• Title/Summary/Keyword: Optimal Structure

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Effect of Alkali and Heat Treatments of Ti-6Al-4V Alloy on the Precipitation of Calcium Phosphate (Ti-6Al-4V 합금의 알칼리 및 열처리가 인산칼슘 침착에 미치는 영향)

  • Park, Jae-Han;Lim, Ki-Jung;Kim, Sang-Mok;Kim, Byung-Ock;Han, Kyung-Yoon
    • Journal of Periodontal and Implant Science
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    • v.30 no.1
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    • pp.187-203
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    • 2000
  • The precipitation of calcium phosphate on implant surface has been known to accelerate osseointegration and to enhance osseous adaptation. The present study was performed to examine whether the precipitation of calcium phosphate on Ti-6Al-4V alloy could be affected by the immersion in NaOH solution and heat treatment. Ti-6Al-4V alloy plates of $15{\times}3.5{\times}1mm$ in dimension were polished sequentially from #240 to #2,000 emery paper and one surface of each specimen was additionally polished with $0.1{\mu}m$ alumina paste. Polished specimens were soaked in various concentrations of NaOH solution(0.1, 1.0, 3.0, 5.0, 7.0, 10.0 M) at $60^{\circ}C$ for 24 hours for alkali treatment, and 5.0 M NaOH treated specimens were heated for 1 hour at each temperature of 400, 500, 600, 700, $800^{\circ}C$. After the alkali and heat treatments, specimens were soaked in the Hank's solution with pH 7.4 at $36.5^{\circ}C$ for 30days.The surface ingredient change of Ti-6Al-4V alloy was evaluated by thin-film X-ray diffractometer(TF-XRD) and the surface microstructure was observed by scanning electron microscope(SEM), and the elements of surface were analyzed by X-ray photoelectron spectroscopy(XPS). The results were obtained as follows ; 1. The precipitation of calcium phosphate on Ti-6Al-4V alloy was accelerated by the immersion in NaOH solution and heat treatment. 2. In Alkali treatment for the precipitation of calcium phosphate on Ti-6Al-4V alloy, the optimal concentration of NaOH solution was 5.0 M. 3. In heat treatment after alkali treatment in 5.0 M NaOH solution, the crystal formation on alloy surface was enhanced by increasing temperature. In heat treated alloys at $600^{\circ}C$, latticed structure and prominences of calcium phosphate layer were most dense. On heat treated alloy surface at the higher temperature(${\geq}700^{\circ}C$), main crystal form was titanium oxide rather than apatite. The above results suggested that the precipitation of calcium phosphate on the surface of Ti-6Al-4V alloy could be induced by alkali treatment in 5.0 M-NaOH solution and by heat treatment at $600^{\circ}C$.

A Mechanical Information Model of Line Heating Process using Artificial Neural Network (인공신경망을 이용한 선상가열 공정의 역학정보모델)

  • Park, Sung-Gun;Kim, Won-Don;Shin, Jong-Gye
    • Journal of the Society of Naval Architects of Korea
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    • v.34 no.1
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    • pp.122-129
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    • 1997
  • Thermo-elastic-plastic analyses used in solving plate forming process are often computationally expensive. To obtain an optimal process of line heating typically requires numerous iterations between the simulation and a finite element analysis. This process often becomes prohibitive due to the amount of computer time required for numerical simulation of line heating process. Therefore, a new techniques that could significantly reduce the computer time required to solve a complex analysis problem would be beneficial. In this paper, we considered factors that influence the bending effect by line heating and developed inference engine by using the concept of artificial neural network. To verify the validity of the neural network, we used results obtained from numerical analysis. We trained the neural network with the data made from numerical analysis and experiments varying the structure of neural network, in other words varying the number of hidden layers and the number of neurons in each hidden layers. From that we concluded that if the number of neurons in each hidden layers is large enough neural network having two hidden layers can be trained easily and errors between exact value and results obtained from trained network are not so large. Consequently, if there are enough number of training pairs, artificial neural network can infer similar results. Based on the numerical results, we applied the artificial neural network technique to deal with mechanical behavior of line heating at simulation stage effectively.

