• 제목/요약/키워드: Optical absorbance

검색결과 142건 처리시간 0.027초

Spectral Change and Surface Images of the Azobenzene Functionalized Dendrimer in LB Monolayers

  • Shin, Hoon-Kyu;Kwon, Young-Soo
    • KIEE International Transactions on Electrophysics and Applications
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    • 제11C권4호
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    • pp.146-149
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    • 2001
  • The functionalized dendrimer containing 48 azobenzene was synthesized. Many isolated featureless domains were explicitly observed even at the air/water interface. Also, these monolayers were representatively observed, showing the change of surface pressure with irradiation time and wavelength. In AFM images, larger domains irregularly shaped structures on the top, while smaller ones were free from such defects. In the optical absorption spectra of the monolayer films by UV irradiation and heat treatment, only the photoiosmerization of the G4-48 Azo monolayers was observed, revealing a decrease of absorbance peaks without any change of the spectral shape. This suggests that the functional group and the symmetric chain affect optical behavior and morphological change.

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근적외선 영상을 이용한 후지사과의 결점 검출에 관한 연구 (I) -결점의 광학적 특성 구명 및 유의파장 선정- (Defect Detection of ‘Fuji’ Apple using NIR Imaging(I) -Optical characteristics of defects and selection of significant wavelelength-)

  • 이수희;노상하
    • Journal of Biosystems Engineering
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    • 제26권2호
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    • pp.169-176
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    • 2001
  • Defect of apple was depreciated the product value and causes storage disease seriously. To detect the defect of ‘Fuji’apple with machine vision system, the optical characteristics of defect should be investigated. In this research, absorbance spectra of defect were acquired by spectrophotometer in the range of visible and NIR region(400∼1,100nm) and L*a*b* color values were also acquired by colorimeter. NIR machine vision system was constructed with B&W camera, frame grabber, 16 tungsten-halogen lamps, variable focal length lens and NIR bandpass filter which was mounted to lens outward. Average gray values of defect at 15 NIR wavelength were acquired and the significant NIR wavelength was selected by comparing Mahalanobis distance between sound and defective apple. As the result of Mahalanobis distance analysis, the significant wavelength to discriminate the defectives in ‘Fuji’apple were found to be 720nm for scab and 970nm for bruise and cuts and 920nm was also effective regardless of defective types.

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건습시약 스트립을 사용한 임상화학분석장치 개발[I] (Development of Clinical Chemistry Analyzer with the Dry Reagent Strip(I))

  • 유동주;정태화;민홍기;허웅
    • 대한의용생체공학회:의공학회지
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    • 제13권4호
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    • pp.299-306
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    • 1992
  • For quantitative measurement of reflected light from a clinical diagnostic scrip, a prototype of reflectance photometer was designed. The strip loader and cassette were made to obtain more accurate re(leclance parameters. The strop was illuminated at $45^{\circ}C$ through optical fiber and the intensity of reflected light was determined at rectangulat angle using a photodiode. The kubelka-munk coefficient and reflection optical density were determined ar four different wavelengths(500,550,570 and 610nm) for blood glucose strip. For higher concentration than 300mg/dl about glucose, a saturation state of absorbance was observed at 500,550 and 570nm. The correlation between glucose concentration and parameters was the best at 610nm.

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분광기에 고 분해능 Charge Coupled Device의 설계 및 제작에 의한 Hematoporphyrin Derivative의 분석 (Analysis of Hematoporphyrin Derivative by Design and Manufacture of High Resolution Charge Coupled Device in Spectrometry)

  • 김기준
    • 한국응용과학기술학회지
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    • 제22권1호
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    • pp.77-83
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    • 2005
  • The influence of fluorescence, scattering, and absorbance in turbid material by light scattering was interpreted by the scattered fluorescence intensity and wavelength. The effect of optical property in scattering media was investigated. It is very important to study the charge coupled device(CCD) in spectrometry because we can use the molecular energy level, molecular structure, absorption or emission, intermolecular reaction, weakly bound molecular energy, photochemistry, fluorescence and photodynamic therapy. CCD is very essential to study the molecular structure and medical engineering combined laser spectroscopy in the modem physical and chemistry. Accordingly, this study has designed and manufactured the electromagnetic spectrometry with CCD, and has analyzed the hematoporphyrin derivative.

Theoretical and Experimental Studies on the Kinetics of Cation Redistribution Processes in Complex Oxides

  • Shi, Jianmin;Becker, Klaus-Dieter
    • 한국세라믹학회지
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    • 제47권1호
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    • pp.39-46
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    • 2010
  • The kinetics of cation reequilibration have been studied theoretically and experimentally in complex oxides after an external perturbation of equilibrium by temperature jumps. A general kinetic model for cation redistribution amongst non-equivalent sites in complex oxides is derived based on a local homogeneous point defect mechanism involving cation vacancies. Temperature-jump optical relaxation spectroscopy has been established to investigate cation kinetic processes in spinels and olivines. The kinetic model satisfactorily describes the experimental absorbance relaxation kinetics in cobalt containing olivines and in nickel containing spinels. It is found that the kinetics of cation redistribution in complex oxides shows a strong temperature- and composition-dependence. Activation energies for cation redistribution in Co-Mg olivines are found to range between 200 and 220 kJ/mol whereas an energy barrier of about 230 kJ/mol is observed in the case of nickel gallate spinel.

