• Title/Summary/Keyword: Oil behavior

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Characteristics of Malodor Pollutants and Their Dispersion Measured in Several Industrial Source Regions in Yangsan (양산시 산업단지에서 측정한 악취물질의 농도 분포 특성 및 대기확산 모델링)

  • Song, Sang-Keun;Shon, Zang-Ho;Kim, Yoo-Keun;Park, Heung-Jai
    • Journal of Environmental Science International
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    • v.18 no.10
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    • pp.1103-1114
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    • 2009
  • In this study, the environmental behavior of malodor pollutants (MPs: $H_2S$, $CH_3SH$, DMS, and DMDS) was investigated around areas influenced by strong anthropogenic processes based on observations and modeling study (a CALPUFF dispersion model). The MP emission concentrations were measured from 8 industrial source regions (tire plants (S1-S3), waste water disposal plant (S4), and oil refinery (S5) in an urban center area and paper mill/incineration plant (S6) and livestock feedlots (S7-S8) in Ungsang area) in Yangsan city during a fall period in 2008 (21 October 2008). Overall, the most MPs emitted from the urban center area were found to affect the malodor pollution in their downwind areas during early morning (06:00 LST) and nighttime (18:00 and 21:00 LST), compared with those in the Ungsang area. For malodor intensity, the most MPs in the urban center area (especially S1 and S2) were found to be a significant contributor, whereas $CH_3SH$ and $H_2S$ in the Ungsnag area (especially S6) were the dominant contributor. The model study showed agreement in the spatial distributions of simulated MPs with those of the observations. The largest impact of MPs in the urban center area on the malodor pollution in its residential areas occurred at S1, S2, and S3 sites during nighttime, while that of MPs in the Ungsang area occurred at S6 and S8 sites. This may be caused mainly by the high MP emissions and in part by wind conditions (prevailing northeasterly winds with low wind speeds of 2-3 m/s).

Coalescence behavior of dispersed domains in binary immiscible fluid mixtures having bimodal size distributions under steady shear flow

  • Takahashi Yoshiaki;Kato Tsuyoshi
    • Korea-Australia Rheology Journal
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    • v.17 no.3
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    • pp.125-130
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    • 2005
  • Coalescence process of binary immiscible fluid mixtures having bimodal size distributions, prepared by mixing two pre-sheared samples at different shear rates, ${\gamma}_{pre1}\;and\;{\gamma}_{pre2}$, under shear flow at a final shear rate, ${\gamma}_f$, are examined by transient shear stress measurements and microscopic observations in comparison with the results for simply pre-sheared samples having narrow size distributions (unimodal distribution samples). Component fluids are a silicone oil (PDMS) and a hydrocarbon-formaldehyde resin (Genelite) and their viscosities are 14.1 and 21.0 $pa{\cdot}sec$ at room temperature $(ca.\;20^{\circ}C)$, respectively. The weight ratio of PDMS: Genelite was 7:3. Three cases, $({\gamma}_{pre1}=7.2sec^{-1},\;{\gamma}_{pre2}=12.0sec^{-1}\;and\;{\gamma}_f=2.4sec^{-1}),\;({\gamma}_{pre1}=0.8sec^{-1},\;{\gamma}_{pre2}=4.0sec^{-1}\;and\;{\gamma}_f=2.4sec^{-1}),\;and\;({\gamma}_{pre1}=7.2sec^{-1},\;{\gamma}_{pre2}=12.0^sec^{-1}\;and\;{\gamma}_f=7.2sec^{-1})$ the first case, transient shear stress did not show any significant difference but domains larger than the initial state are observed at short times. In the latter cases, there exist undershoot of shear stress, reflecting existence of deformed large domains, which is confirmed by the direct observation. It is concluded that coalescence between large and small domains more frequently occur than coalescence between the domains with similar size in the bimodal distribution samples.

The Effects of Hot Corrosion on the Creep Rupture Properties of Boiler Tube Material (보일러 管材料의 크리프破斷特性에 미치는 고온부식의 影響)

  • 오세욱;박인석;강상훈
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.2
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    • pp.236-242
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    • 1989
  • In order to investigate the effects of hot corrosion on the creep rupture properties and creep life of 304 stainless steel being used as tube materials of heavy oil fired boiler, the creep rupture tests were carried out at temperature 630.deg.C, 690.deg.C and 750.deg.C in static air for the specimens with or without coating of double layer corrosives according to the new hot corrosion test method simulating the situation commonly observed on superheater tubes of the actual boiler. The double layer corrosives are 85% V$_{2}$O$_{5}$ + 10% Na$_{2}$So$_{4}$ + 5% Fe$_{2}$O$_{3}$ as the inner layer corrosive being once melted at 900.deg. C and crushed to powder, and 10% V$_{2}$O$_{5}$ + 85% Na$_{2}$SO$_{4}$ +5% Fe$_{2}$O$_{3}$ as the outer layer corrosive. As results, in the specimen coated with the double layer corrosives, the rupture strength was extremely lowered and showed a large difference each other. The rupture ductility also lowered remarkably as a result of the brittle fracture mode due to hot corrosion. These results indicate that hot corrosion could essentially alter the creep fracture mechanism. From the metallographic observation, it was clarified that the rupture life of 304 stainless steel subjected to hot corrosion was chiefly determined by the behavior of the aggressive intergranular penetration of sulfides.des.

