• Bulletin of the Korean Chemical Society
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• v.23 no.6
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• pp.865-872
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• 2002

A systematic way of determining the equilibrium orientation of carbon monoxide (CO) in heme proteins using time-resolved polarized mid-IR spectroscopy is presented. The polarization anisotropy at pump-probe delay time of zero in the limit of zero photolysis and the angular distrbution function of CO are required to obtain the equilibrium orientation of CO. An approach is developed for determining the polarization anisotropy in the zero-photolysis limit from the anisotropy measured under finite photolysis conditions in an optically thick sample where the fraction of molecules photolyzed decreased as the pump pulse passes through and is absorbed by the sample. This approach is verified by measuring the polarization anisotropy of CO of carbonmonoxy myoglobin at various levels of photolysis. This method can be readily applied to other photoselection experiments determining precise angle between transition dipoles.

• Publications of The Korean Astronomical Society
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• v.30 no.2
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• pp.433-437
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• 2015

We show the results of a time series analysis of the long-term light curves of four blazars. 3C 279, 3C 345, 3C 446, and BL Lacertae. We used densely sampled light curves spanning 32 years at three frequency bands (4.8, 8, 14.5 GHz), provided by the University of Michigan Radio Astronomy Observatory monitoring program. The spectral indices of our sources are mostly flat or inverted (-0.5 < ${\alpha}$ < 0), which is consistent with optically thick emission. Strong variability was seen in all light curves on various time scales. From the analyses of time lags between the light curves from different frequency bands and the evolution of the spectral indices with time, we find that we can distinguish high-peaking flares and low-peaking flares according to the Valtaoja et al. classification. The periodograms (temporal power spectra) of the light curves are in good agreement with random-walk power-law noise without any indication of (quasi-)periodic variability. We note that random-walk noise light curves can originate from multiple shocks in jets. The fact that all our sources are in agreement with being random-walk noise emitters at radio wavelengths suggests that such behavior is a general property of blazars. We are going to generalize our approach by applying our methodology to a much larger blazar sample in the near future.