• 제목/요약/키워드: Organic Cation

검색결과 487건 처리시간 0.032초

포도 '캠벨얼리' 품질에 미치는 토양이화학성의 상대적 기여도 (Contribution of Soil Pysico-chemical Properties to Fruit Quality of 'Campbell Early' Grapes in the Vineyards)

  • 김승희;최인명;윤석규;조정건;임태준;윤해근
    • 한국토양비료학회지
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    • 제42권3호
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    • pp.187-191
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    • 2009
  • 'Campbell Early', a major grape cultivar, occupies more than 70% of cultivated vineyard areas, however, recommendable standard management system of soil environmental conditions has not been developed yet in Korea. The consideration for the correlation between fruit quality and soil condition in the vineyard is required in the efficient management system of soil. This study was carried out to investigate the optimum soil environmental conditions for 'Campbell Early' grape production with high quality. The results from analyses of correlation between them were used to develop soil management guideline for promoting efficiency in grape production. Soil properties were analyzed from 120 vineyards in Hawsung, Sangju, Yeongdong, Gimcheon, Yeongju, and Yeongwol, major grape production regions. Because there is neither coloring disorder nor delayed coloration in grape production of 'Campbell Early', relative contribution of soil hardness and solid phase to fruit quality and fruit weight was analyzed. Among the soil properties, while cation and soil hardness affected sugar content at the level of 39.3% and 36.8%, respectively, saturated hydraulic conductivity, solid phase, and cation exchange capacity (CEC) showed relatively low contribution to sugar content in the vineyard. The sugar content in grapes was influenced more critically by the chemical properties than the physical ones in the soil of vineyards. While soil hardness and solid phase affected grape weight at the level of 27.8% and 26.0%, respectively, phosphate content, organic matter content, and cation showed low contribution to grape weight. Grape guality such as sugar content and grape weight was affected highly by cation and organic matters. Therefore, cation and organic matter content of soil contributed to fruit quality at the level of 33.8% and 15.5%, respectively, in the vineyard.

Pulsed Electron Paramagnetic Resonance Application on the Photoinduced Charge Separation of Alkylphenothiazine Derivatives in Molecular Assemblies

  • Kang, Young-Soo;Park, Chan-Young
    • 한국자기공명학회논문지
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    • 제4권2호
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    • pp.82-90
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    • 2000
  • Photoinduced charge separation of alkylphenothiazines in molecular assemblies such as positively, negatively and neutrally charged micelle interface results in the paramagnetic phenothiazine cation radical. This was studied as a model system for the light energy conversion into chemical energy. The photoproduced phenothaizne cation radical was identified and its amount was quantized with electron spin resonance (ESR). The microenvironment of photoproduced cation radical was studied with pulsed-ESR. Such a charge separation is enhanced by the optimization of various structural factors of the molecular assemblies. The structural factors of molecular assemblies have focused on the interface charge, interface structure with different headgroups and interfacial perturbation by disolving interface active organic additives.

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人工酸性 빗물에 의한 여러 土壤으로부터의 이온 洗脫 (Cation Leaching from Soils Percolated with Simulated Sulfuric Acid Rainn)

  • Rhyu, Tae-Cheol;Joon-Ho Kim
    • The Korean Journal of Ecology
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    • 제16권2호
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    • pp.169-180
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    • 1993
  • Soils of four combinations, sand with high content of organic matter(SL), sand with low content of OM(SS), siltyl loam with high content of OM(LL) and silty loam with low content OM (LS), were filled on column and then percolated with simulated sulfuric acid rain with pH 5.6, 4.0, 3.5, 3.0 and 2.5. From soil leachates, pH and concentrations of basic cations and Al were determined. Cation concentrations in the leachates increased as pH of the rain decreased. The orders of buffering capacity of soil, leachability of cation from soil, leaching sensitivity of ion andbase saturation sensitivity of soil to acidity of the rain water were SS$\leq$K <$\leq$LL

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Study on the of the Correlation between Soil Chemical Properties and Bioactive Compounds of Acer tegmentosum Maxim.

