• Journal of the Korean Society of Safety
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• v.7 no.3
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• pp.3-13
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• 1992

In recent years, the study about the high efficiency and low fuel consumption of the internal conbustion engine has been mainly proceeding. To achieve these goals, the improvement of combustion process in Sl engine and the use of substitute energy are suggested. When the methanol blend fuel Is used, the combustion rate of the initial ignition is diminishing by high latent evaporation of methanol. But it attracts the attention because of the high octane number, and lean mixture peculiarity. Considering these facts, the gasoline-methanol blend fuel In engine operation has been used to compare and analyze the pressure development, rate of heat release, mass burned fraction, and combustion process. The results of experiment show the power increase, lean combustion and low harmful component of emission.

• Bulletin of the Korean Chemical Society
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• v.16 no.7
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• pp.604-609
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• 1995

The relative dissociation constants of 4-substituted bicyclo[2,2,2]octane-1-carboxylic acids, 4-substituted quinuclidines, and 3-and 4-substituted pyridines were collected from a number of sources. In order to understand the actual substituent effects with a combination of inductive effect (σI) and resonance effect (σR) components. The DSP correlation has been employed statistically for each of the p-and m-series. The inductive effect from the m-position was 1.2 times more effective than that from the p-position and the requirement of σR+ for the best-fit led to the conclusion that pyridine system belongs to the σ+-class reactivity. Also compared with results from Yukawa-Tsuno's LArSR treatment and relevant treatment.

• Textile Coloration and Finishing
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• v.10 no.1
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• pp.25-32
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• 1998

In the prior study, we found that the dye uptakes of C. I. Disperse Violet 1 on PET in hexane and cyclohexane were higher than those in the other solvents. Therefore, in this study, the dye uptakes and the partition coefficients in alkanes having different number of carbon atoms were obtained and their relationship to the solubilities of the dye in alkanes was also investigated. As the number of carbon atoms of alkanes increases, solubility of the dye increases but the dye uptake decreases. This is due to the fact that the hydrophobicity of alkanes become relatively strong as increasing the number of carbon atoms. It was also found that the dye uptakes in iso-alkanes were larger than those in normal alkanes. This is because that the branched alkanes(iso-alkanes), judging from the tendency of lowering solubility and increasing dye uptake as decreasing the number of carbon atoms of alkanes, behave like the alkanes with less number of carbon atoms rather than the alkanes with the same number of carbon atoms. The logarithmic plot of the dye uptakes vs. the solubilities of the dye showed that the dye uptakes are linearly and inversely proportional to the solubilities. This is in good accordance with the results of the prior study. The heat of dyeing was also calculated from the equilibrium adsorptions at various temperatures. It seemed that the dyeings of PET by C. I. Disperse Violet 1 in nonane, decane, iso-pentane and iso-octane were rather endothermic processes. Dyeing rates in alkanes were somewhat delayed unlike general appearances in solvent dyeing.

• Journal of Environmental Policy
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• v.1 no.1
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• pp.75-90
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• 2002

Methyl tertiary-butyl ether(MTBE) is used as an octane enhancer in gasoline. MTBE can enter the environment at any stage in the production, storage, and transport of undiluted MTBE or MTBE-blended gasoline. Although data on concentrations of MTBE in the environment are not available, modelling of fate of MTBE has provided predictions for concentrations of MTBE in the various media to which humans and other organisms may be exposed. Many individuals do not taste or smell MTBE at the $5{\mu}g/L$ level, and thus may be exposed to higher concentrations for a significant amount of time. MTBE exposure through inhalation is likely to be below health-threatening levels, except for occupational workers such as gasoline station attendants and auto mechanics. It should be stressed, however, that there are important data gaps in our understanding of the acute and chronic toxicity of MTBE. Little or no research concern including being conducted that directly addresses these issues. Rather than any immediate ban on MTBE, I recommend consideration of phasing out MTBE in USA and other countries. During the transition phase, a number of policies are suggested to reduce the risk of using MTBE. One of these policies is that the state should invest in a research program. Such research should, for example, examine effective alternatives for motor vehicle fuels, and detect concentrations of MTBE in ambient air, water, and other environmental media.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.3
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• pp.351-359
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• 2010

Bi-fuel system in a spark ignition engine (SIE) is a rising phenomena in today's automobile technology. In a gasoline driven vehicle, alternatively adoption of compressed natural gas (CNG) could be used as a potential substitute to meet the energy requirement and this is possible by some minor changes in the hardware of the existing engine. Gasoline engine is widely used in the passenger cars, light, medium and heavy duty vehicles but the consumption status of the petroleum is decreasing worldwide and at the same time environmental pollution from automobiles is seriously establishes as a threat for every nation in respect to global warming and climate changes. Now-a-days most vehicles operate using CNG for its popularity stems, clean burning properties and cost effective solution compared to other alternative fuels. It refers as a good gaseous fuel because of its high octane number and self ignition temperature. Though the power output is slightly lesser than the gasoline fuel; its thermal efficiency is better than the gasoline for the same SIE. The research paper highlights the reduction of CO, reasonable outcomes of HC emissions with minor increase in $NO_x$ emissions compared with the gasoline fuel to bi-fuel mode in the SIE that meets the emission challenges.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.6
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• pp.31-39
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• 2000

