• Title/Summary/Keyword: Omega phase

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Analysis of Intermolecular Interaction in Thermotropic Aromatic Polyurethanes with Flexible Spacers (Spacer를 가지고 방향족 polyurethane의 분자간 상호 작용에 의한 액정성의 발견)

  • Lee, Jong Back;Song, Jin Cherl
    • Textile Coloration and Finishing
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    • v.7 no.4
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    • pp.8-15
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    • 1995
  • A series of thermotropic Polyurethanes mesogenic unit were synthesized by polyaddition of a para-type diisocyanate such as 2,5-tolylene diisocyanate(2,5-TDI) with 4-4'-bis($\omega$-hydroxyalkoxy) biphenls(BPm: $HOCmH_{2m}OC_{6}H_{4}OC_{m}H_{2m}OH$ : m is the carbon number of the hydroxyalkoxy group) in DMF. Intrinsic viscosities of the polymers were in the range of 0.41~0.99dL/g DSC thermograms for these polymers exhibited two endothermic peaks corresponding to phase transitions of melting and isotropization. For examplem polyurethane 2,5-TDI/BPll with [η]=0.99 prepared from 2.5-TDI and 4,4'-bis[11-hydroxyundecaoxy biphenyl(BP11) a liquid crystalline phase from 156 to 173$^{\circ}C$. The thermotropic properites of liquid crystalline polyurethanes have been investigated by wide-angle X-ray scatter(WAXS), infrared (IR) spectroscopy, and differential scanning calorimetry (DSC). The mesomorphic behavior of the polyurethanes was concluded to be greatly dependent on the intermolecular hydrogen bonds through the urethane.

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PTCR Properties of $BaTiO_3$ Ceramic Variation of Dopant (불순물 첨가에 따른 $BaTiO_3$ 세라믹스의 PTCR 특성)

  • Kang, Jeong-Min;Cho, Hyun-Moo;Lee, Jong-Deok;Park, Sang-Man;Lee, Young-Hie;Lee, Sung-Gap
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.412-415
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    • 2004
  • PTC Thermistors specimens were fabricated by added $MnO_2$ as donors, and $Nb_2O_5$ as accepters and sintered $1250^{\circ}C/2hrs$. Average grain size decreased with increased in added $MnO_2$, and increased with added in $Nb_2O_5$. But, appeared liquid phase as $BaTiO_3$ and $TiO_2$, affect to grain growth. XRD result, peak strength waslowed then crystallization not well, but, secondary phase were not showed all specimens. All specimens resistance were so high, about $40M{\Omega}$ over, couldn't measured to those resistance and doesn't appear PTCR effect.

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A Study on the Contact Resistance of Plug-In MCCB Placed in Distributing Board (배전반에 설치된 Plug-In MCCB의 접촉 저항에 관한 연구)

  • Lee, Byung-Seol;Choi, Chung-Seog
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2013.04a
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    • pp.56-57
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    • 2013
  • Plug-In MCCB는 전원부의 연결 단자가 없으며, 차단기 후면에 설치된 하우징 형태(housing type)의 플러그 유닛으로 부스바에 원터치(one touch) 설치 및 분리 등이 가능하다. 그러므로 차단기의 교체 시간이 짧고, 전원 복구가 신속하여 설비의 효율적 운용에 기여할 수 있다. 차단기의 후면에 있는 플러그 유닛이 동 부스바에 연결되었을 때 저항 특성을 초저항측정기(Resistance Tester)로 분석하였다. 3상 3선식 플러그인 배선용차단기를 동 부스바에 설치했을 때 R-phase과 플러그 단자 사이의 접촉 저항은 $0.51m{\Omega}$으로 확인되었다. 즉, 개발된 Plug-In MCCB를 이용하여 부스바에 설치할 때 접촉(속)부의 전기적 특성이 우수한 것을 확인할 수 있었다.

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Preparation of Epitaxial $LaSrCoO_3/SrTiO_3(100)$ Structures by The Chemical Solution Process (화학적 용액법에 의한 에피탁샬 $LaSrCoO_3/SrTiO_3(100)$ 구조의 제조)

  • 이형민;황규석;송종은;류현욱;강보안;윤연흠;김병훈
    • Journal of the Korean Ceramic Society
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    • v.36 no.10
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    • pp.1075-1079
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    • 1999
  • LaSrCoO3 thin films were spin-coated onto the SrTiO3(100) substrates by the chemical solution process. X-ray diffraction $\theta$-2$\theta$ scans and X-ray diffraction $\beta$ scans were used to determine the crystallinity and in -plane alignment behavior of the films. The X-ray diffraction pattern showed the film obtained by annealing at 80$0^{\circ}C$ was highly oriented. The X-ray diffraction pole-figure analysis and reciprocal-space mapping (2$\theta$-$\Delta$$\omega$ scans) of the resulting film showed that the film comprising the pseduocubic phase had an epitaxial relationship with the SriO3 substrate.

