• Title/Summary/Keyword: Organic acid mixture

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Kinetic modeling analysis for the decolorization of dyes using a mixed adsorbent

  • Ravikumar, K.;Son, Young-A
    • Textile Coloration and Finishing
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    • v.18 no.5 s.90
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    • pp.42-47
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    • 2006
  • A mixed adsorbent prepared by pyrolysing a mixture of carbon and flyash in 1:1 ratio was tested for its deceleration ability for three different classes of dyes namely, Astrazone Blue FRR(Basic Blue 69), Teflon flue ANL(Acid Blue 125) and Verofix Red(Reactive Red 3GL). Kinetic analyses were carried out at the optimum conditions obtained by the author in the previous studies. The data was fitted with three kinetic model equations. The results showed that the dye uptake mechanism followed the second-order rate expression.

Preparation of Zeolite-Filled PDMS Membranes and Its Properties for Organic Vapor Separation

  • Kim, Min-Joung;Youm, Kyung-Ho
    • Korean Membrane Journal
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    • v.2 no.1
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    • pp.48-55
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    • 2000
  • In order to improve organic vapor separation efficiency of polydimethylsiloxane (PDMS) membrane, various zeolites (zeolite 4A, zeolite 13X and natural zeolite) were introduced into a thin PDMS film. The measurements of permeability and selectivity of zeolite-filled PDMS membranes were carried out with a CO$_2$gas and a CO$_2$gas/acetic acid vapor mixture, respectively. The CO$_2$permeability of zeolite-filled membranes decreased with increasing zeolite content and then recovered up to 30 wt% content. The effect of zeolite type on the improvement of CO$_2$permeability was found to be in the order of zeolite 13X > natural zeolite > 4A. The CO$_2$selectivity of zeolite-filled membranes was enhanced up to 9 times compared with the selectivity of a pure (unfilled) PDMS membrane. The effect of zeolite type on the improvement of CO$_2$selectivity was found to be in the order of natural zeolite > zeolite 13X > zeolite 4A.

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Effect of Thermal Annealing of Gravure Printed Polymer Solar Cells

  • Lee, Ji-Yeon;Kim, Jung-Woo;Kim, Hyung-Sub;Cho, Sung-Min;Chae, Hee-Yeop
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1571-1572
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    • 2009
  • Polymer solar cells were fabricated with gravure printing process and the effect of thermal annealing of gravure printed organic layer was investigated. The layer structure of polymer solar cells is glass / ITO / hole transfer layer / active layer / Al structure was fabricated. For the active layer, 1:1 ratio of poly-3-hexylthiophene (P3HT) and [6,6]-phenyl C61-butyric acid methyl ester (PCBM) mixture was applied. The P3HT/PCBM blend was gravure printed onto the substrates. The effect of thermal annealing was investigated by changing annealing time and the number of printing. Maximum 3.6% of power conversion efficiency was achieved with gravure printing of organic layer and thermal annealing in this work.

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Rapid Formation of Optically Active and Organosoluble Polyamides Containing L-Alaninephthalimide Side Chain via Microwave Irradiation

  • Mallakpour, Shadpour;Rafiee, Zahra
    • Macromolecular Research
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    • v.17 no.11
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    • pp.901-906
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    • 2009
  • Several aromatic optically active polyamides (PA)s were synthesized from 5-(2-phthalimidiylpropanoylamino)isophthalic acid with various aromatic diamines via direct polycondensation with triphenyl phosphite and pyridine in the presence of calcium chloride and N-methyl-2-pyrrolidone under microwave irradiation and conventional heating conditions. Under the optimized conditions, the reaction mixture was irradiated for 2 min. with a 100% irradiation power (900 W). The resulting polymers were obtained in high yield and moderate inherent viscosity ranging from 0.35 to 0.60 dL/g. All synthesized polymers showed excellent solubility in amide-type solvents. Thermogravimetric analysis revealed a 10% weight loss temperature and char yield at $600^{\circ}C$ in a nitrogen atmosphere of > $350^{\circ}C$ and > 58%, respectively, which suggests that the resulting PAs have good thermal stability.

