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Optimization of ZnO-based transparent conducting oxides for thin-film solar cells based on the correlations of structural, electrical, and optical properties (ZnO 박막의 구조적, 전기적, 광학적 특성간의 상관관계를 고려한 박막태양전지용 투명전극 최적화 연구)

  • Oh, Joon-Ho;Kim, Kyoung-Kook;Song, Jun-Hyuk;Seong, Tae-Yeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.42.2-42.2
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    • 2010
  • Transparent conducting oxides (TCOs) are of significant importance for their applications in various devices, such as light-emitting diodes, thin-film solar cells, organic light-emitting diodes, liquid crystal displays, and so on. In order for TCOs to contribute to the performance improvement of these devices, TCOs should have high transmittance and good electrical properties simultaneously. Sn-doped $In_2O_3$ (ITO) is the most commonly used TCO. However, indium is toxic and scarce in nature. Thus, ZnO has attracted a lot of attention because of the possibility for replacing ITO. In particular, group III impurity-doped ZnO showed the optoelectronic properties comparable to those of ITO electrodes. Al-doped ZnO exhibited the best performance among various doped ZnO films because of the high substitutional doping efficiency. However, in order for the Al-doped ZnO to replace ITO in electronic devices, their electrical and optical properties should further significantly be improved. In this connection, different ways such as a variation of deposition conditions, different deposition techniques, and post-deposition annealing processes have been investigated so far. Among the deposition methods, RF magnetron sputtering has been extensively used because of the easiness in controlling deposition parameters and its fast deposition rate. In addition, when combined with post-deposition annealing in a reducing ambient, the optoelectronic properties of Al-doped ZnO films were found to be further improved. In this presentation, we deposited Al-doped ZnO (ZnO:$Al_2O_3$ = 98:2 wt%) thin films on the glass and sapphire substrates using RF magnetron sputtering as a function of substrate temperature. In addition, the ZnO samples were annealed in different conditions, e.g., rapid thermal annealing (RTA) at $900^{\circ}C$ in $N_2$ ambient for 1 min, tube-furnace annealing at $500^{\circ}C$ in $N_2:H_2$=9:1 gas flow for 1 hour, or RTA combined with tube-furnace annealing. It is found that the mobilities and carrier concentrations of the samples are dependent on growth temperature followed by one of three subsequent post-deposition annealing conditions.

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Fabrication of $TiO_2$ Electrode Containing Scattering Particles in Dye-Sensitized Solar Cells (산란 입자를 포함하는 염료감응 태양전지용 $TiO_2$ 전극 제조)

  • Lee, Jin-Hyoung;Lee, Tae-Kun;Kim, Cheol-Jin
    • Journal of the Microelectronics and Packaging Society
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    • v.18 no.2
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    • pp.57-62
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    • 2011
  • The energy conversion efficiency of DSSCs (Dye-Sensitized Solar Cells) is dependent on the powder size, the structure, and the morphology of $TiO_2$ electrode. The higher efficiency is obtained with high surface area of the nanoanatase-$TiO_2$ powder adsorbed onto a lot more of the dye. Also, the enhancement of light scattering increases the efficiency with high adsorption of the dye. Powder size, crystalline phase, and shape of $TiO_2$ obtained by hydrothermal method have 15-20 nm, anatase and round. $TiO_2$ electrode has fabricated with the mixture of scattering $TiO_2$ particle with 0.4 ${\mu}m$ in nano-sized powder. Conversion efficiency of series of DSSCs was measured with volume fraction of scattering particle. Photovoltaic characteristics of DSSCs with 10% scattering particles are 3.51 mA for Jsc (short circuit current), 0.79 V for Voc(open circuit potential), filling factor 0.619 and 6.86% for efficiency. Jsc was improved by 11% and enhancement of efficiency by 0.77% compared with that of no scattering particles. The confinement of inserted light by light scattering particles has more increase of the injection of exiton(electron-hole pair) and decrease of moving path in electron. Efficiencies of DSSCs with more than 10% for scattering particles have reduced with increasing the pore in the $TiO_2$ electrode.

Study on Anisotropy of Completely Weathered Mudstone under Ko Normally Consolidation (Ko 정규압밀 이암풍화토의 이방성에 관한 연구)

  • Kim, Young-Su;Kim, Byung-Tak;Kim, Jong-Seung;Park, Myung-Lyul
    • Journal of the Korean GEO-environmental Society
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    • v.1 no.1
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    • pp.5-12
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    • 2000
  • Mudstone, found Du-Ho Dong and around there in Po-Hang, is used as construction material. When it is exposed to the air and contacts with water, the strength is decreased rapidly and then it causes a lot of problems. In the field, clay soils with $K_o$ condition have anisotropic characteristics which behave differently according to the change of principal stress direction. In this study, $K_o$ consolidation is performed to make the completely weathered mudstone under the same conditions of construction place. Then, the triaxial compression test is performed at different shear velocity and anisotropy by sampling degree and the stress - strain behavior is shown the strain softening behavior. The stress - strain relationship from triaxial compression test is compared with the prediction value of Cam-clay model. From the results of tests, $K_o$ value decreases with the increase of sampling degree. Generally the behavior of $K_o$ consolidated specimen shows work-softening characteristic. The trend of behaviour of the measured is nearly to same to the predicted by Cam-clay model. But the measured value of deviator stress is very higher than the predicted. Therefore, Cam-clay model was not appropriate to the completely weathered mudstone consolidated with $K_o$ condition in Pohang region.