In this paper, characteristics of a port injection type LPG fuel system were investigated to adopt the system to a spark ignition engine through rig test. Engine combustion characteristics for limited conditions and the precise control method of LPG fuel supply were also studied. As a basic experiment, the effects and the relationships of parameters such as orifice area, fuel delivery pressure, fuel temperature and flow coefficient were established. From this, one dimensional compressible flow equation can be applied to control gaseous fuel flow rate by setting pressure difference between vaporizer and manifold to a certain range, for example about 1.2 bar in a naturally aspirated engine. The combustion analysis results of LPG engine were also compared with those of gasoline engine according to spark timing and load change. At part load and stoichiometric condition, the MBT spark timing of LPG fueled engine is retarded by 2$^{\circ}$ - 4$^{\circ}$CA compared to that of gasoline engine. On the contrary, the spark timing of LPG fueled engine can be advanced by 5$^{\circ}$- 10$^{\circ}$ CA at WOT, which results from higher Octane Number and burned fraction of LPG fuel compared to gasoline.

• Transactions of the Korean Society of Automotive Engineers
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• v.11 no.3
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• pp.85-91
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• 2003

In this study, the potential possibility of oxygenated fuel such as Methyl tertiary butyl ether (MTBE) was investigated for the sake of exhausted smoke reduction from diesel engine. MTBE has been used as a fuel additive blended into unleaded gasoline to improve octane number, but the study of application for diesel engine was incomplete. Because MTBE includes oxygen content approximately 18%, it is a kind of oxygenated fuel that the smoke emission of MTBE is reduced remarkably compared with commercial diesel fuel. But, the NOx emission of MTBE blended fuel is increased compared with commercial diesel fuel. And, it was tried to analyze not only total hydrocarbon but individual hydrocarbon components from $C_1$ to $C_6$ in exhaust gas using gas chromatography to seek the reason for remarkable reduction of smoke emission. Individual hydrocarbons($C_1$~$C_6$) as well as total hydrocarbon of oxygenated fuel are reduced remarkably compared with diesel fuel. And, the effects of exhaust gas recirculation(EGR) on the characteristics of NOx emission has been investigated, too. It was found that simultaneous reduction of smoke and NOx was achieved with oxygenated fuel and cooled EGR method.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.5
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• pp.334-342
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• 2009

Trends in the automotive market require the application of new engine technologies, which allows for the use of different types of fuel. Since ethanol is a renewable source of energy and has lower $CO_2$ emissions than gasoline, ethanol produced from biomass is expected to be used more frequently as an alternative fuel. It is recognized that for spark ignition (SI) engines, ethanol has the advantages of high octane number and high combustion speed. Due to the disadvantages of ethanol, it may cause extra wear and corrosion of electric fuel pumps. On-board hydrogen production out of ethanol is an alternative plan. This paper investigates the influence of ethanol fuel on SI engine performance, thermal efficiency and emissions. The combustion characteristics with hydrogen-enriched gaseous fuel from ethanol are also examined. As a result, thermal efficiency increase compared to gasoline. Also, reductions in $CO_2$, NOx, and THC combustion products for ethanol vs. gasoline are described.

• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.1
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• pp.35-42
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• 2009

In this study, a spark ignition engine operated with LPG and DME blended fuel was studied experimentally. The effect of n-butane and propane on performance and emissions of a SI engine fuelled by LPG/DME blended fuel were examined. Stable engine operation was achieved for a wide range of engine loads with propane containing LPG/DME blended fuel compare to butane containing LPG/DME blended fuel since octane number of propane was much higher than that of butane. Also, engine output operated with propane containing blended fuel was comparable to pure LPG fuel operation. Engine output power was decreased and break specific fuel consumption (BSFC) was increased with the blended fuel since the energy content of DME was much lower than that of LPG. Considering the results of engine output power, bsfc, and exhaust emissions, the propane containing LPG/DME blended fuel could be used as an alternative fuel for LPG.

• Journal of ILASS-Korea
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• v.21 no.3
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• pp.144-154
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• 2016

This review will be concentrated on the spray characteristics of biobutanol and its blends fuels in internal combustion engines including compression ignition, spark ignition and gas turbine engines. Butanol can be produced by fermentation from sucrose-containing feedstocks, starchy materials and lignocellulosic biomass. Among four isomers of butanol, n-butanol and iso-butanol has been used in CI and SI engines. This is due to higher octane rating and lower water solubility of both butanol compared with other isomers. The researches on the spray characteristics of neat butanol can be classified into the application to CI and SI engines, particularly GDI engine. Two empirical correlations for the prediction of spray angle for butanol as a function of Reynolds number was newly suggested. However, the applicability for the suggested empirical correlation is not yet proved. The butanol blended fuels used for the investigation of spray characteristics includes butanol-biodiesel blend, butanol-gasoline blend, butano-jet A blend and butanol-other fuel blends. Three blends such as butanol/ethanol, butanol/heptane and butanol/heavy fuel oil blends are included in butanol-other fuel blends. Even though combustion and emission characteristics of butanol/diesel fuel blend in CI engines were broadly investigated, study on spray characteristics of butanol/diesel fuel blend could not be found in the literature. In addition, the more study on the spray characteristics of butanol /gasoline blend is required.