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Effects of Ta addition in Co-sputtering Process for Ta-doped Indium Tin Oxide Thin Film Transistors

  • Park, Si-Nae;Son, Dae-Ho;Kim, Dae-Hwan;Gang, Jin-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.334-334
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    • 2012
  • Transparent oxide semiconductors have recently attracted much attention as channel layer materials due to advantageous electrical and optical characteristics such as high mobility, high stability, and good transparency. In addition, transparent oxide semiconductor can be fabricated at low temperature with a low production cost and it permits highly uniform devices such as large area displays. A variety of thin film transistors (TFTs) have been studied including ZnO, InZnO, and InGaZnO as the channel layer. Recently, there are many studies for substitution of Ga in InGaZnO TFTs due to their problem, such as stability of devices. In this work, new quaternary compound materials, tantalum-indium-tin oxide (TaInSnO) thin films were fabricated by using co-sputtering and used for the active channel layer in thin film transistors (TFTs). We deposited TaInSnO films in a mixed gas (O2+Ar) atmosphere by co-sputtering from Ta and ITO targets, respectively. The electric characteristics of TaInSnO TFTs and thin films were investigated according to the RF power applied to the $Ta_2O_5$ target. The addition of Ta elements could suppress the formation of oxygen vacancies because of the stronger oxidation tendency of Ta relative to that of In or Sn. Therefore the free carrier density decreased with increasing RF power of $Ta_2O_5$ in TaInSnO thin film. The optimized characteristics of TaInSnO TFT showed an on/off current ratio of $1.4{\times}108$, a threshold voltage of 2.91 V, a field-effect mobility of 2.37 cm2/Vs, and a subthreshold swing of 0.48 V/dec.

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One-cyclic Volcanic Processes at Udo Crater, Korea (우도(牛島) 분화구(噴火口)에서의 일윤회(一輪廻) 화산과정(火山過程))

  • Hwang, Sang Koo
    • Economic and Environmental Geology
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    • v.26 no.1
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    • pp.55-65
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    • 1993
  • Udo Island, some 3 km off the coast of Sungsan Peninsula at the eastern promontory of Cheju Island, occurs in such a regular pattern on the sequences which reprent an excellent example of an eruptive cycle. The island comprises a horseshoe-shaped tuff cone, a nested cinder cone on the crater floor, and a lava delta which extends over northwest from the moat between two cones. The volcanic sequences suggest volcanic processes that start with emergent Surtseyan eruption, progress through Strombolian eruption and end with lava effusion followed by reworking of smooth tephra on the tuff cone. Eruptive environment and hydrology of vent area in the Udo tuff cone are poorly constrained because the stratigraphic units under the tuff cone are unknown. It is thoughl, however, that the tuff cone could be mainly emergent because the present cone deposits show no evidence of marine reworking, and standing body of sea water could play a great role. The emergent volcano is characterized by distinctive steam-explosivity that results primarily from a bulk interaction between rapidly ascending magma and a highly mobile slurry. The sea water gets into the vent by flooding accross or through the top or breach of tephra cone. Udo tuff cone was constructed from Surtseyan eruption which went into with tephra finger jetting activities in the early stage, late interspersed with continuous uprush activities and proceeded to only continuous uprush activities in the last. When the enclosure of the vent by a long-lived tephra barrier would prevent the flooding and thus allow the vent to dry out, the Surtseyan eruption ceased to transmit into Strombolian activities, which constructed a cinder cone on the crater floor of the tuff cone. The Strombolian eruption ceased when magma in the conduit gradually became depleted in gas. In the case of Udo, the last magmatic activity was Hawaiian-type (and/or fountain) which accumulated basalt lava delta. And then the loose tephra of the tuff cone reworked over the moat lava and the northeastern flank.

