• 제목/요약/키워드: Off-gas

검색결과 894건 처리시간 0.03초

Effects of Ta addition in Co-sputtering Process for Ta-doped Indium Tin Oxide Thin Film Transistors

  • 박시내;손대호;김대환;강진규
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
    • /
    • pp.334-334
    • /
    • 2012
  • Transparent oxide semiconductors have recently attracted much attention as channel layer materials due to advantageous electrical and optical characteristics such as high mobility, high stability, and good transparency. In addition, transparent oxide semiconductor can be fabricated at low temperature with a low production cost and it permits highly uniform devices such as large area displays. A variety of thin film transistors (TFTs) have been studied including ZnO, InZnO, and InGaZnO as the channel layer. Recently, there are many studies for substitution of Ga in InGaZnO TFTs due to their problem, such as stability of devices. In this work, new quaternary compound materials, tantalum-indium-tin oxide (TaInSnO) thin films were fabricated by using co-sputtering and used for the active channel layer in thin film transistors (TFTs). We deposited TaInSnO films in a mixed gas (O2+Ar) atmosphere by co-sputtering from Ta and ITO targets, respectively. The electric characteristics of TaInSnO TFTs and thin films were investigated according to the RF power applied to the $Ta_2O_5$ target. The addition of Ta elements could suppress the formation of oxygen vacancies because of the stronger oxidation tendency of Ta relative to that of In or Sn. Therefore the free carrier density decreased with increasing RF power of $Ta_2O_5$ in TaInSnO thin film. The optimized characteristics of TaInSnO TFT showed an on/off current ratio of $1.4{\times}108$, a threshold voltage of 2.91 V, a field-effect mobility of 2.37 cm2/Vs, and a subthreshold swing of 0.48 V/dec.

  • PDF

우도(牛島) 분화구(噴火口)에서의 일윤회(一輪廻) 화산과정(火山過程) (One-cyclic Volcanic Processes at Udo Crater, Korea)

  • 황상구
    • 자원환경지질
    • /
    • 제26권1호
    • /
    • pp.55-65
    • /
    • 1993
  • Udo Island, some 3 km off the coast of Sungsan Peninsula at the eastern promontory of Cheju Island, occurs in such a regular pattern on the sequences which reprent an excellent example of an eruptive cycle. The island comprises a horseshoe-shaped tuff cone, a nested cinder cone on the crater floor, and a lava delta which extends over northwest from the moat between two cones. The volcanic sequences suggest volcanic processes that start with emergent Surtseyan eruption, progress through Strombolian eruption and end with lava effusion followed by reworking of smooth tephra on the tuff cone. Eruptive environment and hydrology of vent area in the Udo tuff cone are poorly constrained because the stratigraphic units under the tuff cone are unknown. It is thoughl, however, that the tuff cone could be mainly emergent because the present cone deposits show no evidence of marine reworking, and standing body of sea water could play a great role. The emergent volcano is characterized by distinctive steam-explosivity that results primarily from a bulk interaction between rapidly ascending magma and a highly mobile slurry. The sea water gets into the vent by flooding accross or through the top or breach of tephra cone. Udo tuff cone was constructed from Surtseyan eruption which went into with tephra finger jetting activities in the early stage, late interspersed with continuous uprush activities and proceeded to only continuous uprush activities in the last. When the enclosure of the vent by a long-lived tephra barrier would prevent the flooding and thus allow the vent to dry out, the Surtseyan eruption ceased to transmit into Strombolian activities, which constructed a cinder cone on the crater floor of the tuff cone. The Strombolian eruption ceased when magma in the conduit gradually became depleted in gas. In the case of Udo, the last magmatic activity was Hawaiian-type (and/or fountain) which accumulated basalt lava delta. And then the loose tephra of the tuff cone reworked over the moat lava and the northeastern flank.