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Quantitative Evaluation of Free CaO in Electric Arc Furnace Reduction Slag using the Ethylene Glycol Method (에틸렌 글리콜법을 이용한 전기로 환원슬래그의 Free CaO 정량 평가에 관한 연구)

  • Kwon, Seung-Jun;Lim, Hee-Seob;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.4
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    • pp.321-327
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    • 2018
  • Blast furnace slag has been actively used as a substitute for cement in the construction field with high value-added through resource recycling research. However, most of the slag cannot find a clear recycling purpose. This is because some slags contain unstable materials and are used for road-use asphalt and embankment, which are low value-added materials. Electric arc furnace reduction slag(ERS) has been reported to contain a large amount of unstable free CaO due to deoxidation and component adjustment. In this study, free CaO of ERS which is generated in Korean steelmakers is quantitatively evaluated by using ethylene glycol method. As a result of free CaO quantitative evaluation of ERS, it was confirmed that there is a big difference according to the location of each field. In addition, ERS generally existed in powder form as undifferentiated characteristics, but it was confirmed that free CaO content was different due to hydration product in aggregate form due to water treatment. In addition, free CaO is an amorphous material and its crystallization characteristics are different due to the influence of temperature when it is cooled. ERS requires a long-term aging period as it contains a lot of free CaO.

A Study on the Propagation Path Considering the Horizontal Alignment of Road (도로의 평면선형을 고려한 전파경로 분석)

  • Kim, Song-Min
    • 전자공학회논문지 IE
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    • v.44 no.1
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    • pp.27-32
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    • 2007
  • This study was to suggest the predictive model of propagation, considering the effect by the multipath waves produced by the sending and receiving vehicles' left/right reflectors and the adjacent vehicles when the communication between the vehicles on the one-way two-lanes road in the urban city with a lot of traffic jams. Then, the radius of curved road was 600[m], the length of curved roads $52.4\sim471.2[m]$, and the bridge's pier of road was $5o\sim45o$. Also, it was simulated by changing the receiving vehicle located on the curved road's gap from minimum 3.3[m] to maximum 29.5[m], corresponding to the change of distance of the bridge's pier of road and curved road. As a result of this research above, in case of $5o\sim15o$ bridge's pier of road, it was within l[dB] regardless of the receiving vehicle's position on the curved road in case of propagation path loss. In case of $15o\sim45o$, it was approximately $1\sim8[dB]$ as the bridge's pier of road is changed. And, in case of propagation path, it found out that it was changed to $0.4\sim120[m]$ according to the change of bridge's pier of road. Then, the delay time of propagation was 400[nsec] as it produced 120[m] in the difference of propagation path.

Research on the Necessity of Building the Second Space Rocket Launching Sites for Breakthrough Development of R.O.K National Space Power (도약적 국가 우주력 발전을 선도할 제2 우주센터 구축 필요성 연구)

  • Park, Ki-tae
    • Journal of Space Technology and Applications
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    • v.2 no.2
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    • pp.146-168
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    • 2022
  • Witnessing current military conflicts in South China Sea and Eastern Europe, most defense analysts evaluate one of the most serious security threat toward the US is coming from the superpower competitions with Russia and China. The main means for such super power hegemonic competitions is military power and space power is a key enabler to maximize the efficiency and effectiveness of military employment. Reflecting above circumstances, the space hegemonic competition between the Unites States and China is spreading into all aspects of national powers. Under such an environment, R.O.K needs to significantly develop national space power to preserve life and assets of people in space. On the other hand, the R.O.K has a lot of limitations in launching space assets into orbits by land-based space rockets due to its geographic locations. The limitation of rocket launching direction, the failure to secure a significant area enough to secure safety and the limitation to secure open area enough to build associated facilities are among them. On this paper, I will suggest the need to build the 2nd space rocket launching site after analyzing a lot of short-falls the current 'Naro' space center face, compared to those of advanced space powers around the world.

