• 제목/요약/키워드: Organic pollutants

검색결과 793건 처리시간 0.029초

Mesoporous Titanium Oxo-Phosphate에 의한 살균제 Chlorothalonil의 광분해 (Photocatalytic Degradation of Fungicide Chlorothalonil by Mesoporous Titanium Oxo-Phosphate)

  • 최충렬;김병하;이병묵;최정;이인구;김장억
    • 한국환경농학회지
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    • 제22권4호
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    • pp.284-289
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    • 2003
  • Mesoporous titanium oxo-phosphate(Ti-MCM)은 기존의 유기성 오염물질의 광분해제로 널리 이용되고 있는 $TiO_2$에 비해 표면적이 매우 넓은 장점이 있다. 그러므로 본 연구에서는 Ti-MCM에 의한 chlorothalonil의 흡착 및 광분해 특성을 $TiO_2$와 비교하였다. 합성된 Ti-MCM은 hexagonal 형태로 d-spacing이 4.1 nm이었다. 암조건에서 $TiO_2$에 의한 chlorothalonil의 흡착은 거의 일어나지 않았으나, Ti-MCM에 의한 흡착은 반응 1시간까지 25%로 급격히 증가하여 흡착평형에 도달하였다. UV조사 하에서 반응 9시간 후의 $TiO_2$와 Ti-MCM에 의한 chlorothalonil의 제거율은 각각 88%와 100%로 나타났다. 그러나 정치상태에서의 광분해 속도는 chlorothalonil과 Ti-MCM사이의 낮은 접촉에 의한 반응성의 감소로 느린 경향을 나타내었다. 또한 Ti-MCM에 의한 chlorothalonil의 분해효율은 용액의 초기 농도가 낮을수록, pH 7까지 반응용액의 pH가 높을수록 증가하였다.

차량 운전자의 공기오염물질 잠재적 노출 및 차량용 공기청정기에 의한 제어 (Potential Exposure to Air Pollutants for Driver and Its Control Using Commercial Air Cleaning Device Inside Vehicle)

  • 김대원;김문현;양원호
    • 한국환경보건학회지
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    • 제30권5호
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    • pp.481-486
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    • 2004
  • Vehicle occupant exposure to air pollutants has been a subject of concern in recent years because of higher levels of air pollutants inside gasoline or diesel-using vehicle, comparing to the surrounding atmosphere. Contrary to previous studies, fuel of vehicles operated in this study was liquefied petroleum gas (LPG). This study examined the potential exposure and removal efficiency of selected volatile organic compounds (VOCs), nitrogen dioxide ($NO_2$) and respirable suspended particle (RSP) by commercial air cleaning device inside vehicle under different ventilation conditions. Vehicle concentrations inside of benzene, toluene, m,p-xylene, $NO_2$ and RSP were lower under the low ventilation condition. This was indicated that outdoor air pollutants could affect the vehicle air quality inside in case metropolitan cities such as Daegu. The urban vehicle concentrations inside of benzene, toluene, m,p-xylene, $NO_2$ and RSP with air cleaning device were higher than those without air cleaning device. This means that the use of air cleaning device equipped with activated carbon filter, which was used in this study, in the interior of vehicles could be expected to reduce the vehicle occupants exposure to air pollutants effectively. In batch type reactor of laboratory scale, removal efficiencies of air cleaning device used were $97.0\%,\;95.7\%,\;94.6\%\;and\;85.5\%$ respectively in benzene, toluene, m,p-xylene and $NO_2$.

고속도로 노면유출수의 중금속 유출 특성 및 상관성 (Washoff Characteristics of Metal Pollutants in Highways)

  • 이은주;고석오;강희만;이주광;임경호;이병식;김이형
    • 한국물환경학회지
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    • 제22권1호
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    • pp.128-133
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    • 2006
  • The paved areas in nonpoint source are highly polluted landuses because of high imperviousness and high pollutant mass emissions from vehicle activities. Particularly, the metal pollutants are a big issue in the paved area. It is usually washed-off during storms by adsorbing on sediments or soluble status. Therefore, this research was achieved for understanding the characteristics of metal pollutants in stormwater runoff in highways. Five monitoring sites were equipped with an automatic rainfall gage and an automatic flow meter. This manuscripts will summarize the washoff characteristics of metal pollutants and its concentration changes during storms. Usually first flush phenomenon was observed for all of the storm events and visibly confirmed with hydro- and polluto-graphs. Also it was coincided with the tendency of particulates and organic matters. The decrease rate per total reduced amount for metals during initial 30-min storm duration was obtained on 80%. The result may be able to use for determining the economical treatment criteria for stormwater runoff in highways.

