• 제목/요약/키워드: Odor compounds

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가지제(加脂劑) 생산공정에서 배출되는 악취원인물질 연구 (The Study of Odor-causing Compounds Emitted from a Stuffing Agent Production Process)

  • 서용수;서정민
    • 한국환경과학회지
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    • 제27권9호
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    • pp.781-788
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    • 2018
  • The volatile odor compounds emitted form a stuffing agent production process were quantified by ATD and GC-MS, and then odor causing compounds were identified by the method of EOI using each TLV. As the results, 72 odor compounds were detected and total concentration was turned up 87.6 ppmv level. In these compounds, aldehyde group is higher 45.49 ppmv than others group, the next is turn up the order of aliphatics, alcohols, esters, ketones. The EOA of aldehyde group show up 101,720 and 97.2%, respectively, the odor causing compounds were identified each of odor 2-Octenal 28.31%, Hexanal 24.06%, Valeraldehyde 16.07%, Butyraldehyde 9.69%, Heptanal 4.97%, Propionaldehyde 4.64%, Acetaldehyde 3.31%. The TLVs of 7 major odor compounds are lower value level of 0.001~0.0001 ppmv, odor causing even in trace level. We need to be concerned with reduction of aldehyde compounds in the odor problem by a stuffing agent production process or ironing process of the textile containing a stuffing agent.

제조방법과 숙성기간에 따른 된장의 향기특성 변화 (Changes in Odor Characteristics of Doenjang with Different Preparing Methods and Ripening Periods)

  • 최미경;손경희;전형주
    • 한국식생활문화학회지
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    • 제12권3호
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    • pp.265-274
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    • 1997
  • This study was conducted in ordor to find the most suitable conditions for producing the Doenjang with optimal odor compound contents. Three sample groups with the different preparing methods -Doenjang that has not gone through the soy sauce separation process (Doenjang A), Doenjang that has gone through the soy sauce separation process; Meju-20% salt water ratio of 1 : 4 (Doenjang B), and that with the ratio of 1.3 : 4 (Doenjang C)- were tested during different ripening periods. Odor compound contents were analyzed through Solvent Extraction Method and Simultaneous Steam Distillation Extraction (SDE). The number of odor compounds was greatest in Doenjang A and during the mid to late stage in each groups. In the sensory evaluation of Doenjang odors, Doenjang A received the highest scores in the categories of overall preferences, while Doenjang C got the lowest scores. Individual odor didn't vary significantly during ripening periods, but the overall odor and taste preference was highest in the samples ripened for 75 to 120 days. Stepwise multiple regression analysis of major odor compounds of Doenjang revealed that benzeneacetaldehyde is the major explanatory variable for offensive odor. Benzeneethanol, 3-methylthio-propanal and 4-methyl-phenol are the explanatory variables for salty odor, nutty odor and rancid odor, respectively. Odor compounds that contribute to the overall odor preference varied from the compounds that affect the taste preference.

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반월.시화공단 주변 주거지역의 악취현황 및 황화합물의 체감도 (The Concentrations of Sulfur Compounds and Sensation of Odor in the Residential Area Around Banwol-Sihwa Industrial Complex)

  • 김종보;정상진;송일석
    • 한국대기환경학회지
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    • 제23권2호
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    • pp.147-157
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    • 2007
  • This study was carried out to investigate the characteristics of fourteen odor compounds from a total of 10 sampling sites in residential areas around Banwol-Sihwa industrial complex. The measurement data are analyzed and compared with sensation of odor unit. Only a hydrogen sulfide out of four sulfur compounds was quantified above the detection limit (0.06 ppb) in the residential area around Banwol industrial complex with leather companies and a sewage treatment plant. The concentrations of VOCs were higher than those measured from a big city, and styrene showed the relatively high concentration from all sampling sites ($2.1{\sim}37.8\;ppb$). In the case of carbonyl compounds, acetaldehyde was found most frequently with the mean of 3.97 ppb, and its concentration difference was not significant between Banwol and Sihwa industrial complex. Of the nitrogen compounds, ammonia was measured at the relatively high concentration from all the sampling sites ($12{\sim}707\;ppb$), and a trimethylamine was found at the odor threshold level (0.1 ppb). The concentrations of styrene and ammonia showed relatively seasonal variation, the concentration of styrene in summer was five times higher than that in autumn, the concentration of ammonia in autumn was two times higher than that in summer. However other odorous compounds did not show such strong seasonal variation. Odor-concentration relationship between odor unit and $H_{2}S$ concentrations from industrial sources was examined and used as odor sensation evaluation, and thus the neighbourhood odor complaints maybe caused during the four seasons from the results.

