• 제목/요약/키워드: Organic degradation

검색결과 924건 처리시간 0.026초

Effects of Water Vapor, Molecular Oxygen and Temperature on the Photocatalytic Degradation of Gas-Phase VOCs using $TiO_2$Photocatalyst: TCE and Acetone

  • Kim, Sang-Bum;Jo, Young-Min;Cha, Wang-Seong
    • Journal of Korean Society for Atmospheric Environment
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    • 제17권E2호
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    • pp.35-42
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    • 2001
  • Recent development of photocatalytic degradation method that is mediated by TiO$_2$ is of interest in the treatment of volatile organic compounds(VOCs). In this study, trichloroethylene(TCE) and acetone were closely examined in a batch scale of photo-reactor as a function of water vapor, oxygen, and temperature. Water vapor inhibited the photocatalytic degradation of acetone, while there was an optimum concentration in TCE. A lower efficiency was found in nitrogen atmosphere than air, and the effect of oxygen on photocatalytic degradation of acetone was greater than on that of TCE. The optimum reaction temperature on photocatalytic degradation was about 45$^{\circ}C$ for both compounds. NO organic byproducts were detected for both compounds under the present experimental conditions. It was ascertained that the photocatalytic reaction in a batch scale of photo-reactor was very effective in removing VOCs such as TCE and acetone in the gaseous phase.

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PL Degradation을 활용한 OLED 소자의 사진 이미지 구현 (Realization of Static Image on OLEO using Photoluminescence Degradation)

  • 서원규;문대규
    • 한국전기전자재료학회논문지
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    • 제21권9호
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    • pp.859-862
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    • 2008
  • We have realized static image on organic light emitting diodes (OLEDs) using photoluminescence degradation. Ultraviolet (UV) was irradiated to the glass side of device. UV power was 350 Wand the wavelength was 365 nm. The UV irradiation gives rise to the degradation of photoluminescence. Due to the degradation, the current density-voltage curve was shifted to the higher voltage side and the luminescence was also degraded by the current and photoluminescence drop. The negative imaged films were prepared to control the transmittance of UV. The UV light was passed through the film. By this method, the film image was transferred to the device with reversed image and the static image was realized on the OLED.

Photocatalytic degradation of organic compounds by 2-ethylimidazole-treated titania under visible light illumination

  • Seo, Jiwon;Jeong, Junyoung;Lee, Changha
    • Membrane and Water Treatment
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    • 제10권3호
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    • pp.223-229
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    • 2019
  • Titania modified by 2-ethylimidazole (2-EI) (denoted as $2-EI-TiO_2$) demonstrated visible light photocatalytic activity for the degradation of organic compounds. $2-EI-TiO_2$ was a bright brown powder that exhibited similar crystallinity and morphology with the control $TiO_2$. A diffuse reflectance spectrum indicated that $2-EI-TiO_2$ absorbs visible light of all wavelengths. X-ray photoelectron spectroscopy (XPS) confirmed the cationic state of nitrogen species (e.g. Ti-O-N) on the surface of $2-EI-TiO_2$. Visible light-illuminated $2-EI-TiO_2$ degraded $10{\mu}M$ 4-chlorophenol (4-CP) by approximately 85% in 4 h. The photochemical activity of $2-EI-TiO_2$ was selective in targeting the organic compound. The repeated use of $2-EI-TiO_2$ decreased the photocatalytic activity for the 4-CP degradation. Experiments using radical scavengers and oxidant probes revealed that the oxidation by photogenerated holes is responsible for the degradation of organic compounds by illuminated $2-EI-TiO_2$ and the role of $^{\bullet}OH$ is negligible.

TREATMENT OF ANIMAL MANURE AND WASTES FOR ULTIMATE DISPOSAL - Review -

  • Winter, J.;Hilpert, R.;Schmitz, H.
    • Asian-Australasian Journal of Animal Sciences
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    • 제5권2호
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    • pp.199-215
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    • 1992
  • Sources of organic waste materials for aerobic and/or anaerobic degradation, or for composting of solid wastes in Germany were estimated. The basic microbiology and the energetics of these processes were compared with special emphasis on anaerobic degradation, for which a general degradation scheme of carbohydrates is presented. Advantages of anaerobic over aerobic treatment processes are pointed out and conditions for maintaining a highly stable anaerobic process as well as producing a sanitized, hygienic product are discussed. Reactor systems suitable for efficient treatment of wastes with a high or low proportion of suspended solids are principally compared and results of laboratory studies on the degradation of several wastes and animal manures summarized. Finally, a piggery slurry treatment factory for an ultimate slurry processing to obtain a dry fertilizer and a harmless, disposable liquid, as it is in operation in Helmond/Holland, is presented and preliminary process data are presented.