Viologen 유도체를 이용한 항만오염물질의 전기화학적 특성 (Electrochemical Sensing Property of Harbor Pollutants using Viologen Derivative)

  • 최용성;지유강;박수봉;이경섭
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2008년도 춘계종합학술대회 A
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    • pp.997-999
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    • 2008
  • 본 연구에서는 항만오염의 주원인의 하나인 오염물질을 검출할 수 있는 센서 개발을 위하여 Viologen 유도체를 사용하였다. 자기조립법을 이용하여 Viologen 유도체를 수정진동자의 금 전극에 수식하였으며, 순환전압전류법을 이용하며 산화 환원 반응 특성과 피크전류의 변화를 관찰하였다. 그리고 벤젠, 인산염, 계면활성제 등의 오염물질에 대한 선택적 특성을 검토하였다.

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중소규모 조선소 인근 주거지역의 유해대기오염물질 농도에 대한 사례연구 (Case Study of Hazardous Air Pollutant Concentrations in Residential Areas nearby Small and Medium scale Shipbuilding Companies)

  • 정재우;이명은
    • 한국환경과학회지
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    • 제18권5호
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    • pp.517-525
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    • 2009
  • We measured ambient concentrations of hazardous air pollutants such as volatile organic compounds (VOCs) and aldehydes in residential areas nearby small and medium scale shipbuilding companies. The VOC concentrations were higher during the normal operation periods than vacation at which almost all operations were shutdown. Concentrations of VOCs was higher, as the sampling site was nearer from shipbuilding companies. The major components of VOCs were m,p-xylene, ethylbenzene, o-xylene, toluene, and 1,3,5-trimethylbenzene which had been found as major VOC compounds emitted from painting processes of shipbuilding in the previous studies. The major components of aldehydes analyzed were benzaldehyde, acrolein, formaldehyde, and acetaldehyde. The concentration of aldehydes was highest at the furthest sampling point from shipbuilding companies because the formation of aldehyde compounds could be occurred by the secondary chemical reactions of VOCs. The results of this study shows a proper counterplan need to be established for the reduction of hazardous air pollutants emitted from small and medium scale shipping companies.

폐타이어 건류 소각에서 발생되는 재와 배기 가스에서의 독성 오염 물질의 정량 (Characterization of Toxic Pollutants in Ash and Flue Gas from Gasification Incinerator of Waste Tires)

  • 구자공;서영화;김석완;유동준
    • 대한토목학회논문집
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    • 제13권1호
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    • pp.213-220
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    • 1993
  • 본 논문에서는 해마다 수 십만 개씩 발생되는 폐타이어의 열적 처리 방법인 건류 소각 처리 방법에서 발생되는 이차 오염 물질을 정량하여 폐타이어의 안전한 최종 처리 방법까지 고찰하였다. 건류-소각처리 방법에서 발생되는 배기 가스에서 이차 독성 오염 물질을 화학 평형 모델을 응용하여 예측하였고 실질적인 잔류 물질인 건류재와 소각재에서 유기성 독성 물질과 중금속을 정량하였다. 건류재에서는 폐타이어의 불완전 연소에 따른 유기성 이차 오염 물질이 다량 포함되어 있는 반면에 소각재에서는 납과 카드뮴과 같은 중금속 화합물의 함량이 높았다. 건류재 및 소각재의 안전한 최종 매립을 위하여는 서로 다른 전처리 방법이 요구된다.

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백화점 내 업종별 판매매장에 따른 오염물질 배출현황 평가 (Evaluation of Pollutants Emissions according to the Selling Store in Department Store)

  • 왕형석;황준석;장성진;김수민
    • 한국가구학회지
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    • 제26권1호
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    • pp.71-76
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    • 2015
  • It is important thing that air quality affects human health. And It is more important thing that Indoor Air Quality more affects human health than Outdoor Air Quality. The cause of that is indoor air pollutants are more absorbed than outdoor air pollutants. By the way, in case of Multi-use facility for example office, department store, school etc., it has a feature that there are more people than any other buildings. therethrough, effects of Indoor Air Quality of Multi-use facility affect more people's health than Indoor Air Quality of any other buildings. However, in multi-use facility, specifically retail store, chemical treated materials are used for interior finishing, showcase finishing and product finishing because esthetic element is more added for detention of customer. Consequently, in place where demands brisk sales, possibility that indoor air is polluted by VOCs is high. This study considered retail store's Indoor Air Quality. as result of experiment, figure of department store's air pollution exceed about 5~20 times in guideline of multi-use facility's Indoor Air Quality in any kind of shop of department store (guideline : $500{\mu}g/m^3$).

