• 환경위생공학
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• 제10권3호
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• pp.78-84
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• 1995

Cationic surfactants can be used to modify surface of solids to promote adsorption of hydrophobic organic compounds. This behavior is due to the surfactant forming aggregate structure on the solid surface. Partition coefficients are commonly used to quantify the distribution of organic pollutants between the aqueous and particulate phases of aquatic system Partitioning of hydrophobic compounds to cetyltrimethylammonium bromide ( CTAB ) coated silicate has been investigated as a function of surfactant surface coverage at I=0 and 0.1 ionic strength. Toluene, Xylene, TCI sorption experiments demonstrated that the CTAB coated silicate was able to remove these hydrophobic organic compounds from solution The hydrophobic organic compound with the higher Kow had higher removals than lowest Kow hydrophobic organic compound.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.257-257
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• 2013

In order to selectively remove oil and organic compound from water, silica nanoparticles with hydrophobic coating was used. Since silica nanoparticles are generally hydrophilic, removal efficiency of oil and organic compound, such as toluene, in water can be decreased due to competitive adsorption with water. In order to increase the removal efficiency of oil and toluene, hydrophobic polydimethylsiloxane (PDMS) was coated on silica nanoparticles in the form of thin film. Hydrophobic property of the PDMS-coated silica nanoparticles and hydrophilic silica nanoparticles were easily confirmed by putting it in the water, hydrophilic particle sinks but hydrophobic particle floats. PDMS coated silica nanoparticles were dispersed on a slide glass with epoxy glue on and the water contact angle on the surface was determined to be over $150^{\circ}$, which is called superhydrophobic. FT-IR spectroscopy was used to check the functional group on silica nanoparticle surface before and after PDMS coating. Then, PDMS coated silica nanoparticles were used to selectively remove oil and toluene from water, respectively. It was demonstrated that PDMS coated nanoaprticles selectively aggregates with oil and toluene in the water and floats in the form of gel and this gel remained floating over 7 days. Furthermore, column filled with hydrophobic PDMS coated silica nanoparticles and hydrophilic porous silica was prepared and tested for simultaneous removal of water-soluble and organic pollutant from water. PDMS coated silica nanoparticles have strong resistibility for water and has affinity for oil and organic compound removal. Therefore PDMS-coated silica nanoparticles can be applied in separating oil or organic solvents from water.

• 한국토양비료학회지
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• 제25권1호
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• pp.52-56
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• 1992

1. 유기물(O.M)함량과 염기치환용량(C.E.C.)이 극히 낮은 본 시험 토양의 시험 토양 분석 결과에 의하면 기타 물질 시용에 관계없이 복비 시용이 토양 중 N.P.K 함량 모두를 증가 시켰으며 특히 N은 Peat 시용에 의하여도 현저히 증가하였고 미원 비료시용에 의하여도 약간 증가하는 경향을 보였다. 2. 식물체중 양분함량을 보면 무의 경우 N, Ca 및 Mg 함량이 지하부보다 지상부에 P는 지하부에 많이 분포함을 보였으며 각처리에 따른 양분함량 분포는 복비시용은 기타처리에 관계없이 복비 무시용구에 비하여 높은 N함량 분포를 나타냈다. 3. 배추의 경우도 역시 N.P.K성분 모두가 모든 처리에서 무처리에 비하여 높은 함량을 나타내었으며 또한 무우의 경우와 유사하게 복비시용이 무시용에 비하여 N.P.K함량이 더욱 높이는 경향이었다. 4. 무우, 배추수확량은 모든처리가 무처리에 비하여 수량을 증가시켰으나 모든 유기질 비료들의 단독효과는 미원비료 2배수준을 제외하고는 모두 복비효과보다 낮았으며 복비를 추천량과 함께 유기질 비료를 시용할 경우는 전연 반대로 모든 유기질 비료가 복비 단독 효과보다는 월등히 높았다. 5. 수량에 미치는 유기질 비료종류간의 상대적 효과는 복비 시용여부에 관계없이 다음과 같은 순서로 요약 될 수 있다. 미원 비료 ${\geq}$ Biovin > 일반퇴비 ${\geq}$ Peat

• 한국염색가공학회지
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• 제24권3호
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• pp.153-157
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• 2012

One of organic dye materials which have been long lasting investigated is rhodamine 6G dye series. This dye has been attracted with considerable interests due to the reason of its promising photochemical properties. In this study, a novel fluorescent dye compound based on rhodamine 6G derivative was synthesized through the reaction of rhodamine 6G hydrazide and indole-3-carboxaldehdyde. Absorption and fluorescent emission spectra of this dye were determined with the properties of solvatofluorochromism. Related electron energy states of the dye compound were also characterized by computational calculations.

• 한국군사과학기술학회지
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• 제18권5호
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• pp.548-557
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• 2015

This paper is results on Chemisorption of organic compound for the sea water fire fighting line of naval vessels. The quantitative analysis of Chemisorption has been investigated in seawater after immersion in 0.1 % of NaDDTC solutions for 43 hours. The morphology and topography were investigated by FE-SEM and AFM. The chemical elements were analyzed by SEM-EDS, XPS and the depth of chemical elements was measured by depth profiles. The effect of NaDDTC comes from Chemisorption between Copper and Sulfur of NaDDTC. As a result, test results showed that sulfur is helpful to protect a corrosion of seawater line.

