• 천문학회지
• /
• 제34권4호
• /
• pp.309-311
• /
• 2001

Strong thermal X-ray emission, called Galactic Ridge X-ray Emission, is observed along the Galactic plane (Koyama et al. 1986). The origin of hot ($\~$7 keV) component of GRXE is not known, while cool ($\~$0.8 keV) one is associated with supernovae (Kaneda et al. 1997, Sugizaki et al. 2001). We propose a possible mechanism to explain the origin; locally strong magnetic fields of $B_{local}\;\~30{\mu}G$ heat interstellar gas to $\~$7 keV via magnetic reconnection (Tanuma et al. 1999). There will be the small-scale (< 10 pc) strong magnetic fields, which can be observed as $(B)_{obs} \;\~3{\mu}G$ by integration of Faraday Rotation Measure, if it is localized by a volume filling factor of f $\~$ 0.1. In order to examine this model, we solved three-dimensional (3D) resistive magnetohydrodynamic (MHD) equations numerically to examine the magnetic reconnect ion triggered by a supernova shock (fig.l). We assume that the magnetic field is Bx = 30tanh(y/20pc) $\mu$G, By = Bz = 0, and the temperature is uniform, at the initial condition. We put a supernova explosion outside the current sheet. The supernova-shock, as a result, triggers the magnetic reconnect ion, and the gas is heatd to > 7 keV. The magnetic reconnect ion heats the interstellar gas to $\~$7 keV in the Galactic plane, if it occurs in the locally strong magnetic fields of $B_{local}\;\~30{\mu}G$. The heated plasma is confined by the magnetic field for $\~10^{5.5} yr$. The required interval of the magnetic reconnect ions (triggered by anything) is $\~$1 - 10 yr. The magnetic reconnect ion will explain the origin of X-rays from the Galactic ridge, furthermore the Galactic halo, and clusters of galaxies.

• Bulletin of the Korean Chemical Society
• /
• 제35권1호
• /
• pp.51-56
• /
• 2014

The solvolysis rate constants of 2,4-dimethoxybenzenesulfonyl chloride (1) in 30 different solvents are well correlated with the extended Grunwald-Winstein equation, using the $N_T$ solvent nucleophilicity scale and $Y_{Cl}$ solvent ionizing scale, with sensitivity values of $0.93{\pm}0.14$ and $0.65{\pm}0.06$ for l and m, respectively. These l and m values can be considered to support a $S_N2$ reaction pathway. The activation enthalpies (${\Delta}H^{\neq}$) were 12.4 to $14.6kcal{\cdot}mol^{-1}$ and the activation entropies (${\Delta}S^{\neq}$) were -15.5 to -$32.3kcal{\cdot}mol^{-1}{\cdot}K^{-1}$, which is consistent with the proposed bimolecular reaction mechanism. The solvent kinetic isotope effects (SKIE) were 1.74 to 1.86, which is also in accord with the $S_N2$ mechanism and was possibly assisted using a general-base catalysis. The values of product selectivity (S) for solvolyses of 1 in alcohol/water mixtures was 0.57 to 6.5, which is also consistent with the proposed bimolecular reaction mechanism. Third-order rate constants, $k_{ww}$ and $k_{aa}$, were calculated from the rate constants ($k_{obs}$), together with $k_{aw}$ and $k_{wa}$ calculated from the intercept and slope of the plot of 1/S vs. [water]/[alcohol]. The calculated rate constants, $k_{calc}$ ($k_{ww}$, $k_{aw}$, $k_{wa}$ and $k_{aa}$), are in satisfactory agreement with the experimental values, supporting the stoichiometric solvation effect analysis.

• Bulletin of the Korean Chemical Society
• /
• 제24권3호
• /
• pp.350-356
• /
• 2003

The mechanism of the decomposition of a bronchodilator, S-nitroso-N-acetyl-D,L-penicillamine (SNAP) by a bronchoconstrictor, aqueous sulfite, has been investigated in detail. The decomposition was studied using a conventional spectrophotometer at 336 nm over the ranges: 0.010 ≤ $[S^{IV}]_T$ ≤ 0.045 mol $dm^{-3}$, 3.96 ≤ pH ≤ 6.80 and 15.0 ≤ θ≤ 30.0 ℃, 0.60 ≤ I ≤ 1.00 mol $dm^{-3}$, and at ionic strength 1.00 mol $dm^{-3}$ (NaCl). The rate of reaction is dependent on the total sulfite concentration and pH in a complex manner, i.e., $k_{obs}\;=\;k_1K_2[S^{IV}]_T/ ([H^+]\;+\;K_2)$. At 25.0 ℃, the second order rate constant, $k_1$, was determined as $12.5\;{\pm}\;0.15\;mol^{-1}\;dm^3\;s^{-1}$. ${\Delta}H^{neq}\;=\;+32\;{\pm}\;3 kJ\;mol^{-1}\;and\;{\Delta}S^{\neq}\;=\;-138\;{\pm}\;13\;J\;mol^{-1}K^{-1}$. The N-nitrosohydroxylamine-N-sulfonate ion was detected as an intermediate before the formation of any of the by-products, namely, N-acetyl-D,L-penicillamine. The effect of concentration of aqueous copper(Ⅱ) ions on this reaction was also examined at pH 4.75, but there was no dependence on $[Cu^{2+}]$. In addition, the $pK_a$ of SNAP was determined as 3.51 ± 0.06 at 25.4 ℃ [I = 1.0 mol $dm^{-3}$ (NaCl)].

