• 청정기술
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• 제24권4호
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• pp.365-370
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• 2018

Oil shale은 kerogen을 함유한 퇴적암으로 대표적인 비재래 에너지자원으로 알려져 있다. 열분해 공정을 통하여 oil shale이 분해되면 oil, gas 및 coke를 생성하게 된다. 본 연구에서는 oil shale의 청정 전환기술을 개발하기 위하여 oil shale의 TGA 및 연속 열분해 연구를 수행하였다. Oil shale의 열분해 전환율에 대한 반응 온도 및 체류시간의 영향을 살펴보고 oil의 생성율을 살펴보았다. Oil shale의 열분해 전환율은 온도와 체류시간에 따라 증가하였으며 $450{\sim}500^{\circ}C$, 체류시간 30 min의 조건에서 최대 oil 생산 수율을 나타내었다.

• 에너지공학
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• 제19권2호
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• pp.57-61
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• 2010

국내 에너지자원 자급률을 높이기 위해서는 적극적인 해외유전개발투자를 통한 생산 유 가스전 매입, M&A, 기존 생산광구 증산 등을 추진해야할 것이다. 이를 위해서는 생산 유 가스전 평가, 설계, 운영 등과 관련된 핵심 전략 기술에 대한 확보가 필수적이라고 할 수 있다. 향후 지속적인 연구개발 지원을 통한 생산광구평가와 생산 최적 설계.운영 기술 축적으로 해외 매입 가능한 유 가스전의 증가와 기존 유 가스전의 생산량 증대, 효율적인 광구 운영을 통한 석유 가스 자주개발률 제고를 기대할 수 있을 것이다.

• 한국초지조사료학회지
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• 제34권3호
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• pp.193-201
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• 2014

This study was conducted to examine the effects of defaunation (removal of live protozoa) on fermentation characteristics, degradation of ryegrass hay and $CH_4$ (methane) production by rumen microbes when incubated with plant oils (SO, sunflower oil and LO, linseed oil) in vitro. Sodium lauryl sulfate (0.000375 g/ml) as a defaunation reagent was added into the culture solution and incubated anaerobically up to 24 h at $39^{\circ}C$. pH from defaunation was increased for all treatments from 6 h incubation times (p<0.01-0.001) compared with those from fauantion. Concentration of ammonia-N from defaunation is higher than that from faunation at 3 h (p<0.001), 12 h (p<0.05) and 24 h (p<0.001) incubation times. Defaunation decreased (p<0.01-0.001) total volatile fatty acid concentration at all incubation times. Molar proportions of $C_2$ (acetate, p<0.05-0.001) and butyrate (p<0.01-0.001) were also decreased by defaunation at all incubation times. Molar proportion of $C_3$ (propionate), however, was increased by defaunation at all incubation times (p<0.001). Thus the rate of $C_2$ to $C_3$ was decreased by defaunation at all incubation times (p<0.001). Defaunation decreased ED (effective degradability) of dry matter (p<0.001) and ED of neutral detergent fiber (p<0.001) of ryegrass hay. Defaunation decreased total gas, $CH_4$ production, $CH_4$ % in total gas and $CH_4/CO_2$ at all incubation times (p<0.001). Oil supplementation decreased total gas (p<0.05-0.001), $CH_4$ production (p<0.001) and $CH_4$ % in total gas (p<0.001) compared with control at all incubation times. The result of this study showed that defaunation combined with oil supplementation may cause an alteration of microbial communities and further medicate the fermentation pattern, resulting in both reduction of degradation of ryegrass hay and $CH_4$ production. No difference, however, was observed in all the examinations between SO and LO.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2014년도 추계학술대회
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• pp.53-55
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• 2014

Offshore 에서의 oil & gas 생산은 해상이라는 환경으로 인한 고유의 특성 때문에 항상 다수의 변수들에 영향을 받으며, 막대한 비용이 소요되기 때문에 비용을 최소화하며, 비용 대비 수익을 최대화시키기 위한 optimal design이 필수이다. 본 논문은 가상의 offshore plant와 이에서 생산된 oil의 수요지들을 설정하여 시장수요에 따른 offshore 생산의 최적화 문제를 연구대상으로 하며, 다수의 offshore oil fields를 보유한 major oil company가 당면할 수 있는 offshore production에 관한 문제를 일반화하여 정의하고, 이윤을 극대화시킬 수 있는 최적화 모형을 혼합정수계획모형(mixed integer programming)으로 정식화 하였다. 최적화 모형의 해는 Microsoft office excel solver를 통해 구하였으며 그 계산실험의 결과를 요약하여 보고한다.