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Streamflow Estimation using Coupled Stochastic and Neural Networks Model in the Parallel Reservoir Groups (추계학적모형과 신경망모형을 연계한 병렬저수지군의 유입량산정)

  • Kim, Sung-Won
    • Journal of Korea Water Resources Association
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    • v.36 no.2
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    • pp.195-209
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    • 2003
  • Spatial-Stochastic Neural Networks Model(SSNNM) is used to estimate long-term streamflow in the parallel reservoir groups. SSNNM employs two kinds of backpropagation algorithms, based on LMBP and BFGS-QNBP separately. SSNNM has three layers, input, hidden, and output layer, in the structure and network configuration consists of 8-8-2 nodes one by one. Nodes in input layer are composed of streamflow, precipitation, pan evaporation, and temperature with the monthly average values collected from Andong and Imha reservoir. But some temporal differences apparently exist in their time series. For the SSNNM training procedure, the training sets in input layer are generated by the PARMA(1,1) stochastic model and they covers insufficient time series. Generated data series are used to train SSNNM and the model parameters, optimal connection weights and biases, are estimated during training procedure. They are applied to evaluate model validation using observed data sets. In this study, the new approaches give outstanding results by the comparison of statistical analysis and hydrographs in the model validation. SSNNM will help to manage and control water distribution and give basic data to develop long-term coupled operation system in parallel reservoir groups of the Upper Nakdong River.

Effect of $N_2$-back-flushing in Multi Channels Ceramic Microfiltration System for Paper Wastewater Treatment (제지폐수 처리를 위한 다채널 세라믹 정밀여과 시스템에서 질소 역세척 효과)

  • Park Jin-Yong;Choi Sung-Jin;Park Bo-Reum
    • Membrane Journal
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    • v.16 no.1
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    • pp.31-38
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    • 2006
  • The ceramic microfiltration system with periodic $N_2$-back-flushing was operated for treating paper wastewater discharged from a company making toilet papers by recycling milk or juice cartons. Two kinds of alumina membranes with 7 channels used here for recycling paper wastewater. The optimal filtration time interval for HC04 membrane with $0.4{\mu}m$ pore size was lower value of 4 min than 16 min for HC10 with $1.0{\mu}m$ pore size at fixed back-flushing time 40 sec, trans-membrane pressure $1.0kg_f/cm^2$ and back-flushing pressure $5.0kg_f/cm^2$. From the results of TMP effect at fixed filtration time interval and back-flushing time, the lower TMP was better on membrane fouling because high TMP could make easily membrane cake and fouling inside membrane structure. However, we could acquire the highest volume of total permeate at the highest TMP for the reason that TMP was driving force in our filtration system to treat paper wastewater. Then the permeate water of low turbidity was acquired in our microfiltration system using multi channels ceramic membranes, and the treated water could be reused in paper process.

Design of a Double-Faced Monopole Antenna Using the Coupling Effect of Induced Currents (유도 전류의 커플링 효과를 이용한 모노폴 안테나 설계)

  • Choi, Young;Lee, Seungwoo;Kim, Nam
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.23 no.12
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    • pp.1327-1336
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    • 2012
  • In this paper, the dual-faced monopole antenna, which is arranged by numerous rectangular ring patches in sequence for the multi-bands is proposed. The ring type structure of the patch can be increased the bandwidth. Therefore the bandwidth and beam width are improved by using multiple arrayed patches. When the ring type patches are inserted serially, the resonance frequencies are occurred by the current flow from the first ring patch. It is possible because the gap between the patches is very narrow. In addition, if the patches are composed on the same plane as the feed-line, fabrication could be very difficult because the gap between the patches is extremely narrow. The thickness and permittivity of the antenna, moreover, are very important parameters because both sides of the substrate are used. We finally found the optimal thickness and permittivity to generate the coupling effect by simulation. All patches are consisted of 4-steps which the patch size was decreased 85 % by each step. In conclusion, the resonant frequency bands are 1.75~2.6 GHz(850 MHz), 3.24~3.46 GHz(220 MHz), 3.8~4.0 GHz(200 MHz), and 4.4~4.9 GHz(500 MHz).