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Residues of Diazinon in Growing Chinese cabbage: A study Under Greenhouse Conditions

  • Khay, Sathya;El-Aty, A.M. Abd;Lim, Kye-Taek;Shim, Jae-Han
    • Korean Journal of Environmental Agriculture
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    • v.25 no.2
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    • pp.174-179
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    • 2006
  • Chinese cabbage, Braccica campestris has long been consumed as a staple food for Koreans in various forms of fresh, salted, and fermented Kimchi. Cultivation of the crop under greenhouse has become a general practices to fulfill its off-seasonal consumer's demand. However, agricultural practices of the crop have always accompanied with heavy applications of pesticides caused by severe outbreaks of diseases and pose under warm and humid circumferences. Since dissipation patterns of pesticide residues in/on the crop under greenhouse conditions ate quite different from those in the open-air, changes of diazinon, O,O-diethyl O-2-isopropyl-6-methylpyrimidin-4-yl phosphornthioate, in/on the Chinese cabbage applied by foliar spraying under greenhouse were studied. Diazinon 34% EC was applied with dilution of recommended and double dose to the crop. The shoots of crop were harvested immediately after this application and at regular intervals over a 10-day. After sample preparations, the diazinon residue was analyzed using gas chromatography equipped with electron capture detector (GC/ECD). Initially deposited amount of the chemical in/on the crop right after applications with recommended and double doses were 8.3 and 15.2 mg/kg, respectively. The residue levels after 10 days of application were 0.03 and 0.09 mg/kg with 1.3 and 1.5 days of half-life in/on the crop, respectively. In consequent 10 days of pre-harvest interval (PHI) for diazinon EC formulation in/on Chinese cabbage under greenhouse condition was fulfill maximum residue level set by Korea Food and Drug Administration (KFDA, 0.1 mg/kg).

First record of a marine microalgal species, Chlorella gloriosa (Trebouxiophyceae) isolated from the Dokdo Islands, Korea

  • Kang, Nam Seon;Lee, Jung A;Jang, Hyeong Seok;Kim, Kyeong Mi;Kim, Eun Song;Yoon, Moongeun;Hong, Ji Won
    • Korean Journal of Environmental Biology
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    • v.37 no.4
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    • pp.526-534
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    • 2019
  • Chlorella gloriosa (Chlorellaceae, Trebouxiophyceae) was isolated from seawater off the coast of the Dokdo Islands in Korea. An axenic culture was established using the streak-plate method on f/2 agar media supplemented with antibiotics, allowing identification of the isolate by morphological, molecular, and physiological analyses. The morphological characteristics observed by light and electron microscopy revealed typical morphologies of C. gloriosa species. The molecular phylogenetic inference drawn from the small-subunit 18S rRNA sequence verified that the microalgal strain belongs to C. gloriosa. Additionally, gas chromatography-mass spectrometry analysis showed that the isolate was rich in nutritionally important omega-3 and -6 polyunsaturated fatty acids and high-performance liquid chromatography analysis revealed that the high-value antioxidants lutein and violaxanthin were biosynthesized as accessory pigments by this microalga, with arabinose, galactose, and glucose as the major monosaccharides. Therefore, in this study, a Korean marine C. gloriosa species was discovered, characterized, and described, and subsequently added to the national culture collection.

A Study for the Advanced Design of Rotary Kiln Incinerator III : 3-Dimensional CC1$_4$/CH$_4$Gas-phase Turbulent Reaction Model (로타리 킬른 소각로 고도 설계를 위한 연구 III : 3차원 CC1$_4$/CH$_4$기상난류 반응 모델)

  • 엄태인;장동순;채재우
    • Journal of Energy Engineering
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    • v.2 no.1
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    • pp.54-67
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    • 1993
  • Two turbulent reaction models of the premixed CC1$_4$/CH$_4$/air mixture are successfully incorporated in a 3-dimensional computer program and is applied for Dow Chemical incinerator equipped with two main off-center burners. The first reaction model is fast chemistry model(model 1), in which chemical reaction is governed by the turbulent mixing itself. And the second one is nonequilibrium model(model 2), where the effect of the chemical kinetics due to the presence of CC1$_4$is considered by the incorporation of the burning velocity data of CC1$_4$. The second model not only shows the flame inhibition trend due to the presence CC1$_4$compound, but also predicts qualitatively the vortical stratification of the CC1$_4$concentration appeared experimentally at the kiln exit. Other comparisions of two models are made in detail.

