• 제목/요약/키워드: Oil adsorption

검색결과 159건 처리시간 0.026초

경유오염 농경지의 톱밥 처리효과 (Effect of Sawdust Treatment at Oil Contaminated Soil)

  • 이종식;이용환;홍승길
    • 한국환경농학회지
    • /
    • 제19권3호
    • /
    • pp.191-193
    • /
    • 2000
  • 경유로 인한 농작물 피해를 줄이기 위한 방법으로 톱밥처리 효과를 구명하기 위하여 톱밥의 경유 흡착능과 시용 효과를 상탄(上炭(Muck)), 이탄(泥炭(Peat)) 및 PEAT SORB 등과 비교, 검토한 결과, 흡착제 종류별 경유 제거효율은 톱밥과 PEAT SORB가 토탄 및 이탄에 비해 높았다. 톱밥의 경유 제거효율은 경유에 대한 처리 비율이 1:2(w/v)이상일 때 97% 이상으로 높게 나타났으며, 흡착된 경유의 재용출은 거의 없었다. 경유오염 토양에서의 톱밥 처리효과는 분얼기에 $4,000L{\cdot}ha^{-1}$의 경유를 처리하고 흡착제를 처리하지 않은 구에서는 초장과 엽록소 함량이 대조구에 비해 감소한 반면 톱밥 처리구에서는 생육이 좋았다.

  • PDF

STUDY OF SYNTHESIS, MATTER S PROPERTIES AND APPLICATION OF MICA/TIA$_2$/SIO$_2$PIGMENT IN COSMETICS AREA

  • Ju, Namgung;Lee, Dong-Kyu
    • 대한화장품학회지
    • /
    • 제24권3호
    • /
    • pp.51-58
    • /
    • 1998
  • Generally pigment differs from dye stuff because it cannot be melted in water but also because it is stable physically and chemically. In this study you will discover the function, properties and effects of Micai-TiO$_2$-SiO$_2$pigment as abase material pigment. But until now used Mica of the base material is about 7-l5${\mu}{\textrm}{m}$ with an average diameters of 15${\mu}{\textrm}{m}$. A new characteristic superficial pigment was obtained from covering the TiO$_2$ and SiO$_2$ with the adsorption result of isoelectric point of a Mica flake, TiO$_2$ and SiO$_2$In the composition reaction study of adsorption was done as well as the physical characteristics of the superficial texture of the obtained material. L,a,b of color change as oil was absorbed, optical nature and change of reflection according to direct and diffused reflection. In the composition of Mica slurry the best result obtained was in a solution with pH 2.0 to 2.3. Following this result, we can come to the idea that electrical attraction was done during the change of electrical charge of the Mica and TiO$_2$ deposit. Also this pigment shows a big scale between the direct reflection and diffused reflection light. Using this characteristic in cosmetic, it was obtained a natural but a contrast between light and shadow making possible a sculptured make-up. Color change due to oil adsorption was insignificant which improved the last of make up.

  • PDF

유체 계면에서 콜로이드 흡착에 대한 전해질 농도의 영향 (The Effect of Electrolyte Concentration for Colloid Adsorption toward a Fluid-Fluid Interface)

  • 박범준
    • Korean Chemical Engineering Research
    • /
    • 제51권4호
    • /
    • pp.527-530
    • /
    • 2013
  • 이 논문은 콜로이드 입자가 기름-물 사이의 계면으로 흡착될 때 필수적으로 존재하는 정전기적 반발력에 대한 실험적, 이론적 연구이다. 광집게(optical laser tweezers)와 피에조(piezo controller)를 사용하여, 개별 입자를 트랩(trap)한 후, 계면으로 강제 전이시킨다. 이때 수용액이 전해질을 포함한 경우에만, 입자가 계면으로 전이되며, 포함하지 않을 경우에는 흡착이 일어나지 않는다. 이러한 현상을 근본적으로 이해하기 위해, 광학 트랩핑 힘(optical trapping force)과 입자와 계면 사이에 존재하는 정전기적 분리압력(electrostatic disjoining pressure)를 정량적으로 계산하였다. 이를 바탕으로, 입자가 계면으로 흡착될 때, 그들 사이에는 필연적으로 문턱 에너지(threshold energy)가 존재함을 밝혀냈다. 콜로이드 입자가 에멀젼(emulsions)이나 거품(foams)등 두 개 이상의 섞이지 않는 유체계면을 안정화 시키는 "콜로이드 계면 활성제(colloid surfactants)" 역할을 한다는 사실을 고려했을 때, 본 연구는 이러한 입자의 흡착 현상을 근본적으로 이해하는데 있어서 중요한 지식을 제공한다.