• Journal of Microbiology and Biotechnology
• /
• 제20권12호
• /
• pp.1653-1663
• /
• 2010

The first gene (${\alpha}$-gal1) encoding an extracellular ${\alpha}$-Dgalactosidase from the thermophilic fungus Talaromyces emersonii was cloned and characterized. The ${\alpha}$-gal1 gene consisted of an open reading frame of 1,792 base pairs interrupted by six introns that encoded a mature protein of 452 amino acids, including a 24 amino acid secretory signal sequence. The translated protein had highest identity with other fungal ${\alpha}$-galactosidases belonging to glycosyl hydrolase family 27. The ${\alpha}$-gal1 gene was overexpressed as a secretory protein with an N-terminal histidine tag in the methylotrophic yeast Pichia pastoris. Recombinant ${\alpha}$-Gal1 was secreted into the culture medium as a monomeric glycoprotein with a maximal yield of 10.75 mg/l and purified to homogeneity using Hisbinding nickel-agarose affinity chromatography. The purified enzyme was maximally active at $70^{\circ}C$, pH 4.5, and lost no activity over 10 days at $50^{\circ}C$. ${\alpha}$-Gal1 followed Michaelis-Menten kinetics ($V_{max}\;of\;240.3{\mu}M/min/mg,\;K_m\;of\;0.294 mM$) and was inhibited competitively by galactose ($K_m{^{obs}}$ of 0.57 mM, $K_i$ of 2.77 mM). The recombinant T. emersonii ${\alpha}$-galactosidase displayed broad substrate preference, being active on both oligo- and polymeric substrates, yet had strict specificity for the ${\alpha}$-galactosidic linkage. Owing to its substrate preference and noteworthy stability, ${\alpha}$-Gal1 is of particular interest for possible biotechnological applications involving the processing of plant materials.

• 천문학논총
• /
• 제30권2호
• /
• pp.699-701
• /
• 2015

The high plateaus in west China may provide suitable sites for astronomical observations with the institute's middle-range telescopes and possibly with larger telescopes. Under China-Japan collaborations for site survey in west China, we have been conducting searches for good sites and monitoring their characteristics over several years. As recent results of our site survey show, sites in west Tibet are revealed with a high possibility of good astronomical observations. Weather characteristics at Gar in Ali, Tibet, show its high clear-sky ratios, especially in winter, comparable to Mauna Kea, Hawaii. But it has some wind problem in winter, where stronger wind speeds, over 20m/sec, occur frequently even though the sky is clear. To find calmer sites, we have conducted numerical simulations for the Ali area using the Japan Meteorological Agency NonHydrostatic Model. We have found another site, named ZoZo Hill, near Gar. We will continue to monitor the Gar site to clarify weather characteristics over the whole year and hopefully start to negotiate for site monitoring at ZoZo Hill this year.

• 한국건설관리학회논문집
• /
• 제15권2호
• /
• pp.23-32
• /
• 2014

한옥에 대한 관심이 급증을 하고 있는 가운데, 가격경쟁력을 갖춘 신한옥이 개발되고 있다. 이러한 신한옥 개발에 있어서, 공법의 개발은 필수적이다. 이에, 본고에서는 신한옥의 개발과정 중 실제 건설된 전통한옥 1채와 신한옥 2채의 사례를 중심으로 신공법 사례 소개와 각 한옥의 부위별 공법을 비교하였다. 또한, 부위별 공법별로 공사비 및 공기의 영향도를 분석하였다. 그 결과, 전통한옥 대비 신한옥의 공사비는 모든 부위에서 저감되었으며, 공기는 대부분의 부위에서 단축되었다. 두 신한옥 사례의 분석 결과, 목재 구조체와 지붕의 공사비 및 공기 비율이 가장 높았으며, 다음으로 벽체, 바닥, 창호, 기초 순으로 나타났다. 효과적인 공사비 저감 및 공기 단축을 위해서는 목재 구조체 및 지붕 부위의 공법개발에 집중해야 한다.

• 한국통신학회논문지
• /
• 제42권3호
• /
• pp.686-697
• /
• 2017

고령자들의 정신적/육체적 건강 유지를 위해 디지털 메디신 (Digitial Medicine)의 일환으로 일상에서의 운동 프로그램을 사용하는 시도가 다양하게 이루어지고 있다. 특히 웨이러블 기기에 부착된 센서를 활용한 운동 처방과 분석 방법은 IoT 기술을 헬스케어 분야에 적용시키는 대표적인 예로 제시된다. 본 연구에서는 현재 수원시 노인정신건강센터에서 운영하는 운동 프로그램에서 기존에 수기로 수집되고 작성되는 데이터 분석의 신뢰성을 개선하고 노인들의 운동 동기를 촉구하고자 스마트밴드와 BLE 스캐너 장치를 활용하여 IoT(Internet of Thing)기반 행동 인터벤션(intervention) 시스템을 구현한다. 실제 운동 처방과 운동 데이터 분석을 통해 행동 인터벤션 시스템을 테스트하여 데이터 수집과 분석의 무결성을 검증하고 시스템의 개발과 적용에 대한 일련의 과정을 제시한다.

