristics of paldang lake watershed were changed by climate exchange. Both of land use state of upper Paldang lake watershed and number of limit excess from load duration curve indicated that seasonal action related with land use such as agricultural fertilizer distribution in upper watershed affected Paldang lake water quality. So focused BOD (biological oxygen demand) management during spring season from march to June is required to control organic materials in Paldand lake. The main affecting factor of TOC (total organic carbon) increase in Paldang lake was initial rainfall after march. T-N (total nitrogen) kept increasing during research period, so enhancement of T-N standard is needed to T-N control. Initial rainfall and increase of temperature during spring season from March to June showed a positive correlation with TP (total phosphorus) and Chl-a, respectively.

• Korean Journal of Organic Agriculture
• /
• v.12 no.4
• /
• pp.411-425
• /
• 2004

The aim of this experiment was to investigate the effects of applying times and dilution rates of cattle slurry with water on dry matter yields and feed values of orchard grass. Cattle slurry was applied at the rates of average nitrogen fertilizer equivalent to 150kg/ha/year in 3 cutting frequency. Significantly higher dry matter yields than that of no fertilization (7.36 ton DM/ha) were recorded in the application of diluted cattle slurry (10.74~13.54 ton DM/ha) (p<0.05). Especially, this tendency was shown with higher annual dry matter yields at the partitioned dressing times, such as at the applications for 1st and 3rd growth, 2nd and 3rd growth, and 1st, 2nd and 3rd growth respectively. The yields of annual dry matter at fertilizing phosphorus, potassium and nitrogen were higher than no fertilization as 12.42 tons per ha. However, with application of diluted cattle slurry, dry matter yields per year (11.96 ton DM/ha) were significantly higher than those of fertilizing phosphorus and potassium (7.52 ton DM/ha) (p<0.05). The efficiencies of dry matter production with mineral and cattle slurry nitrogen application (kg DM/kg N) were 32.7 and 13.4~26.9kg DM/kg N respectively. Especially, these tendencies were higher in diluted application plots than in no-diluted application plots of cattle slurry. The contents of crude protein (CP, %), neutral detergent Eber (NDF, %), acid detergent fiber (ADF, %), annual yields of CP (kg/ha) and total digestible nutrient (TDNY, kg/ha) of orchardgrass were significantly higher at the application of diluted cattle Slurry than those at non-fertilizer application (p<0.05).

• Korean Journal of Soil Science and Fertilizer
• /
• v.48 no.5
• /
• pp.436-441
• /
• 2015

The chemical properties of paddy fields in Gyeonggi province were monitored every 4 years from 1999 to 2015 in order to provide basic information for soil fertility management of paddy fields. In 2015, the soil chemical properties of paddy fields were 5.9 in pH, $23g\;kg^{-1}$ in organic matter (OM), and $84mg\;kg^{-1}$ in available phosphate (Avail. $P_2O_5$). Exchangeable (Exch.) potassium (K), calcium (Ca) and magnesium (Mg) were 0.30, 5.1 and $1.3cmol_ckg^{-1}$, respectively, and available silicate (Avail. $SiO_2$) was $129mg\;kg^{-1}$. In the long-term analysis, the contents of Avail. $SiO_2$, Exch. Ca and pH of paddy soils showed increasing tendency. However, Avail. $P_2O_5$ and Exch. K tended to decrease, and there were no significant changes in the contents of OM and Exch. Mg. Paddy soil within appropriate pH range increased from 44% in 1999 to 76% in 2003, 84% in 2007, 63% in 2011, and 80% in 2015. But soil within appropriate range of Exch. Ca tended to decrease, showing 36% in 1999, 42% in 2003, 38% in 2007, 37% in 2011 and 32% in 2015. In case of Avail. $SiO_2$, soil within appropriate range increased from 14% in 1999 to 17% in 2003, 18% in 2007, 16% in 2011, and 31% in 2015. As a result, paddy fields with less in nutrient level need to be more fertilized based on soil analysis. And the application of silicate fertilizer is strongly recommended to those of paddy fields in need. Also soil management such as the cultivation of green manure crop or application of rice straw will be necessary to increase the organic matter content of paddy soil.

• Journal of Applied Biological Chemistry
• /
• v.64 no.4
• /
• pp.439-446
• /
• 2021

A field-scale study was conducted to evaluate the effect of organic matter amendments on the solubility of arsenic (As) in paddy soil and uptake by rice. Six organic matter (rice bran, rice straw, pig/cattle/fowls manure compost and swine liquid manure) were added to two polluted soils with high As (53 mg kg^-1) and low As concentration (28 mg kg^-1), and changes in soil solution constituents was monitored. The mean As concentrations in soil solution from the high As soil with rice bran, pig manure compost and swine liquid manure addition were significantly higher (0.61-1.15 mg L^-1) than that of the control (0.42-0.66 mg L^-1). Regression between As and Fe in soil solution indicated that As was attributable to reductive dissolution of Fe (hydr)oxides and it was driven by organic matter addition. Mean As concentrations in brown rice from the high As soil were 0.35-0.46 mg kg^-1, above the maximum safety level of inorganic As (0.35 mg kg^-1), and tended to be higher in organic matter amended soils than that of the control. The significant correlation between grain As and soil solution As was not observed and it was probably attributable to As tolerance of rice causing the reduction of As uptake and/or translocation to grain. However, considering the significant As release in soil solution from the high As soil and the tendency of grain As elevation after organic matter addition, it is needed to be cautious for food safety when amending organic matter to paddy soil with high As concentration.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.4 no.1
• /
• pp.81-88
• /
• 2009

