• 제목/요약/키워드: Organic Coatings

검색결과 146건 처리시간 0.025초

$SrZrO_3 $박막의 접착강도에 미치는 Sr/Zr 몰비와 유기화합물 첨가효과 (Effect of Sr/Zr Ratio and Organic Vehicle Addition on Bond Strength of $SrZrO_3 $ Thin Films)

  • 이세종;이득용;예경환;송요승
    • 한국초전도ㆍ저온공학회논문지
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    • 제4권1호
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    • pp.13-16
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    • 2002
  • $SrZrO_3 $resistive oxide barriers on Ag sheathed Bi2223 tapes were prepared by the sol-gel and dip coating method to reduce AC coupling loss. The performance of the dip-coated $SrZrO_3 $ thin films was evaluated in terms of bond strength by varying the Sr/Zr mol ratio and the amount of organic vehicle (ethyl cellulose and a-terpineol) additives. The bond strength of the coatings increased as the Sr/Zr ratio decreased and the amount of organic vehicle rose, respectively. It was found that the effect of organic vehicle addition was more pronounced, suggesting that the adherence of the $SrZrO_3 $ films on Bi2223 tapes was governed primarily by the amount of organic vehicle additive.

PET 기판위의 투습율 향상을 위한 다층 보호막에 관한 연구 (Study on permeability improved multi-layer encapsulation on Ethylene Terephthalate(PET))

  • 한진우;강희진;김종연;강동훈;한정민;오용철;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.313-314
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    • 2006
  • In this paper, the inorganic-organic thin film encapsulation layer was newly adopted to protect the organic layer from moisture and oxygen. Using the electron beam, Sputter and Spin-Coater system, the various kinds of inorganic and organic thin-films were deposited onto the Ethylene Terephthalate(PET) and their interface properties between organic and inorganic layer were investigated Results indicates that the SiON/PI/SiON/PI/PET barrier coatings have high potential for flexible organic light-emitting diode(OLED) application.

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무기흡착제가 적용된 친환경 수성 코팅제의 특성 연구 (Characteristics of Environment-friendly Waterborne Coating Agent Applied to Inorganic Adsorbent)

  • 신종섭;이정희;곽은미;윤종국;김현범
    • 폴리머
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    • 제36권5호
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    • pp.622-627
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    • 2012
  • 친환경 수성 코팅제의 물성 강화 및 VOCs의 저감 특성을 연구하기 위해서 poly(tetramethylene glycol) 2000, polycarbonate diol 2000, isophorone diisocyanate, dimethylolpropionic acid, 그리고 titanium dioxide를 사용하여 유/무기 하이브리드 수분산 폴리우레탄 코팅제를 제조하였다. R ratio([NCO]/[OH])에 따른 코팅제의 필름 물성 및 무기물의 적용으로 인한 VOCs의 저감 특성에 대해서 연구한 결과 R ratio가 1.5 이상인 경우에서 코팅제로 적합함을 확인하였으며 이는 하드 세그먼트의 영향으로 여겨지며 $TiO_2$의 적용으로 코팅 후 VOCs의 저감 특성을 확인하였다.

UV-Curable Fluorinated Crosslinkable Polyurethane-Acrylates for Marine Antifouling Coatings

  • Park, Jin-Myung;Kim, Sung Yeol;An, Seung-Kook;Lee, Young-Hee;Kim, Han-Do
    • 청정기술
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    • 제23권2호
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    • pp.148-157
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    • 2017
  • To prepare UV-curable polyurethane-acrylate oligomer, NCO-terminated urethane prepolymers with trimethylolpropane, [TMP; 0 (0), 0.1 (0.021) and 0.2 (0.043) mole (mole fraction)] as crosslinkable tri-functional chain extender were end-capped with pentaerythritol triacrylate [PETA; 2.0 (0.400), 1.7 (0.354) and 1.4 (0.304) mole (mole fraction)] with one hydroxyl group/three vinyl functionalities. The stable as-formulated UV-curable polyurethane-acrylates [stable mixtures of PETA-capped oligomer/reactive acrylic monomer diluents without/with heptadecafluorodecyl methacrylate (PFA; 0, 6 and 9 wt%)] were formed up to 0.2 (0.043) mole (mole fraction) of TMP content in the prepolymer, while homogeneous-mixing failed at 0.3 (0.068) mole (mole fraction), in which the crosslink density in NCO-terminated urethane prepolymer was too high to enable the formation of stable mixture. This study examined the effect of TMP/PETA molar ratio and heptadecafluorodecyl methacrylate (PFA) content (wt%) on the properties of UV-cured polyurethane-acrylates as marine antifouling coating materials. The properties of UV-cured polyurethane-acrylate were found to be significantly dependent on the crosslinkable TMP/PETA ratio and PFA content. With the increasing of the TMP and PFA contents, the contact angles increased, and consequently the surface tension decreased. The adhesion of algae/barnacles to PFA contained film samples were found to be sufficiently weak to allow their easy removal. These results suggest that the UV-cured samples containing PFA have strong potential as coating materials for antifouling applications.