Indoor exposure to hazardous air pollutants and volatile organic compounds in low-income houses in Lagos, Nigeria

  • Luqmon, Azeez;Musa, Olaogun;Mariam, Adeoye;Abdulazeez, Lawal;Babatunde, Agbaogun;Ibrahim, Abdulsalami;Adija, Majolagbe
    • Advances in environmental research
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    • 제1권4호
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    • pp.277-288
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    • 2012
  • This study investigated exposure to air pollutants in rooms in low-income houses at Shomolu (R1), Mafoluku (R2) and Mushin (R3) in Lagos state. The concentrations of most measured exceeded limits of Illinois Department of Public Health (IDPH) for indoor air quality. Air quality index (AQI) in rooms studied was unhealthy for sensitive people in terms of CO, unhealthy in terms of $SO_2$ and very unhealthy in terms of $NO_2$ while moderate air quality was obtained in terms of $PM_{10}$ in most rooms. High concentrations of carbontetrachloride, formaldehyde and xylene measured could have been responsible for some of the health complaints of the occupants. Factor analysis shows that cooking with kerosene, use of gasoline generator and insecticide were the major contributors to indoor air pollution in these rooms. Therefore, there is need to urgently tackle poverty as all affected by these pollutants were poor who live in substandard houses without kitchens.

대기오염측정에 대한 정도관리의 필요성 - 1998년도 한국대기환경학회 측정분석분과회의 실험실간 비교분석사업 시행과 전개방향 (The Need for QA/QC in the Measurements of Airborne Pollutants - Conduction of and Directions towards an Interlaboratory Comparison Test in 1998 by the Measurement and Analysis Division of KOSAE)

  • 김기현;이강웅;김조천;서영화;이종해;허귀석
    • 한국대기환경학회지
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    • 제15권1호
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    • pp.63-69
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    • 1999
  • To offer a general guideline for the quantitative analysis of airborne pollutants, we designed and conducted a comprehensive QA/QC test using two different strategic approaches, namely (1) field-based comparative measurement and (2) laboratory-based comparative analysis. The former task was performed to make meaningful comparison of combined errors occurring from both sampling and analytical techniques in the measurements of such components as: (1) criteria pollutants, (2) volatile organic compounds (VOCs), and (3) particulate matters with the associated metals and ions. The latter task was also conducted to compare various types of bias arising mainly from the laboratory analytical procedures of (1) gaseous standards of VOCs and (2) of aqueous standards of metals and ions. The concentration data derived from each of these two different types of major tasks were evaluated per chemical species categorized as above. While the very details of these studies are to be reported on an individual basis according to the above classification of the project, this paper is presented to provide an overview of the whole project - its aim and direction.

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Acute Toxicity of Heavy Metals, Tributyltin, Ammonia and Polycyclic Aromatic Hydrocarbons to Benthic Amphipod Grandidierella japonica

  • Lee, Jung-Suk;Lee, Kyu-Tae;Park, Gyung-Soo
    • Ocean Science Journal
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    • 제40권2호
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    • pp.61-66
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    • 2005
  • Benthic amphipod, Grandidierella japonica widely inhabits the Korean coastal waters and is developed as a standard test species for sediment toxicity tests. We exposed G. japonica to various pollutants including 4 kinds of inorganic metals (Ag, Cd, Cu and Hg), tributyltin [TBT], ammonia and 7 polycyclic aromatic hydrocarbon (PAH) compounds (acenaphthene, chrysene, fluoranthene, fluorene, naphthalene, phenanthrene and pyrene) to estimate the no observed effect concentration (NOEC) and the median lethal concentration (LC50) of each pollutant during the 96-hour acute exposure. Among all tested pollutants, TBT was most toxic to G. japonica, and Rg was most toxic among inorganic metals. The toxicity of pyrene to G. japonica was greatest among PAH compounds, followed by fluoranthene, phenanathrene, acenaphthene, fluorene and naphthalene. The toxicity of PAH compounds was closely related to their physico-chemical characteristics such as $K_ow$ and water solubility. G. japonica responded adequately to pollutant concentrations and exposure durations, and the sensitivity of G. japonica to various inorganic and organic pollutants was generally comparable to other amphipods used as standard test species in ecotoxicological studies, indicating this species can be applied in the assessment of environments polluted by various harmful substances.