• Title/Summary/Keyword: Optical and chemical properties

Search Result 1,175, Processing Time 0.021 seconds

Phase Transition Characteristics in $Ge_xSb_{100-x}$ Film for Optical Storage Media

  • Park Tae-jin;Kang Myung-jin;Choi Se-young
    • 정보저장시스템학회:학술대회논문집
    • /
    • 2005.10a
    • /
    • pp.124-127
    • /
    • 2005
  • Rewritable optical memory devices such as an CD-RW and DVD+RW are data storage media, which take advantage of the different optical properties in the amorphous and crystalline states of phase change materials. The switching property, structural transformation, transformation kinetics and chemical bindings of $Ge_xSb_{100-x}$($6{\le}x{\le}$34) were studied to investigate the feasibility of applying $Ge_xSb_{100-x}$ alloys in optical memory. The $Ge_xSb_{100-x}$ thin film was deposited by RF magnetron co-sputtering system and phase change characteristics were investigated by X-ray diffraction (XRD), static tester, inductively coupled plasma atomic emission spectrometer (ICP-AES) and atomic force microscopy (AEM). Optimum fiim composition of $Ge_xSb_{100-x}$ was studied and its minimum time fur laser induced crystallization and optical contrast fur phase transition was performed. These results might be correlated with the binding energies between Ge and Sb, and indicate that $Ge_xSb_{100-x}$ have an potential far optical memory applications.

  • PDF

Crystal Growth and Second Harmonic Generation of YCa$_4$O$({BO_3})_3$ (YCa$_4$O$({BO_3})_3$ 단결정 성장 및 2차고조파 발생)

  • Yu, Young-Moon;A. Ageyev;Jeong, Suk-Jong
    • Proceedings of the Optical Society of Korea Conference
    • /
    • 2000.08a
    • /
    • pp.88-89
    • /
    • 2000
  • The properties for self-frequency doubling (SFD) is unique phenomena for a small number of special single crystals. It is known that there are serious limitations to vary the concentration of active ions, for example high doping of active ions from 1 to 50 atomic %, in nonlinear materials. Until now, the Nd:YAl$_3$(BO$_3$)$_4$ (YAB) and Nd:(Ce,Gd)Sc$_3$(BO$_3$)$_4$ (CSB) crystals with high doping rates are well studied for the application of SFD purpose. They have much useful SFD properties, but also have big problems in crystal growth. In case of YAB crystal, it can be grown by solution melt method with very low growth rates and easy occurrence of inclusions. In case of CSB crystal, it has optically heterogeneity problems because of disarrangement of ions in huntite structure [1]. These problems make above crystals not so attractive for optical applications. Some popular nonlinear materials, such as LiNbO$_3$(LN), KTiOPO$_4$(KTP), LiB$_3$O$_{5}$ (LBO) crystals, are impossible to substitute by Rare Earth activators because of their crystallo-chemical problems of structure. When we dope active ions with the requisite concentrations for laser generation, it results in decreasing of optical quality of crystals or destroying of acentrosymmetric structure. (omitted)d)

  • PDF

Polypyrrole Film Studied by Three-Parameter Ellipsometry

  • 김동래;이덕환;백운기
    • Bulletin of the Korean Chemical Society
    • /
    • v.17 no.8
    • /
    • pp.707-712
    • /
    • 1996
  • Growth and changes of electronically conducting polypyrrole (PPy) in the form of thin films polymerized on metal electrodes were investigated by electrochemical and in situ three-parameter ellipsometry methods at the wavelength of 632.8 nm. Although the optical equations produced multiple sets of solution, it was possible to determine a unique set of thickness and the optical constants of a film by auxiliary measurements and/or physical reasoning. The changes in the thickness and the optical properties of the polymers during polymerization and electrochemical oxidation/reduction was successfully followed by the three-parameter ellipsometric technique. The optical properties of the polymers continuously changed as the film grew. The imaginary part of the refractive index of polypyrrole seemed to be dominantly determined by the existence of an absorption band around the visible range.