수용성 경화제에 의한 에폭시 수지의 물성에 관한 연구 (A Study on the Mechanical Properties of Water Soluble Curing Agent and Epoxy Resins)

  • 김용호;이광원;곽영채
    • Elastomers and Composites
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    • 제35권1호
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    • pp.12-18
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    • 2000
  • 환경에 대한 관심과 정부의 규제 강화로 에폭시 코팅 산업 분야에서 발생되는 휘발성 유기 물질 방출을 최소화하기 위하여 꾸준히 기술 개발을 해오고 있다. 환경 친화적인 기술 개발의 일환으로 본 연구에서는 amine-epoxy adduct (AEA)형의 수용성 에폭시 경화제를 합성하였고, 그의 구조를 FT-IR, GPC, TG/DTA로 확인하였으며, 합성한 수용성 경화제를 이용하여 KER-828 그리고 KER-500과의 경화 물성을 비교 조사하였다. 실험 결과에 의하면 건조시간은 KER-828이 KER-500보다 빨랐으나 접착력 및 내 충격성은 KER-500이 우수하였다.

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환경친화형 고고형분 자동차용 도료의 개발 (Development of Eco-Friendly High-Solids Paints for Automotive Coatings)

  • 박찬남;이원기;장성호
    • 한국환경과학회지
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    • 제17권8호
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    • pp.925-932
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    • 2008
  • Manufactures of automotive repair finishes are tending to reduce more and more the level of volatile organic compounds (VOCs) in their paint processes in order to comply with increasingly strict environmental legislation. The production of high solids paints is a way to solve this problem. However, the application of high-solids paints is limited primarily by the viscosity of resin which is strongly related to painting ability: the higher solid content, the lower desired property. In this study, alkyl copolymer with low viscosity was synthesized by the introduction of the monomers with long-side chains and functional groups which improve flexibility and cross-linking density, respectively. The solid content of the paint prepared with the synthesized resin was 80wt% and its VOCs was reduced by 20%, compared to the commercialized paint. Also, the physical and mechanical properties of coatings on steel sheets were similar to commercialized one.

Corrosion protection of magnesium alloys by organic coatings

  • Fazal, Basit Raza;Moon, Sungmo
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2016년도 추계학술대회 논문집
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    • pp.194.2-194.2
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    • 2016
  • Magnesium has many desirable properties of which the high strength/weight ratio makes it extremely valuable in automobile and aerospace industry. However, the high corrosion susceptibility of magnesium and its alloys has greatly limited their large scale use for various applications. Organic coating is one of the most effective ways to prevent magnesium alloys from corrosion. An organic coating is normally used in the final stage of a coating process. It can enhance corrosion resistance of magnesium and its alloys. Organic coating involves a variety of process such as painting, powder coating, cathodic electrocoating (E-painting) and the application of lacquers, enamel and varnishes.

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Variable surface coatings composed of organic-inorganic hybrid polymers

  • Kessler, Daniel;Bahnmuller, Stefan;Theato, Patrick
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.315-315
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    • 2006
  • A variable surface coating with the potential to fulfill the requirements of industry will be presented. Via controlled radical polymerization methods from a functionalized Polymethylsilsesquioxane delivers an inorganic-organic block copolymer, which can be easily modified and tuned for different applications. Spin coated or dip coated on various substrates show promising results. By using different block copolymers the contact angle on a silicon wafer can be varied in a range of $90^{\circ}\;up\;to\;145^{\circ}$ After curing and complete condensation a perfect adhesion on glasses, plastics and metals is achieved.

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Roll-to-Roll Barrier Coatings on PET Film by Using a Closed Drift Magnetron Plasma Enhanced Chemical Vapor Deposition

  • Lee, Seunghun;Kim, Jong-Kuk;Kim, Do-Geun
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2012년도 춘계학술발표회 논문집
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    • pp.124-125
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    • 2012
  • Korea institute of materials science (KIMS) use a linear deposition source called as a closed drift linear plasma source (CDLPS) as well as dual magnetron sputtering (DMS) to deposit SiOxCyHz films in $HMDSO/O_2$ plasma. The CDLPS generates linear plasma using closed drifting electrons and can reduce device degradations due to energetic ion bombardments on organic devices such as organic photovoltaic and organic light emission diode by controlling an ion energy. The deposited films are investigated by Fourier transform infrared (FT-IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM). Optical emission spectroscopy (OES) is used to measure relative radical populations of dissociation and recombination products such as H, CH, and CO in plasma. And SiOx film is applied to a barrier film on organic photovoltaic devices.

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용사를 이용한 고기능 $TiO_2$-생분해성 플라스틱 복합재료의 개발 (The Development of Functional $TiO_2$-Biodegradable Plastic Composite Material by Thermal Spraying)

  • 방희선;방한서;;;주성민;윤덕영
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2004년도 춘계 학술발표대회 개요집
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    • pp.316-318
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    • 2004
  • In recent years, plastic waste has been recognized as a worldwide environmental issue. To solve the disposal problem of the plastic waste, alternative treatment such as the use of biodegradable plastic(polybutylene succinate: PBS) is indeed highly in demand due to its merit of PBS buried in soil decomposed into carbon dioxide and water. In the present study, for the production of further functional PBS with TiO$_2$ as photocatalyst, which shows the decomposition of detrimental organic compound and pollutant under ultraviolet irradiation, we attempted to prepare photocatalytic TiO$_2$ coatings on PBS substrate by HVOF and plasma spraying techniques under various conditions using three kinds of agglomerated powders (P200: 200nm, P30: 30nm, P7: 7nm). The microstructures of coatings were characterized with SEM and XRD analysis, and the photocatalytic efficiency of coatings was evaluated through the photo degradation of gaseous acetaldehyde. Therefore, such functional TiO$_2$-Plastic composite material is expected to considerably contribute to the reduction of aggravated environmental problem.

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