• Journal of Wetlands Research
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• v.17 no.1
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• pp.11-18
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• 2015

As the seriousness of water pollution resulted from nitrogen is being magnified, research has been conducted to reduce nitrogen in sewage as well as wastewater. Particularly research on innovative nitrogen removal methods that are based on the reaction of nitritation and are economically feasible and eco-friendly has been receiving attention. However, research on the applicability and efficiency of the methods based on the reaction of nitritation has not been completely done yet. Accordingly, the current study has analyzed the characteristics of sewage flowing into municipal wastewater treatment plants, primary clarifier supernatant, recycled water, and livestock wastewater and also operated a laboratory-level reactor. The result shows that recycled water and livestock wastewater contain higher-concentration nitrogen than other kinds of sewage, so they increase nitrogen loading in the water treatment line. And the result of operating a reactor shows that because of ammonium nitrogen low concentration, sewage and primary clarifier supernatant do not induce the reaction of nitritation. Also, there exist differences in the conditions of retention time inducing the reaction of nitritation by the types of sewage, and this seems to be attributed to organic compound and ammonium nitrogen concentration. Among the kinds of sewage inducing the reaction of nitritation, anaerobic digester supernatant indicates the highest efficiency.

• Applied Chemistry for Engineering
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• v.16 no.5
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• pp.705-711
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• 2005

The reaction of lauric acid vinyl ester with n-butanol was established to give lauric acid butyl ester by subtilisin A-catalyzed transesterification in organic media containing nonionic surfactants. Pyridine has been used as an organic solvent since it provides higher yields than other organic solvents. However, because of stench of pyridine, compounds enzymatically synthesized in pyridine may be unsuitable as ingredients for foods and drugs. Hence, in order to select an organic solvent to replace pyridine, sugar esters were synthesized with the protease in various organic media. However, no solvent paralleled pyridine in yields. On the basis of this result, pyridine-based W/O microemulsions containing nonionic surfactants and water were used in enzymatic synthesis of the sugar ester, and when Tween 60, Brij 56, or 1-O-octyl-${\beta}$-D-glucopyranose was used for the W/O microemulsions, the yield was higher.

• Microbiology and Biotechnology Letters
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• v.16 no.3
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• pp.250-258
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• 1988

Lipases are well known as the enzymes which catalyze the hydrolysis of ester bonds combining aliphatic chains and glycerol on mono-, di- and triglycerides. Their reactions are characterized by be-ing heterogeneous and catalyzing the water-insoluble substrates. This property has been one of the Hurdles which delayed the application of lipases in fats and oils industry, However, with the development of biological reaction system of which organic solvent is introduced in part or whole as the reaction media, enzymatic manipulation of fats and oils is attracting increasing attention from the academic and industrial sectors. Trials in two-phase system and reversed micellar system to produce fatty acids through enzymatic hydrolysis of triglycerides preyed to be efficient in respect to volumetric productivity, fat hydrolysis rate, product separation, etc. In organic solvent system lipases have been found to have the ability to catalyze aminolysis, transesterification, esterification, thiotransesterification and oximolysis that are virtually impossible to catalyze in water. The organic solvent system is being extensively used in interesterifying glycerides to produce a fat with the modified physical and chemical nature.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.4
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• pp.412-418
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• 2007

The purpose of this study was to determine the several factors for affecting chlorine disinfection by-products(DBPs) characteristics by reacting chlorine and organic matters in the aquatic phase. The results of this research yield the following specific conclusions: The concentration of trihalomethanes(THMs) was increased with increasing dissolved organic carbon(DOC), and a trend of THMs formation was parabolic with increasing organic matters. Formations of THMs increased straightly for the first 4 hours and the amounts of producted THMs for the 30 minutes were up to $25\sim43%$ in the entire experiment periods(168 hours). When keeping up the concentration of organic matters at constant and changing that of bromide, the quantity of formed THMs did not show distinguished difference with the reaction times. THMs were gradually increased at $4^{\circ}C$ even though a reaction phase was parabolic formation(PF) phase. However, THMs were increased rapidly in the instantaneous formation(IF) phase and then became slowdown in the PF phase between $20\sim35^{\circ}C$. THMs were gradually increased although entering in the PF phase at pH 5. However, THMswere increased rapidly in the IF phase and then became slowdown in the PF phase at pH 7 and pH 9, and these treads were much more clear at pH 9 than at pH 7.

