• Title/Summary/Keyword: Organic Cation

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Antioxidant Enzyme Activities and Soil Properties of Healthy and Declining Abies koreana (Wils.) in Mt. Halla (한라산 구상나무 건전개체와 쇠약개체의 항산화효소활성 및 토양특성)

  • Lim, Jong-Hwan;Woo, Su-Young;Kwon, Mi Jeong;Kim, Young Kul
    • Journal of Korean Society of Forest Science
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    • v.96 no.1
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    • pp.14-20
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    • 2007
  • In order to examine the differences in antioxidant enzyme activities which represent defence mechanism to stressful environments, and soil properties between healthy and declining (or unhealthy) trees, we selected three sites, Witseorum, Youngsil and Sungpanak (Jindallebat). Antioxidant enzymes including Ascorbate peroxidase (APX) and Glutathione Reductase (GR), forest soil properties including soil texture, soil pH, organic matter, total nitrogen, available phosphate, cation exchange capacity, exchangeable cation content and nutrient contents in leaves of Abies koreana (Korean fir) trees were analyzed. There were no significant differences between healthy and declining trees in GR activity. However, seasonal difference in antioxidant enzyme activity was observed. GR activity was lower in June and August than that of September. Soil chemical and physical properties of each site showed a tendency that organic content, total nitrogen content, available phosphorus, cation exchange capacity and cation content were lower at the site of declining trees than the site of healthy trees.

Effect of Scutellaria baicalensis Georgi Extract on Oxidant-Induced Inhibition of Organic Cation in Rabbit Renal Cortical Slices (황금약침액(黃芩藥鍼液)이 가토(家兎)의 신피질절편(腎皮質切片)에서 Oxidant로 유발된 유기양이온의 이동장애에 미치는 영향(影響))

  • Son, In-suk;Cho, Tae-sung;Kwon, Hae-yon;Jo, Mi-hyeong;Youn, Hyoun-min;Jang, Kyung-jeon;Song, Choon-ho;Abn, Chang-beohm
    • Journal of Acupuncture Research
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    • v.19 no.2
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    • pp.211-220
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    • 2002
  • Objective : This study was undertaken to determine whether Scutellaria baicalensis Georgi extract (SbG) exerts the protective effect against oxidant-induced alterations in organic cation transport in the renal proximal tubule. Methods : Organic cation transport was estimated by examining alterations in tetraethylammonium (TEA) uptake in rabbit renal cortical slices. The slices were treated with 0.2 mM tBHP for 60 min at $37^{\circ}C$. tBl-IP caused an inhibition in TEA uptake by renal cortical slices. Such an effect was accompanied by depressed Na+-K+-ATPase activity and ATP depletion. Result : SbG prevented tBHP-induced inhibition of TEA uptake in a dose-dependent manner at the concentration ranges of 0.05-0.1%. SbG also prevented H2O2-induced reduction in TEA uptake. tBHP-induced inhibition of Na+-K+-ATPase activity and ATP depletion were significantly prevented by 0.05% SbG. Oxidants increased LDH release, which was blocked by SbG. Oxidants caused a significant increase in lipid peroxidation and its effect was prevented by SbG. Conclusion : These results suggest that SbG prevents oxidant-induced alterations in organic cation transport in rabbit renal cortical slices. Such protective effects of SbG may be attributed to inhibition of peroxidation of membrane lipid.

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A Study of Intercalations-complexes of Montmorillonite as Model-Systems (Model-system으로서의 몬트모릴로나이트의 층간화합물에 관한 연구 (I))

  • Jo, Seong-Jun;Kim, Jong-Ok
    • The Journal of Natural Sciences
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    • v.5 no.1
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    • pp.77-86
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    • 1992
  • By cation-exchange-reaction long-chain organic cationic tensides can be intercalated in the montmorillonite layer space, and thus intercalations-complexes of montmorillonite with different properties of materials can be obtained. Such intercalations-complexes are finding strong technical appliances in many areas and are also used very often as model-systems for studying behaviors of materials. Therefore in this research intercalations-complexes of montmorillonite with organic cationic tensides ad model-systems were synthesized and their behabiors under various different conditions were studied.

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Adsorption and Leaching of EPN in the Soil

  • Kim, Jung-Ho;Kam, Sang-Kyu;Park, Moon-Ki;Moon, Yung-Soo
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 1999.10a
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    • pp.221-223
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    • 1999
  • The adsorption and leaching of organophosphorus pesticide, EPN are investigated in Namwon soil(black volcanic soil), Aewol soil(very dark brown volcanic soil) and Mureung soil(dark brown nonvolcanic soil) sampled in Cheju Island. The organic matter of Namwon soil, Aewol soil and Mureung soil is 19.8%, 6.2%, 2.4%, respectively. The cation exchange capacity of Namwon soil, Aewol soil and Mureung soil is 24.8 meq/100g, 13.0 meq/100g, 9.5 meq/100g, respectively. The Freundlich constant, K value, is 89.4, 26.9 and 9.25 for Namwon soil, Aewol soil and Mureung soil, respectively. The K value of Namwon soil with very high organic matter content and cation exchange capacity was the highest for Aewol soil and Mureung soil. The Freundlich constant, 1/n, show a high correlation with organic matter content, i.e., it is less than unity for organic matter rich soil of Namwon soil and greater than unity for organic matter poor soil of Mureung soil. The leaching of EPN is slower for Namwon soil with high K values, and faster for Mureung soil with low K values. The results of the study is demonstrated the potential of pollution for EPN have little leached into soil environment.