• Asian-Australasian Journal of Animal Sciences
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• 제20권8호
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• pp.1196-1200
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• 2007

Eight feeds (mixture of wheat straw and oil seed cakes in 3:1 ratio) were evaluated for methane emission and fermentation pattern with buffalo rumen liquor as inoculum in an in vitro gas production test. The cakes tested were groundnut cake (GNC), soybean cake (SBC), mustard seed cake (MSC), cotton seed cake (CSC), karanj seed cake expeller extracted (KCEE), karanj seed cake solvent extracted (KCSE), caster bean cake expeller extracted (CBCEE) and caster bean cake solvent extracted (CBCSE). The gas production (ml/g dry matter) was significantly higher with SBC and MSC followed by CSC, GNC, KCSE, KCEE, CBCSE and was the lowest with CBCEE. Methane emission was significantly lower with KCEE, KCSE, CBCEE, CBCSE (20.32- 22.43 ml/g DM) than that with SBC, GNC, CSC (27.34-31.14 ml/g DM). Mustard seed cake was in-between the two groups of oil cakes in methane production. In vitro true digestibility was highest with SBC followed by GNC, CSC, MSC, KCSE, KCEE, CBCSE and CECEE. Ammonia nitrogen level was positively correlated with the amount of protein present in the cake. Total holotrich protozoa were significantly higher with SBC, whereas, large spirotrich protozoa tended to be lower than with other cakes. The counts of small spirotrich and total protozoa were similar with all the cakes. Total volatile fatty acid production and acetate to propionate ratio were significantly higher with SBC and significantly lower with KCEE as compared to the other cakes. Among the conventional oil cakes tested in the present experiment (GNC, SBC, MSC and CSC), mustard seed cake-based feed produced the minimum methane without affecting other fermentation characteristics adversely.

• 한국지구물리탐사학회:학술대회논문집
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• 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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• pp.695-702
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• 2003

In this study, an experimental apparatus has been designed and set-up to analyse the dissociating phenomena of hydrate in porous rock using electric heating method supplied at downhole. The electric heat injecting experiments have been performed to investigate the heat transfer within the core, the dissociating phenomena of hydrate, and the productivities of dissociated gas and water. These experiments were under constant heat injecting method as well as preheating methods. From the experimental results, it is seen that the hydrates is dissociated along the phase equilibrium curve and dissociation of hydrate is accelerated with heat. The injected heat is consumed for the dissociation and also it is lost together with outflow of the dissociated gas and water. From the investigation of gas producing behavior for various heat injecting methods, as the injected heat is greater, dissociation is accelerated faster at outlet and hence the initial gas production becomes higher. Also, it is shown that the initial gas productivity under the constant heating method is better, however, the energy efficiency is low because of smaller amount of the produced gas comparing to the amount of heat injected. In the experiments of preheating method, it was seen that gas production only initial stage is different with the preheating time, but the producing behaviors of gas production are similar.

• Journal of Biosystems Engineering
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• 제25권6호
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• pp.481-488
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• 2000

This study was initiated in order to find alternative fuel substituting for light oil the most common fuel for heating greenhouse. The tire oil used in this research was produced by pyrolysis process, one of the final products besides steel string and carbon black in which waste tires as a form of chopped pieces broken by shredding machine are heated up to 200~30$0^{\circ}C$ with maximum restraining of oxygen supply. In order to justify light oil equivalent qualities in tire oil combustion characteristics were defined in the way of comparing kinetic viscosities in the wide range of temperature flame sizes and exhaust gas components in the various combustion conditions. We found that kinetic viscosity of tire oil was lower than light oil by 1 to 2 cSt in the temperature range showing better flowing mobility in the fuel line of the burner and no significant difference in flame size between the two oils in the all combustion treatments. However much more NO and SO$_2$ were detected from the exhaust gases of tire oil than light oil combustions. In fact tire oil contains more nitrogen and total sulfur, by 25 times and 40 times respectively than light oil according to the composition analysis. Tolerable limit for SO$_2$discharge amount defined by the national air pollution standards is under 540ppm so tire oil combustion satisfies the requirement though. It is desirable if sulfur and nitrogen filtering process shall be added in the tire oil production line. Except the exhaust gas components all greenhouse heating qualities of tire oil including hot air temperature are very identical to those of light oil.

