• 제목/요약/키워드: Oil Recovery Efficiency

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The developments of heavy hydrocarbon reformer for SOFC

  • 배중면
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2012년도 춘계학술발표대회
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    • pp.58.2-58.2
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    • 2012
  • Heavy hydrocarbon reforming is a core technology for "Dirty energy smart". Heavy hydrocarbons are components of fossil fuels, biomass, coke oven gas and etc. Heavy hydrocarbon reforming converts the fuels into $H_2$-rich syngas. And then $H_2$-rich syngas is used for the production of electricity, synthetic fuels and petrochemicals. Energy can be used efficiently and obtained from various sources by using $H_2$-rich syngas from heavy hydrocarbon reforming. Especially, the key point of "Dirty energy smart" is using "dirty fuel" which is wasted in an inefficient way. New energy conversion laboratory of KAIST has been researched diesel reforming for solid oxide fuel cell (SOFC) as a part of "Dirty energy smart". Diesel is heavy hydrocarbon fuels which has higher carbon number than natural gas, kerosene and gasoline. Diesel reforming has difficulties due to the evaporation of fuels and coke formation. Nevertheless, diesel reforming technology is directly applied to "Dirty fuel" because diesel has the similar chemical properties with "Dirty fuel". On the other hand, SOFC has advantages on high efficiency and wasted heat recovery. Nippon oil Co. of Japan recently commercializes 700We class SOFC system using city gas. Considering the market situation, the development of diesel reformer has a great ripple effect. SOFC system can be applied to auxiliary power unit and distributed power generation. In addition, "Dirty energy smart" can be realized by applying diesel reforming technology to "Dirty fuel". As well as material developments, multidirectional approaches are required to reform heavy hydrocarbon fuels and use $H_2$-rich gas in SOFC. Gd doped ceria (CGO, $Ce_{1-x}Gd_xO_{2-y}$) has been researched for not only electrolyte materials but also catalysts supports. In addition, catalysts infiltrated electrode over porous $La_{0.8}Sr_{0.2}Ga_{0.8}Mg_{0.2}O_3-{\delta}$ and catalyst deposition at three phase boundary are being investigated to improve the performance of SOFC. On the other hand, nozzle for diesel atomization and post-reforming for light-hydrocarbons removal are examples of solving material problems in multidirectional approaches. Likewise, multidirectional approaches are necessary to realize "Dirty energy smart" like reforming "Dirty fuel" for SOFC.

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복합 사이클의 배기가스 열회수 시스템에 의한 선박용 디젤엔진의 연료 절약에 관한 이론적 연구 (Theoretical Study on Fuel Savings of Marine Diesel Engine by Exhaust-Gas Heat-Recovery System of Combined Cycle)

  • 최병철;김영민
    • 대한기계학회논문집B
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    • 제37권2호
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    • pp.171-179
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    • 2013
  • 선박의 주 추진용 디젤엔진으로부터 배출되는 배기가스의 열을 회수하는 폐열회수 발전시스템에 대하여, 상대적으로 고온에 상부의 3 변 사이클과 상대적으로 저온부에 하부의 유기 랭킨 사이클이 적용되는 복합 사이클에 대한 열역학적 특성을 조사하였다. 그 결과, 상부와 하부 사이클 사이에 경계온도의 증가에 따라, 총 파괴된 엑서지율(${\sum}\dot{E}_d$) 및 엑서지 손실율($\dot{E}_{out2}$)이 각각 감소되었기 때문에, 시스템의 에너지 및 엑서지 효율이 모두 최대화되었다. 그리고 상부의 체적 팽창비가 크게 감소되었다. 그 경우에 대하여, 부가적인 추진동력으로써 활용되는 폐열회수 발전시스템이 적용된 선박용 디젤엔진의 경우에, 추진 효율은 엔진부하 변동에 따라 기본 엔진에 대비하여 평균적으로 9.17 %가 향상되었다. 이에 대하여, 디젤엔진의 연료 소비율과 이산화탄소 배출률은 각각 평균 8.4 및 8.37 %가 저감되었다.

우리 나라의 환경정책 방향 (Environmental Health Strategies in Korea)