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A study on the flow and aeroacoustic characteristics of the sirocco fan of OTR (Over The Range) (후드겸용 전자레인지 시로코홴의 유동 및 소음특성에 관한 연구)

  • Jeon, Wan-Ho;Rew, Ho Seon;Song, Sung-Bae;Shon, Sang-Bun
    • The KSFM Journal of Fluid Machinery
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    • v.7 no.1 s.22
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    • pp.17-23
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    • 2004
  • Aeroacoustic characteristics of sirocco fan used in Over-The-Range (OTR) has been analyzed in this paper. A microwave hood combination over the gas range is short for the OTR. The flow phenomena of the double-sided sirocco fan was analyzed numerically and experimentally by using commercial code and three dimensional PIV for flow visualization. Also, microphone array is used in order to understand acoustic characteristics of OTR. Two dimensional unsteady flow and acoustic simulation is tried to qualitatively estimate the effects of tonal noise and broadband noise on the overall sound pressure level. It is found that tonal sound is generated from the strong interaction between the impeller and cutoff while broadband sound is generated from the strong secondary flows along the scroll surface. To reduce the noise level, the V-shape cut-off was applied to improve the sound quality by reducing tonal noise. So the peak noise at BPF (Blade Passing Frequency) was almost reduced. The shape of flow-guide to suppress the secondary flow over the scroll surface was carefully checked. It is found that this affects flow pattern at the fan exit and reduces the broad band noise. Through this numerical and experimental study, the sound pressure level was lowered by 4dBA compared to that of the previous fan at the operating point.

Development of Mathematical Model to Predict Specific Wear Rates of Graphite Seal (흑연 씰의 비마모율 예측에 관한 수학적 모델 개발)

  • Kim, Yeonwook;Kim, Jaehoon;Park, Sunghan;Lee, Hwangyu;Kim, Beomkeun;Lee, Seongbeom;Kwak, Jae Su
    • Journal of the Korean Society of Propulsion Engineers
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    • v.18 no.4
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    • pp.67-73
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    • 2014
  • The dry sliding wear behavior of graphite that is used as the sealing material to cut off hot gas was evaluated as a function of applied load, sliding speed and temperature. The reciprocating wear tests were carried out at room temperature and elevated temperatures. An attempt has been made to develop a mathematical model by response surface methodology and an analysis of variance technique was applied to confirm the validity of the developed model. Also, the wear mechanism was compared through the observation of the worn surface by SEM analysis.

Etch Characteristics of $SiO_2$ by using Pulse-Time Modulation in the Dual-Frequency Capacitive Coupled Plasma

  • Jeon, Min-Hwan;Gang, Se-Gu;Park, Jong-Yun;Yeom, Geun-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.472-472
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    • 2011
  • The capacitive coupled plasma (CCP) has been extensively used in the semiconductor industry because it has not only good uniformity, but also low electron temperature. But CCP source has some problems, such as difficulty in varying the ion bombardment energy separately, low plasma density, and high processing pressure, etc. In this reason, dual frequency CCP has been investigated with a separate substrate biasing to control the plasma parameters and to obtain high etch rate with high etch selectivity. Especially, in this study, we studied on the etching of $SiO_2$ by using the pulse-time modulation in the dual-frequency CCP source composed of 60 MHz/ 2 MHz rf power. By using the combination of high /low rf powers, the differences in the gas dissociation, plasma density, and etch characteristics were investigated. Also, as the size of the semiconductor device is decreased to nano-scale, the etching of contact hole which has nano-scale higher aspect ratio is required. For the nano-scale contact hole etching by using continuous plasma, several etch problems such as bowing, sidewall taper, twist, mask faceting, erosion, distortions etc. occurs. To resolve these problems, etching in low process pressure, more sidewall passivation by using fluorocarbon-based plasma with high carbon ratio, low temperature processing, charge effect breaking, power modulation are needed. Therefore, in this study, to resolve these problems, we used the pulse-time modulated dual-frequency CCP system. Pulse plasma is generated by periodical turning the RF power On and Off state. We measured the etch rate, etch selectivity and etch profile by using a step profilometer and SEM. Also the X-ray photoelectron spectroscopic analysis on the surfaces etched by different duty ratio conditions correlate with the results above.