MODFLOW를 이용한 유류오염지역 지하수 유동 및 오염물질 이동 평가

  • 전권호;문철환;이진용;이재영
    • 한국지하수토양환경학회:학술대회논문집
    • /
    • 한국지하수토양환경학회 2003년도 추계학술발표회
    • /
    • pp.536-539
    • /
    • 2003
  • This study area has been contaminated by oils. To identify contaminated ranges and to assess the possibility of contamination dispersion, monitoring wells were installed and slug test, field soil permeability test, automatic or manual measurement of groundwater table, and groundwater quality analyses in field and laboratory were performed. In addition, a groundwater modeling program was used to assess the possibility of oil contamination dispersion, based on field data and groundwater quality data. The results showed that concentration of oil contaminants in groundwater have been decreased by dispersion and adsorption.

  • PDF

엔진 수트 측정 센서 표면에서의 흡착 오염 저감을 위한 실험적 연구 (I) (An Experimental Study for the Minimization of Soot Adsorption on the Optical Surface of an Engine Soot Detector (I))

  • 윤의성;김학열;공호성;한흥구
    • Tribology and Lubricants
    • /
    • 제20권6호
    • /
    • pp.343-349
    • /
    • 2004
  • The adsorption of soot particles onto a sensor surface of the engine soot detector posses a critical problem in the measurement. In order to prevent the optical rod surface from soot contamination, various functional coatings and flow-induced cleaning were applied to the surface in this work. For surface coatings, various materials of self-assembled monolayers (SAM) such as OTS (octadecyltrichlorosilane), PFDTES (perfluorodecyl-triethoxysilane) and PFDTMS (perfluorodecyltrimethoxysilane) were coated on the optical rod surface ,which have different characteristics in both hydrophobicity and oleophobicity. These coatings were tested with soot content varying from $0\%\;to\;3wt\%$ and oil temperature from 20 to $70^{\circ}C$. Test results showed that surface coatings were not effective for preventing the adsorption of soot panicles on the surface of optical rod. It was thought that these coatings provided the surface with additional attractive surface forces. However, it was found that adsorption of soot particles onto a sensor surface was minimized by flow-induced cleaning. This effect was tested with varying the flow velocity.

Effect of Dodecylbenzene Sulfonic Acid on the Behavior of Asphaltene Aggregation in a Solvent Deasphalting System

  • Liu, Lingyu;Go, Kang Seok;Nho, Nam Sun;Kim, Kwang Ho;Rhee, Young-Woo
    • Korean Chemical Engineering Research
    • /
    • 제56권1호
    • /
    • pp.14-23
    • /
    • 2018
  • The effect of dodecylbenzene sulfonic acid (DBSA) with different addition amount of DBSA ($M_{DBSA}$), temperatures and solvent-to-oil ratio (SOR, v/v) on asphaltene aggregation in a solvent deasphalting system was investigated. Increasing the $M_{DBSA}$ at SOR 10 and $55^{\circ}C$ caused the asphaltene removal ratio (ARR) to increase first, then maximize at 1 wt% of $M_{DBSA}$ and then decrease continuously. Based on the SARA (saturate, aromatic, resin, asphaltene) composition, the adsorption amount of DBSA on the asphaltene surface and the self-aggregation of the DBSA, the reason for the change in ARR with $M_{DBSA}$ was found due to the adsorption mechanism. In addition, the asphaltene-resin-DBSA colloidal size confirmed the change of adsorption behavior between the asphaltene and DBSA. Based on the results of this study, a hypothetical adsorption mechanism of DBSA on asphaltene aggregation in the solvent deasphalting system was conceived of and proposed.