  • 조병극
    • 환경위생공학
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    • 제7권2호
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    • pp.1-10
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    • 1992
  • Since 1960's along with industrialization and urbanization, economic growth has been . achieved, however, at the same time, environmental condition has been seriously deteriorated. . Currently, volume of wastewater has been increasing at annual rate of 7% in sewage and 20% in industrial wastewater. However, the nation's sewage treatment serves only 33% of the municipal wastewater as of 1991. Major portion of air pollutants comes from combustion of oil and coal which comprise 81% of total energy use and emission gases from motor vehicles increasing at an accelerated rate. It is known that Korea generates the highest amount of waste per capta. Nevertheless, it is not sufficient to reduce the volume of waste by means of resources recovery and recycling. Recognizing the importance of global environmental problems such as ozone layer depletion, global warming and acid rain, international society has been making various efforts since the 1972 Stockholm conference. In particular, it is expected that the Rio conference which has adopted the Rio declaration and Agenda 21 will form a crucial turning point of the emerging new world order after the Cold War confrontation. To cope with such issues as domestic pollution and global environmental problems, the fundamental national policy aims at harmonizing "environmental protection and sustainable development". The Ministry of Environment has recently set up a mid-term comprehensive plan which includes annual targets for environmental protection. According to the government plan, gradual improvement of various environmental conditions and specific measures to achieve them is planned in time frame. Additional sewage treatment plants will be constructed in urban areas with the target to treat 65% of the nation's municipal sewage by 1996. Supply of clean fuels such as LNG will also be expanded starting from large cities as a cleaner substitute energy for coal and oil. In parallel with expansion of LNG, emphasis will be placed on installation of stack monitoring system. Due to the relatively limited land, government's basic policy for solid waste treatment is to develop large scale landfill facilities rather than small sized ones. Thirty three regional areas have been designated for the purpose of waste management. For each of these regions, big scale landfill site is going to be developed. To increase the rate of waste recycling the government is planning to reinforce separate collection system and to provide industries with economic incentives. As a part of meeting the changing situation on global environmental problems after UNCED, and accommodation regulatory measures stipulated in the global environmental conventions and protocols, national policy will try to alter industrial and economic structure so as to mitigate the increasing trends of energy consumption, by encouraging energy conservation and efficiency. In this regard, more attention will be given to the policy on the development of the cleaner technology. Ultimately, these policies and programs will contribute greatly to improving the current state of national public health.

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공기조화, 냉동 분야의 최근 연구 동향 -2004년 및 2005년 학회지 논문에 대한 종합적 고찰- (Recent Progress in Air Conditioning and Refrigeration Research - A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2004 and 2005 -)

  • 최영돈;강용태;김내현;김만회;박경근;박병윤;박진철;홍희기
    • 설비공학논문집
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    • 제19권1호
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    • pp.94-131
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    • 2007
  • A review on the papers published in the Korean Journal of Air-Conditioning and Refrigerating Engineering in 2004 and 2005 has been done. Focus has been put on current status of research in the aspect of heating, cooling, air-conditioning, ventilation, sanitation and building environment. The conclusions are as follows. (1) Most of fundamental studies on fluid flow were related with heat transportation of facilities. Drop formation and rivulet flow on solid surfaces were interesting topics related with condensation augmentation. Research on micro environment considering flow, heat, humidity was also interesting for comfortable living environment. It can be extended considering biological aspects. Development of fans and blowers of high performance and low noise were continuing topics. Well developed CFD and flow visualization(PIV, PTV and LDV methods) technologies were widely applied for developing facilities and their systems. (2) The research trends of the previous two yews are surveyed as groups of natural convection, forced convection, electronic cooling, heat transfer enhancement, frosting and defrosting, thermal properties, etc. New research topics introduced include natural convection heat transfer enhancement using nanofluid, supercritical cooling performance or oil miscibility of $CO_2$, enthalpy heat exchanger for heat recovery, heat transfer enhancement in a plate heat exchanger using fluid resonance. (3) The literature for the last two years($2004{\sim}2005$) is reviewed in the areas of heat pump, ice and water storage, cycle analysis and reused energy including geothermal, solar and unused energy). The research on cycle analysis and experiments for $CO_2$ was extensively carried out to replace the Ozone depleting and global warming refrigerants such as HFC and HCFC refrigerants. From the year of 2005, the Gas Engine Heat Pump(GHP) has been paid attention from the viewpoint of the gas cooling application. The heat pipe was focused on the performance improvement by the parametric analysis and the heat recovery applications. The storage systems were studied on the performance enhancement of the storage tank and cost analysis for heating and cooling applications. In the area of unused energy, the hybrid systems were extensively introduced and the life cycle cost analysis(LCCA) for the unused energy systems was also intensively carried out. (4) Recent studies of various refrigeration and air-conditioning systems have focused on the system performance and efficiency enhancement. Heat transfer characteristics during evaporation and condensation are investigated for several tube shapes and of alternative refrigerants including carbon dioxide. Efficiency of various compressors and expansion devices are also dealt with for better modeling and, in particular, performance improvement. Thermoelectric module and cooling systems are analyzed theoretically and experimentally. (5) According to the review of recent studies on ventilation systems, an appropriate ventilation systems including machenical and natural are required to satisfied the level of IAQ. Also, an recent studies on air-conditioning and absorption refrigeration systems, it has mainly focused on distribution and dehumidification of indoor air to improve the performance were carried out. (6) Based on a review of recent studies on indoor environment and building service systems, it is noticed that research issues have mainly focused on optimal thermal comfort, improvement of indoor air Quality and many innovative systems such as air-barrier type perimeter-less system with UFAC, radiant floor heating and cooling system and etc. New approaches are highlighted for improving indoor environmental condition as well as minimizing energy consumption, various activities of building control and operation strategy and energy performance analysis for economic evaluation.