A Kinetic Study on the Photocatalytic Degradation of Gas-Phase VOCs Using TiO$_2$ photocatalyst

  • Kim, Sang-Bum;Jo, Young-Min;Hong, Sung-Chang
    • Journal of Korean Society for Atmospheric Environment
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    • 제17권E3호
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    • pp.117-124
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    • 2001
  • The present paper examined the kinetics of photocatalytic degradation of volatile organic compounds (VOCs) including gaseous trichloroethylene (TCE) and acetone. In this study, we examined the effects of the initial concentration of VOCs and the light intensity of ultra-violet (UV). A batch photo-reactor was specifically designed for this work. The photocatalytic degradation rate increased with the initial concentration of VOCs but remained almost constant beyond a certain concentration. It matched well with the Langmuir-Hinshelwood (L-H) kinetic model. When the effect of light intensity was concerned, it was found that photocatalytic degradation occurs in two regimes with respect to light intensity.

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Cathode material에 따른 organic photovoltaics 안정성의 영향 (The influence of cathode material on the stability of organic photovoltaics)

  • 박준기;김영훈;한정인
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2011년도 제42회 하계학술대회
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    • pp.1266-1267
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    • 2011
  • We studied the influence of cathode material on the stability of organic phtovoltaics (OPVs). OPVs with LiF/Al and Ag/Ca/Ag cathode were fabricated and the stability were evaluated. The sample with LiF/Al cathode showed efficiency degradation from 2.42% to 2.04% during 50 days. On the other hand, the sample with Ag/Ca/Ag cathode showed more steeper efficiency degradation from 2.38% to 0.80% during 50 days. The different of degradation can be attributed to a larger increase of series resistance ($R_s$) in Ag/Ca/Ag cathode sample.

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Preparation of Graphene-BiOCl/Fe3O4 Nanocomposites and Their Use as Photocatalysts for Organic Dyes Degradation

  • Zhang, Fuyong;Ko, Weon Bae
    • Elastomers and Composites
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    • 제52권1호
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    • pp.9-16
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    • 2017
  • Graphene-$BiOCl/Fe_3O_4$ nanocomposites were synthesized from $BiOCl/Fe_3O_4$ and graphene in an electric furnace operating at $700^{\circ}C$ for 12 h. The nanocomposite surface morphology and crystal structure were characterized by scanning electron microscopy and X-ray diffraction. The produced graphene-$BiOCl/Fe_3O_4$ nanocomposites acted as efficient heterogeneous photocatalysts for the degradation of organic dyes, as confirmed by UV-vis spectrophotometry.

Physical Aging Mechanism of Epoxy Coating by Hygrothermal Cycling Test

  • Kim, Min Hong;Lee, Gun Dae;Park, Jin Hwan
    • Corrosion Science and Technology
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    • 제5권5호
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    • pp.177-180
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    • 2006
  • The anticorrosive performance of epoxy coating was examined by using the hygrothermal cyclic test and the degradation mechanism of the coating was investigated by using the AC impedance method. The relationship between the results obtained from different tests was studied. It was revealed that the hygrothermal cyclic test can be used as an effective acceleration test for the degradation of organic coating. It was also found in hygrothermal cyclic test that the epoxy coatings have the resistance to stresses at some extent. The degradation of organic coating seems to be caused by the decrease of resistance of coating and the increase of both capacitance and free volume in the organic coating.

목질바이오칩에 의한 음식물쓰레기 발효-소멸반응에서의 아데노신3인산의 변화 (Variation of Adenosine tri-Phosphate(ATP) in Fermentation-Extinction of Food Wastes with Wood Bio-Chip)

  • 오정익
    • 대한환경공학회지
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    • 제32권4호
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    • pp.363-368
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    • 2010
  • 본 연구에서는 아데노신3인산의 측정을 통하여 음식물 쓰레기의 발효-소멸반응에서의 미생물이 발생 및 활성정도를 총괄할 수 있는 인자를 도출할 수 있었다. 목질바이오칩을 이용한 음식물 쓰레기의 발효-소멸에서 무게감량 및 유기물 분해율이 높아질수록 아데노신3인산의 농도가 증가하였다. 아데노신3인산은 목질바이오칩의 종류별 유기물 분해 및 무게 감량에 대한 성능 선택성 설정에 유용한 인자로 활용 기대된다.