• Title/Summary/Keyword: OCT

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Depth-resolved Stokes parameters of light backscattered from turbid media with polarization-sensitive optical coherence tomography system and successive phase-shifting algorithm (위상천이원리 와 PS-OCT시스템을 적용한 역산란광의 매질 깊이별 스톡스변수 추출)

  • Oh, Jung-Taek;Kim, Seung-Woo
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.02a
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    • pp.286-287
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    • 2003
  • Polarization-sensitive optical coherence tomography (PS-OCT) was developed to image highly scattering tissues with accounting for polarization effects in the sample. These polarization-sensitive images can provide additional information on the structure of the tissue because of a polarization state of the light is changed at its interaction with biological tissues. The scattering and birefringence are two phenomena, which change the polarization state of light passing through medium. (omitted)

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$\pi$-Participation in Bicyclo [3.2.1]oct-6-en-2-yl Cation. $^{19}F$ NMR Spectroscopy as a Probe

  • Chae Jong-Kun;Shin Jung-Hyu
    • Bulletin of the Korean Chemical Society
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    • v.15 no.1
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    • pp.12-14
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    • 1994
  • p-Fluorophenyl bicyclo[3.2.l]oct-6-en-2-yl cation (3) prepared in $FSO_3H-SO_2-CIF$ solution at -90$^{\circ}$C and examined by fluorine-19 nmr spectroscopy. The nmr data give a clear evidence for the formation of a stabilized ${\pi}$-bridging cation species in superacids. The degree of ${\pi}$delocalization in this cation is found to be inferior to the onset of nonclassical stabilization in 2-norbornenyl cation.

Synthesis and Properties of Novel Flame-Retardant and Thermally Stable Poly(amideimide)s from N,N'-(bicyclo[2,2,2]oct-7-ene-tetracarboxylic)-bis-L-amino Acids and Phosphine Oxide Moiety by Two Different Methods

  • Faghihi, Khalil;Hajibeygi, Mohsen;Shabanian, Meisam
    • Macromolecular Research
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    • v.17 no.10
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    • pp.739-745
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    • 2009
  • N,N'-(bicyclo[2,2,2]oct-7-ene-tetracarboxylic)-bis-L-amino acids 3a-g were synthesized by the condensation reaction of bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride 1 with two equimolars of Lalanine 2a, L-valine 2b, L-leucine 2c, L-isoleucine 2d, L-phenyl alanine 2e, L-2-aminobutyric acid 2f and L-histidine 2g in an acetic acid solution. Seven new poly(amide-imide)s PAIs 5a-g were synthesized through the direct polycondensation reaction of seven chiral N,N'-(bicyclo[2,2,2]oct-7-ene-tetracarboxylic)-bis-L-amino acids 3a-g with bis(3-amino phenyl) phenyl phosphine oxide 4 by two different methods: direct polycondensation in a medium consisting of N-methyl-2-pyrrolidone (NMP)/triphenyl phosphite (TPP)/calcium chloride ($CaCl_2$/pyridine (py), and direct polycondensation in a tosyl chloride (TsCl)/pyridine (py)/N,N-dimethylformamide (DMF) system. The polymerization reaction produced a series of flame-retardant and thermally stable poly(amide-imide)s 5a-g with high yield. The resulted polymers were fully characterized by FTIR, $^1H$ NMR spectroscopy, elemental analyses, inherent viscosity, specific rotation and solubility tests. Data obtained by thermal analysis (TGA and DTG) revealed that the good thermal stability of these polymers. These polymers can be potentially utilized in flame retardant thermoplastic materials.

Effects of Sowing Date and Cutting Time on Feed Value of Rye in Paddy Field (파종기와 예취시기가 답리작 호밀의 동료가치에 미치는 영향)

  • ;Je-Cheon Chae
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.39 no.6
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    • pp.519-525
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    • 1994
  • This experiment was conducted to investigate the effects of sowing date and cutting time on feed value of rye in paddy field at Yesan from Oct. 1990 to June 1991. The field experiment was sown 5 times at 10 day intervals from Oct. 5. The content of crude protein, digestible protein, total digestible nutrient(TDN), minerals(P, K, Ca, Mg), and energy(ENE, NEL, NEM, NEG) were decreased due to earlier sowing, while the content of acid detergent fiber (ADF) and neutral detergent fiber(NDF) increased. On the other hand, the yields per unit area for crude and digestible protein, TDN, minerals, and energy increased due to earlier sowing, but there was no significant difference among the plots sown on Oct. 5 through Oct. 25. The highest yield of crude protein was shown at late flowering stage, digestible protein and net energy gain (NEG) at heading stage and TDN at milk stage respectively.

