• Title/Summary/Keyword: OH 라디칼 자발광

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OH-and CH-Radical Chemiluminescence Characteristics in the Spray Combustion of Ultransonically Atomized Kerosene (초음파에 의해 무화된 케로신 분무연소에서의 OH 라디칼 및 CH 라디칼 자발광 특성)

  • Kim, Min Cheol;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.1
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    • pp.72-79
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    • 2018
  • An experimental study was performed to investigate the chemiluminescence characteristics in the spray combustion of ultransonically atomized kerosene. The radical intensity of the spray flame was measured using an ICCD camera and the amount of fuel consumed was obtained by a precise flow-rate measurement technique during combustion. Fuel consumption increased linearly with the increase in carrier-gas flow rate, and typical group combustion, which is a characteristic of spray combustion, was observed. It was found from the analysis of chemiluminescence that the maximum emission intensities of OH and CH radicals decrease, and they move downstream resulting in the increase in a vivid reaction zone as the spray flow rate increases.

Characteristics of Chemiluminescence Intensities of Kerosene/Air Swirl Flames (케로신/공기 와류 화염의 화학발광 세기 특성에 관한 실험적 연구)

  • Lee, Hyeonjae;Seo, Seonghyeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.6
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    • pp.485-496
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    • 2015
  • The present study presents experimental results on the characteristics of emission spectra of kerosene/air swirl flames. The aviation fuel Jet A-1, which is used for the liquid rocket engines of the Korea Space Launch Vehicle, is used with three different swirlers to investigate the swirl strength effects. The emission spectra from the flames are measured with a spectrometer as the swirl strength and combustion air temperature are varied. Chemiluminescence intensities of $OH^*$, $CH^*$ and $C_2{^*}$ are identified from the spectra. The chemiluminescence intensities from the kerosene flames show sensitivity to the swirl strength and are affected by changes in the combustion air temperature. Among the three radicals of interest, $C_2{^*}$ show the most significant changes in chemiluminescence intensity with the swirl strength and equivalence ratio. The intensity ratios $I_{OH^*}/I_{CH^*}$ and $I_{C_2{^*}}/I_{CH^*}$ are adequate for indicating changes in the equivalence ratio with the air and fuel mass flow rates, respectively.

Symptoms on Generation of Combustion Oscillation and their Detection (진동연소 발생에 관한 징후와 이의 검출)

  • 양영준
    • Journal of Energy Engineering
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    • v.13 no.3
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    • pp.205-213
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    • 2004
  • Usefulness of an optical fiber was demonstrated by detecting the generation of self-excited combustion oscillations. OH chemiluminescence intensity detected by the optical fiber showed mostly excellent agreement with those obtained by high speed CCD camera measurements when combustion oscillations were strong. Symptoms of self-excited combustion oscillation were also studied in order to predict the onset of combustion oscillation before it proceeded to a catastrophic failure. For the purpose, we have found and proposed unique measures to tell the onset of self-excited combustion oscillations based on the careful statistics of fluctuating properties in flames, such as pressure or omission of OH radicals.

Effects of Swirl/Shear-coaxial Injector on the Dynamic Behavior of Gaseous Methane-Gaseous Oxygen Diffusion Flame (스월/전단 동축형 인젝터가 기체메탄-기체산소 확산화염의 동역학적 거동에 미치는 영향)

  • Hong, Joon Yeol;Bae, Dae Seok;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.1-8
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    • 2019
  • To analyze the dynamic behavior and the structure of the gaseous methane-gaseous oxygen diffusion flame formed by a swirl/shear-coaxial injector, combustion experiments were carried out under different propellant injection conditions. As a result, the OH radical emission intensity of the diffusion flame visualized through chemiluminescence was observed to increase as the propellant mass flow and the momentum flux ratio increased. And flames with swirl showed a more high radical emission intensity than those without swirl.

Effects of the Recess and Propellants Mass Flow on the Flammability Limit and Structure of Methane-Oxygen Diffusion Flame (인젝터 리세스와 추진제 공급유량이 메탄-산소 확산화염의 가연한계와 구조에 미치는 영향)

  • Hong, Joon Yeol;Bae, Seong Hun;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.1
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    • pp.28-35
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    • 2018
  • In order to analyze the flammability limit and structure of the gaseous methane-gaseous oxygen diffusion flame formed through a shear coaxial injector, combustion experiments were carried out according to the condition of injector recess and propellant mass-flow rate. As a result, it was confirmed that stable anchored flame was observed even at the high oxygen Reynolds number as the propellant momentum flux ratio increased, and that the recess had no significant influence on the flame shape and flammability limit. The anchored flame visualized through a chemiluminescence showed the maximum OH radical emission intensity at a specific position, irrespective of the propellant injection condition, and the radical intensity was greatly reduced by the injector recess.