• Proceedings of the KIEE Conference
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• 2003.07c
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• pp.1580-1582
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• 2003

Transformation of molecular film occurs only usually in air-water interface, 2 dimensions domain's growth and crash are achieved. Organic thin film that consist of growth of domain can understand correct special quality of accumulation film supplying information about fine structure and properties of matter of device observing information and so on that is surface forward player and optic enemy using AFM one of SPM application by nano electronics. In this paper Langmuir (L) that is one of basis technology to manufacture of organic matter device using Biology material PBDG that is kind of polypeptide that have Biology adaptedness. Detected of accumulation condition in observing Surface Pressure change by stimulus reaction of Langmuir (L) and Spin-Coating film. Therefore AFM by this confirm and compared.

• Journal of Korean Society of Water and Wastewater
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• v.20 no.6
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• pp.837-848
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• 2006

This paper presents the test results of biological aerated filtration(BAF) process to replace activated sludge process by enhancing treated effluent quality and reducing the costs. In BAF process both BOD and SS compounds in wastewater are degraded and removed by biological reaction and filtration. Upflow BAF with expanded polypropylene media and downflow BAF with ceramic media were used to investigate the effects of hydraulic and organic loads on effluent quality. As a result, in BAF processes which has different media, upflow BAF reactor shows 5% higher efficiency than downflow BAF and this phenomena caused by backwashing methods and operational conditions. The results of influence factors analyzed by Factor Analysis Method in BOD and SS treatment efficiency are the size of media, hight of media bed and type of media. The quantitative effects of media size are 5.73% in TBOD, 5.78% in SBOD and 7.65% in TSS, so we confirmed the main factor is media size.

• Clean Technology
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• v.7 no.4
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• pp.281-290
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• 2001

A microwave-assisted process to prepare chitosan from natural crabshells has been investigated. This study was primarily to examine the effectiveness of microwave as clean energy for chitosan preparation. Several human-edible organic acids were used as clean catalyst, possibly to improve the current HCl-based hydrolysis process of polymeric chitosan. The microwave was found to be effective substantially in reducing the reaction time. Nonetheless, no beneficial effect of microwave other than time, such as the chemical selectivity, was hardly observed. The organic acids were very effective in the hydrolysis reaction of polymeric chitosan. Their catalytic behavior was greatly improved especially when reactions were performed under pressure. In the case of autoclave reaction for 60 minutes at $120^{\circ}C$, viscous solution of polymeric chitosan (mol. wt. > 300,000) turned into thin solutions of water-like viscosity, which means chitosan molecules were decomposed to very small-sized oligomers.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2003.10a
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• pp.559-562
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• 2003

The results and discussions of surveyed case site at constructed steel pile in potential acid sulfate soil were as follows. Topography at surveyed site was local alluvial valley and that site soils was classified as BanGog and YuGye series as detailed soil surveyed results in RDA and soil texture was Clay/Clay Loam. Soils pH was neutral, which was average 7.5 but much decreased to average 4.2 after $H_2O_2$ treatment. Organic matter and sulfate ions contents were very rich. The corrosion was severe at ground water fluctuation depth. Deposits colored black were attached to steel pile surface, which because of violent reaction in treatment HCI solution, were guessed as corrosion products (FeS) reduced by sulfate reducing bacteria(SRB). Consequently, main cause was thought microbiologically induced corrosion at this site where there is ground water fluctuation occurring oxidation and reduction reactions in turn and the soil is potential acid sulfate soil.

• Journal of Korean Society of Water and Wastewater
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• v.31 no.1
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• pp.73-81
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• 2017

The UV/chlorine process is a UV-based advanced oxidation process for removing various organic pollutants in water. The process is becoming increasingly popular because of its effectiveness in practice. It is important to the safe and efficient operation of a UV/chlorine process that the optimal operating conditions for both target removal objective and saving energy are determined. Treatment efficiency of target compounds in UV/chlorine process was mainly affected by pH and scavenging factor. In this study, kinetic based mathematical model considering water characteristics and electrical energy dose calculations model was developed to predict of treatment efficiency and optimal operating conditions. The model equation was validated for the UV/chlorine process at the laboratory scale and in pilot tests at water treatment plants.

• Proceedings of the KIEE Conference
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• 2005.07c
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• pp.2193-2195
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• 2005

The hybrid discharge reactor was designed for the application of wastewater treatment and the removal of hazardous volatile organic substances in water. This discharge type was similar to the barrier discharge, and the surface discharge on the dielectric surface was propagated to the water surface. That caused the heterogeneous chemical reaction strongly at the interface between the working gases and the water surface. Changes of the conductivity, acidity, and the dissolved ozone with respect to the treatment time and water quantities were studied as the fundamental experiment. The concentration of hydrogen ions largely increased with increasing the treatment time and the conductivity increased with respect to the increase of water quantities under the constant other discharge parameters.