• Title/Summary/Keyword: Organic complex

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Evaluation of Organic Matter and Trace Metal Contamination in Surface Sediments around the Geum River Estuary using Sediment Quality Guidelines (퇴적물 오염기준을 이용한 금강 하구역 표층 퇴적물내 유기물 및 미량금속 오염 평가)

  • Hwang, Dong-Woon;Lee, In-Seok;Choi, Minkyu;Kim, Sook-Yang;Choi, Hee-Gu
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.46 no.6
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    • pp.930-940
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    • 2013
  • We evaluated contamination with organic matter and trace metals by analyzing grain size, ignition loss (IL), chemical oxygen demand (COD), acid volatile sulfide (AVS), and trace metals (Al, Fe, Cu, Pb, Zn, Cd, Ni, Cr, Mn, Hg, and As) in surface sediments at 28 stations around the Geum River estuary in July 2008. The surface sediments in the estuary were mainly composed of coarse sediment (sand and muddy sand), with mean grain size (Mz) ranging between $2-4{\O}$. The high concentrations of IL, COD, and trace metals were mainly found at stations in front of the Gusan outer port and industrial complex, and near the Seocheon coast with relatively fine sediments. In addition, the concentrations of IL and all trace metals, except Pb and As, showed good positive correlations with Mz, indicating that the concentrations of organic matter and trace metals were mainly dependent on sediment grain size. The concentrations of COD, AVS, and trace metals in most sediments did not exceed the sediment quality guideline (SQGs). Although the sediments in the study region are not polluted with organic matter and trace metals, there are many point sources of pollutants, such as Gusan port and industrial complex, Janghang refinery, and a thermoelectric power plant around the Geum River estuary. Thus, the management of coastal environments through periodic monitoring of organic matter and trace metals is required in the future.

Deep red electrophosphorescent organic light-emitting diodes based on new iridium complexes

  • Gong, Doo-Won;Kim, Jun-Ho;Lee, Kum-Hee;Yoon, Seung-Soo;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1075-1078
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    • 2006
  • New iridium complex was synthesized and demonstrated a deep red light emission in organic light-emitting diodes (OLEDs). The maximum luminance of 8320 cd/m2 at 15 V and the luminance efficiency of 2.5 cd/A at 20 mA/cm2 were achieved. The peak wavelength of the electroluminescence was at 626 nm with the CIE coordinates of (0.69, 0.30), and the device also showed a stable color chromaticity with various voltages.

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Factors related to Performance of Reverse Osmosis Membrane in Seawater Desalination Process (해수담수화 공정에서 역삼투막의 거동에 영향을 주는 요인)

  • Park, Jun-Young;Hong, Sung-Ho;Kim, Ji-Hoon;Jeong, Woo-Won;Nam, Jong-Woo;Kim, Young-Hoon;Lee, Chang-Ha;Kim, Hyung-Soo
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.2
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    • pp.171-176
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    • 2011
  • Organic matters that comprise a tiny part of seawater generally occur over 50% of membrane fouling in Reverse Osmosis Process. This study evaluates Foundation efficiency of reverse osmosis membranes under brackish and seawater conditions and resistance of organic fouling. Moreover, analyzing the membrane surface through roughness, contact angle and zeta potential results in roughness and contact angle are proportional to flux decline rate (FDR), yet FDR has high value when zeta potential is low level. Furthermore, with various membrane fouling of different raw water conditions, the flux tends to improve when pH value is high and raw water which is complex with organic and cation pollutes membrane faster than organic separated raw water condition.