Determination of sulfur containing organic drugs by means of thin layer chromatography and flask combustion method (Thinlayer chromatography및 oxygen combustion flask method에 의한 유기유황약품의 분리정량)

  • 백남호;김박광
    • YAKHAK HOEJI
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    • v.13 no.2_3
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    • pp.84-87
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    • 1969
  • Microanalysis of organic sulfur compounds by means of combining thin layer chromatography and oxygen combustion flask method was attempted. The following procedure was found to be very simple and to give accurate results. The mixture of sulfa drugs was separated with T.L.C., and it was burned in a flask filled with oxygen, and the gas formed was absorbed in a dilute solution of sodium hydroxide. The solution was neuralized with hydrochloric acid and heated in a water bath. The sulfate ion formed was then treated with barium chromate solution and its absorbancy at 370 m.mu. was measured.

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Identification, Characteristics, and Growth Inhibition of the Strain Isolated from Spoiled Wet Noodle

  • Kim, Hyeong-Hyoi;Jeong, Eun-Jeong;Jeong, Do-Yeong;Kim, Yong-Suk;Shin, Dong-Hwa
    • Food Science and Biotechnology
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    • v.14 no.4
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    • pp.461-465
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    • 2005
  • To determine the cause of wet noodle spoilage, microorganisms isolated from wet noodles were identified and characterized. In addition, the growth inhibitory effects of organic acid mixture (OA: lactic acid 27.8%, acetic acid 12.0%, succinic acid 1.0%) and sodium dehydroacetate (SD) on the isolated strain were estimated in nutrient broth medium. The isolated strain was Gram-positive, rod shaped, motile, and spore forming. Based on physiological characteristics and the API 50 CHB-kit test results for the assimilation of 49 carbohydrates, the isolated strain was identified as Bacillus amyloliquefaciens (92.6%), which is able to degrade starch. Decimal reduction times (D-values) at 100, 105, and $110^{\circ}C$ for spores of B. amyloliquefaciens were 8.5, 5.1, and 2.5 min, respectively, and the z-value was $12.8^{\circ}C$. We estimated that B. amylo-liquefaciens isolated from spoiled wet noodles was a thermophilic species having high heat-resistance. Viable cell numbers in wet noodles and broth medium inoculated with B. amyloliquefaciens were decreased by 2-4 log cycles by combined treatment with 0.03 or 0.05% OA and 0.3% SD. These results revealed that OA combined with SD could be used as a potential agent to inhibit B. amyloliquefaciens in wet noodles.

Solvent Extraction of Li(I) from Weak HCl Solution with the Mixture of Neutral Extractants Containing FeCl3 (FeCl3를 함유한 중성추출제의 혼합용매로 약한 염산용액으로부터 리튬(I)의 용매추출)

  • Xing, Weidong;Lee, Seah;Lee, Manseung
    • Resources Recycling
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    • v.27 no.6
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    • pp.53-58
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    • 2018
  • Solvent extraction of Li(I) from weak HCl solution was investigated by the mixture of TBP/MIBK with other neutral extractants such as Cyanex 923, TOPO and TOP. The TBP/MIBK organic phase was loaded with 0.1 M $FeCl_3$ at different HCl concentrations (1-9 M). Extraction of Li(I) from weak HCl solution is related to the stability of $FeCl_3$ in the organic mixture. As HCl concentration increased in preparing the loaded TBP phase, the stripping percentage of Fe(III) during the extraction of Li(I) became reduced and thus Li(I) could be extracted by ion exchange reaction with hydrogen ion in the organic. The concentration of TBP in the extractant mixture affected the stability of $FeCl_3$. Compared to TBP, Fe(III) was easily stripped from the loaded MIBK and thus no Li(I) was extracted by the mixture with MIBK. The nature of neutral extractant with TBP/MIBK showed little difference in the extraction of Li(I) and stripping of Fe(III).

