• Title/Summary/Keyword: OCV

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Effect of Compensation for Thickness Reduction by Chemical Degradation of PEMFC Membrane on Performance and Durability (PEMFC 고분자막의 화학적인 열화에 의한 두께 감소 보정이 성능 및 내구성에 미치는 영향)

  • Sohyeong Oh;Yoojin Kim;Seungtae Lee;Donggeun Yoo;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.62 no.1
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    • pp.1-6
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    • 2024
  • As the demand for hydrogen electric vehicles for commercial vehicles increases, the durability of PEMFCs must increase more than five times that of passenger cars, so research and development to improve durability is urgent. When the PEMFC membrane electrode assembly (MEA) undergoes chemical degradation, the MEA thickness decreases and pinholes occur. In this study, changes in the performance and durability of the MEA were measured while increasing the clamping pressure of the unit cell after open circuit voltage (OCV) holding, an accelerated chemical degradation experiment. As the clamping pressure increased, the resistance of the polymer membrane and the membrane/electrode contact resistance decreased, improving the I-V performance and reducing the hydrogen permeability. As the hydrogen permeability decreased, the OCV increased. When the pinhole area was removed and the MEA clamping pressure was increased, the hydrogen permeability decreased sharply, confirming that the local degradation has a large effect on the performance and durability of the entire cell. When the pinhole was removed and re-clamping and OCV holding was evaluated, it was confirmed that the durability improved according to the decrease in membrane resistance and hydrogen permeability.

Validation of Nursing-sensitive Patient Outcomes;Focused on caregiver outcomes (간호결과분류(NOC)에 대한 타당성 검증;돌봄제공자 결과를 중심으로)

  • Yom, Young-Hee;Yee, Jung-Ae;Ahn, Soo-Yeon;Lee, Myung-Ok
    • Journal of Korean Academy of Nursing Administration
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    • v.6 no.2
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    • pp.245-257
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    • 2000
  • The purpose of this study was to validate caregiver outcomes included Nursing Outcomes Classification(NOC) developed by Johnson and Maas at the University of Iowa. A sample of 73 nurse experts working in university affiliated hospitals participated in this study. They were asked to rate indicators that examplified the outcomes on a scale of 1(indicator is not at all characteristic) to 5(indicator is very characteristic). A questionnaire with an adaptation of Fehring's methodology was used to establish the content validity of outcomes. The results were as follow: 1. Eight outcome label were considered to be 'supporting' and three outcome label were considered to be 'nonsupporting'. 2. 'Caregiver-Patient Relationship' attained an OCV score of 0.64 and the highest OCV score among caregiver outcomes.. 3. 'Caregiver Emotional Health' attained an OCV score of 0.54 and the lowest OCV score among caregiver outcomes. Replication study will be needed and outcomes sensitive to Korean culture need to be developed.

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A study on the Characteristics of In-Cylinder Intake Flow in Spark Ignition Engine Using the PIV

  • Lee Suk-Young;Jeong Ku-Seob;Jeon Chung-Hwan;Chang Young-June
    • Journal of Mechanical Science and Technology
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    • v.19 no.2
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    • pp.704-715
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    • 2005
  • In this study, to investigate in-cylinder tumble or swirl intake flow of a gasoline engine, the flow characteristics were examined with opening control valve (OCV) and several swirl control valves (SCV) which intensify intake flow through steady flow experiment, and also turbulent characteristics of in-cylinder flow field were investigated by 2-frame cross-correlation particle image velocimetry (PIV) method. In the investigation of intake turbulent characteristics using PIV method, the different flow characteristics were showed according to OCV or SCV figures. The OCV or SCV installed engine had higher vorticity and turbulent kinetic energy than a baseline engine, especially around the wall and lower part of the cylinder. Above all, SCV B type was superior to the others. About energy dissipation and reynolds shear stress distribution, a baseline engine had larger loss than OCV or SCV installed one because flow impinged on the cylinder wall. It should be concluded, from what has been said above, as swirl component was added to existing tumble flow adequately, it was confirmed that turbulent intensity was enlarged, flow energy was conserved effectively through the experiment. In other words, there is a suggestion that flow characteristics as these affected to in-cylinder combustion positively.

