• 제목/요약/키워드: Ocean discharge

검색결과 423건 처리시간 0.028초

Fabrication of nickel nanoparticles-embedded carbon particles by solution plasma in waste vegetable oil

  • Pansuwan, Gun;Phuksawattanachai, Surayouth;Kerdthip, Kraiphum;Sungworawongpana, Nathas;Nounjeen, Sarun;Anantachaisilp, Suranan;Kang, Jun;Panomsuwan, Gasidit;Ueno, Tomonaga;Saito, Nagahiro;Pootawang, Panuphong
    • Journal of Advanced Marine Engineering and Technology
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    • 제40권10호
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    • pp.894-898
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    • 2016
  • Solution plasma is a unique method which provides a direct discharge in solutions. It is one of the promising techniques for various applications including the synthesis of metallic/non-metallic nanomaterials, decomposition of organic compounds, and the removal of microorganism. In the context of nanomaterial syntheses, solution plasma has been utilized to produce carbon nanoparticles and metallic-carbon nanoparticle systems. The main purpose of this study was to synthesize nickel nanoparticles embedded in a matrix of carbon particles by solution plasma in one-step using waste vegetable oil as the carbon source. The experimental setup was done by simply connecting a bipolar pulsed power generator to nickel electrodes, which were submerged in the waste vegetable oil. Black powders of the nickel nanoparticles-embedded carbon (NiNPs/Carbon) particles were successfully obtained after discharging for 90 min. The morphology of the synthesized NiNPs/Carbon was investigated by a scanning electron microscope, which revealed a good dispersion of NiNPs in the carbon-particle matrix. The X-ray diffraction of NiNPs/Carbon clearly showed the co-existence of crystalline Ni nanostructures and amorphous carbon. The crystallite size of NiNPs (through the Ni (111) diffraction plane), as calculated by the Scherrer equation was found to be 64 nm. In addition, the catalytic activity of NiNPs/Carbon was evaluated by cyclic voltammetry in an acid solution. It was found that NiNPs/Carbon did not show a significant catalytic activity in the acid solution. Although this work might not be helpful in enhancing the activity of the fuel cell catalysts, it is expected to find application in other processes such as the CO conversion (by oxidation) and cyclization of organic compounds.

Sea Level Rise at the Southwestern Coast of Korean Peninsula

  • Oh Nam-Sun;Kang Ju-Whan;Moon Seung-Rok
    • 한국항해항만학회지
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    • 제29권4호
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    • pp.327-333
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    • 2005
  • Sea level (MSL, MHWL, or MLWL) change has been main concern to scientists and engineers and it can be primarily due to both change of climate and vertical movement of land. This paper reports the intensive analysis of the sea level changes and broad discussion of the future at the southwestern coast of Korean peninsula. Regression analysis was conducted to investigate general tendency and periodicity of the sea levels at the six different study sites such as Gunsan-I(inner port), Gunsan-O(outer port), Mokpo, Yeosu, Heuksan and Jeju and the results were compared with global values. Besides the changes of sea levels due to global warming, the influence of the man-made structure such as seadike and seawall was attempted to quantify using the minimization of the Root Mean Square(RMS) error. The results show that it is a general tendency that the values of mean sea level rise at the southwestern coast of Korean Peninsula, especially at Gunsan-I and Jeju, are somewhat larger compared to global average values. There is also some evidence that tidal amplifications are found just after construction of man-made structure at Gunsan-I and Mokpo. However, both sites show different mechanism in relation to tidal choking, tidal flat and river discharge. The impact due to construction of man-made structure is considerably larger at Mokpo site, while the impacts due to man-made structure and the effect of sea level rise are relatively identical at Gunsan-I site. This study is expected to provide some intuition to future design.

