• 제목/요약/키워드: Organic phosphorus

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Capping 기술을 이용한 하천 및 호소 퇴적토의 인 용출 저감 효과 분석 (Analysis on the Reduction of Phosphorus Release in River and Lake Sediments through Application of Capping Technology)

  • 김석구;윤상린
    • 대한환경공학회지
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    • 제36권11호
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    • pp.781-790
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    • 2014
  • 유속이 약한 하천이나 호소에 침강된 유기물, 영양염류, 유해화학물질 등의 오염물질은 일단 수중으로부터 제거되어 퇴적물 속에 축적되었다가 확산, 재 부유, 생물교란 등의 물리 화학 생물학적 과정에 의해 다시 수층으로 용출되어 수질 및 수생생태에 직 간접적인 악영향을 미칠 수 있게 된다. 특히 인은 수중생태계의 일차 생산량을 결정하는 중요한 물질중의 하나로 수체 내 물질순환 과정에서 주로 퇴적물에 저장되는 원소로 물리적인 교란 및 생 화학적 작용에 의해 수층으로용출되어 부영양화현상을 가속시키는 것으로 알려져 있다. 본 연구에서는 수층 미생물의 영향을 고려한 경우(호소수)와 미생물의 영향을 배제한(증류수)경우로 구분하여 각각 다른 capping 소재를 적용하여 퇴적물에서의 인 용출 저감 효과를 분석하였다. 실험 결과 화학적소재인 Fe-Gypsum, $SiO_2$-Gypsum로 capping을 할 경우, control보다 인 용출을 약 40% 이상 저감시키는 것을 확인할 수 있었다. 또한 복합소재인 granule gypsum+Sand는 약 50% 이상 용출을 저감 효과가 나타났다. 따라서 화학적 소재인 granule-gypsum과 그 위에 모래와 같은 친환경소재로 capping을 한다면 인 용출 저감에 효과적일 것으로 판단된다. Capping 처리 전후의 퇴적층내의 인 성상변화를 살펴본 결과, gypsum 투입에 의하여 호소 퇴적층에 존재하는 인이 용출되기 어려운 안정한 형태인 apatite-P 변화된 것으로 확인되었다. 이상의 결과를 토대로 capping 기술의 적용을 통하여 하천 및 호소 퇴적물에서 발생되는 인 용출에 대한 저감 효율을 기대할 수 있을 것으로 사료된다.

유기산 첨가가 닭뼈(대퇴골) 스톡(stock)에 용출되는 무기질량에 미치는 영향 (The Effect of Organic Acids on Mineral Extraction from Chicken Thigh Bone Stock)

  • 이승언;남출항구;대곡귀미자;최석현;한재숙
    • 동아시아식생활학회지
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    • 제12권5호
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    • pp.379-387
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    • 2002
  • 본 연구는 여러 가지 조리 및 영양 생리작용을 가진 유기산을 닭뼈에 이용하여 조리할 때 산의 종류와 조리 시간에 따른 칼슘, 마그네슘, 인의 용출량에 미치는 영향을 조사하였으며 그 결과는 다음과 같다. 1. 칼슘, 마그네슘, 인의 용출량은 산의 농도가 높을수록 증가하였고, 끓이는 시간에 비례하여 증가하였다. 같은 농도에서는 초산의 첨가군보다 구연산, 사과산의 첨가군이 많이 용출되었다. 2. 단백질과 총 유리아미노산의 용출량도 무기성분의 용출과 같은 경향을 나타내었다. 이상의 결과는 유기산을 첨가하여 12시간 끓이면 무기성분뿐만 아니라 단백질, 아미노산의 용출량이 증가하는데, 이것은 유기산의 첨가로 인하여 가용화 상태가 된 뼈가 끓임으로써 한층 더 연해져 뼈 중의 성분이 용출되기 쉽다는 사실을 확인할 수 있었다.

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부산광역시 일부하천의 수질특성 (Water Quality Characteristics of Busan Metropolitan Streams)

  • 김부길;문종익;고현웅;임영석;성낙창;이용두
    • 환경위생공학
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    • 제16권2호
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    • pp.56-62
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    • 2001
  • This study is carried out to investigate the water quality changes in Busan Metropolitan streams, The results are as follows. The level of organic contaminants($BOD_{5}$ and $COD_{Mn}$) is found to be low and does not show seasonal variation in domestic waste water streams. But, the level of organic contaminants in industrial waste water streams is relatively high and seems to be seasonally variable, which is affected by other factors. The nutrient materials, such as nitrogen(as T-N, about 20mg/L) and phosphorus(as T-P about 2.0mg/L), are abundant than Nak Dong River and the general trends of contaminants level are similar to those of organic contaminants. The chronic water qualities, including organic, nutrient contaminants levels, show that the loading rates in 1998 are smaller than the past(1983, 1992). And this trend is more evident in industrial waste water streams than domestic waste water streams.