On Resistance of Bit Permutation Based Block Cipher against Nonlinear Invariant Attack (비트 순열 기반 블록암호의 비선형 불변 공격 저항성 연구)

  • Jeong, Keonsang;Kim, Seonggyeom;Hong, Deukjo;Sung, Jaechul;Hong, Seokhie
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.30 no.3
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    • pp.325-336
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    • 2020
  • Nonlinear Invariant Attack is an attack that should be considered when constructing lightweight block ciphers with relatively simple key schedule. A shortcut to prove a block cipher's resistance against nonlinear invariant attack is checking the smallest dimension of linear layer-invariant linear subspace which contains all known differences between round keys is equal to the block size. In this paper, we presents the following results. We identify the structure and number of optimal bit-permutations which require only one known difference between round keys for a designer to show that the corresponding block cipher is resistant against nonlinear invariant attack. Moreover, we show that PRESENT-like block ciphers need at least two known differences between round keys by checking all PRESENT-like bit-permutations. Additionally, we verify that the variants of PRESENT-like bit-permutations requiring the only two known differences between round keys do not conflict with the resistance against differential attack by comparing the best differential trails. Finally, through the distribution of the invariant factors of all bit-permutations that maintain BOGI logic with GIFT S-box, GIFT-variant block ciphers require at least 8 known differences between round keys for the resistance.

Synthesis of Mesoporous Silica Using Municipal Solid Waste Incinerator Ash Slag : Influence of NaOH Concentration (생활(生活) 폐기물(廢棄物) 소각재(燒却材) 슬래그를 이용(利用)한 메조포러스 실리카 합성(合成) : NaOH 농도(濃度)의 영향(影響))

  • Han, Yo-Sep;Jung, Jong-Hoon;Park, Jai-Koo
    • Resources Recycling
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    • v.19 no.1
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    • pp.40-48
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    • 2010
  • It was investigated that effects of NaOH concentration on synthesis of mesoporous materials using municipal solid waste incinerator ash slag (MSWI-ash slag). In order to increase the purity and maximize the amount of extracted Si content the raw MSWI-ash slag was mechanically activated. Extraction of Si from the MSWI-ash slag was carried out by alkali treatment using concentrated NaOH solution, which varied from 1M to 4M. Physical properties (i.e., pore size, specific surface area and total pore volume) of the synthesized mesoporous silica were also evaluated as a function of NaOH concentration via BET, SEM, TEM and small-angle X-ray scattering analyses. Over the entire range of NaOH concentration investigated (i.e., 1-4M), the synthesized mesoporous materials were determined to be SBA-15, which exhibited a hexagonal structure with the pore size of approximately 7 nm. On the other hand, specific surface area and total pore volume increased with NaOH concentration up to 3M while the values decreased at 4M, indicating that the optimal NaOH concentration for the synthesized mesoporous silica was approximately 3M. Further comparison analysis between two conditions (3M versus 4M) showed that the decrease in two physical properties at 4M NaOH concentration was likely due to the potential inhibition by excess Na ions on the formation of mesophase and the consequent increase of pore wall thickness by remaining Si ions.

A Study on the Reorganization of Science and Technology Law by Changes in the Science and Technology Environ (과학기술 환경 변화와 과학기술 법제 개편 방향)

  • Yoon, Chong-Min
    • Journal of Korea Technology Innovation Society
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    • v.15 no.4
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    • pp.881-915
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    • 2012
  • These days, according as the role and function of science and technology become a important solving means of various national and social problems caused in knowledge information society as well as the development of national economy, the national target and mission of science and technology have been newly illuminated. The task of science and technology has embodied into national policies, and these policies acquired institutional foundation through the legal system related to science and technology. Recently, the discussions about the operating system of present science and technology legislation are often happened, if or not the legal system is optimal and appropriate itself under the changed environment. In special, some issues are raised continuously, for example, about the improvement of coordination system on S&T policies, and the governance system on national R&D programs, etc. This paper aims to research and suggest the reorganization method of science and technology law. For this purpose, the development and existing state of S&T legislation was investigated, the government role and policy driving direction were reviewed under the recent changed environment, and the problems of S&T law in structure and content were analyzed in variety of perspectives. On this basis, the reorganization methods of science and technology law are suggested.