Temperature-dependent dielectric relaxation in ITO/Alq3/Al organic light-emitting diodes

  • Ahn, Joonho;Kim, Tae Wan;Lee, Won Jae
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.163-165
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    • 2012
  • Impedance spectroscopy informs electrical properties of materials as accumulated charges, contact status between electrode and organic materials. We carried out impedance spectroscopy of organic light-emitting diodes as ITO/Alq3(60 nm)/Al on temperatures from 10 K to 300 K. The result described Z'-Z" plot, cole-cole plot and dielectric relaxation time τ. Z'-Z" plot means that real and imaginary part of materials in organic and electrode by frequencies and temperature. Z' as real part of impedance by applied frequency depending on temperature shows the plateau in low frequency region as Rs+ Rp and over 100 kHz in high frequency region as Rs. Cole-cole plot shows resistance of materials in equivalent circuit of the device by temperatures. And equivalent circuit and dielectric relaxation could be accomplished by using the complex impedance analysis.

The effect on the Rf value by the number of thiocyanate radical in various thiocyanate ammine chromium complex salts (Thiocyanato ammine계 chromium complex salts에 있어 thiocyanato기의 수가 Rf치에 미치는 영향)

  • 최종인
    • YAKHAK HOEJI
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    • v.10 no.4
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    • pp.1-6
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    • 1966
  • Various thiocyanatoammine chromium complex salts are prepared by the known methods and the Rf. value of these complex salts are determined by four developers. These four developers were used in the paper chromatographical work of cobalt complex salts by Yamamoto in 1954. It was also found that the developer A (Ch$_{3}$OH, acetone, NH$_{4}$OH) gave best results of these four developers and the decending development gave better results than ascending development in this experiment. In the case of decending development using developer A, it is found that the Rf. value is increased with the number of thiocyanate radical. The reason of this curious results can be explained that the thiocyanate radical in the complex ion is more active for the organic solvent than ammine radical. Shifting of electrons to the central metal and the charge of the complex ion can also effect ot the Rf. value but much questions are remained for the explanation of the above curious phenomenon. Separation of mixed sample is also studied for various mixture of the above complex salts. In the case of the mixture of hexammine and diammine complex salt, the clear separation is possible but in almost all other mixed sample, the results are not clear. Therefore it can be said that the results of this work can be used in the qualitative analysis of the individual complex salts, except the mixed sample of hexammine and diammine complex salts.

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Dielectric Properties depending on Frequency in ITO/$Alq_3$/Al (ITO/$Alq_3$/Al의 주파수 변화에 따른 유전 특성)

  • Oh, Y.C.;Lee, D.K.;Kim, J.S.;Shin, C.G.;Lee, S.I.;Kim, C.H.;Kim, T.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.292-293
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    • 2006
  • We have Investigated dielectric properties depending on bias voltage in organic lightemitting diodes using 8-hydroxyquinoline aluminum($Alq_3$) as an electron transport and emissive material. We analyzed the dielectric properties of organic light emitting diodes using impedance characteristics measurement by the auto-balancing bridge technique and equivalent cirrcuit of ITO/$Alq_3$/Al. Impedance characteristics was measured complex impedance Z and phase ${\theta}$ in the frequency range of 40 [Hz] to $10^8$ [Hz]. We obtained complex electrical conductivity, dielectric constant, and loss tangent ($tan{\delta}$) of the device at room temperature. From these analyses, we are able to interpret a conduction mechanism and dielectric properties contributed by an interfacial and orientational polarization.

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The Characteristic of Volatile Organic Compounds(VOCs) Emission from the Type of Indoor Building Materials as the Temperature and Humidity (온.습도에 따른 건축 내장재별 휘발성유기화합물의 방출특성)

  • Seo, Byeong-Ryang;Kim, Shin-Do;Park, Seong-Kyu
    • Journal of Environmental Health Sciences
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    • v.32 no.4 s.91
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    • pp.292-303
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    • 2006
  • The Volatile Organic Compounds(VOCs) are emitted from various sources and have lots of different form. Recently human are spending the many times at indoor area and indoor air pollution is issued the important social problem. The emission sources of indoor air pollutants are very various, also indoor building materials are composed of very complex chemical compounds, these indoor building materials discharge very much VOCs and other hazardous compounds. In this study, we performed the small chamber test to investigate the VOCs emission concentration and characteristics involving five kinds of the indoor building materials(furniture material, wooden floor, wall paper, paint and tile) under different conditions of four temperature and relative humidity as account of the air flow rate(AFR), air exchange rate(AER), loading factor and air velocity respectively. As the result, It was showed that building materials are emitted the highest VOCs concentration at the beginning of experiment and furniture material is emitted the highest VOCs concentration. Most of the materials were affected by temperature, but paint and tile material were affected by humidity.