세탁조건에 따른 면직물 중의 악취성분 분석 (Analysis of the Compounds of Unpleasant Odor from the Cotton Fabrics through Different Washing Conditions)

  • 박명자;최해운
    • 복식문화연구
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    • 제10권5호
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    • pp.555-564
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    • 2002
  • The purpose of this research was to analysis compounds of unpleasant odor from the cotton fabrics in dehydration and drying process during washing. The cotton fabrics were treated with various commercial detergents and fabric softener or cationic surfactants such as Cetyltrimethylammonium bromide(CTAB) and Benzalkonium chloride(BC), then dehydrated and dried. The compounds of odor impregnated in fabric were detected by using CC-MS. The results are as follows: The fabrics treated with a powder-type detergent, CTAB and BC gave out compounds unpleasant odor. n-Butyraldehyde and isobutyaldehyde produced during microorganism growth were revealed as source of the compounds of the unpleasant odor. However, no aldehydes were detected from the fabrics treated with commercial fabric softener which seems to act as a deodorizer.

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한국전통간장의 맛과 향에 관여하는 주요 향미인자의 분석(III) -향기성분 분석 - (Analysis of Significant Factors in the Flayer of Traditional Korean Soy Sauce (III) - Aroma Compound Analysis -)

  • 박현경;손경희;박옥진
    • 한국식생활문화학회지
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    • 제12권2호
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    • pp.173-182
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    • 1997
  • This study was carried out in order to investigate effective aroma components of Korean traditional soy sauce. Volatile aroma compounds were extracted by solvent extraction, TMS esterification of methyl acetate extracts and SDE, and analyzed by GC/MSD. 140 voltile aroma compounds were detected by three different extraction methods. Most abundant volatile compounds were acids and phenols and identified aldehydes, hydrocarbons, ketones, furans, furanone, alcohols, esters, nitrogen compounds, sulfur compounds and thiazoles, too. In the analytical sensory evaluation of soy sauce aroma, there were significant differences between each soy sauce sample in all test item. To sum up, Sweet odor was high in Kyupjang. Nutty odor and traditional soy sauce odor were similarly high in Kyupjang and high concentration soy sauce. Kyupjang had high score in overall odor preference than Chungiangs. The result of multiple regression of soy sauce odor characteristics and gas chromatography pattern demonstrated that offensive and sour odor was affected by octadecanoic acid. Contributive compounds to sweet odor were 1,2-benzenedicarboxylic acid and 3,6-dioxa-2,7-disilacotane. Benzoic acid 4-methyl ethyl ester and nonacotane were identified as major compounds of nutty odor. Contribu live variables of traditional soy sauce odor were benzoic acid 4-methyl ethyl ester and 9,12-octadecadienoic acid. The main factors of odor preference were 3-methyl pentanoic acid, acetic acid, 2,6-dimethyl heptadecane and 3,6-dioxa-2,7-disilacotane.

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숯가마 배가스 중 악취물질의 배출특성 (Emission Characteristics of Odor Compounds in a Charcoal Production Kiln)

  • 박성규;최상진;황의현;이정주;김대근
    • 한국대기환경학회지
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    • 제30권4호
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    • pp.319-326
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    • 2014
  • Exhaust gas emitted as a result of the incomplete combustion of biomass in charcoal kilns includes odor compounds as well as other air pollutants such as particulate matters, sulfur and nitrogen oxides, and carbon monoxide. A number of offensive odor compounds affect quality of life. In this study, odor emissions were investigated from biomass burning in a pilot-scale charcoal kiln and a commercial-scale kiln. Complex odor from emission source reached up to 10,000 dilutions to threshold during the study period. Combustion fume was found to contain reduced sulfur compounds, aldehydes, and volatile organic compounds. Hydrogen sulfide and methyl mercaptan were the major odorants which highly contributed to the offensive odor.