Electrochemical Evaluation of Etching Characteristics of Copper Etchant in PCB Etching (PCB 구리 에칭 용액의 에칭 특성에 대한 전기화학적 고찰)

  • Lee, Seo-Hyang;Lee, Jae-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.4
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    • pp.77-82
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    • 2022
  • During etching process of PCB, the electroplated copper line and seed layer copper have different etching rates and it caused the over etching of copper line as well as undercut of lines. In this research, the effects of etchants composition on copper etching characteristics were investigated. The optimum concentration of hydrogen peroxide and sulfuric acid of etchants were obtained using polarization and OCV (open circuit voltage) analysis for both rolled copper and electroplated copper. The inhibiting effects of different inhibitors were investigated using OCV and ZRA (zero resistance ammeter) analysis. The galvanic current between electroplated copper and seed layer copper were measured using ZRA method. Inhibitors for least galvanic current could be chosen based on galvanic coupling in ZRA analysis.

Decrease of Membrane Degradation in PEMFC by Fucoidan (후코이단에 의한 PEMFC 고분자막의 열화 감소)

  • Oh, Sohyung;Kak, Ahyeon;Oh, Sungjun;Lee, Daewoong;Na, Il-Chai;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.58 no.1
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    • pp.59-63
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    • 2020
  • Radical scavenger is used to improve the durability of PEMFC polymer membrane. In this study, we investigated whether fucoidan extracted from seaweed as a radical scavenger prevents electrochemical degradation through Fenton and OCV Holding experiments. Fucoidan has an antioxidant effect, protecting the polymer membrane from hydrogen peroxide and oxygen radicals, reducing the degradation rate to 1/10. Fucoidan has been shown to be more effective than MnO2, which is used as a radical scavenger. In the PEMFC cell, the accelerated durability evaluation method (OCV Holding) showed that fucoidan reduced the hydrogen permeability of the polymer membrane by 12% and enhanced the performance by 29.1% compared to without radical scavenger. And fucoidan was found to be more effective in the cathode side ionomer than the anode side.

A 6-Week Oral Toxicity Study of Oral Cholera Vaccine in Sprague-Dawley Rats

  • Baek, Yeong-Ok;Choi, Seuk-Keun;Shin, Seo-Ho;Koo, Kyo-Hwan;Choi, Ho-Young;Cha, Seung-Bum;Li, Yong-Chun;Yoo, Hyeon-Jeong;Lee, Joo-Young;Kil, Ki-Hyun;Kim, Hak-Soo;Kang, Min-Soo;Kang, Boo-Hyun;Kim, Kap-Ho;Bae, Jin-Sook
    • Toxicological Research
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    • v.28 no.4
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    • pp.225-233
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    • 2012
  • The present study was carried out to examine the toxicity and target organs of oral cholera vaccine (OCV) after repeated oral administration in Sprague-Dawley rats for 6 weeks (3 administrations, once every 2 weeks). OCV is an inactivated oral cholera vaccine that contains Vibrio cholerae and confers protection against cholera caused by V. cholera serogroups O1 (Inaba and Ogawa serotypes) and O139 (strain 4260B). The animals were orally administered either OCV placebo (negative control) or OCV at a dose equivalent to 240 times the anticipated human dose. Throughout the administration period, no significant change was detected in clinical signs, body weight, food or water consumption, urinalysis results, hematological and clinical biochemistry test results, organ weights, necropsy, or histopathological examination results. Minor changes were found in hematological and clinical biochemistry tests; however, these changes were within normal ranges. The above results suggest that oral administration of OCV in rats did not induce any toxicologically meaningful changes, and the target organs could not be determined. This study was conducted in accordance with the guidelines established by Good Laboratory Practice (2009-183, KFDA, December 22, 2009) and the OECD Principles of Good Laboratory Practice (1997).