• 해양환경안전학회:학술대회논문집
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• 해양환경안전학회 2006년도 추계학술발표회
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• pp.169-174
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• 2006

모든 원유 (crude oil)와 제품유 (petroleum product)는 서로 구별되는 탄화수소특성을 가지고 있다. 원유의 경우 산지별로 고유한 특성을 지니고 있으며, 제품유의 경우 같은 유종이라 할지라도 그 원료가 되는 원유의 특성, 생산공정, 생산시기 등에서 차이점이 발생한다. 즉, 생산시기가 동일하다 할지라도 선박의 연료탱크내에 남아있는 잔류유와의 혼합 동에 의해 구별되는 특징을 가지게 되며 이러한 특성을 이용한 기법을 유지문기법(oil fingerprint method) 이라 한다. 본 연구에서는 최근 새로운 유지문기법으로 활용 가능성이 대두되고 있는 2 차원 가스크로마토그래프 (Comprehensive Two Dimensional Gas Chromatography)를 이용하여 기존의 가스크로마토그래프 (GC)와 가스크로마토그래프 질량분석기 (GC/MS) 와의 분석방법 비교 등을 통해 유지문 분석기법의 실효성에 대해서 논하고자 한다.

• 미생물학회지
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• 제9권3호
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• pp.95-102
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• 1971

The growth characteristics of Candida tropicalis KIST 351 on gas oil substrate under different culture conditions were investigated and the preliminary animal feeding experiments using this yeast as a partial substitute of fish meal was also conducted. The yeast assimilates effectively n-paraffins in gas oil ranging from $C_{16}$ to $C_{16}$ with its maximum cell growth at $33^{\circ}C$ and pH 5.5 with aeration of 3 vvn and agitation of 900 rpm. The optimal concentrations of nitrogen sources, $HK_2PO_4$ and $Na_2HPO$ were 4, 2 and 0.5g/1, respectively. Ferrous sulfate, manganese sulfate and zinc sulfate showed positive effect to cell growth with the optimal range of 5-10 ppm. In the feeding experiment with 3 and 5% incorporation of the gas oil grown yeast, neither adverse effects on growth of chicks nor toxic effect were observed. Protein content of the dried cell was 58.8% and its amino acid composition compared well with other single-cell protein products and FAO reference protein.

• Corrosion Science and Technology
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• 제7권6호
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• pp.350-361
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• 2008

Canada's oil sands contain one of the largest reserves of oil in the world. According to recent estimates, there are nearly 180 billion barrels of oil in the Canadian oil sands trapped in a complex mixture of sand, water and clay. More than 40 companies have been currently operating or developing oil sands facilities since the first production in 1967. The process of oil sands upgrading is similar with down stream refinery, but the corrosion environment in upgrading refinery is often more severe than in the refinery because of high chlorides, mineral contents, carbonic acid, heavy viscosity and fouling, higher naphthenic acid [$NA-R(CH_{2})nCOOH$], and greater sulfur contents. Naphthenic acid corrosion (NAC) which is one of the most critical corrosion issues in up & downstream refinery plants was observed for the first time in 1920's in refinery distillation processes of Rumania, Azerbaizan (Baku), Venezuela, and California. As a first API report, the 11th annual meeting stated sources and mechanism of NAC in early 1930's. API has been developing the risk base standards, such as API RP580, 571, and Publication 581 which are based on the worst NAC damage in the world since 2000. Nevertheless not only the NAC phenomena and control in Canadian sands oil process are not much widely known but also there are still no engineering guidances for the Canadian sands oil in API standards. This paper will give NAC phenomina and materials selection guidance against NA environment in Canadian oil sands upgrading processes.