  • Lee, Dong Hwan;Park, Youngki;Hong, Seong Su;Park, Gwang Hun;Kim, Hyun-Jun
    • 한국자원식물학회지
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    • 제34권6호
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    • pp.566-574
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    • 2021
  • This research was carried out to investigate the correlation between soil chemical properties and bioactive compounds of Acer tegmentosum Maxim. The methods of determining bioactive compounds were determined by high performance liquid chromatography, that contained (-)-gallocatechin (0.04±0.01 ~ 0.43±0.28%), salidroside (0.90±0.06 ~ 3.86±0.59%), tyrosol (0.03±0.00 ~ 0.43±0.00%), (-)-catechin (0.05±0.01 ~ 0.37±0.14%), 6'-O-galloylsalidroside (0.02± 0.01 ~ 0.31±0.06%), (-)-epicatechin-gallate (0.01±0.00 ~ 0.04±0.01%). The soil chemical properties analysis such as soil pH, electric conductivity (EC), organic matter (OM), total nitrogen (TN), available phosphate (Avail. P2O5), exchangeable cation and cation exchange capacity (CEC) were performed following the standard manual. The correlation analysis between soil chemical properties and bioactive compounds of A. tegmentosum, soil pH, available phosphate and exchangeable cation (Ca2+ and Mg2+) were negatively correlated with content of salidroside. On the other hand, soil exchangeable cation (Na+) showed positive correlation with content of salidroside. The results of this study was able to investigate the correlation between soil chemical properties and bioactive compounds of A. tegmentosum.

토양의 물리화학적 특성이 세슘 흡착에 미치는 영향 (Influence of Physicochemical Properties on Cesium Adsorption onto Soil)

  • 박상민;이제신;김영훈;이정선;백기태
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제22권1호
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    • pp.27-32
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    • 2017
  • Cesium (Cs) generated by nuclear accidents is one of the most hazardous radionuclides because of its gamma radiation and long half-life. Especially, when Cs is exposed on the soil environments, Cs is mainly adsorbed on the topsoil and is strongly combined with tiny soil particle including clay minerals. The adsorption of Cs onto soil can vary depending on various physicochemical properties of soil. In this study, the adsorption characteristics between soil and Cs were investigated according to various physicochemical properties of soil including organic matter contents, cation exchange capacity (CEC), soil particle size, and the types of clay minerals. Soil organic matter inhibited the adsorption of Cs onto the soil because organic matter was blocking the soil surface. In addition, it was estimated that the CEC of the soil influenced the adsorption of Cs onto the soil. Moreover, more Cs was adsorbed as the soil particles size decreased. It was estimated that Cs was mostly adsorbed onto the topsoil, this is related to the clay mineral. Therefore, soil organic matter, CEC, soil particle size, and clay minerals are considered the key factors that can influence the adsorption characteristics between soil and Cs.

해수담수화 공정에서 역삼투막의 거동에 영향을 주는 요인 (Factors related to Performance of Reverse Osmosis Membrane in Seawater Desalination Process)

  • 박준영;홍성호;김지훈;정우원;남종우;김영훈;이창하;김형수
    • 상하수도학회지
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    • 제25권2호
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    • pp.171-176
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    • 2011
  • Organic matters that comprise a tiny part of seawater generally occur over 50% of membrane fouling in Reverse Osmosis Process. This study evaluates Foundation efficiency of reverse osmosis membranes under brackish and seawater conditions and resistance of organic fouling. Moreover, analyzing the membrane surface through roughness, contact angle and zeta potential results in roughness and contact angle are proportional to flux decline rate (FDR), yet FDR has high value when zeta potential is low level. Furthermore, with various membrane fouling of different raw water conditions, the flux tends to improve when pH value is high and raw water which is complex with organic and cation pollutes membrane faster than organic separated raw water condition.