Fabrication of shape-controlled Au nanoparticle arrays for SERS substrates

  • Shin, Seon Mi;Choi, Kyeong Woo;Ye, Seong Ji;Kim, Young Yun;Park, O Ok
    • Advances in materials Research
    • /
    • v.3 no.3
    • /
    • pp.139-149
    • /
    • 2014
  • Surface enhanced Raman Scattering (SERS) has attracted attention because the technique enables detection of various chemicals, even down to single molecular scale. Among the diverse candidates for SERS substrates, Au nanoparticles are considered promising due to their fine optical properties, chemical stability and ease of surface modification. Therefore, the fabrication and optical characterization of gold particles on solid supports is highly desirable. Such structures have potential as SERS substrates because the localized surface plasmon resonance of gold nanoparticles is very sensitive to combined molecules and environments. In addition, it is well-known that the properties of Au nanoparticles are strongly dependent on their shape. In this work, arrays of shape-controlled Au nanoparticles were fabricated to exploit their enhanced and reproducible optical properties. First, shape-controlled Au nanoparticles were prepared via seed mediated solution-phase synthesis, including spheres, octahedra, and rhombic dodecahedra. Then, these shape-controlled Au nanoparticles were arranged on a PDMS substrate, which was nanopatterned using soft lithography of poly styrene particles. The Au nanoparticles were selectively located in a pattern of hexagonal spheres. In addition, the shape-controlled Au nanoparticles were arranged in various sizes of PDMS nanopatterns, which can be easily controlled by manipulating the size of polystyrene particles. Finally, the optical properties of the fabricated Au nanoparticle arrays were characterized by measuring surface enhanced Raman spectra with 4-nitrobenezenethiol.

Temperature Dependence of Optical Properties on Polymer Materials (폴리머 재료에서의 광학적 물성의 온도의존성)

  • 정승묵;신영곤;이상훈;송국현;김영진;이낙규;나경환
    • Journal of the Semiconductor & Display Technology
    • /
    • v.3 no.4
    • /
    • pp.5-11
    • /
    • 2004
  • Optical properties of PET(Polyethylene terephthalate), PC(Polycarbonate), Acrylic resin and PE(Polyethylene) sheets were studied as a function of heat treating temperature of $60^{\circ}C$ to $150^{\circ}C$. By the heat treatment, optical properties of transmittance, absorbance, and reflectance showed a considerable change with different ways according to the materials. To understand the reason of optical property change, X-ray diffraction and surface morphology were also investigated. It was observed that small crystallite and pore that can cause scattering largely affect the transmittance. It was suggested that change of surface chemical bond induce the reflectance variation.

  • PDF

Scanning Probe Microscopy Study on the Degradation of Optical Recoding Disks by Environmental Factors (광디스크의 노화에 관한 주사 탐침 현미경 연구)

  • Yoon, Man-Young;Shin, Hyun-Chang
    • Journal of the Korean Graphic Arts Communication Society
    • /
    • v.29 no.3
    • /
    • pp.97-104
    • /
    • 2011
  • The storing ability of information of optical disks directly depends on the physical property of recording unit cells. It means that the degradation of optical disks ultimately causes the loss of the physical and chemical properties of recording unit cells and leads also information, too. We investigated the degradation and life time of optical disks which tell us the longevity of the preservation of information. Optical disks were aged using the accelerated aging system and studied by optical reflectivity spectroscopy and atomic force microscopy(AFM), and the preservation environment of electronic media in National central library of Korea also were analysed. Results show that the double reflective coated optical disks have good preservation of recording information but revealed some deformation of dye area in the AFM images. It means that we should include the mechanical and chemical degradation of the optical disks in the life time expectation evaluation.

Electrical and Optical Properties of $SnO_2$ Thin Films by Chemical Vapor Deposition (화학증착법에 의한 $SnO_2$ Film의 전기적 및 광학적 성질)

  • 김광호;김태옥;천성순
    • Journal of the Korean Ceramic Society
    • /
    • v.23 no.5
    • /
    • pp.81-85
    • /
    • 1986
  • $SnO_2$ thin films have been prepared by chemical vapor deposition technique. Electrical and optical properties of the films have been investigated. It is found that the electrical condictivity and optical transparency of the films are most affected by deposition temperature and more affected by $SnCl_4$ partial pressure than by $O_2$ partial pressure. Experimental results show that the conductivity increases with high optical transparency as deposition temperature increases up to 50$0^{\circ}C$ but the conductivity decreases with the loss of transparency as deposition temperature increases above $600^{\circ}C$.