  • PDF

Residues of Diazinon in Growing Chinese cabbage: A study Under Greenhouse Conditions

  • Khay, Sathya;El-Aty, A.M. Abd;Lim, Kye-Taek;Shim, Jae-Han
    • 한국환경농학회지
    • /
    • 제25권2호
    • /
    • pp.174-179
    • /
    • 2006
  • Chinese cabbage, Braccica campestris has long been consumed as a staple food for Koreans in various forms of fresh, salted, and fermented Kimchi. Cultivation of the crop under greenhouse has become a general practices to fulfill its off-seasonal consumer's demand. However, agricultural practices of the crop have always accompanied with heavy applications of pesticides caused by severe outbreaks of diseases and pose under warm and humid circumferences. Since dissipation patterns of pesticide residues in/on the crop under greenhouse conditions ate quite different from those in the open-air, changes of diazinon, O,O-diethyl O-2-isopropyl-6-methylpyrimidin-4-yl phosphornthioate, in/on the Chinese cabbage applied by foliar spraying under greenhouse were studied. Diazinon 34% EC was applied with dilution of recommended and double dose to the crop. The shoots of crop were harvested immediately after this application and at regular intervals over a 10-day. After sample preparations, the diazinon residue was analyzed using gas chromatography equipped with electron capture detector (GC/ECD). Initially deposited amount of the chemical in/on the crop right after applications with recommended and double doses were 8.3 and 15.2 mg/kg, respectively. The residue levels after 10 days of application were 0.03 and 0.09 mg/kg with 1.3 and 1.5 days of half-life in/on the crop, respectively. In consequent 10 days of pre-harvest interval (PHI) for diazinon EC formulation in/on Chinese cabbage under greenhouse condition was fulfill maximum residue level set by Korea Food and Drug Administration (KFDA, 0.1 mg/kg).

First record of a marine microalgal species, Chlorella gloriosa (Trebouxiophyceae) isolated from the Dokdo Islands, Korea

  • Kang, Nam Seon;Lee, Jung A;Jang, Hyeong Seok;Kim, Kyeong Mi;Kim, Eun Song;Yoon, Moongeun;Hong, Ji Won
    • 환경생물
    • /
    • 제37권4호
    • /
    • pp.526-534
    • /
    • 2019
  • Chlorella gloriosa (Chlorellaceae, Trebouxiophyceae) was isolated from seawater off the coast of the Dokdo Islands in Korea. An axenic culture was established using the streak-plate method on f/2 agar media supplemented with antibiotics, allowing identification of the isolate by morphological, molecular, and physiological analyses. The morphological characteristics observed by light and electron microscopy revealed typical morphologies of C. gloriosa species. The molecular phylogenetic inference drawn from the small-subunit 18S rRNA sequence verified that the microalgal strain belongs to C. gloriosa. Additionally, gas chromatography-mass spectrometry analysis showed that the isolate was rich in nutritionally important omega-3 and -6 polyunsaturated fatty acids and high-performance liquid chromatography analysis revealed that the high-value antioxidants lutein and violaxanthin were biosynthesized as accessory pigments by this microalga, with arabinose, galactose, and glucose as the major monosaccharides. Therefore, in this study, a Korean marine C. gloriosa species was discovered, characterized, and described, and subsequently added to the national culture collection.

로타리 킬른 소각로 고도 설계를 위한 연구 III : 3차원 CC1$_4$/CH$_4$기상난류 반응 모델 (A Study for the Advanced Design of Rotary Kiln Incinerator III : 3-Dimensional CC1$_4$/CH$_4$Gas-phase Turbulent Reaction Model)

  • 엄태인;장동순;채재우
    • 에너지공학
    • /
    • 제2권1호
    • /
    • pp.54-67
    • /
    • 1993
  • CC1$_4$/CH$_4$/공기로 이루어진 예혼합 화염에 대한 2종류의 난류반응 모델을 Dow 케미칼사의 3차원 로타리 킬른 소각로에 적용하여 그 타당성을 확인하였다. 첫번째 난류반응 모델은 반응률이 반응물질의 난류혼합 속도에 지배된다는 fast chemistry 모델(모델 1)이고, 두번째 모델은 비평형 난류반응 모델(모델 2)로서 열량이 낮고 화염 억제 작용이 있는 산업폐기물인, CC1$_4$존재에 따른 반응감속을 연소속도 자료에 의해 고려한 모델이다. 수치해석의 결과에 의하면 CC1$_4$의 화염억제 작용을 적절히 고려한 두번째 비평형 난류반응 모델은 Dow 케미칼사 로타리 킬른의 출구에서 실험적으로 나타나는 농도 성층화 현상을 정성적으로 규명할 수 있었으며, CC1$_4$/CH$_4$몰비 변화에 따른 연소반응 지연 양상도 확인할 수 있었다. 기타 두 모델에 대한 비교 및 유동의 결과를 자세히 제시하였다.

