• Title/Summary/Keyword: OLED materials

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New green fluorescent materials for OLEDs

  • Lee, Chil-Won;Lee, Eun-Jung;Kim, Joon-Woo;Yun, Jong-Hyeok;Lee, Jun-Yeob;Gong, Myoung-Seon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.628-631
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    • 2007
  • We developed new green emitting materials based on the spiro moieties. The introduction of a spiro linkage into the structure of DJGH series lead to a reduction in crystallization tendency and an increase in glass transition temperature. they showed much better emitting efficiency and color purity than commercial host material $Alq_3$.

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Optical and Electrical Properties of Two-Wavelength White Tandem Organic Light-Emitting Diodes Using Red and Blue Materials (적색과 청색 물질을 사용한 2파장 방식 백색 적층 OLED의 광학 및 전기적 특성)

  • Park, Chan-Suk;Jua, Sung-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.9
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    • pp.581-586
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    • 2015
  • We studied optical and electrical properties of two-wavelength white tandem organic light-emitting diodes using red and blue materials. White fluorescent OLEDs were fabricated using Alq3 : Rubrene (3 vol.% 5 nm) / SH-1 : BD-2 (3 vol.% 25 nm) as emitting layer (EML). White single fluorescent OLED showed maximum current efficiency of 9.7 cd/A, and tandem fluorescent OLED showed 18.2 cd/A. Commission Internationale de l'Eclairage (CIE) coordinates of single and tandem fluorescent OLEDs was (0.385, 0.435), (0.442, 0.473) at $1,000cd/m^2$, respectively. White hybrid OLEDs were fabricated using SH-1 : BD-2 (3 vol.% 10 nm) / CBP : $Ir(mphmq)_2(acac)$ (2 vol.% 20 nm) as EML. White single hybrid OLED showed maximum current efficiency of 7.8 cd/A, and tandem hybrid OLED showed 26.4 cd/A. Maximum current efficiency of tandem hybrid OLED was more twice as high as single OLED. CIE coordinates of single hybrid OLED was (0.315, 0.333), and tandem hybrid OLED was (0.448, 0.363) at $1,000cd/m^2$. CIE coordinates in white tandem OLEDs compared to those for single OLEDs observed red shift. This work reveals that stacked white OLED showed current efficiency improvement and red shifted emission than single OLED.

Advanced Organic LED Materials for the Excellent Organic LED Displays

  • Enokida, Toshio;Gwon, Tae-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2001.08a
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    • pp.189-190
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    • 2001
  • In this paper, we explain the materials of the advanced organic light emitting diode(OLED) for the excellent OLED displays. We have been designed the various kinds of organic materials like as the hole-injecting materials (HIMs), the hole transporting materials(HTMs). the light emitting materials(LEMs), and the electron injecting materials(EIMs). As the results, we found the excellent materials and their combinations for the OLED displays.

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Surface Control of Planarization Layer on Embossed Glass for Light Extraction in OLEDs

  • Cho, Doo-Hee;Shin, Jin-Wook;Moon, Jaehyun;Park, Seung Koo;Joo, Chul Woong;Cho, Nam Sung;Huh, Jin Woo;Han, Jun-Han;Lee, Jonghee;Chu, Hye Yong;Lee, Jeong-Ik
    • ETRI Journal
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    • v.36 no.5
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    • pp.847-855
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    • 2014
  • We developed a highly refractive index planarization layer showing a very smooth surface for organic light-emitting diode (OLED) light extraction, and we successfully prepared a highly efficient white OLED device with an embossed nano-structure and highly refractive index planarization layers. White OLEDs act as an internal out-coupling layer. We used a spin-coating method and two types of $TiO_2$ solutions for a planarization of the embossed nano-structure on a glass substrate. The first $TiO_2$ solution was $TiO_2$ sol, which consists of $TiO_2$ colloidal particles in an acidic aqueous solution and several organic additives. The second solution was an organic and inorganic hybrid solution of $TiO_2$. The surface roughness ($R_a$) and refractive index of the $TiO_2$ planarization films on a flat glass were 0.4 nm and 2.0 at 550 nm, respectively. The J-V characteristics of the OLED including the embossed nano-structure and the $TiO_2$ planarization film were almost the same as those of an OLED with a flat glass, and the luminous efficacy of the aforementioned OLED was enhanced by 34% compared to that of an OLED with a flat glass.

Low driving voltage and high stability organic light-emitting diodes with rhenium oxide-doped hole transporting layer

  • Leem, Dong-Seok;Park, Hyung-Dol;Kang, Jae-Wook;Lee, Se-Hyung;Kim, Jang-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1650-1653
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    • 2007
  • We demonstrate fluorescent green organic lightemitting diodes employing a rhenium oxide ($ReO_3$)-doped N,N-diphenyl-N,N'-bis(1,1'-biphenyl)-4,4'-diamine (NPB) hole transporting layer (HTL). The devices exhibit significantly reduced driving voltages as well as prolonged lifetime. Details of $ReO_3$ doping effects are described in terms of charge transfer complex and stabilization of HTL morphology.