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산지토양(山地土壤)의 특성(特性)과 개량(改良) (Soil Characteristics and Improvement of Reclaimable Hillside Land)

  • 류인수
    • 한국토양비료학회지
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    • 제11권4호
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    • pp.247-262
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    • 1979
  • Majority of reclaimable soils in hillside lands in Korea are red yellow soils, with exception in Jeju island, where most of reclaimable hillside lands are composed of volcanic ash soils. Songjeong, Yesan and Samgag series are the major soil series of red yellow soils which are available for the reclamation. When observed in the fields, they are distinguished as reddish brown clay loam, red yellow sand loam and yellowish brown sand loam. They have moderately good physical properties but their chemical properties are generally poor for crop cultivations. The chemical properties of red yellow soils, as compared to long time cultivated (matured) soils, are characterized by very low pH, high in exchangeable Al content and phosphorus fixation capacity. Also extraodinary low available phosphorus and organic matter contents are generally observed. On the other, the chemical properties of volcanic ash soils are characterized by high armophous Fe and Al hydroxides and organic matter contents, which are the causative factors for the extremely high phosphorus fixation capacity of the soils. The phosphorus fixation capacity of volcanic acid soils are as high as 5-10 times of that of red yellow soils. Poor growth of crops on newly reclaimed red yellow soils are mainly caused by very low available P and pH and high exchangeable Al. Relatively high P fixation capacity renders the failure of effective use of applied P when the amount of application is not sufficient. Applications of lime to remove the exchangeable Al and relatively large quantity of P to lower the P fixation capacity and to increase the available P are the major recommendations for the increased crop production on red yellow hillside soils. Generally recommendable amounts of lime and P to meet the aforementioned requirements, are 200-250kg/10a of lime and $30-35kg\;P_2O_5/10a$. Over doses of lime. frequently induces the K, B, arid Zn deficiencies and lowers the uptake of P. In volcanic ash soils, it is difficult to alter the exchangeable Al and the P fixation capacity by liming and P application. This may be due to the peculiarity of volcanic ash soil in chemical properties. Because of this feature, the amelioration of volcanic ash soils is not as easy as in the case of red yellow soils. Application of P as high as $100kg\;P_2O_5/10a$ is needed to bring forth the significant yield response in barley. Combined applications of appropriate levels of P, lime, and organic matter, accompanied by deep plowing, results in around doubling of the yields of various crops on newly reclaimed red yellow soils.

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사구식물(砂丘植物)과 Arbuscular 내생균근(內生菌根) 균(菌)의 공생(共生) 특성(特性) (Symbiotic Properties of Arbuscular Mycorrhizal Fungi and Sand Dune Plants)

  • 김준태;리기현;정병철;김종균
    • 한국균학회지
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    • 제21권3호
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    • pp.235-245
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    • 1993
  • The symbiotic properties of arbuscular mycorrhizal fungi(AMF) such as the absence and/or presence of symbiosis, spore density, and six factors of phycochemical properties of soil were investigated in the rhizosphere of seven sand dune plants and three control plants around Kum river. The infection of AMF was confirmed in all plants. Three genera, nine species of the AMF spores were identified in the sand dune; Ac. scrobiculata, G. aggregatum, G. convolutum, G. diaphanum, G. dimophicum, G. geosporum, G. vesiculiferum, G. tortuosum, S. pachycaulis. All of them were also found in the control, but S. pachycaulis were only separated in the sand dune. In the control, three genera, four species were identified; G. flavisporum, Gi. margarita, Sc. gregaria. Sc. persica. The species specificity was not found between the sand dune plant and AMF. However, the AMF was thought to be correlated with the soil factors. The spore density was stimulated with increase of the organic matter and the nitrogen content, but inhibited with the water content and the phosphorus content. In respect of the seasonal factor, the spore density was increased in the late growth period of plants.

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Waste treatment with the pilot scale ATAD and EGSB pig slurry management system followed by sequencing batch treatment

  • Lee, Young-Shin;Han, Gee-Bong
    • Environmental Engineering Research
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    • 제20권3호
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    • pp.277-284
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    • 2015
  • Experiments for highly concentrated contaminants in pig waste slurry were carried out for the feasibility test of a pilot-scale innovative process scheme of engaging autothermal thermophilic aerobic digestion (ATAD) and expended granular sludge bed (EGSB) followed by sequencing batch reactor (SBR) system. Contaminants in pig waste slurry such as organic substance, total nitrogen (TN), ammonia nitrogen and total phosphorus (TP) contents were successfully reduced in the system. Total volatile solids (TVS) and chemical oxygen demands (COD) for organic matter in the feed were 32.92 g/L and 42.55 g/L respectively, and they were reduced by about 98.7% and 99.2%, respectively in the system. The overall removal efficiencies for TN and ammonium nitrogen were found to be 98.1 and 98.5%, respectively. The overall removal efficiency for total phosphorus was also found to be 92.5%. Faecal coliform density was reduced to <$1.2{\times}10^4CFU/g$ total solids. Biogas and $CH_4$ were produced in the range of 0.39-0.85 and $0.25-0.62m^3/kg$ [VS removed], respectively. The biogas produced in the system comprised of $295{\pm}26ppm$ (v/v) [$H_2S$].