Low-flow simulation and forecasting for efficient water management: case-study of the Seolmacheon Catchment, Korea

  • Birhanu, Dereje;Kim, Hyeon Jun;Jang, Cheol Hee;ParkYu, Sanghyun
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2015년도 학술발표회
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    • pp.243-243
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    • 2015
  • Low-flow simulation and forecasting is one of the emerging issues in hydrology due to the increasing demand of water in dry periods. Even though low-flow simulation and forecasting remains a difficult issue for hydrologists better simulation and earlier prediction of low flows are crucial for efficient water management. The UN has never stated that South Korea is in a water shortage. However, a recent study by MOLIT indicates that Korea will probably lack water by 4.3 billion m3 in 2020 due to several factors, including land cover and climate change impacts. The two main situations that generate low-flow events are an extended dry period (summer low-flow) and an extended period of low temperature (winter low-flow). This situation demands the hydrologists to concentrate more on low-flow hydrology. Korea's annual average precipitation is about 127.6 billion m3 where runoff into rivers and losses accounts 57% and 43% respectively and from 57% runoff discharge to the ocean is accounts 31% and total water use is about 26%. So, saving 6% of the runoff will solve the water shortage problem mentioned above. The main objective of this study is to present the hydrological modelling approach for low-flow simulation and forecasting using a model that have a capacity to represent the real hydrological behavior of the catchment and to address the water management of summer as well as winter low-flow. Two lumped hydrological models (GR4J and CAT) will be applied to calibrate and simulate the streamflow. The models will be applied to Seolmacheon catchment using daily streamflow data at Jeonjeokbigyo station, and the Nash-Sutcliffe efficiencies will be calculated to check the model performance. The expected result will be summarized in a different ways so as to provide decision makers with the probabilistic forecasts and the associated risks of low flows. Finally, the results will be presented and the capacity of the models to provide useful information for efficient water management practice will be discussed.

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PET분해효소(PETase) 과발현 전세포 촉매의 해양미세플라스틱 생분해 활성 연구 (Biodegradation of marine microplastics by the whole-cell catalyst overexpressing recombinant PETase)

  • 김현지;박종하;박애란;이대희;전준호;권혁택;임성인
    • 한국해양바이오학회지
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    • 제14권2호
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    • pp.133-142
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    • 2022
  • The increased production and consumption of polyethylene terephthalate (PET)-based products over the past several decades has resulted in the discharge of countless tons of PET waste into the marine environment. PET microparticles resulting from the physical erosion of general PET wastes end up in the ocean and pose a threat to the marine biosphere and human health, necessitating the development of new technologies for recycling and upcycling. Notably, enzyme-mediated PET degradation is an appealing option due to its eco-friendly and energy-saving characteristics. PETase, a PET-hydrolyzing enzyme originating from Ideonella sakaiensis, is one of the most thoroughly researched biological catalysts. However, the industrial application of PETase-mediated PET recycling is limited due to the low stability and poor reusability of the enzyme. Here we developed the whole-cell catalyst (WCC) in which functional PETase is attached to the outer membrane of Escherichia coli. Immunoassays are used to identify the surface-expressed PETase, and we demonstrated that the WCC degraded PET microparticles most efficiently at 30℃ and pH 9 without agitation. Furthermore, the WCC increased the PET-degrading activity in a concentration-dependent manner, surpassing the limited activity of soluble PETase above 100 nM. Finally, we demonstrated that the WCC could be recycled up to three times.

Transverse variability of flow and sediment transport in estuaries with an estuarine dam

  • Steven Figueroa;Minwoo Son
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2023년도 학술발표회
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    • pp.125-125
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    • 2023
  • Estuarine dams are dams constructed in estuaries for reasons such as securing freshwater resources, controlling water levels, and hydroelectric power generation. These estuarine dams alter the flow of freshwater to the coastal ocean and the tidal properties of the estuaries which has implications for the estuaries' circulation and sediment transport. A previous study has analyzed the effect of estuarine dams on 1D (along-channel) circulation and sediment transport. However, the effect of estuarine dams on the transverse variability of along-channel and across-channel circulation and sediment transport has not been studied and is not known. In this study, a coupled hydrodynamic-sediment dynamic numerical model (COAWST) was used to analyze the transverse variability of along-channel and across-channel flow and sediment transport in estuaries with estuarine dams. The estuarine dam was found to change the 3D structure of circulation and sediment transport, and the result was found to depend on the estuarine type (i.e., strongly stratified (SS) or well-mixed (WM) estuary). The SS estuary had inflow in the channel and outflow over the shoals, consistent with estuarine circulation. Longer discharge interval reduced the estuarine circulation. The WM estuary had inflow over the shoals and outflow in the channel, consistent with tide-induced circulation. As the estuarine dam was located nearer to the estuary mouth, the tide-induced circulation was reduced and replaced with estuarine circulation. The lateral circualtion was the greatest in the tide-dominated estuaries. It was reduced and changed direction due to differential advection change as the dam was located nearer the mouth. Overall, the WM estuary transverse flow structure changed the most. Lateral sediment flux was important in all estuaries, particularly for transporting sediments to the tidal flats.