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Emission Characteristics of Fluorescent OLED with Alternating Current Power Source Driving Method (교류전원 구동방식에 의한 형광 OLED의 발광 특성)

  • Seo, Jung-Hyun;Kim, Ji-Hyun;Ju, Sung-Hoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.2
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    • pp.104-109
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    • 2014
  • To operate organic light emitting device (OLED) with alternating current (AC) power source without AC/DC(direct current) converter, we fabricated the fluorescent OLED and measured the emission characteristics with AC and DC. The OLED operated by AC showed higher maximum current efficiency of 8.2 cd/A and maximum power efficiency of 8.3 lm/W. But current efficiency and power efficiency of AC driven OLED showed worse than DC driven OLED at high voltage above 10 V. This result can be explained by the peak voltage of AC was $\sqrt{2}$ times than DC, In case of low driving voltage the emission characteristics were improved by the peak voltage of AC, but in case of high driving voltage the emission efficiencies were decreased by the roll off phenomena. Finally, serial OLED arrays using twelve OLEDs driven by AC 110 V showed average voltage of 9.17 V, voltage uniformity of 99.0%, average luminance of $1,175cd/m^2$, luminance uniformity of 94.4%.

Emission Characteristics of Blue Fluorescence Tandem OLED Using MoOx (MoOx를 사용한 청색 형광 Tandem OLED의 발광 특성)

  • Kwak, Tea-Ho;Ju, Sung-Hoo
    • Journal of the Korean institute of surface engineering
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    • v.47 no.3
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    • pp.104-108
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    • 2014
  • To improve emission efficiency of organic light emitting devices (OLEDs), we fabricated the tandem OLED of ITO / 2-TNATA / NPB / SH-1: 3 vol.% BD-2 / Bphen / Liq / Al / $MoO_x$ (X nm) / 2-TNATA / NPB / SH-1: 3 vol.% BD-2 / Bphen / Liq / Al structure. And emission properties of single OLED and tandem OLED with $MoO_x$ thickness as charge generation layer (CGL) were measured. The current emission efficiency and quantum efficiency of tandem OLED with $MoO_x$ of 3 nm thickness were improved compare with single OLED from 7.46 cd/A and 5.39% to 22.57 cd/A and 11.76%, respectively. In case of thicker or thinner than $MoO_x$ of 3~5 nm, the current emission efficiency and quantum efficiency were decreased, because balance of electron and hole in emission layer was not matching. The driving voltage was increased from 8 V of single OLED to 15 V of tandem OLED by thickness increase of OLED. As a result, it was possible to improve the emission efficiency of OLEDs by optimized $MoO_x$ thickness.

Yellow, Orange, and Red Phosphorescent Materials for OLED Lightings (OLED 조명을 위한 Yellow, Orange, Red 인광 재료)

  • Jung, Hyocheol;Park, Young-Il;Kim, Beomjin;Park, Jongwook
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.247-250
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    • 2015
  • Organic light-emitting diode (OLED) research field has received great attention from academic and industrial circles. Recently, The technical feature of OLEDs is more and more attractive in the lighting market, including area emission characteristics different from other existing light sources. Features are environmentally friendly and efficient use of energy, large area, ultra-light weight, and ultrathin shape, etc. Furthermore, OLED light became the mainstream of next-generation lighting to replace the light emitting diode (LED) fluorescent light. This article summarizes phosphorescent emitting materials that have been applied to white OLEDs. In particular, the chemical structures and device performances of the important yellow, orange, and red phosphorescent emitting materials is discussed. Systematic classification and understanding of the phosphorescent materials can aid the development of new light-emitting materials.

Improved Light Extraction of Organic Light Emitting Diode With Microcavity structure based on $SiO_2/TiO_2/SIO_2$ Multi 1D Layer

  • Kang, Nam-Su;Kim, Jai-Kyeong;Yoo, Jai-Woong;Ju, Byeong-Kwon;Chin, Byung-Doo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1440-1442
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    • 2007
  • In this work, we have modeled and fabricated microcavity-enhanced OLED using the 1-dimensional distributed Bragg reflector model (DBR). Results show that simulated spectrum intensity of microcavity OLED increased more than 30% compared to the conventional OLED, by use of DBR with $TiO_2$ and $SiO_2$. Spectral change of green and blue emission was expected to give the deeper color. The experimental design and characterization as well as the matching with simulated properties were performed for microcavity OLED for actual application.

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Exciton Dynamics and Device Lifetime of Phosphorescent dye doped Polymer Light Emitting Diodes

  • Kim, Jang-Joo;Jeong, W.I.;An, Cheng-Guo;Kang, J.W.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.166-166
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    • 2006
  • The photoluminescence (PL) efficiency of $Ir(ppy)_{3}$:PVK is lower than $Ir(ppy)_{3}$:CBP for the whole range of doping concentration and this low PL efficiency can be a reason of the lower efficiency of PhPLED than PhOLED. The lower efficiency is originated from the large bi-excitonic quenching such as the triplet-triplet annihilation. The PhPLEDs showed very short lifetime. The short lifetime was found to be originated from the instability of the doubly reduced $Ir(ppy)_{3^{-2}}$. The double reduction takes place because of the low electron mobility of PVK and large energy difference of LUMO level between PVK and $Ir(ppy)_{3}$.

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