A Study on the Stress Ratio effect of Metal Matrix Composites on Fatigue Crack Growth Behavior (금속기복합재료의 피로균열성장거동에 대한 응력비 영향에 관한 연구)

  • Choi, Yong-Bum;Huh, Sun-Chul;Yoon, Han-Ki;Park, Won-Jo
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2002.05a
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    • pp.155-160
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    • 2002
  • Metal matrix composites had generated a lot of interest in recent times because of significant in specific properties. It was also highlighted as the materials of frontier industry because strength, heat-resistant, corrosion-resistant, wear-resistant were superiored. In this study the strength properties of $Al_{18}B_4O_{33}/AC4CH$ were represented mixing the binder of $Al_2O_3$ and $TiO_2$. It was also fabricated by squeeze casting. $Al_{18}B_4O_{33}/AC4CH$ was fabricated at the melt temperature of $760^{\circ}C$ the perform temperature of $700^{\circ}C$ and mold temperature of $200^{\circ}C$ under the pressure of 83.4MPa and observed SEM. Fatigue crack growth rate tests on compact tension specimen(half-size) of thickness 12.5mm were conducted by using sinusoidal waveform. Compact tension specimens(half-size) were used and fatigue crack growth rate da/dN and stress intensity factor range ${\Delta}K$ were analyzed concerning to the R value of 0.1 and 0.05. In order to find out the value of ${\Delta}K$, load amplitude constant method was applied by the standard fatigue testing method describes in ASTM E647-95a. As the results of this study, Fatigue crack growth rate increased with in creasing the load ratio, Consequently, At equivalent stress intensity factors, the fatigue crack growth rates in MMC were faster than those of AC4CH alloy. then the fatigue life and the fatigue crack growth rate was investigated using scanning election microscopy(SEM)

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The Study on the Surface Reaction of $SrBi_{2}Ta_{2}O_{9}$ Film by Magnetically Enhanced Inductively Coupled Plasma (MEICP 식각에 의한 SBT 박막의 표면 반응 연구)

  • Kim, Dong-Pyo;Kim, Chang-Il
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.4
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    • pp.1-6
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    • 2000
  • Recently, SrBi$_{2}$Ta$_{2}$ $O_{9}$(SBT) and Pb(Zr,Ti) $O_{3}$(PZT) were much attracted as materials of capacitor for ferroelectric random access memory(FRAM) with higher read/ write speed, lower power consumption and nonvolartility. SBT thin film has appeared as the most prominent fatigue free and low operation voltage. To highly integrate FRAM, SBT thin film has to be etched. A lot of papers have been reported over growth of SBT thin film and its characteristics. However, there are few reports about etching SBT thin film owing to difficult of etching ferroelectric materials. SBT thin film was etched in CF$_{4}$Ar plasma using magnetically enhanced inductively coupled plasma (MEICP) system. In order to investigate the chemical reaction on the etched surface of SBT thin films, X-ray Photoelecton spectrosocpy (XPS) and Secondary ion mass spectroscopy(SIMS) was performed.

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The Effects of Elvan on Physical Properties of Cement Mortar (시멘트 모르타르의 물리적 특성에 미치는 맥반석 골재의 영향)

  • Chu, Yong-Sik;Kim, In-Seop;Lee, Jong-Kyu
    • Journal of the Korea Concrete Institute
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    • v.15 no.3
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    • pp.386-391
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    • 2003
  • Ready mixed mortar has been originated from lime industry of Germany and is being used widely in the world at present. In recent years, the studies of mortar with new faculty have been progressed. In this study, we used elvan instead of using sand in order to make cement mortar and investigated characteristics of elvan and mortar that used elvan. The major compositions of elvan were $SiO_2$ and $Al_2O_3$. The crystal phases of elvan were composed of quartz and sillimanite. Elvan had a lot of pore and absorption ratio was 2.09%. The compressive strength of mortar that used elvan satisfied korean industrial standards under 1:3 (mixing ratio) and water retentivity increased according to increase of elvan contents. Far infrared radiation and deodorization ratio increased and thermal conductivity decreased according to increase of elvan contents.

Line-shape analysis of the Raman-spectrum from B1g bond buckling phonon in Bi2Sr2CaCu2O8+x

  • Jeong, J.;Oh, D.;Song, D.;Eisaki, H.;Kim, C.;Park, S.R.
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.4
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    • pp.9-12
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    • 2019
  • We performed Raman spectroscopy on two different over-doped Bi2Sr2CaCu2O8+x (BSCCO), of which superconducting transition temperatures are 89 K and 77 K. Line-shape analysis of the Raman-spectrum was done, focused on B1g bond buckling mode which have drawn a lot of attention, since photoemission studies showed an evidence for strong coupling between the mode and electron. The line-shapes show asymmetry and are well fitted by the Fano line-shape formula. Remarkably, we found that the peak line-widths from B1g bond buckling mode in BSCCO show much broader than those in YBa2Cu3O7-x. The broad line width can be attributed to the superstructure modulation of BSCCO. Our results imply that B1g bond buckling mode may have close relation to the origin of superconductivity or to boosting the superconducting transition temperature in BSCCO.