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Analysis of the Prediction of Operation Processes based on Mode of Operation for Ships: Applying Delphi method

  • HyeRi Park;JeongMin Kim
    • 한국컴퓨터정보학회논문지
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    • 제28권10호
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    • pp.267-275
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    • 2023
  • 조선 및 해운·물류 분야의 디지털 전환은 자율운항선박의 도입 및 선박의 운항방식의 변화를 이끌 것으로 예상된다. 기존 운항방식과 함께 자율운항, 원격운항 등 다양한 운항형태가 공존하며, 선박 운용 프로세스의 전환과 새로운 이해관계자의 등장이 전망된다. 본 논문에서는 선박 운항방식 변화에 따른 미래 선박 운항 프로세스를 분석하고, 미래 선박의 운항환경 변화를 예측하여 주요 업무별·이해관계자별 기능요건을 도출하고자 한다. 델파이 기법을 활용하여 항해 및 화물운송 계획 수립단계부터 최종 목적항 입항 및 화물 하역단계까지 선박 운항 시나리오를 구성하고, 업무별, 수행 주체별 미래 업무 변화를 예측했다. 원격운항, 자율운항 등으로 선원의 개입이 최소화될 것이며, 각 분야의 전문가가 선박 운항의 다양한 측면에서 책임과 의무를 갖게 될 것으로 예상된다.

강우 발생에 의한 진동만해역의 육상오염원이 해수 및 패류에 미치는 영향 분석 (Impact of Land-based Pollution Sources on Seawater and Shellfish after Rainfall Event in the Jindongman Area)

  • 이장원;윤민철;김지훈;조성래;남기호;하광수;박큰바위
    • 한국수산과학회지
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    • 제56권6호
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    • pp.798-809
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    • 2023
  • In this study, we evaluated the impacts of land-based pollution sources on seawater and shellfish in the Jindongman area after 20.5 mm and 90.6 mm rainfall events. We analyzed sanitary indicator microorganisms used in survey management, such as total coliform, fecal coliform, Escherichia coli, and male-specific coliphage in Waste water treatment plant (WWTP), major inland pollution source,s seawater, and shellfish for 4 days after rainfall events. Our results showed that the range of coliform group and fecal coliform was 1.8-49 and <1.8-4.5 MPN (most probable number)/100 mL, respectively, after rainfall events in WWTP discharge water. Furthermore, the radius of the calculated impacted area of major inland pollution sources ranged from 5 to 798 m after 20.5 mm of rainfall and 30 to 1,031 m after 90.6 mm of rainfall. The fecal coliform of seawater at 30 stations in the shellfish growing area and areas adjacent to four stations was <1.8-130 and from <1.8-79 MPN/100 mL, respectively. The E. coli level of shellfish at 7 stations in the shellfish growing area was <18-220 MPN/100 g.

2020년 하계 장강 저염수가 이어도 해양과학기지 주변 해역의 식물플랑크톤 다양성 및 개체수 변화에 미치는 영향 (Phytoplankton Diversity and Community Structure Driven by the Dynamics of the Changjiang Diluted Water Plume Extension around the Ieodo Ocean Research Station in the Summer of 2020)