Spray-atomization Characteristics of Biodiesel Fuel with Multiple Injection (다단분사를 적용한 바이오디젤 연료의 분무 미립화 특성)

  • Park, Su-Han;Kim, Hyung-Jun;Kim, Se-Hun;Lee, Chang-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.4
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    • pp.40-47
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    • 2010
  • This study deals with the investigation about the effect of the pilot and split injection strategies on the spray-atomization characteristics of biodiesel fuel derived from a soybean oil. Experimental results were compared with the calculation results obtained from the numerical analysis. Fuel properties of biodiesel according to the variation of the fuel temperature were inserted to the fuel library in the KIVA code. The amount of fuel injection is divided into equal mass for each split and main injection. In this work, the pilot injection strategy can be achieved by the amount of fuel injection shortly before the start of the main injection. A spray tip penetration, radial distance and spray area were measured for the analysis of macroscopic spray characteristics. In addition, the local and overall droplet size distribution were calculated by using KIVA-3V code to study the effect of split and pilot injection on the atomization performance under high ambient pressure. From these studies, the experimental results showed the multiple injection induced the decrease of the spray tip penetration due to the reduction and division of the spray momentum compared to single injection. In the atomization performance, the droplet size increased in the case of the multiple injection a little. Moreover, the SMD slightly increased as the fuel droplets goes through the axial direction. The spray behavior of numerical results were well predicted the experimental multiple spray characteristics of biodiesel fuel.

A Study on Perpendicular Flame Retardant Characteristic Improvement of Halogen-free Flame Retardant Compounds by Nanoclay Addition (나노클레이 첨가에 따른 할로겐프리 난연컴파운드의 수직난연 특성 향상에 관한 연구)

  • Hwang, Chan-Yun;Yang, Jong-Seok;Seong, Baeg-Yong;Kim, Ji-Yeon;Park, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.1
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    • pp.51-56
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    • 2015
  • The object of this study is to obtain the optimum mix proportion of halogen free compound with flame resistance and, for the purpose, thermal/electrical characteristics test are conducted using compatibilizing agents, flame resistance agents, hydroxide aluminum, sunscreen, antioxidant and silicon oil on the base resin of linear low density polyethylene (LLDPE), Ethylene vinyl acetate copolymer (EVA). Existing compound method accompanies many requirements to be satisfied including a lot of addition of flame resistance agents, prohibition of impact on mixing capability with base and property and etc. In this study, different from the existing method, the optimum mix proportion is determined and experimented by adding nano clay. Oxygen index test shows no difference between specimens while T-6, T-9 shows oxygen index of 29[%] and 26[%], respectively. This is concluded that hydroxide aluminum, which is a flame resistance agent, leads low oxygen index. From UL94-V vertical flame resistance test, the combustion behavior is determined as V-0, Fail based on UL94-V decision criteria. Viscometry shows low measurements in specimens with separate addition of compatibilizing agents or nano clay. Volume resistivity test shows low measurement mainly in specimens without compatibilizing agents. Therefore, with the flame resistance compound shows better performance for thermal/electrical property and the optimum mix proportion are achieved among many existing materials.

A Study on the Behavior of Class 900 Flange Joints with Metal Ring Gaskets (금속 링 개스킷이 삽입된 Class 900 플랜지 조인트의 거동에 관한 연구)

  • Lee, Min-Young;Jeong, Doo-Hyung;Kim, Byung-Tak
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.1
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    • pp.34-41
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    • 2018
  • A flange joint is a pipe connection used to prevent the leakage of high-pressure fluids by inserting a gasket and tightening the bolts. Among several kinds of gaskets available, metal ring type joint gaskets are most widely used in conditions that require high-temperature and high-pressure fluid flow, such as oil pipelines, gas pipes, pumps, valve joints, etc. The purpose of this study is to investigate the contact pressure and stress characteristics closely related to the sealing performance of Class 900 flange joints used in high temperature and high pressure environments. The dimensions of flange joints with five different nominal pipe sizes were determined with reference to those specified in ASME 16.5. The metal ring gaskets inserted in the joints were octagonal and oval gaskets. The bolt tensile forces calculated from the tightening torques were input as the bolt pretension loads in order to determine the contact pressure and stress levels after fastening. Loading was composed of three steps, including the fastening step, and different amounts of applied pressures were used in each analysis to investigate the effect of fluid pressure on the contact force of the joints. A general-purpose software, ANSYS 17.2, was used for the analysis.