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( Partitioning of Carbon and Nitrogen Reserves During Winter Adaptation and Spring Regrowth IV. Effect of seeding date on the content of organic reserves on the wintering period and forage yeild in rape ( Brassica napus L. ) (저장탄수화물과 질소의 월동성과 재생활력에 대한 이용성 IV. 추파 유채 ( Brassica napus L. ) 의 파종시기가 월동중 저장유기물 함량 및 수량에 미치는 영향)

  • 김태환;김기원;정우진;전해열;김병호
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.16 no.1
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    • pp.1-8
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    • 1996
  • The objective of this study is to obtain the basic data for investigating the effects of organic reserves on winter survial or regrowth yield. Forage rape (Brussicu napus L.) was sown at 10 day> interval from Sep. I to Nov. 1. Field-grown palnts were sampled on the before wintering (Dec. 4) and on the wintering period (Jan. 16) to analyze the nitrogen and non-structural cahohydrate reserves. The rate of winter survival and regrowth yield were also measured in the spring of next year. On the before wintering, the dry matter yields from the plots sown on Sep. 1, Sep.11 and Sep. 21 were 860, 596 and 260 kg/lOa, respectively. No. harvest was canied out on the plots sown after Oct. 1 because the growth state was not enough to cut. Both of nitrogen and starch contents per plant significantly increased as the seeding date was later. On the wintering period, the contents of nitrogen reserves in roots were 176.8. 120.1, 71.7, 84.0, 72.1, 45.3 and 33.3 mg/plant, those of starch reserves were 199.0. 55.8, 21.8, 92.6, 86.5, 36.4 and 29.0 mglplant, resepctively, in the plots sown on Sep. 1, Sep. 11, Sep. 21, Oct. I, Oct. 11, Oct. 21 and Nov. 1. The rates of winter survival were 40, 36, 33, 85, 87, 59 and 49% and regrowth yields were 161, 86, 65, 520, 451, 121 and 33 kgD.M/lOa, respectively, in each plots. 'Ihese results clearly showed that seeding date has a close influence on the level of organic reserves and forage yield, and that the possibility of continuous utilization on the before and alter wintering is extremely limited by seeding date.

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Characteristics and Ring-Opening Isomerization Polymerization of 2-(1,3,3-Trimethyl-6-azabicyclo[3,2,1]-oct-6-yl)-4,5-dihydro-1,3-oxazoline (TAO) (2-(1,3,3-Trimethyl-6-azabicyclo[3,2,1]-oct-6-yl)-4,5-dihydro-1,3-oxazoline(TAO)의 개환이성화중합과 특성평가)

  • Lee, Chan-Woo;Chung, Jin-Do
    • Polymer(Korea)
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    • v.36 no.3
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    • pp.262-267
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    • 2012
  • 2-(1,3,3-Trimethyl-6-azabicyclo [3,2,1]-oct-6-yl)-4,5-dihydro-1,3-oxazoline (TAO) was polymerized at several conditions to clarify the influence of initiators, alkyl halide ($PhCH_2Br$, $PhCH_2Cl$, MeI) and sulfonate (MeOTf). The reactions were conducted at $100^{\circ}C$ for 24 h. The resultant polymer forms several kinds of structures with different combination of initiators. The sole MeOTf initiator caused chain transfer reaction to form the one-order structure for which the resultant polymer exclusively formed pendant structure, while alkyl halide and MeOTf formed two kinds of structures, pendant and main chain, which is caused by partly-proceeded double isomerization polymerization by highly reactive nucleophilic counter anion of halogen. Merrifield polymer was also utilized as an intiator and copolymerized with TAO, which produced a graft structure.

Ultrahigh-Resolution Spectral Domain Optical Coherence Tomography Based on a Linear-Wavenumber Spectrometer

  • Lee, Sang-Won;Kang, Heesung;Park, Joo Hyun;Lee, Tae Geol;Lee, Eun Seong;Lee, Jae Yong
    • Journal of the Optical Society of Korea
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    • v.19 no.1
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    • pp.55-62
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    • 2015
  • In this study we demonstrate ultrahigh-resolution spectral domain optical coherence tomography (UHR SD-OCT) with a linear-wavenumber (k) spectrometer, to accelerate signal processing and to display two-dimensional (2-D) images in real time. First, we performed a numerical simulation to find the optimal parameters for the linear-k spectrometer to achieve ultrahigh axial resolution, such as the number of grooves in a grating, the material for a dispersive prism, and the rotational angle between the grating and the dispersive prism. We found that a grating with 1200 grooves and an F2 equilateral prism at a rotational angle of $26.07^{\circ}$, in combination with a lens of focal length 85.1 mm, are suitable for UHR SD-OCT with the imaging depth range (limited by spectrometer resolution) set at 2.0 mm. As guided by the simulation results, we constructed the linear-k spectrometer needed to implement a UHR SD-OCT. The actual imaging depth range was measured to be approximately 2.1 mm, and axial resolution of $3.8{\mu}m$ in air was achieved, corresponding to $2.8{\mu}m$ in tissue (n = 1.35). The sensitivity was -91 dB with -10 dB roll-off at 1.5 mm depth. We demonstrated a 128.2 fps acquisition rate for OCT images with 800 lines/frame, by taking advantage of NVIDIA's compute unified device architecture (CUDA) technology, which allowed for real-time signal processing compatible with the speed of the spectrometer's data acquisition.