  • 김지훈;최동한;이하은;정진용;정종민;노재훈
    • 해양환경안전학회지
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    • 제27권7호
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    • pp.924-942
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    • 2021
  • 여름철 장강 저염수의 확장은 북부 동중국해의 환경 및 식물플랑크톤 다양성과 군집구조에 영향을 미치는 주요 요인으로 알려져 있다. 2020년 하계는 장강 저염수의 방류량이 매우 높았던 시기로 환경 특성 변화에 따라 식물플랑크톤 다양성 및 군집구조에 미치는 동력을 이해하기 위해 현장관측을 수행하였다. 2020년 8월 16일~17일 이어도호 승선조사와 2020년 8월 15일~21일 이어도 해양과학기지(IORS)에서 체류조사를 실시하였다. 조사 정점들에서 CTD로 측정한 결과 조사 수역 남서쪽은 장강 저염수의 영향을 받아 염분이 낮고 엽록소 형광값이 높았으며, 대마난류의 영향을 받은 남동수역은 염분이 높고 엽록소 형광값이 낮았다. 12개 정점의 표층수 시료의 엽록소 a 농도는 미소형(20~3 ㎛) 및 소형(> 20 ㎛) 식물플랑크톤의 생체량이 우점함을 나타냈으며, 대마난류수의 영향을 받은 정점에서만 초미소 식물플랑크톤(< 3 ㎛) 생체량이 약 50%를 차지하였다. 이러한 표층수의 식물플랑크톤 크기 분포는 영양염류 공급과 관련되어 장강 저염수의 높은 질산염 공급을 받는 정점들은 소형 식물플랑크톤의 생체량 기여율이 높았다. 형태분류 결과 미소형 및 소형 식물플랑크톤은 총 45종이며, 이들 중 우점 분류군은 규조류인 Guinardia flaccida, Nitzschia spp.와 와편모조류인 Gonyaulax monacantha, Noctiluca scintillans, Gymnodinium spirale, Heterocapsa spp., Prorocentrum micans, Tripos furca 등이었다. 대마난류의 영향을 받으며 질산염 농도가 낮은 정점들은 광합성 초미소 진핵생물(PPE)의 개체수와 광합성 초미소 원핵생물(PPP)인 Synechococcus의 개체수가 높았다. 질산염/인산염 비는 대부분 정점에서 인산염 제한을 받고 있음을 나타냈다. 유세포 분석 결과 Synechococcus 개체수는 난류의 영향을 받는 빈영양 수역의 정점들에서 높은 개체수를 보였다. NGS 분석 결과 PPP 중 Synechococcus는 29개의 clades가 나타났고, 이 중 한 시료에서 한 번이라도 1% 이상의 우점율을 보인 clade는 11개로 나타났다. 표층수에선 clade II가 우점분류군이었으며 SCM 층에서 다양한 clades(I과 IV 등)가 차우점군들로 분포하였다. Prochlorococcus 속은 난류 수역에서 high light adapted 생태형이 출현하는 양상을 보였으며 북쪽 수역에선 출현하지 않았다. PPE는 총 163개의 높은 operational taxonomic units(OTUs) 다양성을 보였으며, 이 중 한 시료에서 한 번이라도 5% 이상의 우점률을 나타낸 OTU는 총 11개였다. 장강 저염수의 영향을 받는 정점의 표층수에선 Amphidinium testudo가 우점 분류군이었으며, SCM 층에서 녹조류가 최우점하였다. 대마난류의 영향을 받는 해역에서는 다양한 분류군의 착편모조류가 우점하였다. IORS에서의 관측 결과도 주변 정점들과 식물플랑크톤 생체량, 크기분포, 다양성에서 유사한 수준을 나타냈다. 이번 연구 결과는 장강 저염수의 영향에 따른 식물플랑크톤의 반응을 다양한 분야에서 확인할 수 있었다. 또한, IORS와 승선조사를 비교하여 IORS 관측이 장강 저염수의 식물플랑크톤 동적 역학 모니터링에 활용할 수 있음을 확인하였다. 향후 기후변화에 따라 나타날 동중국해 하계 환경 및 생태계의 변화에 대비하여 IORS의 효과적 이용 방안 수립이 필요할 것으로 판단된다.

"무역상무(貿易商務)에의 역사적(歷史的) 어프로치와 무역취인(貿易取引)의 전자화(電子化)" (E-Commerce in the Historical Approach to Usage and Practice of International Trade)