Polymer 기판에 저온 증착된 ITO의 투과 특성에 대한 흡광도의 영향 (Influence of light absorbance on the optical characteristics in amorphous ITO on polymer substrates)

  • 박연현;윤정흠;이성훈;이건환
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2012년도 춘계학술발표회 논문집
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    • pp.199-199
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    • 2012
  • Display에 사용되는 투명전극의 경우, 가시광 영역에서의 투과도는 중요한 요소 중의 하나이다. 투명 전도막의 광흡수, 반사 및 투과즉성은 박막 내에 존재하는 전공밴드의 전자, 자유전자, polar optical phonon 등의 빛과의 반응에 의해 결정된다고 알려져 있다. 많은 연구결과를 통해 투과 및 반사특성은 알려져 있으나, 가시광 영역내의 흡광특성에 관해서는 밝혀진 연구결과가 많지 않다. 본 연구에서는 ITO 박막의 투과도와 흡광도의 상호관계를 규명하였다.

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Real-time Spectroscopic Methods for Analysis of Organic Compounds in Water

  • Kim, Chihoon;Ji, Taeksoo
    • Current Optics and Photonics
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    • 제3권4호
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    • pp.336-341
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    • 2019
  • This paper proposes an optical system where the organic compound content in water is determined by using an ultraviolet (UV) LED (280 nm) and photodetector. The results obtained by the proposed prototype LED spectroscopy system, which includes a single photodetector and two parallel sample holders, are calculated by applying partial least square regression; the values are highly correlated with the actual concentrations of potassium hydrogen phthalate solutions, with an adjusted coefficient of determination about 0.996. Moreover, the total organic carbon values derived from the UV-Vis spectrometer of real samples (lake, river and sea water) differed little from those obtained by the LED spectroscopy. We confirm that the fast, sensitive, and compact LED sensor system can be readily configured for real-time monitoring of organic compounds in water.

Glass Frit을 이용한 염료감응 태양전지의 광 특성 연구 (Effect of Glass Frit in $TiO_2$ Electrode for DSSCs)

  • 김종우;전재승;김동선;황성진;김형순
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.75.1-75.1
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    • 2010
  • Dye sensitized solar cells(DSSCs) have been extensively studied due to their various advantages such as low production cost, colorful design, and eco-friendly process. Long optical path length is one of the most effective method to improve light harvest efficiency for DSSCs. Multi-layered $TiO_2$ nano-structured film with scattering layer has been studied to generate scattering effect by many researchers. It was expected that the difference of refractive index between $TiO_2$ particles and glass frit would generate the light scattering effect and provide the long optical path length. Therefore, to enhance the scattering effect, the frits of $Bi_2O_3-B_2O_3$-ZnO glass system that has the different refractive index were added to $TiO_2$ pastes in this study. First of all, the absorbance and haze factor of $TiO_2$ electrode with dyes and the refractive index of glass frit and $TiO_2$ were measured, respectively. To study the effect of frits, the efficiencies of DSSCs added glass frit and without glass frit were compared. Our results showed slightly higher efficiency with the different absorbance and haze factor of $TiO_2$ and glass frit. It was considered that the light scattering effect would be improved with adding frits to $TiO_2$ paste. Our preliminary studies will be useful for increasing efficiency of DSSCs.

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Properties of Dye Sensitized Solar Cells with Porous TiO2 Layers Using Polymethyl-Methacrylate Nano Beads

  • Choi, Minkyoung;Noh, Yunyoung;Kim, Kwangbae;Song, Ohsung
    • 한국재료학회지
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    • 제26권4호
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    • pp.194-199
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    • 2016
  • We prepared polymethyl methacrylate (PMMA) beads with a particle size of 80 nm to improve the energy conversion efficiency (ECE) by increasing the effective surface area and the dye absorption ability of the working electrodes (WEs) in a dye sensitized solar cell (DSSC). We prepared the $TiO_2$ layer with PMMA beads of 0.0~1.0 wt%; then, finally, a DSSC with $0.45cm^2$ active area was obtained. Optical microscopy, transmission electron microscopy, field emission scanning electron microscopy, and atomic force microscopy were used to characterize the microstructure of the $TiO_2$ layer with PMMA. UV-VIS-NIR was used to determine the optical absorbance of the WEs with PMMA. A solar simulator and a potentiostat were used to determine the photovoltaic properties of the PMMA-added DSSC. Analysis of the microstructure showed that pores of 200 nm were formed by the decomposition of PMMA. Also, root mean square values linearly increased as more PMMA was added. The absorbance in the visible light regime was found to increase as the degree of PMMA dispersion increased. The ECE increased from 4.91% to 5.35% when the amount of PMMA beads added was increased from 0.0 to 0.4 wt%. However, the ECE decreased when more than 0.6 wt% of PMMA was added. Thus, adding a proper amount of PMMA to the $TiO_2$ layer was determined to be an effective method for improving the ECE of a DSSC.

열변성 물질을 이용한 지하수 온도 측정용 광섬유 온도센서의 특성분석 (Characteristic analysis of a thermochromic material based fiber-optic temperature sensor for measuring temperature of subsurface water)

  • 서정기;유욱재;조동현;장경원;허지연;이봉수;고용권
    • 센서학회지
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    • 제18권6호
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    • pp.467-474
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    • 2009
  • In this study, we describe the feasibility of developing a fiber-optic temperature sensor using a thermochromic material such as 2,4,5-triphenylimidazole or also called Lophine. A sensor-tip is fabricated by mixing of a Lophine powder, which has a non-toxic and hydrophobic characteristics, and an epoxy resin. The temperature change in the sensor-tip gives rise to a change in the optical absorbance of the Lophine, and the transmittance of a light through the Lophine is also changed. We have measured the intensities of modulated lights due to the change of optical absorbance of the Lophine by using of a photo-multiplier tube(PMT). The relationships between the temperatures and the output voltages of PMT are determined to measure the temperature of water. The measurable temperature range of the fiber-optic sensor is from 5 to $30^{\circ}C$.