Changes in Chemical Properties and Microbial Population of Farm-Made Organic Liquid Fertilizer during Fermenting Process (농가 자가제조 액비의 발효과정 중 이화학성 및 미생물상 변화)

  • An, Nan-Hee;Kim, Yong-Ki;Lee, Yeon;Jee, Hyeong-Jin;Park, Jong-Ho;Hong, Sung-Jun;Han, Eun-Jung
    • Korean Journal of Organic Agriculture
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    • v.19 no.3
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    • pp.417-425
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    • 2011
  • This study was conducted to investigate the changes in physicochemical and microbiological properties during fermenting process of farm-made organic liquid fertilizer made of the mixture of organic materials such as blood meal and molasse during fermenting process. The pH level of organic liquid fertilizer during the ermentation decreased from 7.2 to 4.3. The EC of organic liquid fertilizer was increased from 13.9 dS/m to 99.3 dS/m during the fermentation. The total population of aerobic bacteria decreased from $8.2{\times}10^5$ cfu/ml to $3{\times}10^4$ cfu/ml, but Bacillus spp. increased from $2.1{\times}10^2$ cfu/ml to $4.2{\times}10^3$ cfu/ml during the fermentation. Bacterial isolates were obtained from organic liquid fertilizers and identified by fatty acid-base typing. The Genus Bacillus was dominant as fermenting proceeded. The denaturing gradient gel electrophoresis (DGGE) profile showed changes of bacterial communities in organic liquid fertilizers.

Changes in the Characteristics of Dissolved Organic Matter by Microbial Transformation and the Subsequent Effects on Copper Binding (생분해에 따른 용존 유기물질 성상 및 중금속 구리와의 결합특성 변화)

  • Jung, Ka-Young;Hur, Jin
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.1
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    • pp.49-54
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    • 2012
  • Microbial changes in the characteristics of dissolved organic matter (DOM) and the subsequent effects on the conditional stability constants of copper were investigated using 14 day-incubations of Pony Lake fulvic acid (PLFA), Suwannee River fulvic acid (SRFA) and the mixtures of the humic substances and glucose. After incubation, dissolved organic carbon (DOC) concentrations were diminished, and specific UV absorbance values and DOC-normalized fluorescence intensities increased. The microbial changes were minimal for the samples contaning humic substances only whereas they were much pronounced for the mixtures with glucose. The extent of the changes increased with a higher content of glucose in the mixtures. The same trend was observed even for glucose solution. Our results suggest that labile organic moieties may be transformed into more chromophoric and humidified components by biodegradation. For the mixture samples, the copper binding stability constants did not change or even decreased after incubation. Therefore, microbially induced enrichment of the fulvic- and humic-like carbon structures in DOM appears to result in little change or the decrease of the copper binding coefficients.

Control of Meloidogyne incognita Using Mixtures of Organic Acids

  • Seo, Yunhee;Kim, Young Ho
    • The Plant Pathology Journal
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    • v.30 no.4
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    • pp.450-455
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    • 2014
  • This study sought to control the root-knot nematode (RKN) Meloidogyne incognita using benign organo-chemicals. Second-stage juveniles (J2) of RKN were exposed to dilutions (1.0%, 0.5%, 0.2%, and 0.1%) of acetic acid (AA), lactic acid (LA), and their mixtures (MX). The nematode bodies were disrupted severely and moderately by vacuolations in 0.5% of MX and single organic acids, respectively, suggesting toxicity of MX may be higher than AA and LA. The mortality of J2 was 100% at all concentrations of AA and MX and only at 1.0% and 0.5% of LA, which lowered slightly at 0.2% and greatly at 0.1% of LA. This suggests the nematicidal activity of MX may be mostly derived from AA together with supplementary LA toxicity. MX was applied to chili pepper plants inoculated with about 1,000 J2, for which root-knot gall formations and plant growths were examined 4 weeks after inoculation. The root gall formation was completely inhibited by 0.5% MX and standard and double concentrations of fosthiazate; and inhibited 92.9% and 57.1% by 0.2% and 0.1% MX, respectively. Shoot height, shoot weight, and root weight were not significantly ($P{\leq}0.05$) different among all treatments and the untreated and non-inoculated controls. All of these results suggest that the mixture of the organic acids may have a potential to be developed as an eco-friendly nematode control agent that needs to be supported by the more nematode control experiments in fields.