• Title/Summary/Keyword: Off-cycle

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Effect of ON/OFF Cycles of Ar Gas on Structural and Optical Properties of ZnO Nanostructure Grown by Vapor Phase Transport

  • Nam, Gi-Woong;Kim, Min-Su;Cho, Min-Young;Kim, So-A-Ram;Leem, Jae-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.415-415
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    • 2012
  • ZnO nanostructures were synthesized by a vapor phase transport process in a single-zone furnace within a horizontal quartz tube with an inner diameter of 38 mm and a length of 485 mm. The ZnO nanostructures were grown on Au-catalyzed Si(100) substrates by using a mixture of zinc oxide and graphite powders. The growth of ZnO nanostructures was conducted at $800^{\circ}C$ for 30 min. High-purity Ar and $O_2$ gases were pushed through the quartz tube during the process at a flow rate of 100 and 10 sccm, respectively. The sequence of ON/OFF cycles of the Ar gas flow was repeated, while the $O_2$ flow is kept constant during the growth time. The Ar gas flow was ON for 1 min/cycle and that was OFF for 2 min/cycle. The structure and optical properties of the ZnO nanostructures were investigated by field-emission scanning electron microscope, X-ray diffraction, temperature-dependent photoluminescence. The preferred orientation of the ZnO nanostructures was along c-axis with hexagonal wurtzite structure.

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Performance Evaluation of the Gas Turbine for Integrated Ossification Combined Cycle (석탄가스화 복합발전용 가스터빈의 성능 평가)

  • Lee, Chan;Lee, Jin-Wook;Yun, Yong-Seung
    • The KSFM Journal of Fluid Machinery
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    • v.2 no.1 s.2
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    • pp.7-14
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    • 1999
  • This simulation method is developed by using GateCycle code for the performance evaluation of the gas turbine in IGCC(Integrated Gasification Combined Cycle) power plant that uses clean coal gas fuel derived from coal gasification and gas clean-up processes and it is integrated with ASU(Air Separation Unit). In the present simulation method, thermodynamic calculation procedure is incorporated with compressor performance map and expander choking models for considering the off-design effects due to coal gas firing and ASU integration. With the clean coal gases produced through commercially available chemical processes, their compatibility as IGCC gas turbine fuel is investigated in the aspects the overall performance of the gas turbine system. The predictions by the present method show that the reduction of the air extraction from gas turbine to ASU results in a remarkable increase in the efficiency and net power of gas turbines, but it is accompanied with a shift of compressor operation point toward to surge limit. In addition, the present analysis results reveal the influence of compressor performance characteristics of gas turbine have to be carefully examined in designing the ASU integration process and evaluating the overall performance parameters of the gas turbine in IGCC Power plant.

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High Purity Hydrogen Production by Redox Cycle Operation (산화-환원 싸이클 조업에 의한 고순도 수소생성)

  • Jeon, Bup-Ju;Park, Ji-Hun
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.5
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    • pp.355-363
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    • 2010
  • High purity hydrogen, 97-99 vol.%, with CO at just ppm levels was obtained in a fixed bed of iron oxide employing the steam-iron cycle operation with reduction at 823K and oxidation in a steam-$N_2$ mixture at 773K TGA experiments indicated that temperature of the reduction step as well as its duration are important for preventing carbon build-up in iron and the intrusion of $CO_2$ into the hydrogen product. At a reduction temperature of 823K, oxide reduction by $H_2$ was considerably faster than reduction by CO. If the length of the reduction step exceeds optimal value, low levels of methane gas appeared in the off-gas. Furthermore, with longer durations of the reduction step and CO levels in the reducing gas greater than 10 vol.%, carbidization of the iron and/or carbon deposition in the bed exhibited the increasing pressure drop over the bed, eventually rendering the reactor inoperable. Reduction using a reducing gas containing 10 vol.% CO and a optimal reduction duration gave constant $H_2$ flow rates and off-gas composition over 10 redox reaction cycles.