• 한국수정란이식학회지
• /
• 제30권3호
• /
• pp.229-237
• /
• 2015

To improve the developmental potential of bovine somatic cell nuclear transfer (SCNT) embryos, this study compared the developmental rates to blastocyst stage in the SCNT embryos using donor fibroblasts treated with 5-azacytidine (5AC) and S-adenosylhomocysteine (SAH) at different concentrations. Their reprogramming efficiency level was investigated with level of telomerase activity. Donor fibroblasts isolated from adult ear skin of a cow were exposed to 5AC and SAH at different concentrations during 2 passages. After nuclear transfer into enucleated recipient oocytes, the cleavage and developmental rates were significantly (p<0.05) decreased in the SCNT embryos using 5AC-treated fibroblasts (5AC-SCNT embryos), compared with those of non-treated control (control-SCNT embryos) and SAH-treated fibroblasts (SAH-SCNT embryos). The developmental rates to blastocyst stage tended to be slightly increased in the SAH-SCNT embryos at each of the concentrations, and especially, the developmental rates in the SCNT embryos using 1.0 mM SAH-treated fibroblasts were significantly (p<0.05) higher than that of control SCNT embryos. The mean numbers of total and ICM cell in blastocysts were also significantly (p<0.05) decreased in the 5AC-SCNT embryos, compared with those of other SCNT blastocysts. Further, the level of telomerase activity was also significantly (p<0.05) decreased in the 5AC-SCNT embryos than those of control and SAH-SCNT embryos. Whereas, a significantly (p<0.05) up-regulated telomerase activity was observed in SAH-SCNT embryos, compare with that of control-SCNT embryos. In conclusion, SCNT embryos using hypomethylated donor cells with SAH, not 5AC, may improve the developmental potential and reprogramming efficiency.

• 농약과학회지
• /
• 제6권3호
• /
• pp.218-223
• /
• 2002

[ $45^{\circ}C$ ]의 25%(v/v) dioxane-수용액(${\mu}=0.1M$) 중에서 살충제, flupyrazofos의 가수분해 반응속도상수를 자외선 분광법으로 측정하였다. 용매효과($|m|{\ll}|{\ell}|$) 및 반응 속도식($k_{obs.}=k_O+k_{H3O}+[H_3O^+]+k_{OH}-Kw/[H_3O^+]$) 그리고 생성물 분석 결과로부터 flupyrazofos는 trigonal-bipyramidal형($d^2sp^3$) 중간체를 경유하여 pH 4.0 이하의 산성 용액에서는 $A_{AC}2$형의 특정 산-촉매 반응, pH 11.0 이상의 알카리성 용액에서는 $B_{AC}2$ 형의 특정 염기-촉매 반응 그리고 PH $5.0{\sim}10.0$ 사이에서는 $B_{AC}2$형의 일반 산 및 염기-촉매반응에 따른 일련의 가수분해 반응 메카니즘을 제안하였다. 또한, 중성 용액 중에서 flupyrazofos는 매우 안정한 ($8.0{\times}10^{-8}sec^{-1}$) 화합물로 반감기는 약 3개월($45^{\circ}C$) 이상이었다.

• 한국위성정보통신학회논문지
• /
• 제9권4호
• /
• pp.127-133
• /
• 2014

본 논문에서는 탑재운영절차서 실행환경을 위한 Lua 인터프리터 기반의 가상머신 설계와 기능 및 성능분석 결과를 나타낸다. 한국항공우주연구원에서 계획 중인 달 탐사 임무를 온보드상에서 자율적으로 운영하기 위해 탑재운영절차서 실행환경의 개발이 요구되어졌다. 탑재운영절차서는 위성에 탑재되어 지상 간섭없이 자율적으로 임무 수행을 가능케 함으로써 전파 지연과 제한된 데이터 통신용량을 갖는 심우주 임무들에서 이미 적용되고 있다. 가상머신의 실행엔진인 인터프리터는 고급언어로 작성된 원시코드를 한줄씩 번역하고 실행하므로 컴파일러에 의해 생성된 코드가 실행되는 것에 비해서 실행 속도가 현저하게 느리다. 이를 극복하기위해 레지스터 기반의 Lua 인터프리터를 적용하여 탑재운영절차서 실행환경 설계 및 구현하였으며 실험을 통해 여러 요소들에 따른 성능분석을 수행하였다. 성능분석 결과는 탑재운영절차서 스케줄링 방안 뿐 아니라 Lua 인터프리터를 적용하는 시스템에 적용될 수 있을 것으로 기대된다.