• 제목/요약/키워드: Open pore

검색결과 146건 처리시간 0.023초

Fabrication of Porous Yttria-Stabilized Zirconias Controlled by Additives

  • Paek, Yeong-Kyeun;Oh, Kyung-Sik;Lee, Hyuk-Jae
    • 한국세라믹학회지
    • /
    • 제44권2호
    • /
    • pp.79-83
    • /
    • 2007
  • To fabricate a thick, porous yttria-stabilized zirconia without cracking and warping, a method for the simultaneous control of the porosity and shrinkage was designed. As a pore former, a potato starch was used. For the control of shrinkage the oxidation of Al metal particles was used. For the sintering of the above powder mixtures, a partial sintering technique was used at $1300^{\circ}C$ for 10 min in air. Upon adding the additives, high open porosity above 53% and a low shrinkage level were obtained. As a result cracking and warping of the sintered body were deterred. This outcome most likely resulted from the compensation of sintering shrinkage due to the volume expansion caused by oxidation of the Al metal particles during heat-treatment.

Boehmite Sol 함침에 의한 3Y-TZP 소결체의 표면 강화 (Surface Strengthening of 3Y-TZP Ceramics by Boehmite Sol Infiltration)

  • 최기식;김영정;김환
    • 한국세라믹학회지
    • /
    • 제31권6호
    • /
    • pp.671-677
    • /
    • 1994
  • To improve the low resistance of ceramics to tensile stress, many techniques, for introducing and retaining surface compressive stress have been suggested. In present work, in order to introduce the compressive stress on the surface of TZP ceramics TZP-Al2O3 composites were made with infiltration technique. Highly porous 3Y-TZP pre-sintered specimens were submerged in AlOOH(boehmite) sol and the sol penetrated into them through open pore channels with moderate depth after that specimens were sintered. It was known that controlling the number of infiltration time can vary the amount of Al2O3 phase and the fraction of alumina at surface reached up to 18%. The depth of composite surface layer were 100~200 ${\mu}{\textrm}{m}$, and these were acceptable in surface strengthening which were proved by Vickers hardness indentation method.

  • PDF

Capsule Free Hot Isostatic Pressing of Ceria-Doped Tetragonal Zirconia Powder Crystallized in Supercritical Methanol

  • Shu Yin;Satoshi Uehida;Yoshinobu Fujishiro;Mamoru Ohmori;Tsugio Sato
    • The Korean Journal of Ceramics
    • /
    • 제5권1호
    • /
    • pp.73-77
    • /
    • 1999
  • Capsule free hot isostatic pressing (HIPing) of 12 mol% $CeO_2-88 mo% ZrO_2 (12CeO_2-88ZrO_2)$ powder was conducted at 1100~$1200^{\circ}C$ using the powder crystallized in supercritical methanol followed by supercritical drying. Porous $12CeO_2-88ZrO_2$ ceramics with ~35% open porosity, micropore diameter of ~23 nm and a narrow pore size distribution were fabricated by capsule free hot isostatic pressing at $1100^{\circ}C$. The porosity increased with decrease in HIPing temperature and was accompanied by a steady decrease in fracture strength.

  • PDF

금속 섬유 필터층을 이용한 미세 분진 집진 성능 관찰 (Examination of Dust Trapping Mechanism in a Metal Fiber Filter-bed)

  • 이경미;조영민
    • 한국대기환경학회지
    • /
    • 제20권3호
    • /
    • pp.361-369
    • /
    • 2004
  • A metal fiber bed has seldom been applied to the practical filtration process despite its excellent mechanical and chemical stability. The filter-bed used in this work was highly porous with open structure, of which apparent porosity was 80 ∼ 90%. Although pressure loss across the filter-bed was very low, separation efficiency was found to be quite high. This paper focuses on the basic filtration mechanisms of a metal filter-bed and a thin ceramic filter from fly ash for reference. The experimental parameters were face velocity, dust loading and porosity of filter-bed. Pressure drop increased with increasing face velocity and dust feeding load for both filters. It also showed that dust particles deposited in the deep flow path, finally resulting in clogging the pore channels. It thereby indicates that the dominating mechanism of the metal filter-bed would be depth filtration. Meanwhile, the thin fly ash composite filters trapped the aerated dust mainly on the surface of the filter medium, so that the instantaneously formed dust layer might cause a steep increase of pressure drop across the filtration system.

전기적 신호처리에 의한 환경유해물질 검출연구 (A study on the detection method of environment toxic gases by using electrical signal)

  • 전영갑;선종호;이태성
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1999년도 하계학술대회 논문집 E
    • /
    • pp.1997-2000
    • /
    • 1999
  • 본 연구에서 제시하는 기공세라믹(Porous Ceramic)에 의한 누설전류 측정법은 기공 사이즈가 일정한 Open Pore Cell내에서 도전성 물질 및 이온화된 물질이 기공 사이에 침투되었을 때 외부에서 전계를 가하므로 써 이들 이온화 된 물질이 chain처럼 배열되어 전기적 병렬회로를 구성시켜 미세한 누설전류를 흐르게 한다. 이 누설전류법에 의한 도전성분 검출을 여러 환경 배출가스에 대한 모의실험을 실시한 결과 기공세라믹인 센서 자체의 누설전류는 가스 온도 150 ($^{\circ}C$) 이상에서 급격한 변화를 보이고 200($^{\circ}C$)에서 센서 자체의 전류치와 가스를 주입하였을 때의 전류치와는 상당한 격차를 두고 변화됨을 알 수 있었다. 그리고 공장연돌이나 자동차 배기관에서 방출되는 가스 중 HC, CO, NO, $CO_2$, $SO_2$, $N_2$ 등에 대한 센서 특성이 각각 달리 나타남을 알 수 있었다.