Evaluations for Representativeness of Light-Duty Diesel Vehicles' Fuel-based Emission Factors on Vehicle Operating Conditions (연료 소비량에 기반한 소형 경유차 대기오염물질 배출계수의 운전조건별 대표성 평가)

  • Lee, Taewoo;Kwon, Sangil;Son, Jihwan;Kim, Jiyoung;Jeon, Sangzin;Kim, Jeongsoo;Choi, Kwangho
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.6
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    • pp.745-756
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    • 2013
  • The purpose of this study is to evaluate representativeness of fuel-based emission factors. Twelve light-duty diesel vehicles which meet Euro-3 to 5 legislative emission limits were selected for emission tests. Second-by-second modal emission rates of vehicles were measured on a standard laboratory chassis dynamometer system. An off-cycle driving cycle was developed as a representative Korean real-world on-road driving cycle. Fuel-based emission factors were developed for short trip segments that involved in the selected driving cycle. Each segment was defined to have unit travel distance, which is 1 km, and characterized by its average speed and Relative Positive Acceleration (RPA). Fuel-based $NO_x$ emission factors demonstrate relatively good representativeness in terms of vehicle operation conditions. $NO_x$ emission factors are estimated to be within ${\pm}20%$ of area-wide emission factor under more than 40% of total driving situations. This result implies that the fuel-based $NO_x$ emission factor could be practically implemented into the on-road emission management strategies, such as a remote sensing device (RSD). High emitting vehicles as well as high emitting operating conditions heavily affect on the mean values and distributions of CO and THC emission factors. Few high emitting conditions are pulling up the mean value and biasing the distributions, which weaken representativeness of fuel-based CO and THC emission factors.

A Study on the Calculation Method of the Elastomeric Bearing Life Cycle Inventory (LCI) Database to Improve Reliability of Evaluation of Environmental Load of Bridges (교량의 환경부하평가 신뢰성 향상을 위한 교량용 탄성받침 전과정목록 산정방법에 관한 연구)

  • Wie, Deahyung;Kim, Youngchun;Kwak, Inho;Hwang, Yongwoo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.37 no.4
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    • pp.681-691
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    • 2017
  • In this research, life cycle inventory database (LCI DB) was developed for elastomeric bearing employing life cycle assessment (LCA) methodology additionally the reliability improvement rate in the evaluation of the environmental load of the bridge was analyzed. As are result of impact assessment by 6 major impact categories, production of elastomeric bearing puts on environmental impact in the order of resource depletion, global warming, photochemical oxidant creation. and among a wide variety of input, steel plates contributes in most of the impact categories. As a result of applying the elastomeric bearing LCI database constructed in this study, the environmental loads increased by 0.53% on average, and the cut-off based on the cost of input materials increased by 11.36%. It is anticipated that it will be possible to improve the credibility and to provide data based on current production technology, such as estimating GHG emissions and evaluating environmental load, by constructing elastomeric bearing LCI DB.

Materials Properties of Nickel Electrodeposits as a Function of the Current Density, Duty Cycle, Temperature and pH

  • Kim, Dong-Jin;Kim, Myung Jin;Kim, Joung Soo;Kim, Hong Pyo
    • Corrosion Science and Technology
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    • v.5 no.5
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    • pp.168-172
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    • 2006
  • Alloy 600 having a superior resistance to a corrosion is used as a steam generator tubing in nuclear power plants. In spite of its high corrosion resistance, there are many tubings which experience corrosion problems such as a SCC under the high temperature and high pressure environments of nuclear power plants. The Alloy 600 tubing can be repaired by using a Ni electroplating having an excellent SCC resistance. In order to carry out a successful Ni electrodeposition inside a steam generator tubing, the effects of various parameters on the material properties of the electrodeposit should be elucidated. Hence this work deals with the effects of an applied current density, duty cycle($T_{on}/(T_{on}+T_{off})$) of a pulse current, bath temperature and solution pH on the material properties of Ni electrodeposit obtained from a Ni sulphamate bath by analyzing the current efficiency, potentiodynamic curve, hardness and stress-strain curve. Hardness, YS(yield strength) and TS(tensile strength) decreased whereas the elongation increased as the applied current density increased. This was thought to be by a concentration depletion at the interface of the electrodeposit/solution, and a fractional decrease of the hydrogen reduction reaction. As the duty cycle increased, the hardness, YS and TS decreased while the elongation increased. During an off time at a high duty cycle, the concentration depletion could not be recovered sufficiently enough to induce a coarse grain sized electrodeposit. With an increase of the solution temperature and pH, the YS and TS increased while the elongation decreased. The experimental results of the hardness and the stress-strain curves can be supplemented by the results of the potentiodynamic curve.