Poly(1-methyl-4-vinylpyridium iodide-co-styrene)막을 통한 유기음이온의 투과특성 (Transport Characteristics of Organic Anions through Poly (1-methyl-4vinylpyridium iodide-co-styrene) Membrane)

  • 이광재;한정우박돈희조영일
    • KSBB Journal
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    • 제6권2호
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    • pp.207-213
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    • 1991
  • In this study poly (1-methyl-4-vinylpyridinium iodide-co-styrene) membrane with pyridinium cation as a fixed carrier was synthesized and the transport characteristics of the membrane was examined over various factors. As the concentration of the fixed carrier in the membrane was increased, the water content was increased. Meanwhile, the counter current of the organic anion and the chloride ion, the following results were obtained. Initial flux of Cl-, organic anion and Na+ decreased with the increasing thickness of membrane, and as the concentration of the fixed carrier increases, the initial flux of Cl- and organic anion increase but the initial flux of Na+ decreased. The flux equation of the organic anion, CCl3COO- was obtained from saturation kinetics as follows;$V_{o}=\frac{(8.67{\times}10^{-5}){\cdot}[NaCl]}{9.63{\times}10^{-2}+[NaCl]} mol/cm^2h$

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Ag(II)매개산화에 의한 폐 유기이온교환수지의 분해 (Destruction of Spent Organic ion Exchange Resins by Ag(II)-Mediated Electrochemical Oxidation)

  • 최왕규;남혁;박상윤;이근우;오원진
    • 전기화학회지
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    • 제2권4호
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    • pp.183-189
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    • 1999
  • 원자력 시설의 가동 및 유지보수 중에 중$\cdot$저준위 방사성폐기물로 다량 생성되는 폐 유기이온교환수지를 상온의 수용 상 내에서 분해 처리하는 공정을 개발할 목적으로, 전기화학적으로 생성되는 Ag(II)를 매개산화제로 사용하여 양이온 및 음이온교환수지의 분해 연구를 수행하였다. Ag(II) 매개산화 공정에서 제어 가능한 인자인 전류, 온도 및 전해질 농도가 이온교환수지의 분해거동에 미치는 영향을 고찰하였다. 양이온교환수지는 거의 대부분 $CO_2$로 분해되었으며, 전류밀도가 감소할수록 전류효율이 증가됨을 보인 반면에 양극전해질로 사용된 질산의 농도 및 온도가 증가하더라도 분해거동에는 영향을 미치지 않았다. 양이온교환수지와는 달리 음이온교환수지의 분해시에는 온도와 무관하게 약 $10\%$ 정도가 CO로 분해되었고, $CO_2$로의 분해효율은 온도에 의존하는 경향을 보였으며, $60^{\circ}C$ 이상에서 효과적으로 분해가 가능하였다.

양전자단층촬영에 이용 가능한 새로운 심근 혈류 추적자 개발; F-18이 표지된 유기암모늄염의 합성과 체내분포에 관한 연구 (Synthesis and $^{18}F$ Labelling of Organic Ammonium Salts to New Cardiac Flow Tracer for PET and Their Biodistribution)

  • 유국현
    • 대한핵의학회지
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    • 제28권3호
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    • pp.331-337
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    • 1994
  • In order to develop a $^{18}F$-labelled myocardial perfusion agent(flow tracer) for PET, $^{18}F$-labelled organic ammonium cations were synthesized and evaluated in relation to their biodistribution. Five quaternary organic ammonium compounds were labelled with $^{18}F$ in a side chain with moderate to good yields by direct introduction of $^{18}F$-fluoride. Radiochemical yields have been achieved in 30-40min by the precursors (tosylates) in dimethylsulfoxide 15-60% (decay corrected). The reaction was found to be autocatalyzed. A remote controlled procedure was developed in these synthesis. $^{18}F$-Labelling and HPLC-purification of com-pounds needed about 60 min(Yield; 7-20%). Up to now the two compounds N-4-[$^{18}F$]fluorobutyl-pyridinium cation(1) and N, N dibenzyl-4(2-[$^{18}F$]fluoroethyl)piperidinium cation(2) were investigated in relation to their biodistribution in mice. Compound 1 showed at 1 min post injection the high uptake of 19.22% ID/g organ in the myocardium but a following fast decline to 1.12% ID/g organ after 40min. Uptake of compound 2 was after 1min in the heart 5.90% ID/g organ but after 40min at the relative high value of 4.33% ID/g organ. Heart:blood ratio for compound(1) at 1 min was 8.3, at 40 min 2.6 for compound II 2.0(1min) and 15.0(40 min). As data of compound 2 showed greater heart uptake, slower myocardial release, and higher heart: blood ratios, compound 2 is a good candidate for further evaluation.

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