• 제목/요약/키워드: Optical absorbance

검색결과 142건 처리시간 0.041초

Alq3박막의 광학특성과 전계 의존성 (Optical Characteristics and Electric Field Dependency of $Alq_3$ Thin Film)

  • 이청학;박대희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 하계학술대회 논문집 D
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    • pp.1358-1360
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    • 1998
  • In this paper, organic thin film LED(light emitting diode) having ITO glass/$Alq_3$/Al structure using an $Alq_3$ was fabricated by the vacuum evaporation and the absorbance, wave length, 1-V characteristics were investigated. Electroluminescence of green and wavelength of 510[nm] were observed in this device. We observed absorbance form 320[nm] to 430[nm] and knew unstability of $Alq_3$ material as light emitting device.

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광학 전산화단층촬영 스캐너 사용을 위한 중합체 겔과 BANGTM 겔 선량계의 특성 비교 (Comparison of Polymer and BANGTM Gel Dosimeters to Use a Optical Computed Tomography Scanner)

  • 장경환
    • 대한방사선기술학회지:방사선기술과학
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    • 제46권2호
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    • pp.107-114
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    • 2023
  • The purpose of this study was to compare the basic radiological characteristics of in-house polymer gel and commercially-available gel (BANGTM) gel dosimeters with a spectro-photometer to use a optical computed tomography (CT) scanner. We investigated the radiological characteristics including dose linearity, absorbance spectrum, dose rate dependency and inter-and intra-reproducibility at wavelengths of 590, 600 and 630 nm. The optimal dose linearities of two gel dosimeters showed R2 value of 0.939 and 0.948 at wavelengths of 590 nm and 600 nm, respectively. For two polymer gel dosimeters, there is no peak sensitivity within the range of all wavelengths in absorbance spectrum. For in-house gel dosimeter, the dose rate dependency were within 5% for all wavelengths except for the dose rate of 100 MU/min. For BANGTM gel dosimeter, the dose rate dependency showed an error range of ±5% for all wavelengths. The inter-and intra-reproducibility of two gel dosimeters were within the range of 2.5%. We have confirmed that the two gel dosimeters was appropriate for use with a optical CT scanner.

Optical Method for Measuring Deposition Amount of Black Carbon Particles on Foliar Surface

  • Yamaguchi, Masahiro;Takeda, Kenta;Otani, Yoko;Murao, Naoto;Sase, Hiroyuki;Lenggoro, I. Wuled;Yazaki, Kenichi;Noguchi, Kyotaro;Ishida, Atsushi;Izuta, Takeshi
    • Asian Journal of Atmospheric Environment
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    • 제6권4호
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    • pp.268-274
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    • 2012
  • To perform quick measurements of black carbon (BC) particles deposited on foliar surfaces of forest tree species, we investigated an optical method for measuring the amount of BC extracted from foliar surfaces and collected on quartz fiber filters. The seedlings of Fagus crenata, Castanopsis sieboldii, Larix kaempferi and Cryptomeria japonica were exposed to submicron BC particles for one growing season (1 June to 7 December 2009). At the end of the growing season, the leaves or needles of the seedlings were harvested and washed with deionized water followed by washing with chloroform to extract the BC particles deposited on the foliar surfaces. The extracted BC particles were collected on a quartz fiber filter. The absorption spectrum of the filters was measured by spectrophotometer with an integrating sphere. To obtain the relationship between the absorbance of the filter and the amount of BC particles on the filter, the amount of BC particles on the filter was determined as that of elemental carbon (EC) measured by a thermal optical method. At wavelengths below 450 nm, the absorption spectrum of the filter showed absorption by biological substances, such as epicuticular wax, resulting in the low coefficient of determination ($R^2$) in the relationship between the amount of EC on the filter ($M_{EC}$, ${\mu}g\;C\;cm^{-2}$ filter area) and the absorbance of the filter. The intercept of the regression line between $M_{EC}$ and the absorbance of the filter at 580 nm ($A_{580}$) was closest to 0. There was a significant linear relationship between the $A_{580}$ and $M_{EC}$ ($R^2$=0.917, p<0.001), suggesting that the amount of BC particles collected on the filter can be predicted from the absorbance. This optical method might serve as a simple, fast and cost-effective technique for measuring the amount of BC on foliar surfaces.

DFT Calculations on the Wavelength Dispersion of Absorbance and Refractive Indices for Molecular Design of Photonic Polymers

  • Ando, Shinji
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.230-230
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    • 2006
  • Density functional theory (DFT) calculations using the B3LYP hybrid functional and the 6-311++G(d,p) basis set have been performed to predict the wavelength dispersion of optical absorbance and refractive indices for organic compounds and polymers in the range between the vacuum UV (${\sim}157\;nm$) and near-IR (${\sim}850\;nm$). The DFT calculations can reproduce the experimental dispersions of absorbance and refractive indices with high accuracy and low costs. The calculated dispersions demonstrate that the judicious introductions of $-F\;and\;-CF_{3}$ into alicyclic and heterocyclic compounds are effective in reducing the absorption at shorter wavelengths. In addition, the calculated Abbe numbers that represent the refractive index dispersion in the visble region are linearly proportional to the calculated refractive indices at 589 nm.