• 한국표면공학회지
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• 제29권5호
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• pp.593-598
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• 1996

Previously, in trying to prepare perovskite type oxide powders by microwave heating, we found out a non-equilibrium argon plasma is generated around the powders and discharge continues stable at atmospheric pressure. In this study, we tried the plasma decomposition of heat-stable higher organic compound such as palmitic acid which is the principal constituent of the fimger fats. It was proved that suitable amount of coexistence of oxygen radicals into the argon flow accelerates the decomposition of palmitic acid. The argon-oxygen mixed gas plasma was able to perform a complete elimination of higher organic compound.

• 한국초지조사료학회지
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• 제8권2호
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• pp.92-98
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• 1988

山地초지에 고토와 함유된 有機質複合비료의 施用이 목장의 건물수량, 수량구성요소 및 식생변화에 마치는 影響을 究明코자 비종과 시비수준을 달리한 5處理를 亂塊法 3反復으로 團場配置하여 1984年 9月부터 1986年 10月까지 水原 근교의 신 개척지에서 本 試餘을 수행하였던 바 그 결과를 요약하면 다음과 같다. 1. 목장의 耐冬性, 生育勢 및 被覆率 等 初期生 育狀態는 有機質複함포료 施用區가 단비시용에 比해 良好하였다. 2. 2年평균 목장의 乾物收量은 시비水準間에는 有意差있는 增收했果가 있었으며, 少肥施用水準에서 단비구의 乾物수량 7,930.6kg/ha에 比해 有機質 複合비료 施用區는 8,693.1kg/ha로서10%, 普肥施 用水準에서는 單肥區의 11,122.6kg/ha에 比해 有機 質複合肥料 施用區는 12,758.7kg/ha를 生産하여 15% 회수되었으나 有意性은 없었다. 3. 植牛別 건물수량은 未本科 救草의 경우 施肥量이 많아짐에 따라 有意差있게 증가하였으며 (P<0.01), 荳科救草의 收量은 無肥區는 施肥區(少肥, 普肥)에 比해 顧著히 회수되었으나(P< 0.01), 少肥와 普肥施用水準 問에는 有意性이 없었다. 한편 肥種問에서는 有機質複合肥料 施用區가 單肥에 比해 未本科 목초는 8-14%, 荳科는 26-29% 增收되었으나 有意性은 없었다. 4.. 植生構成比率은 草地管理時에 施肥 하지 않은 곳은 荳科의 優古現象이 나타났으나, 3要素 施用區는 植生比率 및 목초율이 적합하였으며, 유기質複合비료 施用區의 荳科比率은 單肥施用區에 比해 漸次 增加되는 碩向이였다. 5. 試嚴後 士壞의 化學成分은 試餘前에比해 顯 著히 높아졌으나 施肥水準을 平均하여 볼때 有機質 複合nE料 施用區는 單肥에 比해 有機物과 有郊憐嚴含量은 높았고, pH 및 置換性 醒基는 若千 낮은 碩向이었다.

• Archives of Pharmacal Research
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• 제25권3호
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• pp.258-269
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• 2002

2-Thiouracil-5-sulfonylchloride 1 reacted with a series of aromatic and heterocyclic amines to give 2a-j. The same compound 1 was reacted with a series of sulphonamides giving different sulphonamides of type 3a-e. On the other hand compound 1 was allowed to react with p-aminoacetophenone givining compound 4 which in turn was allowed to react with derivatives of alkyl thiosemicarbazides to give thiosemicarbazones of type 5a-e, also compound 4 was monobrominated to give compound 6 which in turn was reacted thiosemicarbazones of some aldehydes to give the corresponding thiazole derivatives 7a-f. In the same time compound 4 was reacted with a series of aromatic and heterocyclic aldehydes givining chalcones 8a-g (Claisen-Schemidt reaction). Also compound 4 was allowed to react with a series of aromatic and heterocyclic aldehydes, ethyl cyano acetate and/or malononitrile, and ammonium acetate giving pyridine derivatives 9a-d and 10a-e respectively. The biological effects of some of the new synthesized compounds was also investigated.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.286-291
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• 2001

As part of fundamental studies on the degradation of the organic compounds in industrial waste water, the photocatalytic degradation properties of the organic compound by means of the UV/TiO$_2$degradation process have been investigated. The test organic compound of acetic acid was chosen in this study. The testing of photo catalytic degradation were performed under various operation conditions such as TiO$_2$dosages, initial concentration of the organic, the aqueous pH's, etc. The effects of various parameters on the short time activity of the present acetic acid-UV/TiO$_2$system could be demonstrated from this investigation.

• Bulletin of the Korean Chemical Society
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• 제30권1호
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• pp.197-200
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• 2009

A simple dye having phenol and indole moieties was synthesized and its chromogenic signaling behaviors for the determination of water content in organic solvents were investigated. The compound revealed a pronounced chromogenic behavior in response to the variation of water content in water miscible aprotic organic solvents of acetone, acetonitrile, THF, and dioxane. Significant red shifts and changes in absorption spectra allowed a ratiometric analysis of the signaling behavior. The chemosensing behaviors were particularly pronounced in water content in less than 10% that is suitable for the application of the compound as a probe for the determination of water content in binary aqueous organic solutions having lower water content.