Assessment of Organic Matter Sources in the Singil Stream Flowing into Lake Shihwa, South Korea

  • Kim, Dahae;Kim, Jung-Hyun;Kang, Sujin;Kim, Min-Seob;Shin, Kyung-Hoon
    • Korean Journal of Ecology and Environment
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    • v.53 no.2
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    • pp.138-147
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    • 2020
  • The Singil Stream, flowing into an artificial lake, Lake Shihwa (South Korea), experiences a strong anthropogenic pressure with continuous organic matter (OM) inputs from rural, urban, and industrial areas. In this study, we investigated suspended particulate matter (SPM) and streambed sediments collected along the Singil Stream in 2014 and 2016, by applying a dual element approach (δ13C and δ15N) to identify OM sources. The SPM and streambed sediment samples from the indusrial area showed higher organic carbon and nitrogen concentrations (or contents) than those from the other areas, with distinctively lower δ15N values. Accordingly, our dual element approach indicates that the industrial area was the predominant OM source influencing OM quality and thus water quality of the Singil Stream flowing into Lake Shihwa during the study periods. However, further studies are necessary to better constrain OM sources in the Singil Stream since OM sources from the industrial area appear to be complex.

The Architectural Concepts and Design Properties as a Complex System (복잡계로서의 건축개념과 조형적 특성에 관한 연구(I))

  • 김주미
    • Korean Institute of Interior Design Journal
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    • no.22
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    • pp.123-131
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    • 2000
  • The purpose of this study is to propose a new design concept and properties within new paradigm. Contemporary students of architectural design seem to redefine the mechanic and reductive approach to design method based upon Euclidean geometry. In this study, the organic space-time and holistic view-point that constitutes the background for all this is radically different from the modern design. It consists of three sections as follow: First, it presents a concept of complex system and properties of complexity that we find in new natural science and tries to combine that news geometry with architectural design to provide a methodological basis for morphogenesis and transformation. Second, the complexity in architecture is defined as a fractal shape, folded space, and irreducible organic system that cannot be fully understood by modernist idea of architecture. Third, the complexity in architecture is strategy based on the electronic paradigm that would enable the emergence of creative possibility. The complexity theory offer new insights to explain not only natural laws but also define dynamic architecture. In fine, this study places a great emphasis on the organic world-view to the spatial organization, which I hope will contribute to generating a greater number of creative possibilities for design.

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Racemization of Optical Active tris-Oxalatocobaltate (III) Ion in Mixed Solvants (혼합용매내에서 광학활성인 tris-Oxalatocobaltate (III) ion의 라세미화에 관한 연구)

  • Dong Jin Lee;Doh Myung Ki
    • Journal of the Korean Chemical Society
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    • v.30 no.4
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    • pp.377-382
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    • 1986
  • Racemic tris-oxalatocobaltate (III) complex ions were optically resolved by an optical active complex, ${\Delta}$-tris-ethylenediamine cobalt (III), and then racemization of ${\bigwedge}-[Co(ox)_3]^{3-}$ obtained was investigated in various mixed solvent such as water-organic solvent (organic solvents=ethanol, iso-propyl alcohol, acetone, and dioxane). The rate of racemization was increased with following order; water < ethanol < acetone < isopropyl alcohol < dioxane; which is the same order for polarizability of organic solvent added. Considering ${\Delta}H^{\neq},\;{\Delta}S^{\neq}$ and above facts for the racemization of ${\bigwedge}-[Co(ox)_3]^{3-}$, it seems to be twist mechanism of plausible mechanisms.

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