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Synthesis of scheelite-type nanocolloidal particles by pulsed laser ablation in liquid and their size distribution analysis

  • Lee, Jung-Il;Shim, Kwang Bo;Ryu, Jeong Ho
    • 한국결정성장학회지
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    • 제24권3호
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    • pp.111-119
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    • 2014
  • A novel pulsed laser ablation process in liquid was investigated to prepare scheelite-type ceramic [calcium tungstate ($CaWO_4$) and calcium molybdate ($CaMoO_4$)] nanocolloidal particles. The crystalline phase, particle morphology, particle size distribution, absorbance and optical band-gap were investigated. Stable colloidal suspensions consisting of well-dispersed $CaWO_4$ and $CaMoO_4$ nanoparticles with narrow size distribution could be obtained without any surfactant. Particle tracking analysis using optical microscope combined with image analysis was applied for a fast determination of particle size distribution in the prepared nanocolloidal suspensions. The mean nanoparticle size of $CaWO_4$ and $CaMoO_4$ colloidal nanoparticles were 16 nm and 30 nm, with the standard deviations of 2.1 and 5.2 nm, respectively. The optical absorption edges showed blue-shifted values about 60~70 nm than those of reported in bulk crystals. And also, the estimated optical energy band-gaps of $CaWO_4$ and $CaMoO_4$ colloidal particles were 5.2 and 4.7 eV. The observed band-gap widening and blue-shift of the optical absorbance could be ascribed to the quantum confinement effect due to the very small size of the $CaWO_4$ and $CaMoO_4$ nanocolloidal particles prepared by pulsed laser ablation in liquid.

광섬유 국소화 표면 플라즈몬 공명 센서를 위한 광섬유 표면상의 금 나노 입자 특성 분석 (Characterization of gold nanoparticles on optical fiber for localized surface plasmon resonance sensor)

  • 이훈;이승기
    • 센서학회지
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    • 제18권3호
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    • pp.226-233
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    • 2009
  • In this study, the optical properties of localized surface plasmon resonance sensor using optical fiber was analyzed as the variation of a size and surface density of gold nano particles on the etched optical fiber surface. It is shown that a size and surface density of gold nano particles on optical fiber surface are controlled by $Na_3$ citrate quantity and pH of gold colloid solution. To measure the sensitivity, peak wavelength of absorbance spectrum was detected as the reflective index of the solution. The sensor sensitivity is linearly dependent on the size and surface densities of gold nano particles from the results of optical experiments.

The characteristics of dye containing PMMA films for the PDP filter

  • Oh, Hwa-Shin;Cho, Yong;Jung, Sang-Kooun;Sohn, Sang-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.1364-1366
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    • 2006
  • Optical filters consisting of dye containing Polymethyl methacrylate(PMMA) thick films have been fabricated by a tape casting method. Their optical properties have been investigated as functions of dye contents in films and the film thickness. The absorbance coefficient in 588nm and 830nm could be calculated from the results.

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폴리머 재료에서의 광학적 물성의 온도의존성 (Temperature Dependence of Optical Properties on Polymer Materials)

  • 정승묵;신영곤;이상훈;송국현;김영진;이낙규;나경환
    • 반도체디스플레이기술학회지
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    • 제3권4호
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    • pp.5-11
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    • 2004
  • Optical properties of PET(Polyethylene terephthalate), PC(Polycarbonate), Acrylic resin and PE(Polyethylene) sheets were studied as a function of heat treating temperature of $60^{\circ}C$ to $150^{\circ}C$. By the heat treatment, optical properties of transmittance, absorbance, and reflectance showed a considerable change with different ways according to the materials. To understand the reason of optical property change, X-ray diffraction and surface morphology were also investigated. It was observed that small crystallite and pore that can cause scattering largely affect the transmittance. It was suggested that change of surface chemical bond induce the reflectance variation.

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아조벤젠이 기능화된 덴드리머 유기단분자막의 광학적 거동 (Optical Behavior of Azobenzene Functionalized Dendrimer in Organic Monolayers)

  • 신훈규;손정호;김병상;권영수
    • 한국전기전자재료학회논문지
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    • 제15권7호
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    • pp.627-633
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    • 2002
  • Many isolated featureless domains were explicitly observed even at the air-water interface. We measured the surface pressure shift originating from the photo-isomerization of azobenzene units on the periphery of dendrimers. The maximum surface pressure was gradual1y increased and saturated by cyclic compression and decompression. By irradiation of 365 [nm] light, the surface pressure was increased, which was originated by the photo-isomerization process of the azobenzene group on the periphery from trans to cia form. The increase of the dipole moment ($\mu$), which may increase the interaction among Azo dendrimer molecules, made an important role on surface pressure shift. From the absorbance spectrum by UV irradiation and heat treatment, we can see that the absorbance in the UV region decreases with the increase of the UV irradiation time, but the peak at 350 m, characteristic of dendrimers in the LB monolayers, was not shifted until four irradiation cycles. This suggests that optical behavior and morphological change are affected by the functional group and the symmetric chain.