  • PDF

Comparison of the concentration characteristics and optical properties of aerosol chemical components in different regions (지역별 에어로졸 화학성분 농도 및 광학특성 비교)

  • So, Yun-Yeong;Song, Sang-Keun;Choi, Yu-Na
    • Journal of Environmental Science International
    • /
    • v.28 no.1
    • /
    • pp.107-123
    • /
    • 2019
  • The aerosol chemical components in $PM_{2.5}$ in several regions (Seoul, Busan, Daejeon, and Jeju Island) were investigated with regard to their concentration characteristics and optical properties. The optical properties of the various aerosol components (e.g., water-soluble, insoluble, Black Carbon (BC), and sea-salt) were estimated using hourly and daily aerosol sampling data from the study area via a modeling approach. Overall, the water-soluble component was predominant over all other components in terms of concentration and impact on optical properties (except for the absorption coefficient of BC). The annual mean concentration and Aerosol Optical Ddepth (AOD) of the water-soluble component were highest in Seoul (at the Gwangjin site) ($26{\mu}g/m^3$ and 0.29 in 2013, respectively). Further, despite relatively moderate BC concentrations, the annual mean absorption coefficient of BC ($21.7Mm^{-1}$) was highest in Busan (at the Yeonsan site) in 2013, due to the strong light absorbing ability of BC. In addition, high AODs for the water-soluble component were observed most frequently in spring and/or winter at most of the study sites, while low values were noted in summer and/or early fall. The diurnal variation in the AOD of each component in Seoul (at the Gwangjin site) was slightly high in the morning and low in the afternoon during the study period; however, such distinctions were not apparent in Jeju Island (at the Aweol site), except for a slightly high AOD of the water-soluble component in the morning (08:00 LST). The monthly and diurnal differences in the AOD values for each component could be attributed to the differences in their mass concentrations and Relative Humidities (RH). In a sensitivity test, the AODs estimated under RH conditions of 80 and 90% were factors of 1.2 and 1.7 higher, respectively, than the values estimated using the observed RH.

Microstructure and Third Order Optical Nonlinearities of Ion-Implanted and Thermally Annealed $Cu-SiO_2$ Thin Films

  • 채이;이민영;김현경;문대원
    • Bulletin of the Korean Chemical Society
    • /
    • v.18 no.8
    • /
    • pp.886-889
    • /
    • 1997
  • The crystal structure and optical properties of copper nanoparticles, prepared in fused silica by ion-implantation and subsequent heat-treatment, were characterized by X-ray, TEM, linear absorption, and degenerate four-wave mixing (DFWM) technique. The X-ray data show fcc lattice structure of the nanocrystals and their size was measured as 8-20 nanometer by high resolution TEM. Using DFWM, the third-order nonlinear optical coefficient of the Cu-SiO2 thin films was measured as 0.4-1.1×10-8 esu in the surface plasmon resonance absorption region (540-570 nm).

Near IR Luminescence Properties of Er-doped Sol-Gel Films (Er이 도핑된 졸-겔 코팅막의 발광특성)

  • Lim, Mi-Ae;Seok, Sang-Il;Kim, Ju-Hyeun;Ahn, Bok-Yeop;Kwon, Jeong-Oh
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2003.11a
    • /
    • pp.136-136
    • /
    • 2003
  • In fiber optic networks, system size and cost can be significantly reduced by development of optical components through planar optical waveguides. One important step to realize the compact optical devices is to develop planar optical amplifier to compensate the losses in splitter or other components. Planar amplifier provides optical gain in devices less than tens of centimeters long, as opposed to fiber amplifiers with lengths of typically tens of meters. To achieve the same amount of gain between the planar and fiber optical amplifier, much higher Er doping levels responsible for the gain than in the fiber amplifier are required due to the reduced path length. These doping must be done without the loss of homogeniety to minimize Er ion-ion interactions which reduce gain by co-operative upconversion. Sol-gel process has become a feasible method to allow the incorporation of Er ion concentrations higher than conventional glass melting methods. In this work, Er-doped $SiO_2$-A1$_2$ $O_3$ films were prepared by two different method via sol -Eel process. Tetraethylorthosilicate(TEOS)/aluminum secondary butoxide [Al (OC$_4$ $H_{9}$)$_3$], methacryloxypropylcnethoxysaane(MPTS)/aluminum secondary butofde [Al(OC$_4$ $H_{9}$)$_3$] systems were used as starting materials for hosting Er ions. Er-doped $SiO_2$-A1$_2$ $O_3$ films obtahed after heat-treating, coatings on Si substrate were characterized by X-ray din action, FT-IR, and N-IR fluorescence spectroscopy. The luminescence properties for two different processing procedure will be compared and discussed from peak intensity and life time.

  • PDF