산업단지에서 배출되는 악취원인물질의 규명 (Measurement of odor compounds from odorous emissions source of Industrial Complex)

  • 안상영;최성우
    • 한국환경과학회지
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    • 제14권1호
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    • pp.81-89
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    • 2005
  • As a typical example of simultaneous analysis of the odorous compounds, the volatile organic compounds from inventory sources in Seongseo industrial area were concentrated and analyzed with thermal desorber/GC/MSD, and major malodorous compounds were estimated. Odor intensity and odor concentration was analyzed simultaneously During a period from November in 2002 to December in 2003, this study was conducted to evaluate malodor emission characterization in major treatment facilities. The major components were Dimethyl sulfide, Dimethyl disulfide, Methyl mercaptane, Ammonia, Benzene, Toluene, m,p-xylene, o-xylene, Styrene, 1,2,4­T.M.B and 1,3,5-T.M.B. Among the six major inventory sources, the odor unit concentration of Night-soil disposal facilities was the highest, $669\~2344\;ou/m^{3}.$

대구시 산업단지 환경기초시설의 악취발생 특성 (Emission Characteristics of Odor Compounds from Fundamental Environmental Facilities in an Industrial Complex Area in Daegu City)

  • 이찬형;전현숙;신명철;김은덕;장윤재;권병윤;송희봉
    • 한국환경보건학회지
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    • 제42권4호
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    • pp.246-254
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    • 2016
  • Objectives: This study evaluated the odor emission characteristics from fundamental environmental facilities at an industrial complex area in Daegu City. Methods: The odor samples were collected from May 2015 to January 2016 and were analyzed for specified offensive odor substances. The odor quotient and the odor contribution was calculated. Results: Ammonia was detected in all samples monitoring specified odor compounds, followed by hydrogen sulfide and acetaldehyde. According to contribution analysis, hydrogen sulfide shows the highest contribution in all facilities. At wastewater treatment plants A and B and sewage treatment plant F, it was followed by acetaldehyde. At wastewater treatment plant C, it was followed by imethyl sulfide. Conclusion: The major component of odor can be determined by evaluating the degree of contribution to the odor intensity rather than the concentration of the individual odor components. To increase the effectiveness of odor reduction, policies focused on materials with a high odor contribution are needed rather than focusing on high-concentration odor compounds.

대구시 산업단지 염색폐수처리장의 악취발생 특성 (Emission Characteristics of Odor Compounds from a Dyeing Wastewater Treatment Plant in an Industrial Complex Area in Daegu City)

  • 이찬형;전현숙;권병윤;김은덕;장윤재;이명숙;금종록;송희봉
    • 한국환경보건학회지
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    • 제43권4호
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    • pp.314-323
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    • 2017
  • Objectives: This study evaluated the odor emission characteristics from a wastewater treatment plant in an industrial complex area in Daegu City. Methods: Odor samples were collected from March 2016 to December 2016 and were analyzed for specified offensive odor substances. The odor quotient and the odor contribution was calculated. Results: Ammonia, hydrogen sulfide, acetaldehyde, and toluene were detected in all samples for monitoring specified odor compounds. The result of contribution analysis is that hydrogen sulfide had the highest contribution in all processes, followed by acetaldehyde. Conclusion: The major components of odor can be determined by evaluating the degree of contribution to the odor intensity and the concentration of the individual odor component. To increase the effectiveness of odor reduction, rather than addressing high-concentration odor compounds, policies focused on materials with a high odor contribution are necessary.

대구시 산업단지 인근 하수처리장의 악취발생 특성 (Emission Characteristics of Odor Compounds from a Sewage Treatment Plant Near an Industrial Complex Area in Daegu City)

  • 이명숙;강동훈;금종록;권병윤;조항욱;이찬형;김은덕;임호진;송희봉
    • 한국환경보건학회지
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    • 제44권2호
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    • pp.178-187
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    • 2018
  • Objectives: This study evaluated the odor emission characteristics from a sewage treatment plant near an industrial complex area in Daegu City. Methods: Odor samples were collected from March 2017 to December 2017 and analyzed for specified offensive odor substances. The odor quotient and the odor contribution were calculated. Results: Ammonia, methyl mercaptane, hydrogen sulfide, dimethyl sulfide, acetaldehyde, propionylaldehyde, toluene, xylene, and methylethylketone were detected in all samples for monitoring the specified odor compounds. The result of contribution analysis is that hydrogen sulfide made the highest contribution in all processes, followed by acetaldehyde. Conclusion: The major components of odor can be determined by evaluating their degree of contribution to the odor intensity and the concentration of the individual odor component. To increase the effectiveness of odor reduction, rather than addressing high-concentration odor compounds, policies focused on materials with a high odor contribution are necessary.