This study has shown the tendency to enhance Sand Flux, a device of separating screening the foreign matter, for the recycling of construction waste possible to improve the quality of wet type production system meaningfully as part of research. As a result of experiment on the basic material properties, this study had a tendency to improve the quality and performance significantly in case of absolute surface dried density, 0.08mm sieve throughput, volume of clay lumps, and content of organic foreign matter. In addition, as a result of examining the quality characteristics of mortar, this study has shown the tendency that the flow and compressive strength more increased than the mortar using RS-II by utilizing RS-VI recycled sand produced finally through the device Sand Flux. As for the shrinkage properties, this study has shown the character the generation rate of crack of mortar using RS-IV recycled sand produced finally through the device Sand Flux.

• KOREAN JOURNAL OF CROP SCIENCE
• /
• v.42 no.3
• /
• pp.317-322
• /
• 1997

In order to investigate vigor of rice seed pregerminated, some organic and inorganic component content, response of ecotypes, and effect of gibberellin treatment, under different levels of hastening of germination, were examined. Protein content was high in dried seed, the larger size in length of pregerminated seed, the less protein content, but lipid content was a reverse tendency to protein one. Potassium content was low in dried seed, the larger size in length of pregerminated seed, the more potassium content, but increase dramatically at above 10 mm in length of sprout. Magnesium content showed a same tendency to potassium one. The ability of regermination was high in early maturing cultivar, but almost lost in the pregerminated seeds with above 5 mm in length of sprout. The regermination percentage of dried seed was lower than that of pregerminated seed with 0.1∼0.5 mm in length, but was similar to that of pregerminated one with 1∼3 mm in length of sprout. The effect of gibberellin on regermination percentage was highest at 10 ppm and showed high with small sized one of pregerminated seed. The effect of gibberellin on plant height, fresh weight, and dry weight showed a same tendency to regermination percentage.

• Membrane and Water Treatment
• /
• v.2 no.3
• /
• pp.137-145
• /
• 2011

Membrane processes are major breakthrough for the removal of organic pollutants in water remediation. The separations of solutes depend on nature of the membranes and solutes. The separation performance depends on the nature of the solutes (i.e., molecular volume, polarity, and hydrophobicity) for the same membrane. As 4-chlorophenol is of more dipolemoment compared to 2-chlorophenol, the orientation of the molecule enables it pass through the pores of the membrane, which is of negatively charged and thus separation order follows: 2-chlorophenol > 4-chlorophenol. Hydrophobicity factor also supports the order. Addition of sodium dodecyl sulfate (SDS) to chlorophenol solution shows remarkable increase in separation performance of the membrane. The improvement in separation is 1.8 and 1.5 times for 4- and 2- chlorophenol consecutively in case of 0.0082 M SDS (1cmc = 0.0082 M) in the solution. 4-chlorophenol has better attachment tendency with SDS because of its relatively more hydrophobic nature and thus reflects in performance i.e. the separation performance of 4-chlorophenol with SDS through the membrane is better compared to 2-chlorophenol.

• Journal of Environmental Health Sciences
• /
• v.28 no.5
• /
• pp.22-27
• /
• 2002

The composting practice has been recognized as the most popular way of controlling food waste and many attempt have been made in the field to establish more efficient and economical process. Some of the efforts are mixing cured compost with sawdust as alternative bulking agent, seeding commercially produced microorganism and/or combination of above. However, verification of such efforts is often restricted because of either the lack of engineering consideration on the limitation of composting facility scales. In this study, the effect of mixing materials in food waste composting was investigated by controlling the combination and the mixing ratio of them. When the cured compost was mixed with saw dust. the decomposition of organic material was proven to be more active by observing the compost temperature, the oxygen (O$_2$) consumption, and the cumulative carbon dioxide ($CO_2$) profile. However, the quantity of compost mix-ing seemed not to influence the reaction as long as the minimum required amount was mixed. The feeding of com-mercially produced microorganism had a tendency to prolong the thermophilic stage, which helped to increase the decomposition but it resulted in composting period. Regardless of the composting condition, bacteria and actinomycetes increased in population as the reaction approached to the end. The population of bacteria and actinomycetes were rel-atively higher than those of fungi and yeast throughout the reaction.

• The Korean Journal of Ecology
• /
• v.18 no.2
• /
• pp.243-253
• /
• 1995

Seral changes in environmental factors and recovery of soil fertility during abandoned field succession after shifting cultivation were investigated in eastern Kangwon-Do, Korea. Relative light intensity of herb and shrub layer decreased gradually until 50 years and increased slightly thereafter. Amount of litter and nutrients derived from it were depicted as a parabola form showing the gradual increment during the first 50 years and slight decrease thereafter. Organic matter, pH value, total-N and Mg of soil were plotted as an early depletion-mid pinnacle form showing the extrems depletion during the first 10 years, abrupt increase in about 20 or 50 years and gradual decrease thereafter. Ca, Al, Mn and Na of soil were depicted as a pinnacle form showing the peak in about 20 or 50 years. Thickness and field capacity of soil increased gradually, but K and total-P did not show any tendency as succession proceeded. The soil fertility, overall capacity of soil nutrients and water for plant growth, was plotted as the early depletion-mid pinnacle form.