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Conformation and Reactivity of Herbicidal Benzenesulfonyl urea Compounds (제초성 Benzenesulfonyl urea계 화합물의 형태와 반응성)

  • Yu, Seong-Jae;Lee, Sang-Ho;Ko, Young-Kwan;Sung, Nak-Do
    • Applied Biological Chemistry
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    • v.39 no.3
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    • pp.235-240
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    • 1996
  • The most stable stereo conformer in non substituted benzenesulfonyl urea, 1 was the II-keto form, which the molecule was intramolecular associated(H-bond) coformer between imide group and N atom on the Pyrimidine ring. The hydrolytic degradation of 2 derivatives were proceeds by nucleophilic addition reaction(p<0) with orbital controlled intermolecular interaction between LUMO with electron donating$(\sigma<0)$ groups of 2 and HOMO of water molecule. N-(4,6-disub. pyrimid ine-2-yl)aminocarbonyl-2-(1,1-dimethoxy-2-fluoro)ethylbenze nesulfonamides,3 and N-(4,6-disub. triazine-2-yl)aminocarbonyl-2-(1,1-d imethoxy-2-fluoro)ethylbenzenesulfonamides,4 we re synthesized and their herbicidal activities in vivo against bulrush (Scirpus juncoides.) were measured by the pot test under the paddy conditions And the structure activity relationships(SAR) were analyzed by the multiple regression technique. The results of the SAR suggested that the 3 and 4 derivatives indicated dependent on the hydrophobicity of the 4,6-disubstituents and the heterocyclo group, where the optimal value $((log\;P)_{opt.}=0.89)$ of hydrophobicity was 0.89. The pyrimidine substituents, 3 showed higher herbicidal activity than the triazine substituents, 4. Among them, 4,6-dimethoxypyrimidine substituent, 3a showed the best herbicidal activity.

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The Characteristic Analysis of Calcareous Deposit Films Formed on Steel Plate by Cathodic Current Process in Marine Environment (해양환경 중 음극전류 프로세스에 의해 강판에 형성된 석회질 피막의 특성 분석)

  • Park, Jun-Mu;Kang, Jae Wook;Choi, In-Hye;Lee, Seung-Hyo;Moon, Kyung-Man;Lee, Myeong-Hoon
    • Journal of the Korean institute of surface engineering
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    • v.49 no.2
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    • pp.166-171
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    • 2016
  • Cathodic protection is widely recognized as the most cost effective and technically appropriate corrosion prevention methodology for the port, offshore structures, ships. When applying the cathodic protection method to metal facilities in seawater, on the surface of the metal facilities a compound of calcium carbonate($CaCO_3$) or magnesium hydroxide($Mg(OH)_2$) films are formed by $Ca^{2+}$ and $Mg^{2+}$ ions among the many ionic components dissolving in the seawater. And calcareous deposit films such as $CaCO_3$ and $Mg(OH)_2$ etc. are formed by the surface of the steel product. These calcareous deposit film functions as a barrier against the corrosive environment, leading to a decrease in current demand. On the other hand, the general calcareous deposit film is a compound like ceramics. Therefore, there may be some problems such as weaker adhesive power and the longer time of film formation uniting with the base metal. In this study, we tried to determine and control the optimal condition through applying the principle of cathodic current process to form calcareous deposit film of uniform and compact on steel plate. The quantity of precipitates was analyzed, and both the morphology, component and crystal structure were analyzed as well through SEM, EDS and XRD. And based on the previous analysis, it was elucidated mechanism of calcareous deposit film formed in the sacrificial anode type (Al, Zn) and current density (1, 3, $5A/m^2$) conditions. In addition, the taping test was performed to evaluate the adhesion.