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Basics of Ion Mobility Mass Spectrometry

  • Lee, Jong Wha
    • Mass Spectrometry Letters
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    • v.8 no.4
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    • pp.79-89
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    • 2017
  • Ion mobility mass spectrometry (IM-MS) combines the advantages of ion mobility spectrometry (IMS) and MS for effective gas-phase ion analysis. Separation of ions based on their mobilities prior to MS can be performed without a great loss in other analytical figures of merit, and the extra dimension of analysis offered by IM can be beneficial for isomer and complex sample analyses. In this review, basic principles of IMS and IM-MS are described in addition to an introduction to various IMS techniques and commercial IM-MS instruments. The nature of collision cross-section (${\Omega}_D$), an important parameter determining the transport properties of ions in IMS, is also explained in detail.

Torque Harmonics Minimization in PMSM by Using Flux Harmonics Estimation (쇄교자속 추정을 통한 영구자석형 동기전동기의 토오크 제어)

  • 문형태
    • Proceedings of the KIPE Conference
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    • 2000.07a
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    • pp.439-442
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    • 2000
  • An adaptive nonlinear control of a brushless direct drive motor(BLDDM) is proposed. Comparing to the traditional PMSM the direct drive motor has smaller number of per pole and per phase slots to provide higher torque in low speed. This generic construction generates flux harmonics and finally results in unwanted torque harmonics. To control the speed a feedback linearization method is applied by choosing the $i_{ds}$ and $\omega_{m}$ as the output variables. The control of the flux harmonics is provided by using a flux observer with MRAC technique. As shown in the simula-tion results the proposed nonlinear speed controller has a good speed response in the steady state and robust to the flux variation

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Unsteady Performance Analysis of Accelerating Compressor Cascade (가속되는 압축기 익렬의 비정상 성능해석)

  • Kim M.-H.;Choi J.-Y.;Kim K. S.;Lee G. S.;Kim Y. I.;Lim J. S.
    • 한국전산유체공학회:학술대회논문집
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    • 2001.05a
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    • pp.121-126
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    • 2001
  • An accelerating flow field through a compressor cascade is studied numerically by unsteady computational simulation. The two-dimensional Navier-Stokes equations for compressible flow is used for the study of unsteady high incidence angle flow, with preconditioning scheme to cover the wide range of Mach number and $\kappa-\omega$ model for the turbulent viscous flow analysis. A DCA(double circular arc) compressor blade is accelerated artificially in this study to understand the unsteady effect by comparing the present results with the existing steady-state experimental and computational results. Also, the accelerating flow field during the starting phase of gas turbine is studied with actual experimental data for the understanding of flow field and performance characteristics at off-design condition.

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A Study on the Synthesis and Property of Azide Type Photosensitive Resin (Azide형 감광성수지의 합성과 특성에 관한 연구)

  • 조가람
    • Journal of the Korean Graphic Arts Communication Society
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    • v.14 no.1
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    • pp.115-131
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    • 1996
  • The PVT(pressure-volume-temperature) relation of main-chain dimer liquid crystals having structures such as $\alpha$,$\omega$-bis[(4,4`-cyanobiphenyl) oxy] alkane(CBA-n with=9, 10) were studied. these dimer liquid crystals are known to form an enantiotropic nematic mesophase. In this work, we have determined the volume change as a function of temperature and pressure by using a GNOMIX PVT apparatus. In the V-Tcurves obtaind from isobaris mearements on various pressures, volume changes were observed at the nematic-isotropiz and nematic-crystal phase transitions. The volume changes at the transition exhibit slight odd-even effect with respect to the number of methylene unit n. The values of the (S)v obtained at the NI transition for CBA-9 and -10 were 6.9 and 12.6J/mol k. The valuesof (S)v for the CN transition were estimated on the basis of DSC(differential scanning calorimetry) data: 58.8(CBA-9) and 65.3J/mol k (CBA-10). For both transition, it was found that the correction about the volume change is significant, ranging from 40% to 60% of the total transition entropy observed under constant pressure.

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Design of 1-D and 2-D Linear-phased Half-band Filters (1차원 및 2차원 선형 반대역 필터의 설계에 관한 연구)

  • 김대영;이병기
    • Journal of the Korean Institute of Telematics and Electronics B
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    • v.31B no.5
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    • pp.42-49
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    • 1994
  • In this paper we consider efficient 1-D and 2-D linear-phased half-band filter designs. We first introduce a new derivation of the existing Vaidynathan-Nguyen 's half-band filter design method, which verifies that the design provides optimal half-band filters. We then propose an approximately-linear-phased IIR half-band filter design method, which is based on the all-pass equalizer design with the linear phase -$\omega$/2. Finally, we propose an efficient method to design optimal 2-D half-band filters, for which we utilize a 2-D all pass prototype filter of half the order of the desired 2-D half-band filters.

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Am EMTDC Analysis for Line Faults with a Superconducting Fault Current Limiter (초전도 한류기를 포함한 계통의 단락사고에 대한 EMTDC 해석)

  • 최효상;황시돌;현옥배;정상진
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 1999.02a
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    • pp.101-105
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    • 1999
  • We have performed an EMTDC simulation for the current limiting effects of a superconducting fault current limiter (SFCL). The fault currents in the 154 kV transmission line between the Gaepo and Sungnam substations increased up to 54kA and 60kA during the line-to-line and three phase faults, respectively. The SFCL with 100 $\Omega$ of impedance after quench limited the currents to less than 17 kA within a half cycle. This limited current is well below the upper limit of a circuit breaker, suggesting that the impedance of the SFCL in the transmission line is sufficient.

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