  • PDF

후드겸용 전자레인지 시로코홴의 유동 및 소음특성에 관한 연구 (A study on the flow and aeroacoustic characteristics of the sirocco fan of OTR (Over The Range))

  • 전완호;류호선;송성배;손상범
    • 한국유체기계학회 논문집
    • /
    • 제7권1호
    • /
    • pp.17-23
    • /
    • 2004
  • Aeroacoustic characteristics of sirocco fan used in Over-The-Range (OTR) has been analyzed in this paper. A microwave hood combination over the gas range is short for the OTR. The flow phenomena of the double-sided sirocco fan was analyzed numerically and experimentally by using commercial code and three dimensional PIV for flow visualization. Also, microphone array is used in order to understand acoustic characteristics of OTR. Two dimensional unsteady flow and acoustic simulation is tried to qualitatively estimate the effects of tonal noise and broadband noise on the overall sound pressure level. It is found that tonal sound is generated from the strong interaction between the impeller and cutoff while broadband sound is generated from the strong secondary flows along the scroll surface. To reduce the noise level, the V-shape cut-off was applied to improve the sound quality by reducing tonal noise. So the peak noise at BPF (Blade Passing Frequency) was almost reduced. The shape of flow-guide to suppress the secondary flow over the scroll surface was carefully checked. It is found that this affects flow pattern at the fan exit and reduces the broad band noise. Through this numerical and experimental study, the sound pressure level was lowered by 4dBA compared to that of the previous fan at the operating point.

흑연 씰의 비마모율 예측에 관한 수학적 모델 개발 (Development of Mathematical Model to Predict Specific Wear Rates of Graphite Seal)

  • 김연욱;김재훈;박성한;이환규;김범근;이성범;곽재수
    • 한국추진공학회지
    • /
    • 제18권4호
    • /
    • pp.67-73
    • /
    • 2014
  • 고온고압의 밸브에서 연소가스의 유입을 방지하는 흑연 씰은 밸브 축의 구동으로 인한 마찰 및 마모에 노출된다. 흑연 씰의 마모로 인해 고온 가스 제어가 불가능해지기 때문에 씰의 마모 특성을 예측하는 것은 매우 중요하다. 본 논문은 비마모율을 마모 특성에 대한 척도로 설정하고 접촉하중, 미끄럼 속도, 온도 등을 변수로 하여 흑연의 왕복동 마모 시험을 수행하였다. 반응표면분석법에 근거하여 실험계획을 정립하고 시험 결과에 대하여 분산분석법을 통하여 유효한 수학적 모델을 제시하였다. 또한, 마모된 표면의 SEM 분석을 통해 특정 조건에서의 마모 메커니즘을 분석하고 비교하였다.

Etch Characteristics of $SiO_2$ by using Pulse-Time Modulation in the Dual-Frequency Capacitive Coupled Plasma