단백질과 기름농도가 분리대두단백질의 유화안정성에 미치는 영향 (Effect of protein and oil concentration on the emulsion stability of soy protein isolate)

  • 황재관;김영숙;변유량
    • Applied Biological Chemistry
    • /
    • 제35권6호
    • /
    • pp.457-461
    • /
    • 1992
  • 본 연구에서는 단백질과 기름의 농도가 분리대두단백질의 유화안정성에 미치는 영향을 연구하였다. 특히 유화안정성과 에멀젼의 기름입자크기 및 점도와의 상관관계를 구명하였으며, 또한 유화과정 중 단백질이 물과 기름 사이의 계면에 흡착하는 현상을 조사하였다. 단백질의 농도가 증가할수록 기름입자의 크기는 감소하고 점도는 증가하여 결과적으로 유화안정성이 증가하였다. 반면에 기름농도가 증가한 경우 기름입자의 크기와 점도가 모두 증가하였으며, 이 경우에는 두 요인의 상대적인 지배정도에 따라 에멀젼의 유화안정성이 결정되었다.

  • PDF

섬유 텐터 대기오염물질의 선택적 제거를 위한 싸이클론 및 전기 집진 오일필터의 특성 (Characteristics of Cyclone and Electric Dust Collection Oil Filters for Selective Removal of Fiber Tenter Air Pollutants)

  • 정진호;류승한;권순덕;조윤현
    • 한국염색가공학회지
    • /
    • 제35권4호
    • /
    • pp.256-273
    • /
    • 2023
  • Among the dyeing industries, the tenter process is a process that improves the quality of fibers by drying and ironing (heat treatment) dyed fabrics, and drugs such as water repellents, antistatic agents, and fiber softeners are mainly used in these tenter processes. These drugs are vaporized in the process of treatment by high temperatures (180 ~ 230℃), and are observed in a complex form such as white smoke, oil mist, and fine dust, causing odor. To treat the complex exhaust gas at the rear end of the tenter facility, most companies operate by installing a wet scrubber and an adsorption tower alone or in parallel, but there are many problems. In particular, the insoluble oil mist at the rear end of the tenter has significantly low processing efficiency in the cleaning dust collection facility, and there is a problem in the facility by adsorption due to the occlusion phenomenon caused by the oil mist. In addition, the odor gas at the rear end of the tenter contains a lot of aldehydes, and in order to improve these various problems, a complex exhaust purification device using cyclone and electric support collector was developed. This study examined the applicability of economical and efficient technology by removing complex air pollution at the rear end of the tenter and applying improved technology than the existing technology.

Fabrication and Characterisation of a Novel Pellicular Adsorbent Customised for the Effectvie Fluidised Bed Adsorption of Protein Products

  • Sun, Yam;Pacek, Andrzej W.;Nienow, Alvin W.;Lyddiatt, Andrew
    • Biotechnology and Bioprocess Engineering:BBE
    • /
    • 제6권6호
    • /
    • pp.419-425
    • /
    • 2001
  • A dense pellicular solid matrix has been fabricated by coating 4% agarose gel on to dense zironia-silica(ZS) spheres by watr-in-oil emulsification . The agarose evenly laminated the ZS bead to a depth of 30㎛, and the resultin gpellicular assembly was characterised by densities up to 2.39g/mL and a mean particle dimeter of 136 ㎛. In comparative fluidisation tests, the pellicular solid phase exhibited a two-fold greater flow velocity than commercial benchmark ad-sorbents necessary to achieve common values of bed expansion. Furthermore, the perlicular parti-cles were characterised by improved qualities of chromatographic behaviour, particularly with re-spect to a three-fold increase in the apparent effective diffusivity of lysozyme within a pellicular assembly modified with Cibacron Blue 3GA. The properties of rapid protein adsorption/desorp-tion were attributed to the physical design and pellicular deployment of the reactive surface in the solid phase. When combined with enhanced feedstock throughput, such practical advantages recommend the pellicular assembly as a base matrix for the selective recovery of protein products from complex, particulate feedstocks(whole fermentation broths, cell disruptates and biological extracts).

  • PDF