  • PDF

A survey on the application of oxide nanoparticles for improving concrete processing

  • Khayati, Gholam Reza;Ghasabe, Hojat Mirzaei;Karfarma, Masoud
    • Advances in concrete construction
    • /
    • 제3권2호
    • /
    • pp.145-159
    • /
    • 2015
  • The evolution of nanotechnology provides materials with advance properties. It's a fast growing area of research to introduce the oxide nanoparticles into the cement pastes to improve their performance. The purpose of this paper is to review the effects of oxide nanoparticles (such as $SiO_2$, $TiO_2$, $Fe_2O_3$, $ZnO_2$, $Cr_2O_3$ and $Al_2O_3$) on both of hardened concrete properties (i.e., compressive strength, split tensile strength and flexural strength, water permeability, Abrasion resistance and pore structure of concrete) and fresh concrete properties (i.e., workability and setting time). Graphical representations of all these parameters were presented to facilitate the comparison of the effect of oxide nanoparticles on concrete processing. The paper also introduces some discussion about future work in this direction by identifying some open research area.

A Study on the Preparation of Granules by Mixer Granulation

  • Lee, Kang-Choon;Shin, Hong-Min;Rhee, Shang-hi;Kim, Yong-Bae
    • Archives of Pharmacal Research
    • /
    • 제2권1호
    • /
    • pp.17-24
    • /
    • 1979
  • A first systematic approach on new and simple preparation method of spherical granules in the system using organic granulating solution was carried out. Mixer granulation required narrow range of moisture content but gentle action of tumbling in the mixer and capilary forces were adequate to compact the porous mass and also were highly effective to produce granules close to sphere. Where the granules by massing and screening provided the more open structure, its pore distribution lied between 71 and 16 .mu.m by above 50% and on the contrary, that of the mixer granulated granules showed only below 25%. Increase in retention time in the mixer decreased the intragranular porosity of granules produced, and in comparison with granular particles produced by conventional wet granulation, those from the mixer granulation had the advantages of flow properties, packing characteristics and definite spherocity. They also had extremely low friability resulting in few fines.

  • PDF

Stabilization of Wet Foams for Porous Ceramics Using Amphiphilic Particles

  • Pokhrel, Ashish;Park, Jung-Gyu;Nam, Jeong-Sic;Cheong, Deock-Soo;Kim, Ik-Jin
    • 한국세라믹학회지
    • /
    • 제48권5호
    • /
    • pp.463-466
    • /
    • 2011
  • Wet foams formed through direct foaming were stabilized using various concentrations of amiphiphilic particles that could control pore size and porosity. These porous materials showed moderate strength upon compression with high porosity. Bubble size and wet foam stability were tailored by amphiphile concentration, particle concentration, contact angle, and pH of the suspension to obtain crack-free porous solid after sintering. Closed and open pores were obtained with sizes of 30~300 ${\mu}m$ and porosities of over 80%.

알칼리성 환경에서 부동태 피막 개선에 대한 양쪽성 이온 및 인산염 그룹을 갖는 염화물 이온의 역할 (Role of chloride ions with Zwitterions and phosphate groups on the improvement of the passive film in alkaline environment)

  • 트란득탄;이한승
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2022년도 봄 학술논문 발표대회
    • /
    • pp.43-44
    • /
    • 2022
  • In this study, the optimum amount of chloride ions is used to collaborate with hybrid corrosion inhibitor for carbon steel rebar treatment in simulated pore concrete (SCP) solution is discovered. The corrosion inhibition performance of hybrid inhibitors is carried on by open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization (PP). The highest corrosion inhibition resistance is found in case of LP-C2 after 240 h exposure. Surface studies including scanning electron microscopy (SEM), and atomic force microscopy (AFM) were used to figure out the surface morphology of the steel rebar treated with hybrid inhibitors in order to collaborate well with electrochemical studies. Anodic type inhibition action was confirmed by potentiodynamic polarization study.

  • PDF

3.5 wt.% NaCl로 오염된 SCP 용액의 부식 개시 완화에 대한 하이브리드 억제제의 효과 (Effect of Hybrid Inhibitor on the Mitigation of Corrosion Initiation in SCP Solution Contaminated 3.5 wt.% NaCl)

  • 트란 득 탄;이한승
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2021년도 가을 학술논문 발표대회
    • /
    • pp.65-66
    • /
    • 2021
  • In this study, the optimum amount of hybrid inhibitors i.e. L-Arginine (LA) and sodium phosphate tribasic dodecahydrate (SP), applied for carbon steel rebar in simulated pore concrete (SCP) solution contaminated with 3.5 wt.% NaCl, was discovered. The corrosion inhibition performance of hybrid inhibitors was investigated by open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization. The highest corrosion inhibition efficiency was found as 99.52% corresponding to 2% LA and 0.25% SP after 210 h exposure. Anodic type inhibition action was confirmed by potentiodynamic polarization study. Surface studies including scanning electron microscopy (SEM), and atomic force microscopy (AFM) were used to figure out the surface morphology of the steel rebar treated with hybrid inhibitors in order to collaborate with electrochemical studies.

  • PDF