• Title/Summary/Keyword: Optical Nonlinear Effect

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Mono- and Multi-layer Langmuir-Blodgett Films of Maleimide Polymers Possessing Nonlinear Optical-Active Side Chains

  • Yoon Kuk Ro;Lee Hoosung;Rhee Bum Ku;Jung Changsoo
    • Macromolecular Research
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    • v.12 no.6
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    • pp.581-585
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    • 2004
  • A copolymer P[OSA-MI] was synthesized by copolymerization of its corresponding monomers, N-phenyl maleimide (MI) and 2-octen-l-ylsuccinic anhydride (OSA). The polymer (poly[2-[1-(2,5-dioxo-l-phenylpyrroli­din-3-ylmethyl)heptyl]-succinic acid 4-(2-$\{$ethyl-[4-(4-nitrophen-ylazo)phenyl]amino$\}$ethyl)ester]) P[DR1MA-MI] was obtained from the reaction of P[OSA-MI] with 2-[4-(4-nitrophenylazo)-N-ethylphenylamino] ethanol (DR1). A stable monolayer of P[DRIMA-MI] was formed by spreading the solution of the polymer in chloroform. In Y-type Langmuir-Blodgett (LB) films prepared using this Langmuir-Blodgett method, the second harmonic waves generated from adjacent mono layers canceled each other out. In X-and Z-type LB films, the second harmonic intensity increased upon increasing the number of monolayers, but this increase was somewhat smaller than predicted by the square law. This phenomenon is due to defects or imperfect alignment of the dipoles in the LB film. The generation of second harmonic waves from Y-type LB films having an even number of mono layers supports this argument. The degree of imperfection seemed to increase as the number of layers increased. The second-order nonlinear optical properties of spin-cast films of these polymers were also measured. The largest second harmonic coefficient of the poled P[DRIMA-MI] film coated on a glass plate was 19 pm/V.

The characteristics of nonlinear magneto-optical effect based on coherent population trapping in the D1 line of Rh atoms (87Rb D1 전이선에서 원자결맞음을 이용한 비선형 광자기 효과 신호의 특성)

  • Lee, L.;Moon, H.S.;Kim, J.B.
    • Korean Journal of Optics and Photonics
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    • v.17 no.1
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    • pp.1-6
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    • 2006
  • We investigated the characteristics of the nonlinear magneto-optic effect (NMOE) depend on the transitions, the laser intensity and the temperature of the vapor cell, in the $D_1$ transition of $^{87}Rb$ atoms by using the Rb vapor cell contained with buffer gas of Ne 6.7 kPa. The size and the width of NMOE signal were increased according to the light intensity and temperature in the transition of F=2$\to$F'=2. However, In the case of using the F=2$\to$F'=1 transition, the size of the signal could be increased according to the light intensity without additional broadening of the width. We confirmed that the sensitivity of detecting small magnetic flux improved in this transition, and explained these effects by the different of the CPT configuration between Zeeman sublevels. At the optimal condition in experiment, the sensitivity of this system was evaluated less then $70pT/\sqrt{Hz}$.

Effects of Wavelength Dependent Birefringence inside a Fiber Cavity on the Fiber Laser Output Characteristics with a Nonlinear Amplifying Loop Mirror

  • Kim, Ho-Young;Kim, Kyong-Hon;Lee, El-Hang
    • Journal of the Optical Society of Korea
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    • v.2 no.2
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    • pp.64-73
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    • 1998
  • We have theoretically analyzed and experimentally observed the effects of wavelength dependent birefringence inside a laser cavity on the output characteristics of fiber lasers with a figure eight geometry. The spectral and polarization characteristics of fiber lasers are found to be very susceptible to the resultant birefringence composed of the intrinsically existing wavelength dependent birefringence and the externally induced birefringences inside the fiber. For the variation of twist-induced birefringence inside the nonlinear amplifying loop mirror, the laser output power and center wave-length of continuous wave lasers change periodically, but the polarization characteristics remains nearly unchanged. The changes of the birefringence inside the linear loop has little effect on the spectral characteristics but changes the polarization properties such as the polarization direction.

Preparationand Characteristics of ZnS-doped Borosilicate Glass(I) (ZnS 반도체 미립자 분산 Borosilicate Glass 제조 및 물성(I))

  • 이승한;박성수;박희찬;류봉기
    • Journal of the Korean Ceramic Society
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    • v.35 no.5
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    • pp.493-498
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    • 1998
  • ZnS doped borosilicate glass for nonlinear optical application was prepared by melting and precipitation process. The optical band gap of the precipitated ZnS particles ranged from 3.83 to 3.96 eV compared with the bulk ZnS energy gap of 3.53 eV. This result was interpreted in terms of a quantum confinement effect due to small crystal size. ZnS partilcle size estimated by effective mass approximation ranged from about 39 to 83 $\AA$ It increased wtih the increase of heat tratment time and temperature.

