• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.416-416
• /
• 2016

Organic-inorganic metal halide perovskite solar cells have received attention because it has a number of advantages with excellent light harvesting, high carrier mobility, and facile solution processability and also recorded recently power conversion efficiency (PCEs) of over 20%. The major issue on perovskite solar cells have been reached the limit of small area laboratory scale devices produced using fabrication techniques such as spin coating and physical vapor deposition which are incompatible with low-cost and large area fabrication of perovskite solar cells using printing and coating techniques. To solution these problems, we have investigated the feasibility of achieving fully printable perovskite solar cells by the blade-coating technique. The blade-coating fabrication has been widely used to fabricate organic solar cells (OSCs) and is proven to be a simple, environment-friendly, and low-cost method for the solution-processed photovoltaic. Moreover, the film morphology control in the blade-coating method is much easier than the spray coating and roll-to-roll printing; high-quality photoactive layers with controllable thickness can be performed by using a precisely polished blade with low surface roughness and coating gap control between blade and coating substrate[1]. In order to fabricate perovskite devices with good efficiency, one of the main factors in printed electronic processing is the fabrication of thin films with controlled morphology, high surface coverage and minimum pinholes for high performance, printed thin film perovskite solar cells. Charge dissociation efficiency, charge transport and diffusion length of charge species are dependent on the crystallinity of the film [2]. We fabricated the printed perovskite solar cells with large area and flexible by the bar-coating. The morphology of printed film could be closely related with the condition of the bar-coating technique such as coating speed, concentration and amount of solution, drying condition, and suitable film thickness was also studied by using the optical analysis with SEM. Electrical performance of printed devices is gives hysteresis and efficiency distribution.

• Journal of Korean Society for Atmospheric Environment
• /
• v.20 no.5
• /
• pp.603-613
• /
• 2004

Extensive forest fires occurred across the border in Russia. particularly east of Lake Baikal between the Amur and Lena rivers in May 2003. These forest fires released large amounts of particulates and gases into the atmosphere. resulting in adverse effects on regional air quality and the global radiation budget. Smoke pollution from the Russian fires near Lake Baikal was sometimes transported to Korea through Mongolia and eastern China. In this study ground based radiation (visible and UV-B) data measured during May 2003 at Seoul and Kwangju were analyzed to estimate smoke aerosol impacts on solar radiation. Surface criteria air pollutants ($PM_{10}$, CO, $O_3$) data were also obtained from National Institute of Environmental Research (NIER) during smoke aerosol event period (19 May~24 May 2003). Large Aerosol Optical Depth (AOD) 1.0~3.0 was observed during this period due to the influence of the long range transport of smoke aerosol plume from the Russian fires, resulting in short-wavelength direct aerosol radiative forcing of -90~ -200W/$m^2$. These smoke aerosol plume caused decrease in surface UV-B radiation up to 80% and increase in PM_(10) concentration up to 200${\mu}g/m^3$ exceeding the 24 hour ambient air quality standard.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.30 no.7 s.250
• /
• pp.682-691
• /
• 2006

This study was conducted to assess the effect of mixed fuel composition and mass fraction on spray inner structure in evaporating transient spray under the various ambient conditions. Spray structure and spatial distribution of liquid phase concentration are investigated using a thin laser sheet illumination technique on the multi-component mixed fuels. A pulsed Ar+ laser was used as a light source. The experiments were conducted in a constant volume vessel with optical access. Fuel was injected into the vessel with electronically controlled common rail injector. Used fuel contain $i-octane(C_8H_{18}),\;n-dodecane(C_{12}H_{26})$ and $n-hexadecane(C_{16}H_{34})$ that are selected as low-, middle- and high-boiling point fuel, respectively. Experimental conditions are 25Mpa, 42MPa, 72MPa and 112MPa in injection pressure, $5kg/m^3,\;15kg/m^3\;and\;20kg/m^3$ in ambient gas density, 400K, 500K, 600K and 700K in ambient gas temperature, 300K and 368K in fuel temperature, and different fuel mass fraction. Experimental results indicate that the more high-boiling point component, the longer the liquid phase it were closely related to fuel physical properties, but injection pressure had no effect on. And there was a high correlation between the liquid phase length and boiling temperature at 75% distillation point.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2009.06a
• /
• pp.28-28
• /
• 2009

Fabrications of antireflection structures on solar cell were investigated to trap the light and to improve quantum efficiency. Introductions of patterned substrate or textured layer for Si solar cell were performed to prevent reflectance and to increase the path length of incoming light. However, it is difficult to deposit conformally flat electrode on perpendicular plane. ZnO is II-VI compound semiconductor and well-known wide band-gap material. It has similar electrical and optical properties as ITO, but it is nontoxic and stable. In this study, Al-doped ZnO thin films are deposited as transparent electrode by atomic layer deposition method to coat on Si substrate with micro-scale structures. The deposited AZO layer is flatted on horizontal plane as well as perpendicular one with conformal 200 nm thickness. The carrier concentration, mobility and resistivity of deposited AZO thin film on glass substrate were measured $1.4\times10^{20}cm^{-3}$, $93.3cm^2/Vs$, $4.732\times10^{-4}{\Omega}cm$ with high transmittance over 80%. The AZO films were coated with polyimide and performed selective polyimide stripping on head of column by reactive ion etching to measure resistance along columns surface. Current between the micro-columns flows onto the perpendicular plane of deposited AZO film with low resistance.