Operating Characteristics on Coupling of Fuel-Cell System with Natural Gas Reformer (휴대전원용 직접알코올 연료전지의 OCV특성 연구)

  • Park, Se-Joon;Choi, Yong-Sung;Lee, Kyung-Sup
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.58 no.4
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    • pp.592-596
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    • 2009
  • DAFC(direct alcohol fuel cell) takes the same structure and operational principle with PEMFC(Proton exchange membrane fuel cell). However, DAFC, which uses liquid alcohol instead of hydrogen as fuel, is able to be used as a portable power for small-scaled electronic devices such as MP3, PMP, and mobile phone because alcohol is quite convenient steady-state compound to carry and store it. This paper presents the OCV(open circuit voltage) characteristics of the cases which are alcohol species and different weight rate of ethanol, respectively. The OCV of methanol fuel cell is slightly higher 0.2V than ethanol one, and 8% wt. rate ethanol is rated as the most appropriate fuel for DAFC.

Online SOH Estimation Algorithm Based on Aging Tendency of Open Circuit Voltage and Low Pass Filter (OCV 곡선의 노화 경향과 저주파 통과 필터를 이용한 실시간 SOH 추정 알고리즘)

  • Noh, Tae-Won;Bae, Jeong Hyun;Han, Hae-Chan;Lee, Byoung Kuk
    • Proceedings of the KIPE Conference
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    • 2019.07a
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    • pp.47-49
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    • 2019
  • 본 논문은 노화로 인하여 감소하는 전기자동차용 배터리의 전류 용량을 실시간으로 추정하는 SOH (State-of-health) 알고리즘을 제안한다. 제안하는 알고리즘은 노화에 따른 OCV (Open circuit voltage) 곡선의 변화 경향을 분석하고, 저주파 통과 필터를 이용하여 추정된 OCV를 기반으로 전류 용량 및 SOH를 산출한다. 알고리즘을 검증하기 위하여 전기자동차용 배터리를 이용한 실험 및 시뮬레이션을 진행한다.

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Machine Learning-based SOH Estimation Algorithm Using a Linear Regression Analysis (선형 회귀 분석법을 이용한 머신 러닝 기반의 SOH 추정 알고리즘)

  • Kang, Seung-Hyun;Noh, Tae-Won;Lee, Byoung-Kuk
    • The Transactions of the Korean Institute of Power Electronics
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    • v.26 no.4
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    • pp.241-248
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    • 2021
  • A battery state-of-health (SOH) estimation algorithm using a machine learning-based linear regression method is proposed for estimating battery aging. The proposed algorithm analyzes the change trend of the open-circuit voltage (OCV) curve, which is a parameter related to SOH. At this time, a section with high linearity of the SOH and OCV curves is selected and used for SOH estimation. The SOH of the aged battery is estimated according to the selected interval using a machine learning-based linear regression method. The performance of the proposed battery SOH estimation algorithm is verified through experiments and simulations using battery packs for electric vehicles.

Analysis of Water Transport through Measurement of Temperature and Relative Humidity in PEMFC at OCV (개방회로 상태 PEMFC 내부 온도와 습도 측정을 통한 수분투과 분석)

  • KIM, TAEHYEONG;HAN, JAESU;YU, SANGSEOK
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.4
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    • pp.353-362
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    • 2022
  • In this study, water diffusion in proton exchange membrane fuel cell at open circuit voltage (OCV) was analyzed through experiment. First, the reliability of the micro-sensor (SHT31) was verified. It was concluded the micro-sensor has an excellent reliability at 60℃ and 70℃. After the sensor reliability test, the temperature and relative humidity measurement in bipolar-plate was conducted at OCV. To analyze water distribution and water flux, the temperature and relative humidity was converted into dew point. To the end, it was found water concentration affects water diffusion.