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Evaluation on Mechanical Properties with Welding Processes for Off Shore Wind Tower Application (TMCP강을 적용한 해상용 풍력타워의 용접 공정에 따른 기계적 물성 평가)

  • Ji, Changwook;Choi, Chul Young;Nam, Dae-Geun;Kim, Hyoung Chan;Jang, Jae Ho;Kim, Ki Hyuk;Park, Yeong-Do
    • Journal of Welding and Joining
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    • v.32 no.1
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    • pp.15-21
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    • 2014
  • FCAW(Flux Cored Arc Welding), SAW(Submerged Arc Welding), EGW(Electro Gas Welding), and three-pole SAW are applicable in manufacturing the offshore wind tower. In this paper, mechanical properties of these welded-joints for TMCP steels were evaluated in all above welding processes. The tensile strength of welded-joints for all the welding methods satisfied the standard guideline (KS D 3515). No cracking on weldment was found after the bending test. Changes of weldedments hardness with welding processes were observed. In a weld HAZ (heat-affected zone), a softened HAZ-zone was formed with high heat input welding processes (SAW and EGW). However, the welded-joint fractures were found in the base metal for all cases and small decrease in welded-joint strength was caused by a softened zone. The multi-pole SAW welds exhibited similar mechanical properties comparing to the one with one-pole SAW process.

Evaluating the Headspace Volatolome, Primary Metabolites, and Aroma Characteristics of Koji Fermented with Bacillus amyloliquefaciens and Aspergillus oryzae

  • Seo, Han Sol;Lee, Sunmin;Singh, Digar;Park, Min Kyung;Kim, Young-Suk;Shin, Hye Won;Cho, Sun A;Lee, Choong Hwan
    • Journal of Microbiology and Biotechnology
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    • v.28 no.8
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    • pp.1260-1269
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    • 2018
  • Production of good Koji primarily depends upon the selection of substrate materials and fermentative microflora, which together influence the characteristic flavor and aroma. Herein, we performed comparative metabolomic analyses of volatile organic compounds (VOCs) and primary metabolites for Koji samples fermented individually with Bacillus amyloliquefaciens and Aspergillus oryzae. The VOCs and primary metabolites were analyzed using headspace solid phase microextraction (HS-SPME) followed by gas chromatography time-of-flight mass spectrometry (GC-TOF-MS). In particular, alcohols, ketones, and furans were mainly detected in Bacillus-fermented Koji (Bacillus Koji, BK), potentially due to the increased levels of lipid oxidation. A cheesy and rancid flavor was characteristic of Bacillus Koji, which is attributable to high content of typical 'off-flavor' compounds. Furthermore, the umami taste engendered by 2-methoxyphenol, (E,E)-2,4-decadienal, and glutamic acid was primarily detected in Bacillus Koji. Alternatively, malty flavor compounds (2-methylpropanal, 2-methylbutanal, 3-methylbutanal) and sweet flavor compounds (monosaccharides and maltol) were relatively abundant in Aspergillus-fermented Koji (Aspergillus Koji, AK). Hence, we argue that the VOC profile of Koji is largely determined by the rational choice of inocula, which modifies the primary metabolomes in Koji substrates, potentially shaping its volatolome as well as the aroma characteristics.