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Adsorption of Chlorothalonil and Dicofol by the Soil of Cheju Island (제주도 토양에 의한 Chlorothalonil 및 Dicofol의 흡착)

  • 감상규
    • Journal of Environmental Science International
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    • v.6 no.3
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    • pp.285-291
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    • 1997
  • In order to Investigate the adsorption characteristics of organochlorine pesticides chlorothaloul and dicofol with soul colors and re참tons far souls of an orange orchard, the souls were sampled at 3 re삼tons, respectively. among black volcanic, dark brown volcanic, and broom nonvolcanlc sorts. Every so6 has a higher clay proportion (49-75%) In sol tcuture and the organic carbon content and cation ekchange capacity with soil decreased in the following sequence: Black volcanic > Dark brown volcanic > Brown nonvolcanic sorts. Especially those In black volcauc trolls were much higher than others. The retention time, quantitative detection limit, and extractian , efficiencies of chlorothalonil and dicofol were 2.82min, 1.5ng/mL, 93.6% and 3.64min, 4.5ng/mL. 94 2%, repectlvely. The Freundlich constant, Kd, was higher in dicofol compared to chlorothalonil and In the black volcanic souls that have higher organic carbon content and cation Bkchange capacity. The Freundlich constant, 1 In, was In the range of 0.76-0.89 In the black volcanic sorts that have a higher organic matter(16.4-19.8%), whereas It was In the range of 1.02-1.13 In the brown nonvolcanic souls that have a lower organic matter(2.4-3.4%), and so It was considered that 1 In was dependent on the organic matter.

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Vegetation Structures and Soil Properties of Calanthe discolor and C. sieboldii Population (새우난초(Calanthe discolor)와 금새우난초(C. sieboldii) 개체군의 식생구조와 토양특성)

  • Park, Hye-Rim;Kim, Mu-Yeol;Kwon, Hye-Jin;Song, Ho-Kyung
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.13 no.2
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    • pp.63-71
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    • 2010
  • This study was carried out to analyze the vegetation and soil characteristic, and ordination between Calanthe discolor and C. sieboldii population, Jeju Island. The C. discolor population was classified into Cryptomeria japonica dominant population, Miscanthus sinensis dominant population, and C. discolor typical population. The C. discolor population was located in elevation of 156m to 430m, and C. sieboldii was located in elevation of 424m to 604m in Jeju Island. In the study sites, soil organic matter, nitrogen, exchangeable potassium, exchangeable calcium, exchangeable magnesium, cation exchange capacity, and soil pH were 30.05~53.58%, 0.74~1.64%, 0.80~1.95cmol$^+$/kg, 4.35~22.53cmol$^+$/kg, 4.00~6.63cmol$^+$/kg, 25.60~51.33cmol$^+$/kg, and 4.83~5.70, respectively. C. discolor population was found in the low elevation and steep sloped area that has less organic matter, total nitrogen, and cation exchange capacity than C. sieboldii population. C. discolor typical population was found in the high elevation area that has more organic matter and total nitrogen in the C. discolor. Miscanthus sinensis dominant population was found in the shade of west direction of japanese black pine. C. sieboldii was found in a high elevation and a gentle sloped area that has high percentage organic matter, total nitrogen, and cation exchange capacity.

Transepithelial Transport of Organic Cation and Its Inhibition by Sulfhydryl and Carboxyl Reagents in Opossum Kidney Cell Monolayer