바이오가스 정제 및 고질화 기술 현황 및 전망 (The Present and the Future of Biogas Purification and Upgrading Technologies)

  • 허남효;박재규;김기동;오영삼;조병학
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.172-172
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    • 2011
  • Anaerobic digestion(AD) has successfully been used for many applications that have conclusively demonstrated its ability to recycle biogenic wastes. AD has been successfully applied in industrial waste water treatment, stabilsation of sewage sludge, landfill management and recycling of biowaste and agricultural wastes as manure, energy crops. During AD, i.e. organic materials are decomposed by anaerobic forming bacteria and fina1ly converted to excellent fertilizer and biogas which is primarily composed of methane(CH4) and carbon dioxide(CO2) with smaller amounts of hydrogen sulfide(H2S) and ammonia(NH3), trace gases such as hydrogen(H2), nitrogen(N2), carbon monoxide(CO), oxygen(O2) and contain dust particles and siloxanes. The production and utilisation of biogas has several environmental advantages such as i)a renewable energy source, ii)reduction the release of methane to the atomsphere, iii)use as a substitute for fossil fuels. In utilisation of biogas, most of biogas produced from small scale plant e.g. farm-scale AD plant are used to provide as energy source for cooking and lighting, in most of the industrialised countries for energy recovery, environmental and safety reasons are used in combined heat and power(CHP) engines or as a supplement to natural. In particular, biogas to use as vehicle fuel or for grid injection there different biogas treatment steps are necessary, it is important to have a high energy content in biogas with biogas purification and upgrading. The energy content of biogas is in direct proportion to the methane content and by removing trace gases and carbon dioxide in the purification and upgrading process the energy content of biogas in increased. The process of purification and upgrading biogas generates new possibilities for its use since it can then replace natural gas, which is used extensively in many countries, However, those technologies add to the costs of biogas production. It is important to have an optimized purification and upgrading process in terms of low energy consumption and high efficiency giving high methane content in the upgraded gas. A number of technologies for purification and upgrading of biogas have been developed to use as a vehicle fuel or grid injection during the passed twenty years, and several technologies exist today and they are continually being improved. The biomethane which is produced from the purification and the upgrading process of biogas has gained increased attention due to rising oil and natural gas prices and increasing targets for renewable fuel quotes in many countries. New plants are continually being built and the number of biomethane plants was around 100 in 2009.

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화산회토에서 유기질비료 시용량이 무 생장과 수량 및 양분흡수에 미치는 영향 (Growth, Yield and Nutrient Uptake of Radish as Affected by Amount of Organic Fertilizer in a Volcanic Ash soil)

  • 김유경;조영윤;오한준;강호준;양상호;문봉춘;좌창숙
    • 한국유기농업학회지
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    • 제23권4호
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    • pp.829-846
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    • 2015
  • 본 연구에서는 유기재배시 질소, 인산 및 칼리 비료 시비량에 따른 무의 생육과 수량성, 양분의 흡수량 그리고 투입 양분의 이용율 등을 구명하였다. 처리내용은 무 표준시비량($N-P_2O_5-K_2O$ : 230-70-80)을 기준으로 시비수준을 달리한 T1(무비료), T2 ($N-P_2O_5-K_2O$ : 115-35-40), T3 ($N-P_2O_5-K_2O$ : 230-70-80) 및 T4($N-P_2O_5-K_2O$ : 460-140-160) 처리와, 토양검정에 의한 추천시비량 T5 ($N-P_2O_5-K_2O$ : 230-200-100) 그리고 농가관행 시비량 T6 ($N-P_2O_5-K_2O$ : 158-53-35) 등 6처리를 하였으며 각각의 시비수준에 맞추어 유기질비료의 시비량을 결정하고 부족한 칼리성분은 칼륨비료($K_2O$ 22%)로 보충시비하여 시험을 수행하였다. 무 수량성은 T3 (표준시비량) 및 T5 (토양검정에 의한 추천시비량) 처리구에서 최대수량을 얻었으며 T6 (관행시비량) 처리구 보다 15~23% 증가되었다. 무의 전질소, 인산 및 칼리 흡수량은 시비량이 증가함에 따라 모두 곡선적으로 증가하는 경향을 보였으며 칼리 흡수량이 전질소 및 인산보다 많았다. 그러나 질소 등 투입 양분의 이용율은 시비량이 증가함에 따라 모두 곡선적 또는 직선적으로 감소하였다. 따라서 화산회토에서 무 재배시 유기질비료 시용량은 표준 또는 토양검정시비량을 기준으로 결정하는 것이 보다 안정적인 유기농산물 생산을 위한 적정 시비량으로 판단되었다.