• Korean Journal of Optics and Photonics
• /
• v.7 no.3
• /
• pp.238-243
• /
• 1996

We have developed XeCl laser pumped double-resonator Dye laser and two-stage amplifier system, and generated simultaneously of alternatively two wavelengths suitable in DIAL system. The developed double-resonator is composed of 1st and 2nd diffraction orders on light incidence angle in grazing-incidence grating method with 1200 g/mm. We have obtained spectral linewidth below 10 pm and the total efficiency dependent on pump energy over 6%. The tuning ranges dependent on 1st and 2nd diffraction orders are 434~470 nm and 436~468 nm, respectively. The amplification gain and rine-450 dye laser by using the double-resonator laser system and measured the distribution of $NO_2$ concentration over Suwon as the result of transmission of laser output of 6 mJ in this DIAL system. Consequently, we have confirmed that the developed dye laser system is very useful as the tunable source for DIAL.

• Ceramist
• /
• v.19 no.3
• /
• pp.26-35
• /
• 2016

The purpose of this study is to find the optimum conditions for manufacturing titanium dioxide using a hybrid self-assembly forming method, to confirm the shape, properties and synergy effect of UV protection for hybrid titanium dioxide. Hybrid titanium dioxide, manufactured by forming self-assembly of different sizes consisting of two kinds of titanium dioxides, has micro titanium dioxide (250nm~300nm) for support material, Nano titanium dioxide (20~30nm) for surface material, coating support material. Adjustment experiments of $AlCl_3$ concentration and both titanium dioxide ratio were conducted to find the optimized conditions for the surface coating of titanium dioxide striking a negative charge, a sample made of the optimized process was confirmed through an optical analysis, particle size analysis, and potentiometric analysis. The SPF in-vitro value of the cosmetics samples containing hybrid titanium dioxide showed 15~30% higher levels than the cosmetics samples containing both titanium dioxides mixture.

• Particle and aerosol research
• /
• v.6 no.2
• /
• pp.51-59
• /
• 2010

ZnO quantum dots embedded in a silica matrix without agglomeration were synthesized from $TEOS:Zn(NO_3)_2$ solutions in one-step process by aerosol-gel method. It was successfully demonstrated that the size of ZnO Q-dots could be controlled from 2 to 7 mm verified by a high resolution transmission electron microscope observation. The line scanning energy dispersive X-ray spectroscopy(EDS) revealed that the Q-dots existed preferentially inside SiO2 sphere when Zn/Si < 0.5. However, the Q-dots distributed homogeneously all over the sphere when Zn/Si > 1.0. Blue-shifted UV/Vis absorption peak observation confirmed the quantum size effect on the optical properties. The photoluminescence(PL) emission peaks of the powders at room temperature were consistent with previous reports in the following aspects: 1) PL characteristics are dominated by two peaks of deep-level defect-related emissions at 2.4 - 2.8 eV, 2) the first defect-related peak at 2.4 eV was blue shifted due to the quantum size effect with decreasing the concentration of $Zn(NO_3)_2$(decreasing the size of ZnO q dots). More interestingly, the existence of surface-exposed ZnO q dots affects greatly the second defect PL peak at 2.8 eV.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.13 no.5
• /
• pp.241-246
• /
• 2003

The transparent conducting thin film of ATO (antimony-doped tin oxide) was successfully fabricated on$SiO_2$/glass substrate by a sol-gel dip coating method. The crystalline phase of the ATO thin film was identified as SnO$_2$ major phase and the film thickness was about 100 nm/layer at the withdrawal speed of 50 mm/minute. Optical transmittance and electrical resistivity of the 400 nm-thick ATO thin film which was annealed under nitrogen atmosphere were 84% and $5.0\times 10^{-3}\Omega \textrm{cm}$, respectively. It was found that the $SiO_2$ layer inhibited Na ion diffusion and the formation of impurities like $Na_2SnO_3$ or SnO while increasing Sb ion concentration and higher ratio of $Sb^{5+}/Sb^{3+}$in the film. Annealing at nitrogen atmosphere leads to the reduction of $Sn^{4+}$ as well as $Sb^{5+}$ resulting in decrease of the electrical resistivity of the film.

• Applied Chemistry for Engineering
• /
• v.9 no.1
• /
• pp.71-75
• /
• 1998

Liquid crystalline compounds with amine terminal group and related linear and cross-linked liquid crystal polymers with epoxy resin structure were synthesized and characterized to develope matrix materials for polymer dispersed liquid display applications. Both linear and crosslinked side chain type liquid crystal polymers made with aromatic amine mesogens and ethylene glycol diglycidyl ether exhibited nematic texture as shown by polarized optical microscope(POM) and their transition temperatures were determined both by DSC and POM. Liquid crystal polymer samples also showed even-odd effect as the spacer length of aromatic amine mesogens were varied, however, the effect was samller than that of low molecular weight mesogens. Changes of nematic-to-isotropic transition($T_{NI}$) of crosslinked type polymer liquid crystals were also disscussed in relation to the concentration change of crosslinking agent 1,10-diaminodecane.

• Journal of Life Science
• /
• v.14 no.6 s.67
• /
• pp.891-894
• /
• 2004

The effect of pipe materials on biofilm communities were investigated by CLPP (community level physiology profile) using Biolog GN plates. Heterotrophic bacterial concentrations were $10^4\;-\;10^6\;CFU/cm^2$ and there was no differences between galvanized iron and carbon steel. Average optical density of Biolog plate was similar between two pipe materials. However, CLPP was different according to the type of pipe materials and exposed times to tap water, and CLPP was independent of bacterial concentration. This represents the differences of bacterial communities with pipes and water contact times.