  • Woo, Jae-Suk;Oh, Se-Ok;Jung, Jin-Sup;Kim, Yong-Keun;Lee, Sang-Ho
    • The Korean Journal of Physiology
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    • v.30 no.1
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    • pp.53-62
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    • 1996
  • Transepithelial transport of tetraethylammonium (TEA) was studied in monolayers of opossum kidney cells cultured on permeable membrane filters. $[^{14}C]-TEA$ was transported across the OK cell monolayer from basolateral to apical side by a saturable process which can be stimulated by acidification of the apical medium. The apparent Michaelis-Menten constant $(K_{m})$ and the maximum velocity$(V_{max})$ for the transport were $41\;{\mu}M$ and 147 pmole/ mg protein/ min, respectively. The transport was significantly inhibited by unlabelled TEA, amiloride, cimetidine, choline, and mepiperphenidol added to the basolateral side at 1 mM and was slightly inhibited by 5 mM $N_{1}-methylnicotinamide\;(NMN).$ Unlabelled TEA added to the apical side stimulated the $basolateral-to-apical\;{^{14}C}-TEA$ transport, suggesting that the TEA self-exchange mechanism was involved at the apical membrane. Sulfhydryl reagents such as ${\rho}-chloromercuribenzoic\;acid\;(PCMB)\;and \;{\rho}-chloro-mercuribenzene\;sulfonate \;(PCMBS)$ and carboxyl reagents such as N,N'-dicyclohexylcarbodiimidem (DCCD) and N-ethoxy-carbonyl-2-ethoxy-1,2-dihydro-quinoline(EEDQ) inhibited the TEA transport at both the basolateral and apical membranes of the OK cell monolayer. These results suggest that OK cell monolayers possess a vectorial transport system for organic cations which is similar to that for organic cation secretion in the renal proximal tubule.

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Effects of forest fire on physical and chemical properties of soil (산불이 토양의 물리ㆍ화학적 특성에 미치는 영향)

  • 박관수
    • Journal of Korea Soil Environment Society
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    • v.4 no.1
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    • pp.119-126
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    • 1999
  • This study was carried out to estimate the effect of forest fire on physical and chemical properties of soil The forest fire was in April 1995 at Kongju of Chungnam. Soil samples were collected at 0~5cm, 5~10cm, and 10~20cm soil depths in September 1998 from the burned and unburned sites. Soil organic matter concentrations at 0~5cm and 5~10cm soil depths were significantly greater in unburned site than in burned site. Soil concentrations were greater in unburned site than in burned site at all soil depths. Cation exchange capacity was significantly higher in unburned site than in burned site at 0~5cm soil depth. There were no differences in available soil P, exchangeable soil K, Ca, and Mg, and pH of soil between burned and unburned sites. Soil water content at 0~5cm soil depth was significantly greater in unburned site than in burned site. Bulk density at 0~5cm soil depth was significantly higher in burned site than in unburned site. Forest fire had an adverse effect on physical and chemical properties of soil in this study, Burning of vegetation and forest 리oor organic matter in burned site may reduce organic matter supply to soil and increase soil erosion. Consequently, forest fire may have adverse influence on long-term site productivity.

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Effects of Compost Application on Soil Properties and Leaf and Bud Characteristics of Pear Trees in Orchard Farms (유기질 비료의 시용이 배 과원의 토양과 엽과 눈 특성에 미치는 영향)

  • Lee, Jae-An;Kim, Wol-Soo;Choi, Hyun-Sug
    • Korean Journal of Organic Agriculture
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    • v.17 no.4
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    • pp.567-575
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    • 2009
  • Organic pear (Pyrus pyriforia) fruits have remarkably increased in Korea since year 2000 due to increase consumer's demand for the fruit, and the farmers are keep trying to change their cultivation system that is replaced from conventional farming to organic-base farming for the fruit. However, there is little information for the soil properties, tree nutrition, and tree growth at organic orchards in Korea. Therefore, this study was established to investigate for the chemical properties of soils and leaf and bud characteristics of a conventional and organic pear trees in experimental orchards for two years. Commercial (Sanwool, YoungHwa Co., Korea) compost was applied to the orchard soils with conventional farming systems for two years for pear trees (10 to 15 year old trees) in KyungSan, Korea. The compost application increased pH, organic matter content, cation exchange capacity (CEC), and, microbial biomass in the soil. The compost treatment also increased specific leaf weight and foliar $P_2O_5$ concentration as well as leaf and floral bud sizes.

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Photopolymerization of Vinyl Monomers Using Organic Initiators

  • Kim, Myoung-Hee;Lee, Jun;Cha, Hyo Chang;Ham, Heui-Suk;Woo, Hee-Gweon
    • Journal of Integrative Natural Science
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    • v.2 no.1
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    • pp.1-12
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    • 2009
  • This miniaccount presents the selective examples of our recent discoveries in the photopolymerization of vinyl monomers using the organic initiators such as hydrosilanes, poly(hydroarylsilane)s, benzoin silyl ethers, and thianthrene cation radical. In the photopolymerization of vinyl monomers with silanes polysilanes, while the polymerization yields and polymer molecular weights of the poly(MMA)s containing the silyl moieties decreased, the TGA residue yields and intensities of SiH stretching IR bands increased as the mole ratio of the silanes over MMA increased. The hydroarylsilane and poly(hydroarylsilane) seemed to influence strongly on the photopolymerizaiton of olefinic monomers as both chain initiation and chain transfer agents. For the photohomopolymerization and photocopolymerization of MA and AA, the similar trends were observed. Benzoin silyl ethers and thianthrene cation radical also exhibit the photoinitiating ability in the photopolymerization of MMA.

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