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Efficient quasi-phase-matched second harmonic generation using ferroelastically induced periodic ferroelectric domains in $RbTiOAsO_4$ crystals ($RbTiOAsO_4$ 결정의 주기적인 강탄성-강유전 다분역 구조를 이용한 효율적인 준위상 정합 이차 조화파 발생)

  • Lee Su Seok;Im Min Ho;Yang Yu Sin;Yun Chun Seop;Im Ae Ran;Jo Yong Chan;Jeong Se Yeong
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.02a
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    • pp.232-233
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    • 2003
  • Quasi-phase-match (QPM) can be realized by means of one-dimensional spatial modulation of second-order nonlinear susceptibility and has advantages over the conventional bulk phase-matching method because QPM can not only utilize the largest component of second-order nonlinear susceptibility tensor, but also can circumvent walk-off effect. (omitted)

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Amine Donors in Nonlinear Optical Molecules: Methyl and Phenyl Substitution Effects on the First Hyperpolarizability

  • Park, Gyoo-Soon;Ra, Choon-Sup;Cho, Bong-Rae
    • Bulletin of the Korean Chemical Society
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    • v.24 no.11
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    • pp.1671-1674
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    • 2003
  • The effects of amine donors ($a:NH_2,\;b:NMe_2,\;c:NMePh,\;d:NPh_2$) and conjugation length on the molecular hyperpolarizabilities of a series of dipolar molecules have been theoretically investigated by using CPHF/6-31G method. The first hyperpolarizabilities (${\beta}$) of p-nitrobenzene derivatives increase with the donor in the order, $NH_2\;<\;NMe_2\;<\;NMePh\;<\;NPh_2$, whereas slightly different order is observed in more conjugated derivatives, i.e., $NH_2\;<\;NPh_2\;<\;NMe_2\;<\;NMePh$. The result has been attributed to the extent of charge transfer and torsion angle. Moreover, the results show that "non-traditional" ${\pi}$-conjugation effect exists in small compounds and decreases as the conjugation length between donor and acceptor increases.

Dispersion-managed Link with Unequally Residual Dispersion per Span with Respect to Non-midway Optical Phase Conjugator (Non-midway 광 위상 공액기를 중심으로 중계 구간 당 잉여 분산이 일치하지 않는 분산 제어 링크)

  • Seong-Real Lee
    • Journal of Advanced Navigation Technology
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    • v.25 no.6
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    • pp.517-522
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    • 2021
  • Optical dispersion-managed link combined with optical phase conjugation for compensating of the distorted optical signals due to chromatic dispersion and nonlinear effects, which is required to implement long-haul wavelength division multiplexed system, is proposed and assessed in viewpoint of network topology flexibility. Optical phase conjugator capable to compensate for the distorted optical signal due to nonlinear effects is placed non-midway of total transmission distance. And, in dispersion-managed link, residual dispersion per span (RDPS) of each fiber spans in former half section and latter half section with respect to optical phase conjugator are different to each other. Simulation results show when the RDPS of each fiber sections in one half section makes it's own net residual dispersion slight different from another half section's net residual dispersion, the compensation effect in the proposed link configuration is more increased.

Semiempirical Calculations of Hyperpolarizabilities for Quinoline Derivatives (Quinoline계 분자의 초분극률에 관한 반경험적 계산)

  • Ryu Ungsik;Choi Donghoon;Kim Nakjoong;Lee Yoon Sup
    • Journal of the Korean Chemical Society
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    • v.37 no.1
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    • pp.62-67
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    • 1993
  • The microscopic origin of nonlinear optical properties of quinoline derivatives have been investigated theoretically using MOPAC-AM1 method. In order to prepare promising nonlinear optical active polymers of polyquinoline derivatives, the optimized positions of strong electron donor and electron acceptor are determined in the heterocyclic ring for the energetically favorable structures. For each compound, the effect of the substituted positions on the microscopic nonlinear coefficients were investigated. Polyquinoline was already evaluated to have outstanding physical and mechanical properties so that its monomeric analogues were designed and synthesized for developing new second and third order nonlinear optical main chain polymers. Using the MOPAC-AM1 method, properties calculated include the intrinsic ground-state dipole moments, the polarizabilities, first and second hyperpolarizabilities under the condition of finite-field $(\omega$ = 0).

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Characteristics of Compensation for Distorted Optical Pulse with Initial Frequency Chirp in 3 X 40 Gbps WDM Systems Adopted Mid-Span Spectral Inversion

  • Lee, Seong-Real;Lee, Yun-Hyun
    • Journal of electromagnetic engineering and science
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    • v.3 no.2
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    • pp.79-85
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    • 2003
  • In this paper, we investigated the degree of compensation for distorted optical pulse of wavelength division multiplexed(WDM) channel with initial frequency chirp generated in optical transmitter. The WDM channel signal distortion is due to chromatic dispersion, self phase modulation(SPM) and cross phase modulation(XPM) in fiber. The considered system is 3 ${\times}$ 40 Gbps intensity modulation direct detection(IM/DD) WDM transmission systems, which adopted mid-span spectral inversion(MSSI) as compensation method. We confirmed that the effect of initial frequency chirp on compensation for signal distortion due to a SPM is gradually decreased as a dispersion coefficient of fiber becomes gradually small. But, in the aspect of a compensation for signal distortion due to both SPM and XPM, the effect of initial frequency chirp on compensation is gradually decreased as a dispersion coefficient of fiber becomes gradually large.

Compensation of the Distorted 640 Gbps WDM Signals using Optical Phase Conjugator

  • Lee, Seong-Real;Lee, Young-Gyo
    • Journal of information and communication convergence engineering
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    • v.5 no.3
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    • pp.273-280
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    • 2007
  • The numerical methods for finding the optimal parameters in 640 Gbps (16 channels $\times$ 40 Gbps) WDM system with optical phase conjugator (OPC) are proposed, which effectively compensate the distorted overall WDM channels. The considered optimal parameters are the OPC position and the dispersion coefficient of fibers. The numerical approaches are accomplished through two different procedures. One of these procedures is that the optimal OPC position is previously searched and then the optimal dispersion coefficient is searched at the obtained optimal OPC position. The other is the reverse of the above procedure. From the numerical results, it is confirmed that two optimal parameters depend on each other, but less related with the searching procedure. The methods proposed in this research will be expected to alternate with the method of making a symmetrical distribution of power and local dispersion in real optical link which is a serious problem of applying the OPC into multi-channels WDM system.