A Study of Characteristics of Combustion Radical and Exhausted Emissions in a Radiant Burner with Porous Ceramic Mat (다공성 세라믹 매트를 이용한 복사버너에서의 연소라디칼 특성과 배기배출물에 관한 연구)

  • Kim, Young-Su;Cho, Seung-Wan;Kim, Gyu-Bo;Chang, Young-June;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.6 s.261
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    • pp.539-546
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    • 2007
  • An experimental study was performed to investigate the characteristics of chemiluminescence in a radiant burner, varying the excess air ratio from 0.91 to 1.67 at firing rate 80.5 to 134.2 kW/m2 on $OH^*,\;CH^*,\;{C_2}^*$ in LNG-Air premixed flames. The signals from electronically excited states of $OH^*,\;CH^*,\;{C_2}^*$ were detected using a Intensified Couple Charged Detector (ICCD) camera. The measurements of exhausted emission were made to investigate the correlation between chemiluminescence and emissions. The chemiluminescence intensity was increased with increase of firing rate like characteristics of $NO_x$ emission. $NO_x$ also increased with increase of firing rate and excess air ratio. It is found that offset of firing rate is more dominant excess air ratio $NO_x$ emission. The maximum chemiluminescence intensity occurs near the stoichiometric excess air ratio or lean conditions in case of high firing rate and the maximum intensity occurs rather than rich conditions in case of relatively low firing rate. Amount of $NO_x$ emission is maximum at near stoichiometric excess air ratio, which is chemiluminescence intensity is maximum.

Detailed Local Chemiluminescence Measurement (OH*, CH* and C2*) and Nitrogen Oxides Emissions in Laminar Partially Premixed CH4/Air Flames (메탄/공기 층류 부분예혼합화염의 상세 라디칼(OH*, CH* 그리고 C2*) 정보와 배기매출물에 관한 실험적 연구)

  • Jeong Yong Ki;Oh Jeong Seog;Jeon Chung Hwan;Chang Young June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.2 s.233
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    • pp.263-270
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    • 2005
  • An experimental study was performed to investigate the effects of partially premixing, varying the equivalence ratios from $0.79{\sim}{\infty}$, on NOx emissions and chemiluminescence of excited $OH^{\ast},\;CH^{ast}\;C_2^{\ast}$ radicals in laminar partially premixed flames. the signal from the electronically excited state of $OH^{\ast},\;CH^{ast}\;C_2^{\ast}$ was detected through a band pass filter with a photo multiplier tube, which are processed to the intensity ratio ($C_2^{\ast}/CH^{\ast},\;C_2^{\ast}/OH^{\ast},\;and\;CH^{\ast}/OH^{\ast}$) to reveal the correlation with local equivalence ratio. And measurements of NOx emission were made to investigate the relationship between visible flame appearance, chemiluminescence, and EINOX. The results demonstrated that (1) the flames at ${\phi}<1.59$ exhibited classical double flame structure, at ${\phi}>4.76$, the flames exhibited diffusion flame structure, and the intermediate flames at $1.59<{\phi}<4.76$ was a merged flame, (2) the $OH^{\ast}$ peak was located inside the $CH^{\ast}\;and\;C_2^{\ast}$ radical for all measured conditions and the emission intensity ratio of $C_2^{\ast}/CH^{\ast}\;and\;C_2^{\ast}/OH^{\ast}$ were identified as good marker for local equivalence ratio over a range of ${\phi}=0.79{\sim}1.2\;and\;CH^{\ast}/OH^{\ast}\;is\;0.79<{\phi}<1.9$. However, it was difficult to predict the equivalence ratio in partially premixed flames using this system for ${\phi}>2.38$, (3) the minimum NOX emission index (EINOx) is obtained for a equivalence ratio of 3.19 in the intermediate flames.

An Experimental Study on Flame Structure and Combustion Characteristics of Turbulent Diffusion Flame(III) (난류확산화염의 화염구조와 연소특성에 관한 실험적 연구)

  • Jang, In-Gap;Choe, Gyeong-Min;Choe, Byeong-Ryun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.7
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    • pp.2326-2336
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    • 1996
  • So most practical combustor is considered to the swirl flame, it is very important to examinate swirl flame structure and combustion characteristics. Recently, attention has been paid to the flame diagnostic by radical luminous intensity. For swirl flame structure and combustion characteristic, reverse flow boundary, temperature, ion current and radical luminous intensity were measured in the double-coaxial swirl combustor which was used principle of multi-annular combustor. This study had three experimental condition, S-type, C-type, SC-type. S-type and C-type flames were formed recirculation zone, but SC-type flame wasn't formed. C-type flame had two recirculation zone. The position with maximum value of ion current and CH-radical, temperature and OH-radical had similarity distribution almost. Therefore, it is possible that the macro structure of flame was measured by radical luminous intensity in the high intensity of turbulent combustion field which was formed by swirl.

Combustion Characteristics of Model Gas Turbine Combustor -Radical Luminous Intensity and Local Equivalence Ratio Measurement- (모형 가스터빈 연소기의 연소특성 -라디칼 자발광강도와 국소당량비계측에 대하여-)

  • 최병륜;김태한
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.4
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    • pp.1064-1071
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    • 1994
  • There are three active radicals which become to the scale of flame diagnostics at the flame front. They are OH, CH and $C_2$ radical. For this, optical measurement system which could monitor simultaneously the luminous waves of three radicals, was constructed. These were analyzed statistically into the cross correlation, coherence and phase. Through such an statistical treatment, combustion characteristics was investigated at the primary zone of gas turbine combustor. The local equivalence ratio was predicted with the ratio of luminuous intensity between CH and $C_2$ radical. This result was matched up to the equivalence ratio calculated from gas composition within 5% error. In general, equivalence ratio was said to be 1.0 at flame front, but it could be increased up to about 1.2 depending on the degree of swirl intensity in case of changing properly the air amount of primary zone.