  • 춘홍차
    • 무역상무연구
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    • 제19권
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    • pp.224-242
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    • 2003
  • The author believes that the main task of study in international trade usage and practice is the management of transactional risks involved in international sale of goods. They are foreign exchange risks, transportation risks, credit risk, risk of miscommunication, etc. In most cases, these risks are more serious and enormous than those involved in domestic sales. Historically, the merchant adventurers organized the voyage abroad, secured trade finance, and went around the ocean with their own or consigned cargo until around the $mid-19^{th}$ century. They did business faceto-face at the trade fair or the open port where they maintained the local offices, so-called "Trading House"(商館). Thererfore, the transactional risks might have been one-sided either with the seller or the buyer. The bottomry seemed a typical arrangement for risk sharing among the interested parties to the adventure. In this way, such organizational arrangements coped with or bore the transactional risks. With the advent of ocean liner services and wireless communication across the national border in the $19^{th}$ century, the business of merchant adventurers developed toward the clear division of labor; sales by mercantile agents, and ocean transportation by the steam ship companies. The international banking helped the process to be accelerated. Then, bills of lading backed up by the statute made it possible to conduct documentary sales with a foreign partner in different country. Thus, FOB terms including ocean freight and CIF terms emerged gradually as standard trade terms in which transactional risks were allocated through negotiation between the seller and the buyer located in different countries. Both of them did not have to go abroad with their cargo. Instead, documentation in compliance with the terms of the contract(plus an L/C in some cases) must by 'strictly' fulfilled. In other words, the set of contractual documents must be tendered in advance of the arrival of the goods at port of discharge. Trust or reliance is placed on such contractual paper documents. However, the container transport services introduced as international intermodal transport since the late 1960s frequently caused the earlier arrival of the goods at the destination before the presentation of the set of paper documents, which may take 5 to 10% of the amount of transaction. In addition, the size of the container vessel required the speedy transport documentation before sailing from the port of loading. In these circumstances, computerized processing of transport related documents became essential for inexpensive transaction cost and uninterrupted distribution of the goods. Such computerization does not stop at the phase of transportation but extends to cover the whole process of international trade, transforming the documentary sales into less-paper trade and further into paperless trade, i.e., EDI or E-Commerce. Now we face the other side of the coin, which is data security and paperless transfer of legal rights and obligations. Unfortunately, these issues are not effectively covered by a set of contracts only. Obviously, EDI or E-Commerce is based on the common business process and harmonized system of various data codes as well as the standard message formats. This essential feature of E-Commerce needs effective coordination of different divisions of business and tight control over credit arrangements in addition to the standard contract of sales. In a few word, information does not alway invite "trust". Credit flows from people, or close organizational tie-ups. It is our common understanding that, without well-orchestrated organizational arrangements made by leading companies, E-Commerce does not work well for paperless trade. With such arrangements well in place, participating E-business members do not need to seriously care for credit risk. Finally, it is also clear that E-International Commerce must be linked up with a set of government EDIs such as NACCS, Port EDI, JETRAS, etc, in Japan. Therefore, there is still a long way before us to go for E-Commerce in practice, not on the top of information manager's desk.

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만경강 하구역의 유기탄소 거동 및 분포 (Organic carbon behavior and distribution in the Mankyoung River Estuary)

  • 박준건;김은수;김경태;조성록;박용철
    • 한국해양환경ㆍ에너지학회지
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    • 제9권3호
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    • pp.131-140
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    • 2006
  • 만경강 하구역의 입자성 부유물질 및 유기탄소 거동에 관한 연구가 2003년 2월, 5월, 7월, 8월에 이루어졌다. 갈수기인 2, 5월과 풍수기인 7, 8월에 만경강을 통한 담수 유입량의 차이는 매우 컸으며, 용존유기탄소의 유입량은 갈수기와 풍수기에 각각 약 $8.16{\times}10^2tonC\;month^{-1}$$5.77{\times}10^3tonC\;month^{-1}$, 입자성유기탄소의 유입량은 갈수기와 풍수기 각각 약 $9.37{\times}10^2tonC\;month^{-1}$$3.14{\times}10^4tonC\;month^{-1}$로 나타났다. 특히 많은 강우가 집중되었던 풍수기에 방조제 내 북측 수역의 용존유기탄소 농도가 증가하는 경향을 보였다. 조사기간 중 만경강 히구역에서의 용존유기탄소 분포는 염분에 대해 비교적 보존적인 특성을 보이고 있어, 담수와 해수사이의 물리적 희석작용에 영향을 많이 받는 것으로 나타났다. 그러나 입자성유기탄소의 분포는 부유물질의 거동과 유사하게 60-90% 정도가 하구역에 침강, 제거되는 것으로 나타났다. 이러한 결과로 볼 때 새만금 방조제 완공 후 만경강 하구역이 외해와의 물질 교환이 차단 될 경우, 저층에 퇴적된 다량의 유기 탄소가 저층 용존 산소 고갈의 주요 원인이 될 수 있음을 시사하고 있다.

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