재배지토양의 화학성이 인삼근중의 당류 및 saponin 함량에 미치는 영향 (Effects of the Chemical Properties of Field Soils on the Contents of Sugars and Saponin in Ginseng Roots)

  • 김동철;장상문;최정
    • Applied Biological Chemistry
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    • 제38권1호
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    • pp.72-77
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    • 1995
  • 품질이 좋은 인삼의 생산을 위한 재배지포장의 토양 및 영양관리를 위한 기초자료를 얻기 위하여, 인삼재배지토양의 화학성과 인삼근 중의 전당, 환원당, 유리당류, ginsenoside 및 saponin들의 상관관계를 조사하여, 인삼근의 품질에 미치는 영향을 조사하였다. 토양 중 $NO_3-N$함량은 인삼근 중의 전당 및 환원당의 함량과 고도의 부의 상관이 인정되었다. 토양 중 유기물함량은 인삼근 중의 당류와 ginsenoside계 성분들의 함량과 정의 상관이 인정되었으나, 토양 중 유효인산 및 치환성 양이온들의 함량은 부의 상관이 인정되었다.

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BIO-CLOD를 이용한 고도처리공정에서의 영양염류 제거 (Nutrient Removal in an Advanced Treatment Process using BIO-CLOD)

  • 박완철;이미애;성일화
    • 한국환경보건학회지
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    • 제40권4호
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    • pp.322-329
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    • 2014
  • Objectives: The purpose of this study was to investigate the effect of BIO-CLOD on advanced wastewater treatment for enhanced removal efficiency and meeting the stringent discharge water requirements of wastewater treatment plants. Methods: Two experimental apparatuses consisting of anaerobic, anoxic and aeration tanks were operated. One included a BIO-CLOD cultivation tank. Organic and nutrient parameters and removal efficiency were analyzed by pH, BOD, CODcr, SS, T-N and T-P. Results: The average removal efficiencies of BOD, COD and SS from the apparatus with BIO-CLOD tank installation were 95.5%, 88.6% and 92.9%, respectively, and these were higher than the results from the apparatus without BIO-CLOD. The average TP removal efficiency with BIO-CLOD tank marked 56.0%, higher than the 47.3% from the apparatus without one. BIO-CLOD showed a higher performance for TN removal at 49.6%, compared to the result without BIO-CLOD of 34.3% Conclusion: By reaction with BIO-CLOD, ammonia removal was effective in the aeration tank, as was phosphorus release in the anaerobic tank. Phosphorus luxury uptake and nitrification in aeration tank proceeded smoothly. The application of BIO-CLOD can improve the decrease of odor and settleability of activated sludge in a wastewater treatment plant, as well as increase the removal efficiency of organic and nutrient materials in water.

Neighboring Cage Fish Farming Affecting Water and Seabed Quality of the Jordanian Northern Gulf of Aqaba, Red Sea

  • Mohammad, Al-Zibdah;Firas, Oqaily;Tariq, Al-Najjar;Riyad, Manasrah
    • Ocean Science Journal
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    • 제43권1호
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    • pp.9-16
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    • 2008
  • Environmental qualities of coastal water and bottom sediment were assessed at Jordan's northernmost tip of Gulf of Aqaba to evaluate possible impacts of the bordering fish pen cages in Eilat. Results showed significant differences between surface and bottom water in the chemical and physical variables in the different months of the year (2004-2005). Chlorophyll a was also significantly higher in bottom water when compared to that of the offshore water. Nitrate and ammonia were significantly higher in bottom water than the surface water at each individual station. The upper 2 cm of sediment sample recorded higher values of total phosphorus and organic matter. Seasonality affected the content of total phosphorus, organic matter, redox potential and color especially at the sediment layer below 3 cm of the sediment core. The present investigation showed slight modification of water and sediment qualities but no clear sign of eutrophication was observed. However, to maintain sustainability of healthy environmental conditions at the northern tip of Gulf of Aqaba potentials of any possible environmental risks arising from the fish farms or any other coastal investment should be carefully considered.