  • 전민환;강세구;박종윤;염근영
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
    • /
    • pp.472-472
    • /
    • 2011
  • The capacitive coupled plasma (CCP) has been extensively used in the semiconductor industry because it has not only good uniformity, but also low electron temperature. But CCP source has some problems, such as difficulty in varying the ion bombardment energy separately, low plasma density, and high processing pressure, etc. In this reason, dual frequency CCP has been investigated with a separate substrate biasing to control the plasma parameters and to obtain high etch rate with high etch selectivity. Especially, in this study, we studied on the etching of $SiO_2$ by using the pulse-time modulation in the dual-frequency CCP source composed of 60 MHz/ 2 MHz rf power. By using the combination of high /low rf powers, the differences in the gas dissociation, plasma density, and etch characteristics were investigated. Also, as the size of the semiconductor device is decreased to nano-scale, the etching of contact hole which has nano-scale higher aspect ratio is required. For the nano-scale contact hole etching by using continuous plasma, several etch problems such as bowing, sidewall taper, twist, mask faceting, erosion, distortions etc. occurs. To resolve these problems, etching in low process pressure, more sidewall passivation by using fluorocarbon-based plasma with high carbon ratio, low temperature processing, charge effect breaking, power modulation are needed. Therefore, in this study, to resolve these problems, we used the pulse-time modulated dual-frequency CCP system. Pulse plasma is generated by periodical turning the RF power On and Off state. We measured the etch rate, etch selectivity and etch profile by using a step profilometer and SEM. Also the X-ray photoelectron spectroscopic analysis on the surfaces etched by different duty ratio conditions correlate with the results above.

  • PDF

TMCP강을 적용한 해상용 풍력타워의 용접 공정에 따른 기계적 물성 평가 (Evaluation on Mechanical Properties with Welding Processes for Off Shore Wind Tower Application)

  • 지창욱;최철영;남대근;김형찬;장재호;김기혁;박영도
    • Journal of Welding and Joining
    • /
    • 제32권1호
    • /
    • pp.15-21
    • /
    • 2014
  • FCAW(Flux Cored Arc Welding), SAW(Submerged Arc Welding), EGW(Electro Gas Welding), and three-pole SAW are applicable in manufacturing the offshore wind tower. In this paper, mechanical properties of these welded-joints for TMCP steels were evaluated in all above welding processes. The tensile strength of welded-joints for all the welding methods satisfied the standard guideline (KS D 3515). No cracking on weldment was found after the bending test. Changes of weldedments hardness with welding processes were observed. In a weld HAZ (heat-affected zone), a softened HAZ-zone was formed with high heat input welding processes (SAW and EGW). However, the welded-joint fractures were found in the base metal for all cases and small decrease in welded-joint strength was caused by a softened zone. The multi-pole SAW welds exhibited similar mechanical properties comparing to the one with one-pole SAW process.

Evaluating the Headspace Volatolome, Primary Metabolites, and Aroma Characteristics of Koji Fermented with Bacillus amyloliquefaciens and Aspergillus oryzae

  • Seo, Han Sol;Lee, Sunmin;Singh, Digar;Park, Min Kyung;Kim, Young-Suk;Shin, Hye Won;Cho, Sun A;Lee, Choong Hwan
    • Journal of Microbiology and Biotechnology
    • /
    • 제28권8호
    • /
    • pp.1260-1269
    • /
    • 2018
  • Production of good Koji primarily depends upon the selection of substrate materials and fermentative microflora, which together influence the characteristic flavor and aroma. Herein, we performed comparative metabolomic analyses of volatile organic compounds (VOCs) and primary metabolites for Koji samples fermented individually with Bacillus amyloliquefaciens and Aspergillus oryzae. The VOCs and primary metabolites were analyzed using headspace solid phase microextraction (HS-SPME) followed by gas chromatography time-of-flight mass spectrometry (GC-TOF-MS). In particular, alcohols, ketones, and furans were mainly detected in Bacillus-fermented Koji (Bacillus Koji, BK), potentially due to the increased levels of lipid oxidation. A cheesy and rancid flavor was characteristic of Bacillus Koji, which is attributable to high content of typical 'off-flavor' compounds. Furthermore, the umami taste engendered by 2-methoxyphenol, (E,E)-2,4-decadienal, and glutamic acid was primarily detected in Bacillus Koji. Alternatively, malty flavor compounds (2-methylpropanal, 2-methylbutanal, 3-methylbutanal) and sweet flavor compounds (monosaccharides and maltol) were relatively abundant in Aspergillus-fermented Koji (Aspergillus Koji, AK). Hence, we argue that the VOC profile of Koji is largely determined by the rational choice of inocula, which modifies the primary metabolomes in Koji substrates, potentially shaping its volatolome as well as the aroma characteristics.