Analyse of Trade-off for Implementing RFID Tag to Enhance Security (보안성 향상을 위한 RFID 태그 구현시의 Trade off 분석)

  • Kim, Jung-Tae
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2011.05a
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    • pp.754-756
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    • 2011
  • Most of the sources of security and privacy issues in RFID technology arise from the violation of the air interface between a tag and its reader. This paper will approach the security risk analysis is process from the perspective of the RFID tag life cycle, identify the tag usage processes, identify the associated vulnerability and threat to the confidentiality, integrity and availability of the information assets and its implications for privacy, and then mitigate the risks.

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Performance Characteristics for Off-design Operation of Micro Gas Turbines (마이크로 가스터빈의 탈설계 운전 성능특성)

  • Kim, T.S.;Hwang, S.H.
    • The KSFM Journal of Fluid Machinery
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    • v.7 no.3 s.24
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    • pp.39-47
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    • 2004
  • Micro gas turbines are designed with low turbine inlet temperature and pressure ratio. To overcome the efficiency defect of the simple cycle, adoption of the recuperator is an inevitable choice. In addition to the design performance, we should also pay attention to the off-design performance of gas turbines since they usually operate at part-load conditions lot a considerable amount of their lifetime. This study analyzes off-design performance characteristics of micro gas turbines and addresses the importance of the recuperation process doting the part load operation. Comparative analyses have been performed to evaluate the part load performance differences among various design and operating options : simple vs recuperative cycles, single vs two shaft configurations, various operating strategies for the single shaft configuration, and current vs advanced engines. Major finding is that maintaining high turbine exhaust temperature is crucial for efficient operation of micro gas turbines.

Inrush Current Elimination for a Three-Phase Off-Line UPS System (3상 오프라인 무정전 전원 시스템의 돌입전류 제거)

  • Bukhari, Syed Sabir Hussain;Kwon, Byung-il
    • Proceedings of the KIEE Conference
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    • 2015.07a
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    • pp.944-945
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    • 2015
  • Many sensitive loads always rely on UPS systems to maintain continuous power during abnormal utility power conditions. As any disturbance occurs at the utility side, an off-line UPS system takes over the load within a quarter cycle to avoid a blackout. However, the starting of the inverter can root the momentous inrush current for the transformer installed before the load, due to its magnetic saturation. The consequences of this current can be a reduction of line voltage and tripping of protective devices of the UPS system. Furthermore, it can also damage the transformer and decrease its lifetime by increasing the mechanical stresses on its windings. To prevent the inrush current, and to avoid its disruptive effects, this paper proposes an off-line UPS system that eliminates the inrush current phenomenon while powering the transformer coupled loads, using a current regulated voltage source inverter (CRVSI) instead of a typical voltage source inverter (VSI). Simulations have been performed to validate the operation of proposed off-line UPS system.

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Performance Characteristics for Off-design Operation of Micro Gas Turbines (마이크로 가스터빈의 탈설계 운전 성능특성)

  • Hwang, S.H.;Kim, T.S.
    • 유체기계공업학회:학술대회논문집
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    • 2003.12a
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    • pp.80-87
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    • 2003
  • Micro gas turbines are designed with low turbine inlet temperature and pressure ratio. To overcome the efficiency defect of the simple cycle, adoption of the recuperator is an inevitable choice. In addition to the design performance, we should also pay attention to the off-design performance of gas turbines since they usually operate at part-load conditions for a considerable amount of the time. This study aims at analyzing off-design performance characteristics of micro gas turbines and addressing the importance of the recuperator in the part load operation. Comparative analyses have been performed to evaluate the part load performance differences among various design and operating options : simple vs recuperative cycles, single vs two shaft configurations, various operating strategies for the single shaft configuration (fuel only control, variable speed operation, variable inlet guide vane control), and current vs advanced engines. Major finding is that maintaining turbine at high level is crucial in efficient operation of micro gas turbines.

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