Safety Culture Assessment in Petrochemical Industry: A Comparative Study of Two Algerian Plants

  • Boughaba, Assia;Hassane, Chabane;Roukia, Ouddai
    • Safety and Health at Work
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    • v.5 no.2
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    • pp.60-65
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    • 2014
  • Background: To elucidate the relationship between safety culture maturity and safety performance of a particular company. Methods: To identify the factors that contribute to a safety culture, a survey questionnaire was created based mainly on the studies of $Fern{\acute{a}}ndez-Mu{\tilde{n}}iz$ et al. The survey was randomly distributed to 1000 employees of two oil companies and realized a rate of valid answer of 51%. Minitab 16 software was used and diverse tests, including the descriptive statistical analysis, factor analysis, reliability analysis, mean analysis, and correlation, were used for the analysis of data. Ten factors were extracted using the analysis of factor to represent safety culture and safety performance. Results: The results of this study showed that the managers' commitment, training, incentives, communication, and employee involvement are the priority domains on which it is necessary to stress the effort of improvement, where they had all the descriptive average values lower than 3.0 at the level of Company B. Furthermore, the results also showed that the safety culture influences the safety performance of the company. Therefore, Company A with a good safety culture (the descriptive average values more than 4.0), is more successful than Company B in terms of accident rates. Conclusion: The comparison between the two petrochemical plants of the group Sonatrach confirms these results in which Company A, the managers of which are English and Norwegian, distinguishes itself by the maturity of their safety culture has significantly higher evaluations than the company B, who is constituted of Algerian staff, in terms of safety management practices and safety performance.

Characteristics and Release Behaviors of Aromatic Poly(vinyl acetate) Nanoparticles Prepared by Emulsification-Diffusion Technique (유화-확산법에 의해 얻어진 폴리(비닐 아세테이트) 나노 방향 입자의 특성 및 방출 거동)

  • Sohn, Sung-Ok;Lee, So-Min;Kim, Yun-Mi;Ghim, Han-Do
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.177-183
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    • 2007
  • In this study, nano-sized poly(vinyl acetate) (PVAc) particles containing lavender oil as a core material were prepared by using emulsification-diffusion method. Effects of experimental parameters on the characteristics and the release behavior were examined with a field emission- scanning electron microscope, an electrophoretic light scattering spectrophotometer, a visible spectrophotometer and a high performance liquid chromatography The resulting aromatic particles could be prepared in nano-sized globular shapes with the mean particle size of 224 nm by controlling the experimental conditions. From the evaluation of release properties of aromatic PVAc nanoparticles with or without PVA coating, it was found that the aromatic particles coated with PVA show more sustaining and stable release behaviors. Our research on aromatic PVAc nanoparticles could be applied for durable fragrant finishing for textiles, leather products and so on.

Seismic Performance of a Knee-Braced Moment Resisting Frame (Knee brace가 설치된 모멘트저항골조의 내진성능)

  • Choi, Hyun-Hoon;Kim, Jin-Koo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.1
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    • pp.171-180
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    • 2005
  • In this study the seismic performance of a three-story knee-braced moment-resisting frame (KBMRF), which is typically employed to support pipelines for oil or gas, was investigated. Nonlinear static pushover analyses were performed first to observe the force-displacement relationship of KBMRF under increasing seismic load. The results show that, when the maximum inter-story drift reached 1.5% of the story height, the main structural members, such as beams and columns, still remained elastic. Then nonlinear dynamic time-history analyses were carried out using eight earthquake ground motion time-histories scaled to at the design spectrum of UBC-97. It turned out that the maximum inter-story drift was smaller than the drift limit of 1.5 % of the structure height, and that the columns remained elastic. Based on these analytical results, it can be concluded that the seismic performance of the structure satisfies all the requirements regulated in the seismic code.

Effects of a Sleep Improvement Program Combined with Aroma-Necklace on Sleep, Depression, Anxiety and Blood Pressure in Elderly Women (아로마목걸이를 병용한 수면증진 프로그램이 재가 노인여성의 수면, 우울, 불안 및 혈압에 미치는 효과)

  • Chun, Nami;Kim, Myoungsuk;Noh, Gie ok
    • Journal of Korean Academy of Nursing
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    • v.47 no.5
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    • pp.651-662
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    • 2017
  • Purpose: The purpose of this study was to evaluate the effectiveness of a sleep improvement program combined with an aroma-necklace on sleep, depression, anxiety, and blood pressure in elderly women living at home. Methods: A program consisting of a four-week (one hour per week) sleep improvement intervention plus use of an aroma-necklace, was developed based on Cox's Interaction Model of Client Health Behavior. 70 elderly women were assigned to the experimental (n=35) or control group with no intervention (n=35). Data from 62 participants (32 in the experimental and 30 in the control) were analyzed using the SPSS 21.0 program. Women in the experimental group were instructed to constantly wear the aroma necklace filled with marjoram and orange oil until the program was completed. Sleep quality, sleep duration, sleep satisfaction, depression, anxiety, and blood pressure were measured to identify the effectiveness of the program. Results: Significant group differences were found in sleep quality (t=-5.10, p<.001), sleep duration (z=-3.10, p=.002), sleep satisfaction (z=-4.13, p=<.001), depression (t=2.53, p=.015), and anxiety (z=-2.47, p=.014). No differences were found in the systolic or diastolic blood pressure. Conclusion: The results indicate that a sleep improvement program combined with an aroma-necklace was effective in improving sleep disturbances in elderly women living at home. Nurses may contribute to improving sleep among elderly women by applying this program to aged women living in various environments.